Potential of Pyrogenic Nanosilica to Enhance the Service Life of Concrete
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 5
Abstract
The continuous advancement in construction materials and technology demands novel admixtures to make concrete more sustainable and durable. Several supplementary cementitious materials are already being used to replace cement partially for alleviating the destructive environmental aspects. The common durability issues faced by concrete are drying shrinkage, sulfate attacks, alkali-silica reaction, and chloride attacks. This experimental study presents a solution by analysing the effect of fumed silica nanoparticles on durability, most of which are related to permeability. The fumed silica nanoparticles were incorporated in concrete as cement substitution at 0.5%, 1.0%, 1.5%, and 2.0%. Durability performance was examined by conducting the rapid chloride permeability test (RCPT), sulfate attack resistivity test, drying shrinkage test, and water absorption test. The additional tests were conducted to determine the density, void content, and compressive strength of concrete and cement mortar samples. Also, field emission scanning electron microscopy (FESEM) and energy dispersive X-ray analysis (EDAX) were performed to understand the microstructure. The test results indicated that 2% fumed silica provided optimum results in terms of workability and mechanical performance. Compressive strength was increased by 20% and 27% in mortar and concrete, respectively. In addition, drying shrinkage was reduced by 72%, and expansion due to sulfate attack and alkali-silica were reduced by 79%, and 71% respectively. Furthermore, the rapid chloride permeability test showed that addition of 2% fumed silica resulted in overall reduction in permeability by 47%. This study corroborates that fumed silica nanoparticles-incorporated concrete is more durable than ordinary concrete. Fumed nanosilica can be effectively used in the production of performance-based cement composites. These nanoparticles have shown excellent potential in controlling drying shrinkage and permeability-related issues, including sulfate attacks and corrosion.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
The authors thank the Higher Education Commission, Pakistan, for supporting the work. The research is funded by the HEC-PK (Grant No. TDF-02-111) (Production of special cement). Author Maria Idrees has received research support from the Higher Education Commission, Pakistan.
References
Ahmad, S. A., and M. Adil. 2017. “Production of nano-concrete with fumed silica, metakaolin and Portland cement using high energy mixing.” Int. J. Adv. Eng. Res. Dev. 11 (4): 1043–1050.
Akbar, A., F. Farooq, M. Shafique, F. Aslam, R. Alyousaf, and H. Abduljabbar. 2021. “Sugarcane bagasse ash-based engineered geopolymer mortar incorporating propylene fibers.” J. Build. Eng. 33 (Jan): 101492. https://doi.org/https://doi.org/10.1016/j.jobe.2020.101492.
Akbar, A., and K. M. Liew. 2020a. “Assessing recycling potential of carbon fiber reinforced plastic waste in production of eco-efficient cement-based materials.” J. Cleaner Prod. 274 (Nov): 123001. https://doi.org/10.1016/j.jclepro.2020.123001.
Akbar, A., and K. M. Liew. 2020b. “Influence of elevated temperature on the microstructure and mechanical performance of cement composites reinforced with recycled carbon fibers.” Composites, Part B 198 (Oct): 108245. https://doi.org/10.1016/j.compositesb.2020.108245.
Akbar, A., and K. M. Liew. 2021. “Multicriteria performance evaluation of fiber-reinforced cement composites: An environmental perspective.” Composites, Part B 218 (Aug): 108937. https://doi.org/10.1016/j.compositesb.2021.108937.
Al-Rousan, R. Z. 2022. “Cyclic behavior of alkali-silica reaction-damaged reinforced concrete beam-column joints strengthened with FRP composites.” Case Stud. Constr. Mater. 16 (Jun): e00869. https://doi.org/https://doi.org/10.1016/j.cscm.2022.e00869.
ASTM. 2006. Standard test method for density, absorption, and voids in hardened concrete. ASTM C642. West Conshohocken, PA: ASTM.
ASTM. 2007a. Standard test method for flow of hydraulic cement mortar. ASTM C1437. West Conshohocken, PA: ASTM.
ASTM. 2007b. Standard test method for potential alkali reactivity of aggregates (mortar-bar method). ASTM C1260. West Conshohocken, PA: ASTM.
ASTM. 2009. Standard test method for drying shrinkage of mortar containing hydraulic cement. ASTM C596. West Conshohocken, PA: ASTM.
ASTM. 2012a. Standard test method for electrical indication of concrete’s ability to resist chloride ion penetration. ASTM C1202. West Conshohocken, PA: ASTM.
ASTM. 2012b. Standard test method for length change of hydraulic-cement mortars exposed to a sulfate solution. ASTM C1012. West Conshohocken, PA: ASTM.
ASTM. 2013. Standard test method for determining the potential alkali-silica reactivity of combinations of cementitious materials and aggregate (accelerated mortar-bar method). ASTM C1567. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for slump of hydraulic-cement concrete. ASTM C143/C143M. West Conshohocken, PA: ASTM.
ASTM. 2020. Standard specification for portland cement. ASTM C150/C150M-20. West Conshohocken, PA: ASTM.
Azevedo, A., P. de Matos, M. Marvila, R. Sakata, L. Silvestro, P. Gleize, and J. D. Brito. 2021. “Rheology, hydration, and microstructure of Portland cement pastes produced with ground açaí fibers.” Appl. Sci. 11 (7): 3036. https://doi.org/10.3390/app11073036.
Bellmann, F., B. Möser, and J. Stark. 2006. “Influence of sulfate solution concentration on the formation of gypsum in sulfate resistance test specimen.” Cem. Concr. Res. 36 (2): 358–363. https://doi.org/10.1016/j.cemconres.2005.04.006.
Björnström, J., A. Martinelli, A. Matic, L. Börjesson, and I. Panas. 2004. “Accelerating effects of colloidal nano-silica for beneficial calcium–silicate–hydrate formation in cement.” Chem. Phys. Lett. 392 (1–3): 242–248. https://doi.org/10.1016/j.cplett.2004.05.071.
Carvalho, A., G. de Castro Xavier, J. Alexandre, L. G. Pedroti, A. R. G. de Azevedo, C. M. F. Vieira, and S. N. Monteiro. 2014. “Environmental durability of soil-cement block incorporated with ornamental stone waste.” Mater. Sci. Forum 798–799 (Jun): 548–553. https://doi.org/10.4028/www.scientific.net/MSF.798-799.548.
Cheraghian, G., and M. P. Wistuba. 2020. “Ultraviolet aging study on bitumen modified by a composite of clay and fumed silica nanoparticles.” Sci. Rep. 10 (1): 1–17. https://doi.org/10.1038/s41598-020-68007-0.
Darvell, B. W. 2018. “Resin restorative materials.” Chap. 6 in Woodhead publishing series in biomaterials, edited by T. E. Darvell, 143–191. Amsterdam, Netherlands: Elsevier.
Fanijo, E. O., J. T. Kolawole, and A. Almakrab. 2021. “Alkali-silica reaction (ASR) in concrete structures: Mechanisms, effects, and evaluation test methods adopted in the United States.” Case Stud. Constr. Mater. 15 (Dec): e00563. https://doi.org/https://doi.org/10.1016/j.cscm.2021.e00563.
Fu, W., T. Zou, X. Liang, S. Wang, X. Gao, Z. Zhang, and Y. Fang. 2019. “Preparation and properties of phase change temperature-tuned composite phase change material based on sodium acetate trihydrate–urea/fumed silica for radiant floor heating system.” Appl. Therm. Eng. 162 (Nov): 114253. https://doi.org/10.1016/j.applthermaleng.2019.114253.
Gayathiri, K., and S. Praveenkumar. 2022. “Influence of nano silica on fresh and hardened properties of cement-based materials—A review.” Silicon 14: 8327–8357. https://doi.org/10.1007/s12633-021-01598-z.
Hasan-Nattaj, F., and M. Nematzadeh. 2017. “The effect of forta-ferro and steel fibers on mechanical properties of high-strength concrete with and without silica fume and nano-silica.” Constr. Build. Mater. 137 (Apr): 557–572. https://doi.org/10.1016/j.conbuildmat.2017.01.078.
Hooton, R. D. 2019. “Future directions for design, specification, testing, and construction of durable concrete structures.” Cem. Concr. Res. 124 (Oct): 105827. https://doi.org/10.1016/j.cemconres.2019.105827.
Huang, Q., X. Zhu, L. Zhao, M. Zhao, Y. Liu, and X. Zeng. 2020. “Effect of nanosilica on sulfate resistance of cement mortar under partial immersion.” Constr. Build. Mater. 231 (Jan): 117180. https://doi.org/10.1016/j.conbuildmat.2019.117180.
Idrees, M., A. Akbar, A. M. Mohamed, D. Fathi, and F. Saeed. 2022a. “Recycling of waste facial masks as a construction material, a step towards sustainability.” Materials 15 (5): 1810. https://doi.org/10.3390/ma15051810.
Idrees, M., A. Akbar, F. Saeed, H. Saleem, T. Hussian, and N. I. Vatin. 2022b. “Improvement in durability and mechanical performance of concrete exposed to aggressive environments by using polymer.” Materials 15 (11): 3751. https://doi.org/10.3390/ma15113751.
Idrees, M., O. Ekincioglu, and M. S. Sonyal. 2021a. “Hydration behavior of calcium aluminate cement mortars with mineral admixtures at different curing temperatures.” Constr. Build. Mater. 285 (May): 122839. https://doi.org/10.1016/j.conbuildmat.2021.122839.
Idrees, M., A. T. Hussain, F. Saeed, and T. Hussain. 2021b. “Effectiveness of metakaolin and hybrid polymers incorporated mortar for the compressive strength and acid resistance of industrial and wastewater infrastructure.” Environ. Prog. Sustainable Energy 40 (3): e13534. https://doi.org/10.1002/ep.13534.
Idrees, M., F. Saeed, A. Amin, and T. Hussain. 2021c. “Improvement in compressive strength of styrene-butadiene-rubber (SBR) modified mortars by using powder form and nanoparticles.” J. Build. Eng. 44 (Dec): 102651. https://doi.org/10.1016/j.jobe.2021.102651.
Joshaghani, A., M. Balapour, and A. A. Ramezanianpour. 2018. “Effect of controlled environmental conditions on mechanical, microstructural and durability properties of cement mortar.” Constr. Build. Mater. 164 (Mar): 134–149. https://doi.org/10.1016/j.conbuildmat.2017.12.206.
Juradin, S., and D. Vlajić. 2015. “Influence of cement type and mineral additions, silica fume and metakaolin, on the properties of fresh and hardened self-compacting concrete.” In Mechanical and materials engineering of modern structure and component design, 251–267. Cham, Switzerland: Springer.
Kim, Y. J., and J. Wang. 2019. “Development of ultra-high-performance concrete with various silica admixtures.” ACI Mater. J. 116 (2): 33–44. https://doi.org/10.14359/51714450.
Kong, D., X. Du, S. Wei, H. Zhang, Y. Yang, and S. P. Shah. 2012. “Influence of nano-silica agglomeration on microstructure and properties of the hardened cement-based materials.” Constr. Build. Mater. 37 (Dec): 707–715. https://doi.org/10.1016/j.conbuildmat.2012.08.006.
Kooshafar, M., and H. Madani. 2020. “An investigation on the influence of nano silica morphology on the characteristics of cement composites.” J. Build. Eng. 30 (Jul): 101293. https://doi.org/10.1016/j.jobe.2020.101293.
Korpa, A., and R. Trettin. 2004. “The use of synthetic colloidal silica dispersions for making HPC and UHPC systems, preliminary comparison results between colloidal silica dispersions and silica fumes (SF).” In Proc., Int. Symp. Ultra High Performance Concrete, 155–163. Kassel, Germany: Kassel University Press.
Lahdensivu, J., A. Köliö, and D. Husaini. 2018. “Alkali-silica reaction in southern Finland’s bridges.” Case Stud. Constr. Mater. 8 (Jun): 469–475. https://doi.org/https://doi.org/10.1016/j.cscm.2018.03.006.
Lavergne, F., R. Belhadi, J. Carriat, and A. Ben Fraj. 2019. “Effect of nano-silica particles on the hydration, the rheology and the strength development of a blended cement paste.” Cem. Concr. Compos. 95 (Jan): 42–55. https://doi.org/10.1016/j.cemconcomp.2018.10.007.
Łaźniewska-Piekarczyk, B. 2013. “The influence of chemical admixtures on cement hydration and mixture properties of very high performance self-compacting concrete.” Constr. Build. Mater. 49 (Dec): 643–662. https://doi.org/10.1016/j.conbuildmat.2013.07.072.
Li, L. G., J. Y. Zheng, P. L. Ng, J. Zhu, and A. K. H. Kwan. 2019. “Cementing efficiencies and synergistic roles of silica fume and nano-silica in sulfate and chloride resistance of concrete.” Constr. Build. Mater. 223 (Oct): 965–975. https://doi.org/10.1016/j.conbuildmat.2019.07.241.
Lim, T., J. Seok, and D. D. Kim. 2017. “A comparative study of energy performance of fumed silica vacuum insulation panels in an apartment building.” Energies 10 (12): 2000. https://doi.org/10.3390/en10122000.
Liu, J., Q. Qiu, X. Chen, F. Xing, N. Han, Y. He, and Y. Ma. 2017. “Understanding the interacted mechanism between carbonation and chloride aerosol attack in ordinary Portland cement concrete.” Cem. Concr. Res. 95 (May): 217–225. https://doi.org/10.1016/j.cemconres.2017.02.032.
Liu, X., P. Hou, and H. Chen. 2021. “Effects of nanosilica on the hydration and hardening properties of slag cement.” Constr. Build. Mater. 282 (May): 122705. https://doi.org/10.1016/j.conbuildmat.2021.122705.
Lothenbach, B., K. Scrivener, and R. D. Hooton. 2011. “Supplementary cementitious materials.” Cem. Concr. Res. 41 (12): 1244–1256. https://doi.org/10.1016/j.cemconres.2010.12.001.
Martins, R. O. G., S. Rita de Cássia, L. G. Pedroti, A. F. de Oliveira, B. C. Mendes, and A. R. G. de Azevedo. 2018. “Assessment of the durability of grout submitted to accelerated carbonation test.” Constr. Build. Mater. 159 (Jan): 261–268. https://doi.org/10.1016/j.conbuildmat.2017.10.111.
Marvila, M. T., A. R. G. Azevedo, D. Cecchin, J. M. Costa, G. C. Xavier, D. de Fátima do Carmo, and S. N. Monteiro. 2020. “Durability of coating mortars containing açaí fibers.” Case Stud. Constr. Mater. 13 (Dec): e00406. https://doi.org/10.1016/j.cscm.2020.e00406.
Mobini, M. H., A. Khaloo, P. Hosseini, and A. Esrafili. 2015. “Mechanical properties of fiber-reinforced high-performance concrete incorporating pyrogenic nanosilica with different surface areas.” Constr. Build. Mater. 101 (Dec): 130–140. https://doi.org/10.1016/j.conbuildmat.2015.10.032.
Mobini, M. H., and A. R. Khaloo. 2021. “Investigating the effects of using pyrogenic nanosilica in high-performance concrete on concrete resistivity against rebar corrosion.” Sharif J. Civ. Eng. 36: 81–90. https://doi.org/10.24200/j30.2020.54746.2667.
Mohan, A., and K. M. Mini. 2018. “Strength and durability studies of SCC incorporating silica fume and ultra fine GGBS.” Constr. Build. Mater. 171 (May): 919–928. https://doi.org/10.1016/j.conbuildmat.2018.03.186.
Mora, E., G. González, P. Romero, and E. Castellón. 2019. “Control of water absorption in concrete materials by modification with hybrid hydrophobic silica particles.” Constr. Build. Mater. 221 (Oct): 210–218. https://doi.org/10.1016/j.conbuildmat.2019.06.086.
Oorkalan, A., and S. Chithra. 2021. “Investigation on the properties of sustainable steel fiber reinforced reactive powder concrete by utilization of coir pith aggregates and pyrogenic silica.” Silicon 4 (10): 5545–5562. https://doi.org/10.1007/s12633-021-01266-2.
Peng, S., J. Huang, T. Wang, and P. Zhu. 2019. “Effect of fumed silica additive on supercooling, thermal reliability, and thermal stability of Na2HPO4· 12H2O as inorganic PCM.” Thermochim. Acta 675 (May): 1–8. https://doi.org/10.1016/j.tca.2019.02.013.
Qu, Y., J. Chen, L. Liu, T. Xu, H. Wu, and X. Zhou. 2020. “Study on properties of phase change foam concrete block mixed with paraffin/fumed silica composite phase change material.” Renewable Energy 150 (May): 1127–1135. https://doi.org/10.1016/j.renene.2019.10.073.
Reade. 2020. “Reade advanced materials—Fumed silica powder ().” Accessed January 28, 2022. https://www.reade.com/products/fumed-silica-powder-sio2.
Reddy, A. N., S. P. Priyanka, and P. Mounika. 2019. “The effect of nano silica on mechanical properties of concrete.” Int. Res. J. Appl. Sci. 1 (1): 36–40.
Satoh, H., Y. Kimura, and E. Furukawa. 2018. “Direct transmission electron microscopy visualization of the cement reaction by colloidal aggregation of fumed silica.” Ind. Eng. Chem. Res. 57 (1): 79–83. https://doi.org/10.1021/acs.iecr.7b04137.
Sharma, R., J. G. Jang, and P. P. Bansal. 2022. “A comprehensive review on effects of mineral admixtures and fibers on engineering properties of ultra-high-performance concrete.” J. Build. Eng. 45 (Jan): 103314. https://doi.org/10.1016/j.jobe.2021.103314.
Siddique, R. 2011. “Utilization of silica fume in concrete: Review of hardened properties.” Resour. Conserv. Recycl. 55 (11): 923–932. https://doi.org/10.1016/j.resconrec.2011.06.012.
Tobón, J. I., O. Mendoza Reales, O. J. Restrepo, M. V. Borrachero, and J. Payá. 2018. “Effect of pyrogenic silica and nanosilica on Portland cement matrices.” J. Mater. Civ. Eng. 30 (10): 04018266. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002482.
Uysal, M., and V. Akyuncu. 2012. “Durability performance of concrete incorporating Class F and Class C fly ashes.” Constr. Build. Mater. 34 (Sep): 170–178. https://doi.org/10.1016/j.conbuildmat.2012.02.075.
Vladimirov, V., C. Betchev, A. Vassiliou, G. Papageorgiou, and D. Bikiaris. 2006. “Dynamic mechanical and morphological studies of isotactic polypropylene/fumed silica nanocomposites with enhanced gas barrier properties.” Compos. Sci. Technol. 66 (15): 2935–2944. https://doi.org/10.1016/j.compscitech.2006.02.010.
Wang, K., W. Pan, Z. Liu, T. J. Wallin, G. van Dover, S. Li, E. P. Giannelis, Y. Menguc, and R. F. Shepherd. 2020. “3D printing of viscoelastic suspensions via digital light synthesis for tough nanoparticle–elastomer composites.” Adv. Mater. 32 (25): 2001646. https://doi.org/10.1002/adma.202001646.
Xie, J., H. Zhang, Y. Shao, D. Bao, H. Zhang, and J. Zhu. 2020. “Investigation of the performance of fumed silica as flow additive in polyester powder coatings.” Coatings 10 (10): 977. https://doi.org/10.3390/coatings10100977.
Yang, H., M. Monasterio, D. Zheng, H. Cui, W. Tang, X. Bao, and X. Chen. 2021. “Effects of nano silica on the properties of cement-based materials: A comprehensive review.” Constr. Build. Mater. 282 (May): 122715. https://doi.org/10.1016/j.conbuildmat.2021.122715.
Zahedi, A., and P. Akpinar. 2022. “A case study for exploring the alkali-aggregate reactivity of Cyprus aggregates.” Case Stud. Constr. Mater. 16 (Jun): e01000. https://doi.org/https://doi.org/10.1016/j.cscm.2022.e01000.
Zhu, N., F. Jin, X. Kong, Y. Xu, J. Zhou, B. Wang, and H. Wu. 2018. “Interface and anti-corrosion properties of sea-sand concrete with fumed silica.” Constr. Build. Mater. 188 (Nov): 1085–1091. https://doi.org/10.1016/j.conbuildmat.2018.08.040.
Zhutovsky, S., and K. Kovler. 2012. “Effect of internal curing on durability-related properties of high performance concrete.” Cem. Concr. Res. 42 (1): 20–26. https://doi.org/10.1016/j.cemconres.2011.07.012.
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Published In
Journal of Materials in Civil Engineering
Volume 35 • Issue 5 • May 2023
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© 2023 American Society of Civil Engineers.
History
Received: Apr 28, 2022
Accepted: Oct 4, 2022
Published online: Feb 16, 2023
Published in print: May 1, 2023
Discussion open until: Jul 16, 2023
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