Technical Papers
Apr 25, 2023

Hydrated Lime–Enriched CO2 Sequestration Binders Reinforced by Polyvinyl Alcohol

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 7

Abstract

Carbon capture utilization and storage technique (CCUS) is an effective way to mitigate climate change. Carbon dioxide (CO2) sequestration binders (CSB) composed of hydrated lime (CH) and cement has great application prospects in CCUS. Although CH in CSB can improve the carbon absorption capacity, it causes a significant decrease in flexural strength. This study focused on the effect of polyvinyl alcohol (PVA) on the CO2 absorption capacity and flexural strength of CSB. The results show that PVA is beneficial to enhancing the flexural strength of CSB either under natural carbonation or accelerated carbonation. This enhancement is more pronounced at an early age for CSB with high CH content. Furthermore, CO2 uptake experiments show that the PVA would not reduce the CO2 absorption of CSB and even has a slight improvement effect. Finally, thermodynamic modeling and price calculation were adopted for CSB to illustrate the chemical phase and economic cost changes. The outcomes of this study shed new light on PVA to optimize CSB.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The authors would like to thank the financial support from the Fundamental Research Funds for the Central Universities (B210201041) and the National Natural Science Foundation of China (52178202 and 51808188). Also, the authors thank Jiangsu Research Institute of Building Science Co. and the state key laboratory of high-performance civil engineering materials for funding this research project.

References

Allahverdi, A., K. Kianpur, and M. R. Moghbeli. 2010. “Effect of polyvinyl alcohol on flexural strength and some important physical properties of portland cement paste.” Iran. J. Mater. Sci. Eng. 7 (1): 1–6. https://doi.org/10.1080/08838151.2015.1029123.
ASTM. 2004. Standard test method for measurement of rate of absorption of water by hydraulic-cement concretes. ASTM C1585. West Conshohocken, PA: ASTM.
ASTM. 2014. Standard test methods for specific gravity of soil solids by water pycnometer. ASTM D854-14. West Conshohocken, PA: ASTM.
Bhutta, A., P. H. R. Borges, C. Zanotti, M. Farooq, and N. Banthia. 2017. “Flexural behavior of geopolymer composites reinforced with steel and polypropylene macro fibers.” Cem. Concr. Compos. 80 (Jul): 31–40. https://doi.org/10.1016/j.cemconcomp.2016.11.014.
Castellote, M., L. Fernandez, C. Andrade, and C. Alonso. 2009. “Chemical changes and phase analysis of OPC pastes carbonated at different CO2 concentrations.” Mater. Struct. 42 (4): 515–525. https://doi.org/10.1617/s11527-008-9399-1.
Chang, H., X. Wang, Y. Wang, S. Li, J. Wang, J. Liu, and P. Feng. 2022. “Influence of low vacuum condition on mechanical performance and microstructure of hardened cement paste at early age.” Constr. Build. Mater. 346 (Sep): 128358. https://doi.org/10.1016/j.conbuildmat.2022.128358.
Chinese Standards. 1985. Test method for long term performance and durability of ordinary concrete. GBJ 82-1985. Beijing: Chinese Standards.
Cloete, S., A. Giuffrida, M. C. Romano, and A. Zaabout. 2019. “The swing adsorption reactor cluster for post-combustion CO2 capture from cement plants.” J. Cleaner Prod. 223 (Jun): 692–703. https://doi.org/10.1016/j.jclepro.2019.03.109.
Costa, F. N., and D. V. Ribeiro. 2020. “Reduction in CO2 emissions during production of cement, with partial replacement of traditional raw materials by civil construction waste (CCW).” J. Cleaner Prod. 276 (Dec): 123302. https://doi.org/10.1016/j.jclepro.2020.123302.
Di Maria, A. D., R. Snellings, L. Alaerts, M. Quaghebeur, and K. Van Acker. 2019. “Environmental assessment of CO2 mineralisation for sustainable construction materials.” Int. J. Greenhouse Gas Control 93 (Feb): 102882. https://doi.org/10.1016/j.ijggc.2019.102882.
Gao, H., H. Liao, M. Wang, and F. Cheng. 2021. “Reinforcing the physicochemical properties of concrete through synergism of CO2 curing and Ca(OH)2 solution drenching.” Constr. Build. Mater. 280 (Apr): 122546. https://doi.org/10.1016/j.conbuildmat.2021.122546.
Gao, T., L. Shen, M. Shen, F. Chen, L. Liu, and L. Gao. 2015. “Analysis on differences of carbon dioxide emission from cement production and their major determinants.” J. Cleaner Prod. 103 (Sep): 160–170. https://doi.org/10.1016/j.jclepro.2014.11.026.
Groves, G. W., A. Brough, I. G. Richardson, and C. M. Dobson. 2005. “Progressive changes in the structure of hardened C3S cement pastes due to carbonation.” J. Am. Ceram. Soc. 74 (11): 2891–2896. https://doi.org/10.1111/j.1151-2916.1991.tb06859.x.
Hepburn, C., E. Adlen, J. Beddington, E. A. Carter, S. Fuss, N. Mac Dowell, J. C. Minx, P. Smith, and C. K. Williams. 2019. “The technological and economic prospects for CO2 utilization and removal.” Nature 575 (7781): 87–97. https://doi.org/10.1038/s41586-019-1681-6.
Holland, N. L., A. Nichols, and J. Nichols. 2012. “The use of hydrated lime in concrete as a cement replacement: Effect on compressive strength.” In Vol. 1557 of Proc., Lime—Building on the 100-Year Legacy of ASTM-Committee-C07, edited by M. L. Thomson and J. H. Brisch, 106–112. West Conshohocken, PA: ASTM International.
Jeong, Y. J., K. S. Youm, and T. S. Yun. 2018. “Effect of nano-silica and curing conditions on the reaction rate of class G well cement exposed to geological CO2-sequestration conditions.” Cem. Concr. Res. 109 (Jul): 208–216. https://doi.org/10.1016/j.cemconres.2018.05.001.
Jordal, K., M. Voldsund, S. Størset, K. Fleiger, J. Ruppert, R. Spörl, M. Hornberger, and G. Cinti. 2017. “CEMCAP–making CO2 Capture retrofittable to cement plants.” Energy Procedia 114 (Jul): 6175–6180. https://doi.org/10.1016/j.egypro.2017.03.1755.
Kulik, D. A. 2011. “Improving the structural consistency of C-S-H solid solution thermodynamic models.” Cem. Concr. Res. 41 (5): 477–495. https://doi.org/10.1016/j.cemconres.2011.01.012.
Kulik, D. A., T. Wagner, S. V. Dmytrieva, G. Kosakowski, F. F. Hingerl, K. V. Chudnenko, and U. R. Berner. 2013. “GEM-Selektor geochemical modeling package: Revised algorithm and GEMS3K numerical kernel for coupled simulation codes.” Comput. Geosci. 17 (1): 1–24. https://doi.org/10.1007/s10596-012-9310-6.
Kwon, S., and X. Wang. 2021. “CO2 uptake model of limestone-powder-blended concrete due to carbonation.” J. Build. Eng. 38 (Jun): 102176. https://doi.org/10.1016/j.jobe.2021.102176.
Lanas, J., J. L. Pérez Bernal, M. A. Bello, and J. A. Galindo. 2004. “Mechanical properties of natural hydraulic lime-based mortars.” Cem. Concr. Res. 34 (12): 2191–2201. https://doi.org/10.1016/j.cemconres.2004.02.005.
Levine, J. S. 1991. “Global climate change.” In Global climate change and freshwater ecosystems, edited by P. Firth and S. G. Fisher. New York: Springer.
Li, B., Z. Sun, K. Hu, and J. Yang. 2020. “Influence of carbonation on the volume change of hardened cement pastes.” Constr. Build. Mater. 260 (Nov): 119709. https://doi.org/10.1016/j.conbuildmat.2020.119709.
Li, J., J. Yan, G. Xue, and J. Niu. 2021. “Acoustic emission behavior of polyvinyl alcohol (PVA) fiber reinforced calcium sulphoaluminate cement mortar under flexural load.” J. Build. Eng. 40 (Aug): 102734. https://doi.org/10.1016/j.jobe.2021.102734.
Lin, Q., X. Zhang, C. Lu, X. Lan, G. Hou, and Z. Xu. 2016. “In vivo behaviors of Ca(OH)2 activated nano SiO2 (nCa/nSi=3) cement in rabbit model.” Mater. Sci. Eng., C 58 (Jan): 774–781. https://doi.org/10.1016/j.msec.2015.09.032.
Liu, Z., and W. Meng. 2021. “Fundamental understanding of carbonation curing and durability of carbonation-cured cement-based composites: A review.” J. CO2 Util. 44 (Feb): 101428. https://doi.org/10.1016/j.jcou.2020.101428.
Maravelaki-Kalaitzaki, P., A. Bakolas, and A. Moropoulou. 2003. “Physico-chemical study of Cretan ancient mortars.” Cem. Concr. Res. 33 (5): 651–661. https://doi.org/10.1016/S0008-8846(02)01030-X.
Morandeau, A., M. Thiery, and P. Dangla. 2014. “Investigation of the carbonation mechanism of CH and CSH in terms of kinetics, microstructure changes and moisture properties.” Cem. Concr. Res. 56 (Feb): 153–170. https://doi.org/10.1016/j.cemconres.2013.11.015.
Noor-E-Khuda, S. 2021. “Influence of wetting–drying cycles on compressive and flexural strength of cement mortar and CFRP-mortar bond strength.” Constr. Build. Mater. 271 (Feb): 121513. https://doi.org/10.1016/j.conbuildmat.2020.121513.
Pan, X., C. Shi, X. Hu, and Z. Ou. 2017. “Effects of CO2 surface treatment on strength and permeability of one-day-aged cement mortar.” Constr. Build. Mater. 154 (Nov): 1087–1095. https://doi.org/10.1016/j.conbuildmat.2017.07.216.
Pu, Y., L. Li, Q. Wang, X. Shi, C. Luan, G. Zhang, L. Fu, and A. E.-F. Abomohra. 2021. “Accelerated carbonation technology for enhanced treatment of recycled concrete aggregates: A state-of-the-art review.” Constr. Build. Mater. 282 (May): 122671. https://doi.org/10.1016/j.conbuildmat.2021.122671.
Richardson, I. G., G. W. Groves, A. R. Brough, and C. M. Dobson. 1993. “The carbonation of OPC and OPC/silica fume hardened cement pastes in air under conditions of fixed humidity.” Adv. Cem. Res. 5 (18): 81–86. https://doi.org/10.1680/adcr.1993.5.18.81.
Rostami, V., Y. Shao, A. J. Boyd, and Z. He. 2012. “Microstructure of cement paste subject to early carbonation curing.” Cem. Concr. Res. 42 (1): 186–193. https://doi.org/10.1016/j.cemconres.2011.09.010.
Sevelsted, T. F., and J. Skibsted. 2015. “Carbonation of C–S–H and C–A–S–H samples studied by 13C, 27Al and 29Si MAS NMR spectroscopy.” Cem. Concr. Res. 71 (May): 56–65. https://doi.org/10.1016/j.cemconres.2015.01.019.
Shi, Z., B. Lothenbach, M. R. Geiker, J. Kaufmann, A. Leemann, S. Ferreiro, and J. Skibsted. 2016. “Experimental studies and thermodynamic modeling of the carbonation of Portland cement, metakaolin and limestone mortars.” Cem. Concr. Res. 88 (Oct): 60–72. https://doi.org/10.1016/j.cemconres.2016.06.006.
Singh, N. B., and S. Rai. 2001. “Effect of polyvinyl alcohol on the hydration of cement with rice husk ash.” Cem. Concr. Res. 31 (2): 239–243. https://doi.org/10.1016/S0008-8846(00)00475-0.
Smyth, J. R., and T. C. Mccormick. 1995. “Crystallographic data for minerals.” In Mineral physics and crystallography: A handbook of physical constants, 1–17. Washington, DC: American Geophysical Union. https://doi.org/10.1029/RF002p0001.
Srivastava, S., R. Snellings, V. Meynen, and P. Cool. 2021. “Siderite-calcite (FeCO3CaCO3) series cement formation by accelerated carbonation of CO2(g)-H2O-Fe-Ca(OH)2 systems.” Cem. Concr. Compos. 122 (Sep): 104137. https://doi.org/10.1016/j.cemconcomp.2021.104137.
Thong, C. C., D. C. L. Teo, and C. K. Ng. 2016. “Application of polyvinyl alcohol (PVA) in cement-based composite materials: A review of its engineering properties and microstructure behavior.” Constr. Build. Mater. 107 (Mar): 172–180. https://doi.org/10.1016/j.conbuildmat.2015.12.188.
Tong, Q., S. Zhou, Y. Guo, Y. Zhang, and X. Wei. 2019. “Forecast and analysis on reducing China’s CO2 emissions from lime industrial process.” Int. J. Environ. Res. Public Health 16 (3): 500. https://doi.org/10.3390/ijerph16030500.
Zhang, C., S. Zhang, J. Yu, and X. Kong. 2022. “Water absorption behavior of hydrophobized concrete using silane emulsion as admixture.” Cem. Concr. Res. 154 (Apr): 106738. https://doi.org/10.1016/j.cemconres.2022.106738.
Zhang, Z., S.-Y. Pan, H. Li, J. Cai, A. G. Olabi, E. J. Anthony, and V. Manovic. 2020. “Recent advances in carbon dioxide utilization.” Renewable Sustainable Energy Rev. 125 (Jun): 109799. https://doi.org/10.1016/j.rser.2020.109799.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 7July 2023

History

Received: Mar 3, 2022
Accepted: Nov 17, 2022
Published online: Apr 25, 2023
Published in print: Jul 1, 2023
Discussion open until: Sep 25, 2023

Permissions

Request permissions for this article.

Authors

Affiliations

Master’s Student, College of Mechanics and Materials, Hohai Univ., 8 Focheng Xilu, Nanjing 211100, PR China. Email: [email protected]
Associate Professor, College of Mechanics and Materials, Hohai Univ., 8 Focheng Xilu, Nanjing 211100, PR China (corresponding author). Email: [email protected]
Linhua Jiang [email protected]
Professor, College of Mechanics and Materials, Hohai Univ., 8 Focheng Xilu, Nanjing 211100, PR China. Email: [email protected]
Weizhun Jin [email protected]
Ph.D. Student, College of Mechanics and Materials, Hohai Univ., 8 Focheng Xilu, Nanjing 211100, PR China. Email: [email protected]
Mingzhi Guo [email protected]
Professor, College of Mechanics and Materials, Hohai Univ., 8 Focheng Xilu, Nanjing 211100, PR China. Email: [email protected]
Master’s Student, College of Mechanics and Materials, Hohai Univ., 8 Focheng Xilu, Nanjing 211100, PR China. Email: [email protected]
Guohui Yang [email protected]
Master’s Student, College of Mechanics and Materials, Hohai Univ., 8 Focheng Xilu, Nanjing 211100, PR China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share