Technical Papers
Aug 23, 2023

Effects of Supplementary Cementitious Materials on the Hydration of Ultrahigh-Performance Concrete

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 11

Abstract

With the variety of supplementary cementitious materials (SCMs) available, there have been fundamental questions regarding how they influence the hydration development of ultrahigh-performance concrete (UHPC), especially at early age. To provide a holistic perspective and side-by-side comparisons, the current study explored the partial replacement of cement with silica fume, natural zeolite, and limestone, which represented artificial pozzolans, natural pozzolans, and non-pozzolanic SCMs, respectively. To evaluate the most critical micro- and macro-scale properties of UHPC, the experimental investigations included temperature and free water measurements, further to thermogravimetric analyses (TGA) performed to determine the amount of physically and chemically bound water in the developed mixtures. Moreover, the X-ray diffractometry (XRD) method was employed to obtain the XRD patterns, which were then paired with the TGA results to quantify the crystalline phases of the UHPC mixtures using the Rietveld refinement method. With a detailed assessment of the UHPC’s degree of hydration over time, the outcome of this study shed light on how various SCMs are capable of reducing the heat of hydration, while enhancing the degree of hydration of cement particles.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The research study, results of which reported in this manuscript, was sponsored by the Iowa Department of Transportation and Accelerated Bridge Construction University Transportation Center (ABC-UTC). The authors would like to acknowledge the sponsors for their support. Opinions and conclusions expressed in this manuscript are of the authors and do not necessarily represent those of the sponsors. The authors would like to thank the personnel and staff of the Iowa State University’s Portland Cement Concrete (PCC) Laboratory and Materials Analysis and Research Laboratory (MARL).

References

Abdulkareem, O. M., A. B. Fraj, M. Bouasker, and A. Khelidj. 2018. “Mixture design and early age investigations of more sustainable UHPC.” Constr. Build. Mater. 163 (Feb): 235–246. https://doi.org/10.1016/j.conbuildmat.2017.12.107.
ASTM. 2020a. Standard test method for compressive strength of hydraulic cement mortars. ASTM C109. West Conshohocken, PA: ASTM.
ASTM. 2020b. Standard test method for slump of hydraulic-cement concrete. ASTM C143. West Conshohocken, PA: ASTM.
Bahmani, H., D. Mostofinejad, and S. A. Dadvar. 2022. “Fiber type and curing environment effects on the mechanical performance of UHPFRC containing zeolite.” Iran. J. Sci. Technol. Trans. Civ. Eng. 46 (6): 4151–4167. https://doi.org/10.1007/s40996-022-00911-z.
Black, L., C. Breen, J. Yarwood, J. Phipps, and G. Maitland. 2006. “In situ Raman analysis of hydrating C3A and C4AF pastes in presence and absence of sulphate.” Adv. Appl. Ceram. 105 (4): 209–216. https://doi.org/10.1179/174367606X120179.
Bonavetti, V. L., V. F. Rahhal, and E. F. Irassar. 2001. “Studies on the carboaluminate formation in limestone filler-blended cements.” Cem. Concr. Res. 31 (6): 853–859. https://doi.org/10.1016/S0008-8846(01)00491-4.
Chang, C. F., and J. W. Chen. 2006. “The experimental investigation of concrete carbonation depth.” Cem. Concr. Res. 36 (9): 1760–1767. https://doi.org/10.1016/j.cemconres.2004.07.025.
Environment, U. N., K. L. Scrivener, V. M. John, and E. M. Gartner. 2018. “Eco-efficient cements: Potential economically viable solutions for a low-CO2 cement-based materials industry.” Cem. Concr. Res. 114 (Dec): 2–26. https://doi.org/10.1016/j.cemconres.2018.03.015.
Gallé, C. 2001. “Effect of drying on cement-based materials pore structure as identified by mercury intrusion porosimetry: A comparative study between oven-, vacuum-, and freeze-drying.” Cem. Concr. Res. 31 (10): 1467–1477. https://doi.org/10.1016/S0008-8846(01)00594-4.
Hilal, A. A. 2016. “Microstructure of concrete.” In High performance concrete technology and applications, 3–24. Rijeka, Croati: InTech.
Hossain, M. U., C. S. Poon, Y. H. Dong, and D. Xuan. 2018. “Evaluation of environmental impact distribution methods for supplementary cementitious materials.” Renewable Sustainable Energy Rev. 82 (Feb): 597–608. https://doi.org/10.1016/j.rser.2017.09.048.
Huang, W., H. Kazemi-Kamyab, W. Sun, and K. Scrivener. 2017. “Effect of cement substitution by limestone on the hydration and microstructural development of ultra-high performance concrete (UHPC).” Cem. Concr. Compos. 77 (Mar): 86–101. https://doi.org/10.1016/j.cemconcomp.2016.12.009.
IEA (International Energy Agency). 2009. Cement technology roadmap: Carbon emissions reductions up to 2050. Paris: Organization for Economic Cooperation and Development Publishing.
Juenger, M. C., R. Snellings, and S. A. Bernal. 2019. “Supplementary cementitious materials: New sources, characterization, and performance insights.” Cem. Concr. Res. 122 (Aug): 257–273. https://doi.org/10.1016/j.cemconres.2019.05.008.
Karim, R., M. Najimi, and B. Shafei. 2019. “Assessment of transport properties, volume stability, and frost resistance of non-proprietary ultra-high performance concrete.” Constr. Build. Mater. 227 (Dec): 117031. https://doi.org/10.1016/j.conbuildmat.2019.117031.
Karim, R., and B. Shafei. 2021. “Flexural response characteristics of ultra-high performance concrete made with steel microfibers and macrofibers.” Struct. Concr. 22 (6): 3476–3490.
Karim, R., and B. Shafei. 2022. “Investigation of five synthetic fibers as potential replacements of steel fibers in ultra-high performance concrete.” Mater. Civ. Eng. 34 (7): 04022126.
Kazemian, M., S. Sedighi, A. A. Ramezanianpour, F. Bahman-Zadeh, and A. M. Ramezanianpour. 2021. “Effects of cyclic carbonation and chloride ingress on durability properties of mortars containing Trass and Pumice natural pozzolans.” Struct. Concr. 22 (5): 2704–2719. https://doi.org/10.1002/suco.201900529.
Kazemian, M., and B. Shafei. 2022. “Internal curing capabilities of natural zeolite to improve the hydration of ultra-high performance concrete.” Constr. Build. Mater. 340 (Jul): 127452. https://doi.org/10.1016/j.conbuildmat.2022.127452.
Kazemian, M., and B. Shafei. 2023. “Carbon sequestration and storage in concrete: A state-of-the-art review of compositions, methods, and developments.” J. CO2 Util. 70 (Apr): 102443. https://doi.org/10.1016/j.jcou.2023.102443.
Korpa, A., and R. Trettin. 2006. “The influence of different drying methods on cement paste microstructures as reflected by gas adsorption: Comparison between freeze-drying (F-drying), D-drying, P-drying, and oven-drying methods.” Cem. Concr. Res. 36 (4): 634–649. https://doi.org/10.1016/j.cemconres.2005.11.021.
Lothenbach, B., G. Le Saout, E. Gallucci, and K. Scrivener. 2008. “Influence of limestone on the hydration of portland cements.” Cem. Concr. Res. 38 (6): 848–860. https://doi.org/10.1016/j.cemconres.2008.01.002.
Lv, Y., G. Ye, and G. De Schutter. 2019. “Investigation on the potential utilization of zeolite as an internal curing agent for autogenous shrinkage mitigation and the effect of modification.” Constr. Build. Mater. 198 (Feb): 669–676. https://doi.org/10.1016/j.conbuildmat.2018.12.001.
Malhotra, V. M. 2018. Condensed silica fume in concrete. Boca Raton, FL: CRC Press.
Massazza, F. 1998. “Pozzolana and pozzolanic cements.” Lea’s Chem. Cem. Concr. 4 (Jan): 471–631.
Miller, S. A. 2018. “Supplementary cementitious materials to mitigate greenhouse gas emissions from concrete: Can there be too much of a good thing?” J. Cleaner Prod. 178 (Mar): 587–598. https://doi.org/10.1016/j.jclepro.2018.01.008.
Mo, Z., R. Wang, and X. Gao. 2020. “Hydration and mechanical properties of UHPC matrix containing limestone and different levels of metakaolin.” Constr. Build. Mater. 256 (Sep): 119454. https://doi.org/10.1016/j.conbuildmat.2020.119454.
Monteiro, P. J., S. A. Miller, and A. Horvath. 2017. “Towards sustainable concrete.” Nat. Mater. 16 (7): 698–699. https://doi.org/10.1038/nmat4930.
Oey, T., A. Kumar, J. W. Bullard, N. Neithalath, and G. Sant. 2013. “The filler effect: The influence of filler content and surface area on cementitious reaction rates.” J. Am. Ceram. Soc. 96 (6): 1978–1990. https://doi.org/10.1111/jace.12264.
Paiva, H., A. S. Silva, A. Velosa, P. Cachim, and V. M. Ferreira. 2017. “Microstructure and hardened state properties on pozzolan-containing concrete.” Constr. Build. Mater. 140 (Jun): 374–384. https://doi.org/10.1016/j.conbuildmat.2017.02.120.
Pezeshkian, M., A. Delnavaz, and M. Delnavaz. 2020. “Effect of natural zeolite on mechanical properties and autogenous shrinkage of ultrahigh-performance concrete.” J. Mater. Civ. Eng. 32 (5): 04020093. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002968.
Pezeshkian, M., A. Delnavaz, and M. Delnavaz. 2021. “Development of UHPC mixtures using natural zeolite and glass sand as replacements of silica fume and quartz sand.” Eur. J. Environ. Civ. Eng. 25 (11): 2023–2038. https://doi.org/10.1080/19648189.2019.1610074.
Ramezanianpour, A. A. 2014. “Cement replacement materials.” In Springer Geochemistry/Mineralogy 10: 978. Berlin: Springer.
Rezvani, M., T. Proske, and C. A. Graubner. 2019. “Modelling the drying shrinkage of concrete made with limestone-rich cements.” Cem. Concr. Res. 115 (Jan): 160–175. https://doi.org/10.1016/j.cemconres.2018.09.003.
Schönlein, M., and J. Plank. 2018. “A TEM study on the very early crystallization of CSH in the presence of polycarboxylate superplasticizers: Transformation from initial CSH globules to nanofoils.” Cem. Concr. Res. 106 (Apr): 33–39. https://doi.org/10.1016/j.cemconres.2018.01.017.
Scrivener, K. L., T. Füllmann, E. Gallucci, G. Walenta, and E. Bermejo. 2004. “Quantitative study of portland cement hydration by X-ray diffraction/Rietveld analysis and independent methods.” Cem. Concr. Res. 34 (9): 1541–1547. https://doi.org/10.1016/j.cemconres.2004.04.014.
Sedighi, S., A. A. Ramezanian Pour, M. Kazemian, and A. Ramezanianpour. 2020. “Effect of micro silica and slag on the durability properties of mortars against accelerated carbonation and chloride ions attack.” AUT J. Civ. Eng. 4 (4): 411–422.
Shen, P., L. Lu, F. Wang, Y. He, S. Hu, J. Lu, and H. Zheng. 2020. “Water desorption characteristics of saturated lightweight fine aggregate in ultra-high performance concrete.” Cem. Concr. Compos. 106 (Feb): 103456. https://doi.org/10.1016/j.cemconcomp.2019.103456.
Shi, W., and B. Shafei. 2021. “Bond characteristics between conventional concrete and six high-performance patching materials.” Constr. Build. Mater. 308 (Nov): 124898.
Snellings, R., G. Mertens, Ö. Cizer, and J. Elsen. 2010. “Early age hydration and pozzolanic reaction in natural zeolite blended cements: Reaction kinetics and products by in situ synchrotron X-ray powder diffraction.” Cem. Concr. Res. 40 (12): 1704–1713. https://doi.org/10.1016/j.cemconres.2010.08.012.
Thomas, J. J., H. M. Jennings, and J. J. Chen. 2009. “Influence of nucleation seeding on the hydration mechanisms of tricalcium silicate and cement.” J. Phys. Chem. C 113 (11): 4327–4334. https://doi.org/10.1021/jp809811w.
Tiburzi, N. B., J. Garcia, T. Drimalas, and K. J. Folliard. 2019. “Sulfate resistance of Portland-limestone cement systems containing greater than 15% limestone.” Cem. Concr. Compos. 100 (Jul): 60–73. https://doi.org/10.1016/j.cemconcomp.2019.03.024.
Tydlitát, V., T. Matas, and R. Černý. 2014. “Effect of w/c and temperature on the early-stage hydration heat development in Portland-limestone cement.” Constr. Build. Mater. 50 (Jan): 140–147. https://doi.org/10.1016/j.conbuildmat.2013.09.020.
USGS. 2021. Mineral commodity summaries 2021. Reston, VA: USGS.
Van Tuan, N., G. Ye, K. Van Breugel, and O. Copuroglu. 2011. “Hydration and microstructure of ultra high performance concrete incorporating rice husk ash.” Cem. Concr. Res. 41 (11): 1104–1111. https://doi.org/10.1016/j.cemconres.2011.06.009.
Wang, X. Y. 2018. “Analysis of hydration and strength optimization of cement-fly ash-limestone ternary blended concrete.” Constr. Build. Mater. 166 (Mar): 130–140. https://doi.org/10.1016/j.conbuildmat.2018.01.058.
Yazıcı, H., M. Y. Yardımcı, H. Yiğiter, S. Aydın, and S. Türkel. 2010. “Mechanical properties of reactive powder concrete containing high volumes of ground granulated blast furnace slag.” Cem. Concr. Compos. 32 (8): 639–648. https://doi.org/10.1016/j.cemconcomp.2010.07.005.
Ye, G., X. Liu, G. De Schutter, A. M. Poppe, and L. Taerwe. 2007. “Influence of limestone powder used as filler in SCC on hydration and microstructure of cement pastes.” Cem. Concr. Compos. 29 (2): 94–102. https://doi.org/10.1016/j.cemconcomp.2006.09.003.
Yu, R., P. Spiesz, and H. J. H. Brouwers. 2014. “Effect of nano-silica on the hydration and microstructure development of ultra-high performance concrete (UHPC) with a low binder amount.” Constr. Build. Mater. 65 (Aug): 140–150. https://doi.org/10.1016/j.conbuildmat.2014.04.063.
Zhang, J., and G. W. Scherer. 2011. “Comparison of methods for arresting hydration of cement.” Cem. Concr. Res. 41 (10): 1024–1036. https://doi.org/10.1016/j.cemconres.2011.06.003.
Zhang, M. H., and O. E. Gjørv. 1991. “Effect of silica fume on pore structure and chloride diffusivity of low porosity cement pastes.” Cem. Concr. Res. 21 (6): 1006–1014. https://doi.org/10.1016/0008-8846(91)90060-U.
Zhang, Y., and X. Zhang. 2008. “Research on effect of limestone and gypsum on C3A, C3S and PC clinker system.” Constr. Build. Mater. 22 (8): 1634–1642. https://doi.org/10.1016/j.conbuildmat.2007.06.013.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 11November 2023

History

Received: Dec 17, 2022
Accepted: Mar 28, 2023
Published online: Aug 23, 2023
Published in print: Nov 1, 2023
Discussion open until: Jan 23, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Maziar Kazemian, S.M.ASCE [email protected]
Graduate Research Assistant, Dept. of Civil, Construction, and Environmental Engineering, Iowa State Univ., Ames, IA 50011. Email: [email protected]
Associate Professor, Dept. of Civil, Construction, and Environmental Engineering, and Dept. of Materials Science and Engineering, Iowa State Univ., Ames, IA 50011 (corresponding author). ORCID: https://orcid.org/0000-0001-5677-6324. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share