Technical Papers
Feb 16, 2024

Green Fabrication of Superhydrophobic Zeolite Coating on Cement-Based Material Surfaces to Improve Water-Resistant and Anticorrosion Properties

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 5

Abstract

Constructing a superhydrophobic coating on cement-based materials’ surface can effectively inhibit the invasion of external water and corrosive ions. However, current strategies of fabricating superhydrophobic coatings often require complex processes and some harmful solvents. Herein, an eco-friendly method is proposed for constructing superhydrophobic coatings on mortar surfaces to inhibit water penetration and chloride ion corrosion. The superhydrophobic coating was fabricated using superhydrophobic zeolite powders modified with nontoxic stearic acid. The mortar with superhydrophobic coating (SHC-mortar) possesses a water contact angle of 156° and water slide angle of less than 10°. In addition, the self-cleaning, waterproof and anticorrosion properties of SHC-mortar were explored. The results show that the fabricated superhydrophobic coating endows the mortar with a self-cleaning property, significantly reduces the capillary water absorption of the mortar, and improves the anticorrosion property of the mortar.

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Data Availability Statement

Some or all date, or models that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

This work was supported by the Taishan Scholar Project of Shandong Province (No. TSHW20130956).

References

Al-Oweini, R., and H. El-Rassy. 2009. “Synthesis and characterization by FTIR spectroscopy of silica aerogels prepared using several Si(OR)4 and RSi(OR)3 precursors.” J. Mol. Struct. 919 (1–3): 140–145. https://doi.org/10.1016/j.molstruc.2008.08.025.
Arabzadeh, A., H. Ceylan, S. Kim, K. Gopalakrishnan, A. Sassani, S. Sundararajan, and P. C. Taylor. 2017. “Superhydrophobic coatings on Portland cement concrete surfaces.” Constr. Build. Mater. 141 (Jun): 393–401. https://doi.org/10.1016/j.conbuildmat.2017.03.012.
Blanco Varela, M. T., S. Martinez Ramirez, I. Erena, M. Gener, and P. Carmona. 2006. “Characterization and pozzolanicity of zeolitic rocks from two Cuban deposits.” Appl. Clay Sci. 33 (2): 149–159. https://doi.org/10.1016/j.clay.2006.04.006.
Chinese Standard. 2002. Chemical reagent—Ethanol. GB/T 678-2002. Beijing: General Administration of Quality Inspection and Quarantine of the People’s Republic of China.
Chinese Standard. 2007. Common Portland cement. GB175-2007. Beijing: General Administration of Quality Inspection and Quarantine of the People’s Republic of China.
Chinese Standard. 2013. Industrial stearic acids. GB/T 9103-2013. Beijing: General Administration of Quality Inspection and Quarantine of the People’s Republic of China.
Chinese Standard. 2018. Natural zeolite powder used in concrete and mortar. JG/T566-2018. Beijing: Ministry of Housing and Urban-Rural Development, People’s Republic of China.
Erramilli, S., and J. Genzer. 2019. “Influence of surface topography attributes on settlement and adhesion of natural and synthetic species.” Soft Matter 15 (20): 4045–4067. https://doi.org/10.1039/C9SM00527G.
Esposito Corcione, C., R. Striani, C. Capone, M. Molfetta, S. Vendetta, and M. Frigione. 2018. “Preliminary study of the application of a novel hydrophobic photo-polymerizable nano-structured coating on concrete substrates.” Prog. Org. Coat. 121 (Aug): 182–189. https://doi.org/10.1016/j.porgcoat.2018.04.024.
Feng, Z., F. Wang, T. Xie, J. Ou, M. Xue, and W. Li. 2019. “Integral hydrophobic concrete without using silane.” Constr. Build. Mater. 227 (Dec): 116678. https://doi.org/10.1016/j.conbuildmat.2019.116678.
Flores-Vivian, I., V. Hejazi, M. I. Kozhukhova, M. Nosonovsky, and K. Sobolev. 2013. “Self-assembling particle-siloxane coatings for superhydrophobic concrete.” ACS Appl. Mater. Interfaces 5 (24): 13284–13294. https://doi.org/10.1021/am404272v.
Horgnies, M., and J. J. Chen. 2014. “Superhydrophobic concrete surfaces with integrated microtexture.” Cem. Concr. Compos. 52 (Sep): 81–90. https://doi.org/10.1016/j.cemconcomp.2014.05.010.
Husni, H., M. R. Nazari, H. M. Yee, R. Rohim, A. Yusuff, M. A. Mohd Ariff, N. N. R. Ahmad, C. P. Leo, and M. U. M. Junaidi. 2017. “Superhydrophobic rice husk ash coating on concrete.” Constr. Build. Mater. 144 (Jul): 385–391. https://doi.org/10.1016/j.conbuildmat.2017.03.078.
ISO. 2002. Hygrothermal performance of building materials and products—Determination of water absorption coefficient by partial immersion. ISO 15148-2002. Geneva: ISO.
Kocak, Y., E. Tasci, and U. Kaya. 2013. “The effect of using natural zeolite on the properties and hydration characteristics of blended cements.” Constr. Build. Mater. 47 (Oct): 720–727. https://doi.org/10.1016/j.conbuildmat.2013.05.033.
Liang, T., B. Wang, Z. Fan, and Q. Liu. 2021. “A facile fabrication of superhydrophobic and superoleophilic adsorption material 5A zeolite for oil–water separation with potential use in floating oil.” Open Phys. 19 (1): 486–493. https://doi.org/10.1515/phys-2021-0050.
Liu, B., J. Shi, M. Sun, Z. He, H. Xu, and J. Tan. 2020. “Mechanical and permeability properties of polymer-modified concrete using hydrophobic agent.” J. Build. Eng. 31 (Sep): 101337. https://doi.org/10.1016/j.jobe.2020.101337.
Liu, P., Y. Gao, F. Wang, J. Yang, X. Yu, W. Zhang, and L. Yang. 2017. “Superhydrophobic and self-cleaning behavior of Portland cement with lotus-leaf-like microstructure.” J. Cleaner Prod. 156 (Jul): 775–785. https://doi.org/10.1016/j.jclepro.2017.03.211.
Liu, W., Z. Xie, X. Yang, Y. Wu, C. Jia, T. Bo, and L. Wang. 2011. “Surface modification mechanism of stearic acid to zirconia powders induced by ball milling for water-based injection molding.” J. Am. Ceram. Soc. 94 (5): 1327–1330. https://doi.org/10.1111/j.1551-2916.2011.04475.x.
Muzenski, S., I. Flores-Vivian, and K. Sobolev. 2015. “Durability of superhydrophobic engineered cementitious composites.” Constr. Build. Mater. 81 (Apr): 291–297. https://doi.org/10.1016/j.conbuildmat.2015.02.014.
Qu, Z. Y., and Q. L. Yu. 2018. “Synthesizing super-hydrophobic ground granulated blast furnace slag to enhance the transport property of lightweight aggregate concrete.” Constr. Build. Mater. 191 (Dec): 176–186. https://doi.org/10.1016/j.conbuildmat.2018.10.018.
Ramesh, B. A., and B. Kondraivendhan. 2020. “Effect of accelerated carbonation on the performance of concrete containing natural zeolite.” J. Mater. Civ. Eng. 32 (4): 04020037. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003050.
Sáez del Bosque, I. F., S. Martínez-Ramírez, and M. T. Blanco-Varela. 2014. “FTIR study of the effect of temperature and nanosilica on the nano structure of C–S–H gel formed by hydrating tricalcium silicate.” Constr. Build. Mater. 52 (Feb): 314–323. https://doi.org/10.1016/j.conbuildmat.2013.10.056.
She, W., X. Wang, C. Miao, Q. Zhang, Y. Zhang, J. Yang, and J. Hong. 2018. “Biomimetic superhydrophobic surface of concrete: Topographic and chemical modification assembly by direct spray.” Constr. Build. Mater. 181 (Aug): 347–357. https://doi.org/10.1016/j.conbuildmat.2018.06.063.
She, W., J. Yang, J. Hong, D. Sun, S. Mu, and C. Miao. 2020. “Superhydrophobic concrete with enhanced mechanical robustness: Nanohybrid composites, strengthen mechanism and durability evaluation.” Constr. Build. Mater. 247 (Jun): 118563. https://doi.org/10.1016/j.conbuildmat.2020.118563.
Song, J., Y. Li, W. Xu, H. Liu, and Y. Lu. 2019. “Inexpensive and non-fluorinated superhydrophobic concrete coating for anti-icing and anti-corrosion.” J. Colloid Interface Sci. 541 (Apr): 86–92. https://doi.org/10.1016/j.jcis.2019.01.014.
Song, J., D. Zhao, Z. Han, W. Xu, Y. Lu, X. Liu, B. Liu, C. J. Carmalt, X. Deng, and I. P. Parkin. 2017. “Super-robust superhydrophobic concrete.” J. Mater. Chem. A 5 (28): 14542–14550. https://doi.org/10.1039/C7TA03526H.
Valipour, M., M. Shekarchi, and M. Arezoumandi. 2017. “Chlorine diffusion resistivity of sustainable green concrete in harsh marine environments.” J. Cleaner Prod. 142 (Jan): 4092–4100. https://doi.org/10.1016/j.jclepro.2016.10.015.
Wang, N., Q. Wang, and S. Xu. 2021a. “A review on applications of superhydrophobic materials in civil engineering.” Adv. Eng. Mater. 24 (6): 2101238. https://doi.org/10.1002/adem.202101238.
Wang, N., Q. Wang, S. Xu, and L. Lei. 2021b. “Fabrication of hierarchical structures on concrete surfaces with superhydrophobicity using replicated micro-nano dendritic structures.” J. Ind. Eng. Chem. 103 (Nov): 314–321. https://doi.org/10.1016/j.jiec.2021.07.047.
Wang, Q., S. Xu, X. Xing, and N. Wang. 2022. “Progress in fabrication and applications of micro/nanostructured superhydrophobic surfaces.” Surf. Innov. 10 (2): 89–110. https://doi.org/10.1680/jsuin.21.00031.
Wang, W., S. Wang, D. Yao, X. Wang, X. Yu, and Y. Zhang. 2020. “Fabrication of all-dimensional superhydrophobic mortar with enhanced waterproof ability and freeze-thaw resistance.” Constr. Build. Mater. 238 (Mar): 117626. https://doi.org/10.1016/j.conbuildmat.2019.117626.
Wong, H. S., R. Barakat, A. Alhilali, M. Saleh, and C. R. Cheeseman. 2015. “Hydrophobic concrete using waste paper sludge ash.” Cem. Concr. Res 70 (Apr): 9–20. https://doi.org/10.1016/j.cemconres.2015.01.005.
Xiang, T., J. Liu, Z. Lv, F. Wei, Q. Liu, Y. Zhang, H. Ren, S. Zhou, and D. Chen. 2021. “The effect of silicon-based waterproof agent on the wettability of superhydrophobic concrete and enhanced corrosion resistance.” Constr. Build. Mater. 313 (Dec): 125482. https://doi.org/10.1016/j.conbuildmat.2021.125482.
Xiong, J., D. K. Sarkar, and X. G. Chen. 2017. “Superhydrophobic honeycomb-like cobalt stearate thin films on aluminum with excellent anti-corrosion properties.” Appl. Surf. Sci. 407 (Jun): 361–370. https://doi.org/10.1016/j.apsusc.2017.02.203.
Xu, S., Q. Wang, and N. Wang. 2020. “Chemical fabrication strategies for achieving bioinspired superhydrophobic surfaces with micro and nanostructures: A review.” Adv. Eng. Mater. 23 (3): 2001083. https://doi.org/10.1002/adem.202001083.
Xu, S., Q. Wang, N. Wang, Q. Song, and Y. Li. 2022. “Effects of natural zeolite replacement on the properties of superhydrophobic mortar.” Constr. Build. Mater. 348 (Sep): 128567. https://doi.org/10.1016/j.conbuildmat.2022.128567.
Xu, S., Q. Wang, N. Wang, and X. Zheng. 2019. “Fabrication of superhydrophobic green surfaces with good self-cleaning, chemical stability and anti-corrosion properties.” J. Mater. Sci. 54 (19): 13006–13016. https://doi.org/10.1007/s10853-019-03789-x.
Xue, X., Y. Li, Z. Yang, Z. He, J.-G. Dai, L. Xu, and W. Zhang. 2017. “A systematic investigation of the waterproofing performance and chloride resistance of a self-developed waterborne silane-based hydrophobic agent for mortar and concrete.” Constr. Build. Mater. 155 (Nov): 939–946. https://doi.org/10.1016/j.conbuildmat.2017.08.042.
Yang, H., W. Li, X. Liu, A. Liu, P. Hang, R. Ding, T. Li, Y. Zhang, W. Wang, and C. Xiong. 2019. “Preparation of corrosion inhibitor loaded zeolites and corrosion resistance of carbon steel in simulated concrete pore solution.” Constr. Build. Mater. 225 (Nov): 90–98. https://doi.org/10.1016/j.conbuildmat.2019.07.141.
Yao, H., Z. Xie, C. Huang, Q. Yuan, and Z. Yu. 2021. “Recent progress of hydrophobic cement-based materials: Preparation, characterization and properties.” Constr. Build. Mater. 299 (Sep): 124255. https://doi.org/10.1016/j.conbuildmat.2021.124255.
Yin, B., T. Xu, D. Hou, E. Zhao, X. Hua, K. Han, Y. Zhang, and J. Zhang. 2020. “Superhydrophobic anticorrosive coating for concrete through in-situ bionic induction and gradient mineralization.” Constr. Build. Mater. 257 (Oct): 119510. https://doi.org/10.1016/j.conbuildmat.2020.119510.
Yu, T., Y. Zhao, P. Zheng, L. Wang, Z. Yan, D. Ge, and L. Yang. 2021. “Ultra-durable superhydrophobic surfaces from 3D self-similar network via co-spraying of polymer microspheres and nanoparticles.” Chem. Eng. J. 410 (Apr): 128314. https://doi.org/10.1016/j.cej.2020.128314.
Zhou, Z., S. Li, J. Cao, X. Chen, Z. Wu, and P. Zhou. 2021. “The waterproofing effect and mechanism of graphene oxide/silane composite emulsion on cement-based materials under compressive stress.” Constr. Build. Mater. 308 (Nov): 124945. https://doi.org/10.1016/j.conbuildmat.2021.124945.
Zhu, H., J. Liang, J. Xu, M. Bo, J. Li, and B. Tang. 2018. “Research on anti-chloride ion penetration property of crumb rubber concrete at different ambient temperatures.” Constr. Build. Mater. 189 (Nov): 42–53. https://doi.org/10.1016/j.conbuildmat.2018.08.193.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 5May 2024

History

Received: Jan 10, 2023
Accepted: Oct 5, 2023
Published online: Feb 16, 2024
Published in print: May 1, 2024
Discussion open until: Jul 16, 2024

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Shuangshuang Xu, Ph.D. [email protected]
College of Civil Engineering, Ludong Univ., Shandong 264025, China. Email: [email protected]
Professor, College of Mechanical and Architectural Engineering, Taishan Univ., Shandong 271000, China (corresponding author). ORCID: https://orcid.org/0000-0001-7228-6472. Email: [email protected]
Xiaoya Zhuo [email protected]
Master’s Student, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Ning Wang, Ph.D. [email protected]
College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]

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