Technical Papers
Aug 2, 2023

Mechanical Properties of Constructional PMMA at Elevated Temperatures and Postfire Conditions

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 10

Abstract

The application of Polymethylmethacrylate (PMMA) can be traced back decades ago, which is widely utilized in aerospace, submarine, aquarium, detector, and biomedicine, and now is gradually utilized in civil engineering structures such as large space structures and decorative structures. Due to the different processing methods and service conditions, whether the existing research is applicate to constructional PMMA remains to be explored. The fire resistance of PMMA is poor, and the mechanical properties decline sharply with increasing temperature. Additionally, the description of stress–strain curves is the foundation of engineering application for a material. Therefore, a series of mechanical property tests of constructional PMMA under a quasi-static state were carried out herein, investigating the stress–strain curves and hardness at elevated temperatures and postfire conditions. Scanning electron microscopy (SEM) images were utilized for fractographic analysis at elevated temperatures. The effects of different tensile rates, thicknesses, and adhesive joints were explored. The test results indicated that 80°C was a boundary temperature, because the elastic modulus, peak strength, and yield strength decreased slowly below 80°C and sharply over 80°C due to the softening of PMMA. When the temperature reached 80°C, the peak strength dropped to approximately half of that of room temperature, and the ductility of the specimen increased significantly. To promote the application of constructional PMMA and provide guidance for engineers, a material model from 20°C to 100°C, where the buildings often encountered, was proposed. The mechanical properties, especially the stress–strain curves, of constructional PMMA at elevated temperatures and postfire conditions were comprehensively analyzed, and design suggestions were given.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (No. 52278153). The assistance of Jiangsu Donchamp New Materials Technology Co., Ltd. is acknowledged.

References

Alzarrug, F. A., M. D. Marija, M. J. H. Radmila, V. Radojević, D. B. Stojanović, P. S. Uskoković, and R. Aleksić. 2015. “The use of different alumina fillers for improvement of the mechanical properties of hybrid PMMA composites.” Mater. Des. 86 (Dec): 575–581. https://doi.org/10.1016/j.matdes.2015.07.069.
Aranda, M. T., I. G. García, J. Reinoso, and V. Mantič. 2022. “Experimental evaluation of the similarity in the interface fracture energy between PMMA/epoxy/PMMA and PMMA/epoxy joints.” Eng. Fract. Mech. 259 (Jan): 108076. https://doi.org/10.1016/j.engfracmech.2021.108076.
Arif, M., D. Kumar, and A. N. Siddiquee. 2022. “Friction stir welding and friction stir spot welding of polymethyl methacrylate (PMMA) to other materials: A review.” Mater. Today: Proc. 62 (1): 220–225. https://doi.org/10.1016/j.matpr.2022.02.621.
ASTM. 2022. Standard test method for tensile properties of plastics. ASTM D638. West Conshohocken, PA: ASTM.
Bura, E., Ł. Derpeński, and A. Seweryn. 2019. “Fracture in PMMA notched specimens under compression—Experimental study.” Polym. Test. 77 (Aug): 105923. https://doi.org/10.1016/j.polymertesting.2019.105923.
Chen, W., F. Lu, and M. Cheng. 2002. “Tension and compression tests of two polymers under quasi-static and dynamic loading.” Polym. Test. 21 (2): 113–121. https://doi.org/10.1016/S0142-9418(01)00055-1.
Chinese Standard. 2008. Plastics—Determination of hardness-Part 2: Rockwell hardness. GB/T 3398.2. Beijing: Chinese Standard.
Doitrand, A., R. Estevez, and D. Leguillon. 2019. “Experimental characterization and numerical modeling of crack initiation in rhombus hole PMMA specimens under compression.” Eur. J. Mech. A Solids 76 (Jul–Aug): 290–299. https://doi.org/10.1016/j.euromechsol.2019.04.013.
Fan, R. H. 2012. “The fitting of the constitutive relationship of PMMA and FEA research based on tensile tests.” Dissertation for the Master’s Degree in Engineering, School of Astronautics, Harbin Institute of Technology.
Farotti, E., E. Mancini, A. Lattanzi, M. Utzeri, and M. Sasso. 2022. “Effect of temperature and strain rate on the formation of shear bands in polymers under quasi-static and dynamic compressive loadings: Proposed constitutive model and numerical validation.” Polymer 245 (Apr): 124690. https://doi.org/10.1016/j.polymer.2022.124690.
Gao, Z. T. 1987. The fatigue and fracture morphology of PMMA. Beijing: Science Press.
Garcia-Gonzalez, D., A. Rusinek, A. Bendarma, R. Bernier, M. Klosak, and S. Bahi. 2019. “Material and structural behaviour of PMMA from low temperatures to over the glass transition: Quasi-static and dynamic loading.” Polym. Test. 81 (Jan): 106263. https://doi.org/10.1016/j.polymertesting.2019.106263.
Hertzberg, R. W., and J. A. Manson. 1980. Fatigue of engineering plastics. New York: Academic Press.
Hoey, D., and D. Taylor. 2009. “Comparison of the fatigue behaviour of two different forms of PMMA.” Fatigue Fracture Eng. Mater. Struct. 32 (3): 261–269. https://doi.org/10.1111/j.1460-2695.2009.01327.x.
Hull, D. 1999. Fractography: Observation, measuring and interpreting fracture surface topography. Cambridge, UK: Cambridge University Press.
Jin, T., Z. W. Zhou, Z. H. Wang, G. Y. Wu, Z. G. Liu, and X. F. Shu. 2015. “Quasi-static failure behaviour of PMMA under combined shear–compression loading.” Polym. Test. 42 (Apr): 181–184. https://doi.org/10.1016/j.polymertesting.2015.01.018.
Jo, C., J. Fu, and H. E. Naguib. 2005. “Constitutive modeling for mechanical behavior of PMMA microcellular foams.” Polymer 46 (25): 11896–11903. https://doi.org/10.1016/j.polymer.2005.09.054.
Josef, J., S. H. Robert, J. Ema, and J. Zidek. 2015. “Effect of temperature, strain rate and particle size on the yield stresses and post-yield strain softening of PMMA and its composites.” Polymer 63 (Apr): 196–207. https://doi.org/10.1016/j.polymer.2015.03.001.
Kazarinov, N. A., V. A. Bratov, N. F. Morozov, Y. V. Petrov, V. V. Balandin, M. A. Iqbal, and N. K. Gupta. 2020. “Experimental and numerical analysis of PMMA impact fracture.” Int. J. Impact Eng. 143 (Sep): 103597. https://doi.org/10.1016/j.ijimpeng.2020.103597.
Kuleyin, H., R. Gümrük, and S. Çaliskan. 2022. “The effect of ABS fraction on the fatigue behavior of PMMA/ABS polymer blends.” Mater. Today Commun. 33 (Dec): 104139. https://doi.org/10.1016/j.mtcomm.2022.104139.
Liu, M. J., S. J. Duan, Y. W. Wu, S. G. Fan, and Q. F. Xu. 2022. “Fire resistance design of austenitic SUS316 stainless columns subjected to axial compression.” J. Constr. Steel Res. 198 (Nov): 107540. https://doi.org/10.1016/j.jcsr.2022.107540.
Mulliken, A. D., and M. C. Boyce. 2006. “Mechanics of the rate-dependent elastic–plastic deformation of glassy polymers from low to high strain rates.” Int. J. Solids Struct. 43 (5): 1331–1356. https://doi.org/10.1016/j.ijsolstr.2005.04.016.
Qin, S., H. Q. Yu, J. Yang, W. Z. Zhao, and Z. R. Zhang. 2019. “Experimental study on tensile strength of polymethyl methacrylate at high temperature.” Glass 46 (12): 23–25.
Richeton, J., S. Ahzi, K. S. Vecchio, F. C. Jiang, and R. R. Adharapurapu. 2006. “Influence of temperature and strain rate on the mechanical behavior of three amorphous polymers: Characterization and modeling of the compressive yield stress.” Int. J. Solids Struct. 43 (7–8): 2318–2335. https://doi.org/10.1016/j.ijsolstr.2005.06.040.
Rusinek, A., R. Bernier, R. M. Boumbimba, M. Klosak, T. Jankowiak, and G. Z. Voyiadjis. 2018. “New devices to capture the temperature effect under dynamic compression and impact perforation of polymers, application to PMMA.” Polym. Test. 65 (Feb): 1–9. https://doi.org/10.1016/j.polymertesting.2017.10.015.
Shan, J., L. Y. Lu, and B. Z. Shan. 2011. Structural mechanics. Jiangsu, China: Southeast University Press.
Shieh, Y. T., G. L. Liu, K. C. Hwang, and C. C. Chen. 2005. “Crystallization, melting and morphology of PEO in PEO/MWNT-g-PMMA blends.” Polymer 46 (24): 10945–10951. https://doi.org/10.1016/j.polymer.2005.09.022.
Simsiriwong, J., R. Shrestha, N. Shamsaei, M. Lugo, and R. D. Moser. 2015. “Effects of microstructural inclusions on fatigue life of polyether ether ketone (PEEK).” J. Mech. Behav. Biomed. Mater. 51 (Nov): 388–397. https://doi.org/10.1016/j.jmbbm.2015.07.020.
Siviour, C. R., S. M. Walley, W. G. Proud, and J. E. Field. 2005. “The high strain rate compressive behaviour of polycarbonate and polyvinylidene difluoride.” Polymer 46 (26): 12546–12555. https://doi.org/10.1016/j.polymer.2005.10.109.
Sobieraj, M. C., S. M. Kurtz, and C. M. Rimnac. 2009. “Notch sensitivity of PEEK in monotonic tension.” Biomaterials 30 (33): 6485–6494. https://doi.org/10.1016/j.biomaterials.2009.08.020.
Sun, Y. H., G. J. Peng, G. J. Dou, Y. H. Hu, P. J. Chen, and T. H. Zhang. 2022. “A nano-compression model to characterize the elastic properties of core–shell structured microspheres.” Thin-Walled Struct. 173 (Apr): 108951. https://doi.org/10.1016/j.tws.2022.108951.
Suresh, S. 1998. Fatigue of materials. Cambridge, UK: Cambridge University Press.
Wang, J. F., J. P. Yang, L. H. Tam, and W. Zhang. 2022a. “Effect of CNT volume fractions on nonlinear vibrations of PMMA/CNT composite plates: A multiscale simulation.” Thin-Walled Struct. 170 (Jan): 108513. https://doi.org/10.1016/j.tws.2021.108513.
Wang, Y. Q., Z. Sun, Z. Y. Wang, B. F. Zheng, Y. S. Tang, and Y. W. Ouyang. 2022b. “Engineering application and research progress of structural acrylic.” Eng. Mech. 39 (4): 1–14. https://doi.org/10.3901/JME.2003.04.001.
Wang, Y. Q., L. Zong, Y. K. Heng, Z. Y. Wang, Y. Zhou, S. J. Hou, Z. H. Qin, and X. Y. Ma. 2014. “Application of anacrylic vessel supported by a stainless-steel truss for the JUNO central detector.” Sci. China Technol. Sci. 57 (12): 2523–2529. https://doi.org/10.1007/s11431-014-5715-x.
Wang, Z. Y. 2017. “Research on structural form election and mechanical behaviors of materials and joints for neutrino detectors.” Ph.D. thesis, School of Civil Engineering, Wuhan Univ.
Wang, Z. Y., Y. Q. Wang, X. X. Du, T. X. Zhang, and H. X. Yuan. 2018. “Quasi-static tensile test of thick acrylic sheets at different temperatures.” J. Southeast Univ. 48 (1): 132–137. https://doi.org/10.3969/j.issn.1001-0505.2018.01.020.
Wang, Z. Y., Y. Q. Wang, Y. K. Heng, X. X. Du, and Z. H. Qin. 2016. “Bearing capacities of the structure and joint of JUNO central detector.” Period. Polytech., Civ. Eng. 60 (4): 561–572. https://doi.org/10.3311/PPci.8551.
Wu, H. Y., G. Ma, and Y. M. Xia. 2004. “Experimental study of tensile properties of PMMA at intermediate strain rate.” Mater. Lett. 58 (29): 3681–3685. https://doi.org/10.1016/j.matlet.2004.07.022.
Yao, C. B., Y. Xia, Z. M. Zhu, Z. R. Yang, K. Chen, and H. Jiang. 2020. “Investigation on brittle-ductile transition of PMMA mode-II fracture using time-temperature superposition principle.” Eng. Fract. Mech. 273 (Oct): 108733. https://doi.org/10.1016/j.engfracmech.2022.108733.
Yin, W. H., Z. Y. Xie, Y. M. Yin, J. Yi, X. D. Liu, H. Q. Wu, S. Wang, Y. F. Xie, and Y. N. Yang. 2019. “Aging behavior and lifetime prediction of PMMA under tensile stress and liquid scintillator conditions.” Adv. Ind. Eng. Polym. Res. 2 (2): 82–87. https://doi.org/10.1016/j.aiepr.2019.04.002.
Zhang, J. J., T. Jin, Z. H. Wang, and L. M. Zhao. 2016. “Experimental investigation on yield behavior of PMMA under combined shear–compression loading.” Results Phys. 6: 265–269. https://doi.org/10.1016/j.rinp.2016.05.004.
Zhang, L. H., D. Townsend, N. Petrinic, and A. Pellegrino. 2021. “Pressure and temperature dependent dynamic flow and failure behavior of PMMA at intermediate strain rates.” Int. J. Impact Eng. 158 (Dec): 104026. https://doi.org/10.1016/j.ijimpeng.2021.104026.
Zhou, J. Y., U. Heisserer, W. D. Phillip, T. C. Paul, M. John, and L. T. Vito. 2021. “The sensitivity of the tensile properties of PMMA, Kevlar® and Dyneema® to temperature and strain rate.” Polymer 225 (May): 123781. https://doi.org/10.1016/j.polymer.2021.123781.
Zhou, X. P., L. Fu, W. Ju, and F. Berto. 2019. “An experimental study of the mechanical and fracturing behavior in PMMA specimen containing multiple 3D embedded flaws under uniaxial compression.” Theor. Appl. Fract. Mech. 101 (Jun): 207–216. https://doi.org/10.1016/j.tafmec.2019.03.002.
Zhou, Z. W., B. Y. Su, Z. H. Wang, Z. Q. Li, X. F. Shu, and L. M. Zhao. 2013. “Shear-compression failure behavior of PMMA at different loading rates.” Mater. Lett. 109 (Oct): 151–153. https://doi.org/10.1016/j.matlet.2013.05.081.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 10October 2023

History

Received: Oct 20, 2022
Accepted: Mar 23, 2023
Published online: Aug 2, 2023
Published in print: Oct 1, 2023
Discussion open until: Jan 2, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Ph.D. Candidate, Key Laboratory of Concrete and Prestressed Concrete Structures of Ministry of Education, School of Civil Engineering, Southeast Univ., Nanjing 211189, China. Email: [email protected]
Lei Peng, Ph.D. [email protected]
Senior Engineer, Tianjin Taida Fire Technology Co., Ltd., 14F, Chamber of Commerce Union Building, Hongqi South Rd., Nankai District, Tianjin 300381, China. Email: [email protected]
Yongjia Cui [email protected]
Associate Engineer, Shanghai Municipal Engineering Design Institute (Group) Co., Ltd., 901 North Zhongshan Rd., Yangpu District, Shanghai 200092, China. Email: [email protected]
Shenggang Fan [email protected]
Professor, Key Laboratory of Concrete and Prestressed Concrete Structures of Ministry of Education, School of Civil Engineering, Southeast Univ., Nanjing 211189, China (corresponding author). Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share