Abstract

This study investigated the compatibility of waste plastic, a serious environmental and recycling concern, with styrene-butadiene-styrene (SBS) in asphalt binders. An extensive storage stability analysis of binders modified with varying dosages of low-density polyethylene (LDPE) from postcommercial usage with SBS as a compatibilizer and the understanding of behaviors of each component was conducted in this study. Although SBS-LDPE blends were stable with separation index in terms of G*/sinδ, percent recovery from multiple stress creep recovery (MSCR) detected nonhomogeneity of polymer dispersion in the asphalt blend. To address this nonhomogeneity, waste cooking oil was used to pretreat LDPE to enhance the dispersion and reaction with the binder. Ultimately, 4.5% SBS + 1.5% oil-treated LDPE (TLDPE) was observed to yield a stable SBS-TLDPE blend with a top-bottom separation index ratio of 1.0 in terms of G*/sinδ and percent recovery difference of 3.5% and 1.4% at 0.1 and 3.2 kPa, respectively. The study identified that the presence of LDPE negatively influences the recovery and cracking performance of asphalt binders at low temperatures. From critical temperature differential (ΔTc), Glover-Rowe (G-R) parameter and Black space diagrams at different aging levels, it was concluded that unlike SBS, SBS + LDPE combination had resistance against extended long-term aging.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

This study was conducted for the US Army Corps of Engineers under PE0603119A, “Rapid Entry and Sustainment for the Arctic.” The work was performed by the Engineering Resources Branch (ERB) of the Research and Engineering Division, US Army Engineer Research and Development Center (ERDC), and Cold Regions Research and Engineering Laboratory (CRREL). At the time of publication, Dr. Melisa Nallar was acting branch chief; and Dr. Caitlin A. Callaghan was division chief. The acting deputy director of ERDC-CRREL was Mr. Bryan E. Baker, and the director was Dr. Joseph L. Corriveau. This work was also performed by the Airfields and Pavements Branch of the Engineering Systems and Materials Division, ERDC-Geotechnical and Structures Laboratory (GSL). At the time of publication, Ms. Anna Jordan was branch chief; Mr. Justin S. Strickler was division chief; and Mr. R. Nicholas Boone was the technical director for Force Projection and Maneuver Support. Mr. Charles W. Ertle II was deputy director of ERDC-GSL, and Mr. Bartley P. Durst was the director. colonel (COL) Christian Patterson was the commander of ERDC, and Dr. David W. Pittman was the director. The authors would also like to thank Douglas Congdon from Eagle Plastics, Jeannie Watson from Envision Plastics, and Bob Klutz from Kraton for supplying SBS polymer.
Author contributions: The authors confirm contribution to the paper as follows: study conception and design: Venkatsushanth Revelli, Faisal Kabir; data collection, analysis: Venkatsushanth Revelli; interpretation of results: Venkatsushanth Revelli; draft manuscript preparation: Venkatsushanth Revelli, Faisal Kabir, Ayman Ali, Ben Cox, Mohamed Elshaer and Yusuf Mehta. All authors reviewed the results and approved the final version of the manuscript.

References

AASHTO. 2014. Standard method of test for multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR). AASHTO T350. Washington, DC: AASHTO.
AASHTO. 2016. Standard practice for accelerated aging of asphalt binder using a pressurized aging vessel (PAV). AASHTO R 28-12. Washington, DC: AASHTO.
Aboul-Gheit, A. K., F. H. Khalil, and T. Abdel-Moghny. 2006. “Adsorption of spilled oil from seawater by waste plastic.” Oil Gas Sci. Technol. 61 (2): 259–268. https://doi.org/10.2516/ogst:2006019x.
Ahmadinia, E., M. Zargar, M. R. Karim, M. Abdelaziz, and E. Ahmadinia. 2012. “Performance evaluation of utilization of waste polyethylene terephthalate (PET) in stone mastic asphalt.” Constr. Build. Mater. 36 (Nov): 984–989. https://doi.org/10.1016/j.conbuildmat.2012.06.015.
Airey, G. D. 2003. “Rheological properties of styrene butadiene styrene polymer modified road bitumens.” Fuel 82 (14): 1709–1719. https://doi.org/10.1016/S0016-2361(03)00146-7.
Al-Abdul Wahhab, H. I., M. A. Dalhat, and M. A. Habib. 2017. “Storage stability and high-temperature performance of asphalt binder modified with recycled plastic.” Road Mater. Pavement Des. 18 (5): 1117–1134. https://doi.org/10.1080/14680629.2016.1207554.
Arabani, M., and M. Pedram. 2016. “Laboratory investigation of rutting and fatigue in glassphalt containing waste plastic bottles.” Constr. Build. Mater. 116 (Jul): 378–383. https://doi.org/10.1016/j.conbuildmat.2016.04.105.
Asphalt Institute. 2019. Use of the delta Tc parameter to characterize asphalt binder behavior. IS 240. Lexington, KY: Asphalt Institute.
ASTM. 2012. Standard test method for effect of heat and air on a moving film of asphalt (rolling thin-film oven test). ASTM D2872–04. West Conshohocken, PA: ASTM.
ASTM. 2014. Standard practice for determining the separation tendency of polymer from polymer modified asphalt. ASTM D 7173. West Conshohocken, PA: ASTM.
ASTM. 2016. Standard test method for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). ASTM D6648. West Conshohocken, PA: ASTM.
Bala, N., M. Napiah, I. Kamaruddin, and N. Danlami. 2017. “Rheological properties investigation of bitumen modified with nanosilica and polyethylene polymer.” Int. J. Adv. Appl. Sci. 4 (10): 165–174. https://doi.org/10.21833/ijaas.2017.010.023.
Becker, Y., M. P. Méndez, and Y. Rodríguez. 2001. “Polymer modified asphalt.” Vision Tecnologica 9 (1): 39–50.
Bonemazzi, F., V. Braga, R. Corrieri, C. Giavarini, and F. Sartori. 1996. “Characteristics of polymers and polymer-modified binders.” Transp. Res. Rec. 1535 (1): 36–47. https://doi.org/10.1177/0361198196153500106.
Brooks, A. L., S. Wang, and J. R. Jambeck. 2018. “The Chinese import ban and its impact on global plastic waste trade.” Sci. Adv. 4 (6): eaat0131. https://doi.org/10.1126/sciadv.aat0131.
Cox, B. C., J. Easterling, W. G. Sullivan, A. Middleton, and I. L. Howard. 2022. “Data mining statewide department of transportation volumetrically designed asphalt mixture records.” Transp. Res. Rec. 2676 (5): 242–262. https://doi.org/10.1177/03611981211061356.
Du, Z., C. Jiang, J. Yuan, F. Xiao, and J. Wang. 2020. “Low temperature performance characteristics of polyethylene modified asphalts—A review.” Constr. Build. Mater. 264 (Dec): 120704. https://doi.org/10.1016/j.conbuildmat.2020.120704.
Gao, G., Y. Zhang, Y. Zhang, K. Sun, and Y. Fan. 2002. “Improved storage stability of LDPE/SBS blends modified asphalts.” Polym. Polym. Compos. 10 (3): 229–236. https://doi.org/10.1177/096739110201000305.
Ge, D., K. Yan, Z. You, and H. Xu. 2016. “Modification mechanism of asphalt binder with waste tire rubber and recycled polyethylene.” Constr. Build. Mater. 126 (Nov): 66–76. https://doi.org/10.1016/j.conbuildmat.2016.09.014.
Glover, C. J., R. R. Davison, C. H. Domke, Y. Ruan, P. Juristyarini, D. B. Knorr, and S. H. Jung. 2005. Development of a new method for assessing asphalt binder durability with field validation. Rep. 0-1872-2. Austin, TX: Texas Dept. of Transportation.
Goodrich, J. L., J. E. Goodrich, and W. J. Kari. 1986. “Asphalt composition tests: Their application and relation to field performance.” Transp. Res. Rec. 1096: 146–167.
Hong, Z., K. Yan, D. Ge, M. Wang, G. Li, and H. Li. 2022. “Effect of styrene-butadiene-styrene (SBS) on laboratory properties of low-density polyethylene (LDPE)/ethylene-vinyl acetate (EVA) compound modified asphalt.” J. Cleaner Prod. 338 (Mar): 130677. https://doi.org/10.1016/j.jclepro.2022.130677.
Hossain, R., and N. M. Wasiuddin. 2019. “Evaluation of degradation of SBS modified asphalt binder because of RTFO, PAV, and UV aging using a novel extensional deformation test.” Transp. Res. Rec. 2673 (6): 447–457. https://doi.org/10.1177/0361198119847471.
Joohari, I. B., S. Maniam, and F. Giustozzi. 2022. “Enhancing the storage stability of SBS-plastic waste modified using reactive elastomeric terpolymer.” Int. J. Pavement Res. Technol. 16 (Jan): 304–318. https://doi.org/10.1007/s42947-021-00132-z.
Kabir, S. F., S. Sukumaran, S. Moghtadernejad, E. Barjasteh, and E. H. Fini. 2021. “End of life plastics to enhance sustainability of pavement construction utilizing a hybrid treatment of bio-oil and carbon coating.” Constr. Build. Mater. 278 (Apr): 122444. https://doi.org/10.1016/j.conbuildmat.2021.122444.
Kakar, M. R., P. Mikhailenko, Z. Piao, M. Bueno, and L. Poulikakos. 2021. “Analysis of waste polyethylene (PE) and its by-products in asphalt binder.” Constr. Build. Mater. 280 (Apr): 122492. https://doi.org/10.1016/j.conbuildmat.2021.122492.
Kalantar, Z. N., M. R. Karim, and A. Mahrez. 2012. “A review of using waste and virgin polymer in pavement.” Constr. Build. Mater. 33 (Aug): 55–62. https://doi.org/10.1016/j.conbuildmat.2012.01.009.
Kamiya, S., S. Tasaka, X. Zhang, D. Dong, and N. Inagaki. 2001. “Compatibilizer role of styrene-butadiene-styrene triblock copolymer in asphalt.” Polym. J. 33 (3): 209–213. https://doi.org/10.1295/polymj.33.209.
Karmakar, S., D. Majhi, T. K. Roy, and D. Chanda. 2018. “Moisture damage analysis of bituminous mix by durability index utilizing waste plastic cup.” J. Mater. Civ. Eng. 30 (9): 04018216. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002366.
Kaseer, F., A. E. Martin, and E. Arámbula-Mercado. 2021. “Relationship between rheological indices and cracking performance of virgin, recycled, and rejuvenated asphalt binders and mixtures.” Transp. Res. Rec. 2675 (9): 93–109. https://doi.org/10.1177/03611981211007479.
Khakimullin, Y. N., V. I. Kimeľblat, I. G. Chebotareva, E. V. Muruzina, A. V. Murafa, V. G. Khozin, and S. I. Voľfson. 2000. “Properties of bitumens modified by thermoplastic elastomers.” Mech. Compos. Mater. 36 (Sep): 417–422. https://doi.org/10.1023/A:1026659520096.
Khan, T. A., D. K. Sharma, and B. M. Sharma. 2009. “Performance evaluation of waste plastic/polymer modified bituminous concrete mixes.” J. Sci. Ind. Res. 68 (11): 975–979.
Kumar, A., R. Choudhary, and A. Kumar. 2021. “Characterization of thermal storage stability of waste plastic pyrolytic char modified asphalt binders with sulfur.” PLoS One 16 (3): e0248465. https://doi.org/10.1371/journal.pone.0248465.
Leal Filho, W., U. Saari, M. Fedoruk, A. Iital, H. Moora, M. Klöga, and V. Voronova. 2019. “An overview of the problems posed by plastic products and the role of extended producer responsibility in Europe.” J. Cleaner Prod. 214 (Mar): 550–558. https://doi.org/10.1016/j.jclepro.2018.12.256.
Liu, Y., J. Zhang, R. Chen, J. Cai, Z. Xi, and H. Xie. 2017. “Ethylene vinyl acetate copolymer modified epoxy asphalt binders: Phase separation evolution and mechanical properties.” Constr. Build. Mater. 137 (Apr): 55–65. https://doi.org/10.1016/j.conbuildmat.2017.01.081.
Lu, X., and U. Isacsson. 1997. “Compatibility and storage stability of styrene-butadiene-styrene copolymer modified bitumens.” Mater. Struct. 30 (10): 618–626. https://doi.org/10.1007/BF02486904.
Mashaan, N. S., A. Chegenizadeh, H. Nikraz, and A. Rezagholilou. 2021. “Investigating the engineering properties of asphalt binder modified with waste plastic polymer.” Ain Shams Eng. J. 12 (2): 1569–1574. https://doi.org/10.1016/j.asej.2020.08.035.
Polacco, G., S. Berlincioni, D. Biondi, J. Stastna, and L. Zanzotto. 2005. “Asphalt modification with different polyethylene-based polymers.” Eur. Polym. J. 41 (12): 2831–2844. https://doi.org/10.1016/j.eurpolymj.2005.05.034.
Polacco, G., S. Filippi, F. Merusi, and G. Stastna. 2015. “A review of the fundamentals of polymer-modified asphalts: Asphalt/polymer interactions and principles of compatibility.” Adv. Colloid Interface Sci. 224 (Oct): 72–112. https://doi.org/10.1016/j.cis.2015.07.010.
Punith, V. S., and A. Veeraragavan. 2011. “Behavior of reclaimed polyethylene modified asphalt cement for paving purposes.” J. Mater. Civ. Eng. 23 (6): 833–845. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000235.
Singh, B., L. Kumar, M. Gupta, and G. S. Chauhan. 2013. “Polymer-modified bitumen of recycled LDPE and maleated bitumen.” J. Appl. Polym. Sci. 127 (1): 67–78. https://doi.org/10.1002/app.36810.
Teltayev, B. B., C. O. Rossi, G. G. Izmailova, E. D. Amirbayev, and A. O. Elshibayev. 2019. “Evaluating the effect of asphalt binder modification on the low-temperature cracking resistance of hot mix asphalt.” Case Stud. Constr. Mater. 11 (Dec): e00238. https://doi.org/10.1016/j.cscm.2019.e00238.
Wang, T. 2022. “Study and application of compatibility of waste polyethylene-modified asphalt.” J. Mater. Civ. Eng. 34 (9): 04022203. https://doi.org/10.1061/(ASCE)MT.1943-5533.0004315.
Wen, G., and Y. Zhang. 2002. “Improved properties of SBS-modified asphalt with dynamic vulcanization.” Polym. Eng. Sci. 42 (5): 1070–1081. https://doi.org/10.1002/pen.11013.
West, R. C., J. R. Willis, and M. Marasteanu. 2013. Vol. 75 of Improved mix design, evaluation, and materials management practices for hot mix asphalt with high reclaimed asphalt pavement content. Washington, DC: Transportation Research Board.
Willis, R., F. Yin, and R. Moraes. 2020. Recycled plastics in asphalt part A: State of the knowledge. Greenbelt, MD: National Asphalt Pavement Association.
Wu, S., and L. Montalvo. 2021. “Repurposing waste plastics into cleaner asphalt pavement materials: A critical literature review.” J. Cleaner Prod. 280 (Jan): 124355. https://doi.org/10.1016/j.jclepro.2020.124355.
Yousefi, A. A. 2003. “Polyethylene dispersions in bitumen: The effects of the polymer structural parameters.” J. Appl. Polym. Sci. 90 (12): 3183–3190. https://doi.org/10.1002/app.12942.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 11November 2023

History

Received: Dec 27, 2022
Accepted: Apr 14, 2023
Published online: Aug 31, 2023
Published in print: Nov 1, 2023
Discussion open until: Jan 31, 2024

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Graduate Student, Center for Research and Advanced Transportation Systems, Rowan Univ., Glassboro, NJ 08028 (corresponding author). ORCID: https://orcid.org/0000-0001-7272-3134. Email: [email protected]
Sk Faisal Kabir [email protected]
Postdoctoral Research Associate, Center for Research and Advanced Transportation Systems, Rowan Univ., Glassboro, NJ 08028. Email: [email protected]
Associate Director, Center for Research and Advanced Transportation Systems, Rowan Univ., Glassboro, NJ 08028. ORCID: https://orcid.org/0000-0002-7031-4852. Email: [email protected]
Professor, Center for Research and Advanced Transportation Systems, Rowan Univ., Glassboro, NJ 08028. ORCID: https://orcid.org/0000-0001-9430-3827. Email: [email protected]
Research Civil Engineer, Airfields and Pavements Branch, Engineer Research and Development Center, Vicksburg, MS 39180. ORCID: https://orcid.org/0000-0002-4842-6356. Email: [email protected]
Mohamed Elshaer [email protected]
Research Civil Engineer, US Army Corps of Engineers, Engineer Research and Development Center, Hanover, NH 03755. Email: [email protected]

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  • Understanding the Storage Stability of Polyethylene Modified Binders: A Laboratory Case Study Using Waste Plastics, Journal of Materials in Civil Engineering, 10.1061/JMCEE7.MTENG-17334, 36, 4, (2024).

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