Nonlinear Viscoelasticity and Viscoplasticity Characteristics of Virgin and Modified Asphalt Binders
Publication: Journal of Engineering Mechanics
Volume 149, Issue 10
Abstract
Many engineering materials have coupled nonlinear viscoelasticity and viscoplasticity, which are affected by complex thermomechanical loadings. This study addressed the challenge of accurately separating the viscoplasticity and the nonlinear viscoelasticity and formulated the viscoplasticity by considering the effects of temperatures and loading levels. First, the nonlinear viscoelastic constitutive equation was adopted to accurately separate the viscoplasticity and the nonlinear viscoelasticity. Then a kinetics-based viscoplastic model and a new viscoplastic activation energy indicator are proposed to consider the effects of the temperature and loading level on the viscoplasticity. As typical nonlinear viscoelastic viscoplastic materials commonly used in pavement engineering, asphalt binders were selected to demonstrate the principles in this study. It was found that the proportion of the viscoplastic strain is larger than the nonlinear viscoelastic strain for virgin asphalt binders (VBs) and it increases with the temperature, whereas the opposite is true for high-viscosity modified asphalt binders (HVBs) and rubber asphalt binders (RBs). The logarithm of the viscoplastic strain rate increases linearly with the reciprocal of the temperature, and the viscoplastic strain rates at different temperatures are correlated and can be predicted based on the established viscoplastic strain kinetics model. The viscoplastic activation energy indicator can characterize the viscoplastic deformation resistance for nonlinear viscoelastic viscoplastic materials, and the order of the viscoplastic deformation resistances of the three binders was , based on this indicator.
Practical Applications
This work presents a theoretical framework that clarifies the deformation characteristics of engineering materials. We separated the viscoplasticity and nonlinear viscoelasticity, and formulated a nonlinear viscoelastoplastic kinetics model for engineering materials by considering the effects of temperatures and loading levels. The developed model can reveal the deformation characteristics of asphalt binders at different temperatures and loading levels according to laboratory test results. Some calculated mechanical indicators of asphalt binders are inaccurate; we addressed this problem using the proposed model. Specifically, we employed the separated viscoplastic strain to improve the calculation accuracy of the nonrecoverable creep compliance and percentage recovery of asphalt binders. We adopted the proposed viscoplastic activation energy indicator to evaluate the viscoplastic deformation resistance of asphalt binders. Overall, we expect practitioners to use the framework to calculate relevant mechanical indicators more accurately and better evaluate the resistance to permanent deformation of engineering materials.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request including data of creep and recovery test under a low-stress level and a high-stress level.
Acknowledgments
This research was sponsored by National Key R&D Program of China under Grant No. 2019YFE0117600, Project 52108423 supported by National Natural Science Foundation of China, Zhejiang Provincial Natural Science Foundation of China under Grant No. LZ21E080002, Jiangsu Funding Program for Excellent Postdoctoral Talent, and Start-up Research Fund of Southeast University under Grant No. RF1028623231.
References
AASHTO. 2014. Standard method of test for multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR). AASHTO T 350-14. Washington, DC: AASHTO.
Bahia, H. U., D. I. Hanson, M. Zeng, H. Zhai, M. A. Khatri, and R. M. Anderson. 2001. Characterization of modified asphalt binders in Superpave mix design. NCHRP Rep. 459. Washigton, DC: National Cooperative Highway Research Program, Transportation Research Board.
Bamford, C. H., and C. F. H. Tipper. 1969. In Vol. 2 of Comprehensive chemical kinetics: The theory of kinetics. Amsterdam, Netherlands: Elsevier Scientific.
Brinson, H. F., and L. C. Brinson. 2008. Polymer engineering science and viscoelasticity: An introduction. New York: Springer.
D’Angelo, J., and R. Dongré. 2009. “Practical use of multiple stress creep and recovery test: Characterization of styrene–butadiene–styrene dispersion and other additives in polymer-modified asphalt binders.” Transp. Res. Rec. 2126 (1): 73–82. https://doi.org/10.3141/2126-09.
D’Angelo, J. A. 2009. “The relationship of the MSCR test to rutting.” Road Mater. Pavement Des. 10 (S1): 61–80. https://doi.org/10.1080/14680629.2009.9690236.
Delgadillo, R., H. U. Bahia, and R. Lakes. 2012. “A nonlinear constitutive relationship for asphalt binders.” Mater. Struct. 45 (3): 457–473. https://doi.org/10.1617/s11527-011-9777-y.
Kennedy, T. W., G. A. Huber, E. T. Harrigan, R. J. Cominsky, C. S. Hughes, H. Von Quintus, and J. S. Moulthrop. 1994. Superior performing asphalt pavements (Superpave): The product of the SHRP asphalt research program. Washington, DC: National Academy of Sciences.
Laukkanen, O.-V., H. Soenen, T. Pellinen, S. Heyrman, and G. Lemoine. 2015. “Creep-recovery behavior of bituminous binders and its relation to asphalt mixture rutting.” Mater. Struct. 48 (12): 4039–4053. https://doi.org/10.1617/s11527-014-0464-7.
Leng, Z., R. K. Padhan, and A. Sreeram. 2018a. “Production of a sustainable paving material through chemical recycling of waste PET into crumb rubber modified asphalt.” J. Cleaner Prod. 180 (Apr): 682–688. https://doi.org/10.1016/j.jclepro.2018.01.171.
Leng, Z., A. Sreeram, R. K. Padhan, and Z. Tan. 2018b. “Value-added application of waste PET based additives in bituminous mixtures containing high percentage of reclaimed asphalt pavement (RAP).” J. Cleaner Prod. 196 (Sep): 615–625. https://doi.org/10.1016/j.jclepro.2018.06.119.
Li, H., X. Luo, and Y. Zhang. 2021. “A kinetics-based model of fatigue crack growth rate in bituminous material.” Int. J. Fatigue 148 (Jul): 106185. https://doi.org/10.1016/j.ijfatigue.2021.106185.
Liu, H., W. Zeiada, G. G. Al-Khateeb, H. Ezzet, A. Shanableh, and M. Samarai. 2021. “Analysis of MSCR test results for asphalt binders with improved accuracy.” Mater. Struct. 54 (2): 1–14. https://doi.org/10.1617/s11527-021-01691-0.
Lu, W., X. Peng, S. Lv, Y. Yang, J. Wang, Z. Wang, and N. Xie. 2023. “High-temperature properties and aging resistance of rock asphalt ash modified asphalt based on rutting index.” Constr. Build. Mater. 363 (Jan): 129774. https://doi.org/10.1016/j.conbuildmat.2022.129774.
Luo, X., B. Birgisson, and R. L. Lytton. 2020a. “Kinetics of healing of asphalt mixtures.” J. Cleaner Prod. 252 (Apr): 119790. https://doi.org/10.1016/j.jclepro.2019.119790.
Luo, X., F. Gu, and R. L. Lytton. 2015. “Prediction of field aging gradient in asphalt pavements.” Transp. Res. Rec. 2507 (1): 19–28. https://doi.org/10.3141/2507-03.
Luo, X., F. Gu, and R. L. Lytton. 2019. “Kinetics-based aging prediction of asphalt mixtures using field deflection data.” Int. J. Pavement Eng. 20 (3): 287–297. https://doi.org/10.1080/10298436.2017.1293262.
Luo, X., F. Gu, Y. Zhang, R. L. Lytton, and B. Birgisson. 2018. “Kinetics-based aging evaluation of in-service recycled asphalt pavement.” J. Cleaner Prod. 200 (Nov): 934–944. https://doi.org/10.1016/j.jclepro.2018.07.267.
Luo, X., H. Li, Y. Deng, and Y. Zhang. 2020b. “Energy-Based kinetics approach for coupled viscoplasticity and viscofracture of asphalt mixtures.” J. Eng. Mech. 146 (9): 04020100. https://doi.org/10.1061/(ASCE)EM.1943-7889.0001836.
Masad, E. A., C. W. Huang, J. DAngelo, and D. N. Little. 2009. “Characterization of asphalt binder resistance to permanent deformation based on nonlinear viscoelastic analysis of multiple stress creep recovery (MSCR) test.” J. Assoc. Asphalt Paving Technol. 78 (Jun): 535–566.
Morea, F., J. O. Agnusdei, and R. Zerbino. 2011. “The use of asphalt low shear viscosity to predict permanent deformation performance of asphalt concrete.” Mater. Struct. 44 (7): 1241–1248. https://doi.org/10.1617/s11527-010-9696-3.
Nivitha, M. R., S. P. A. Narayan, and J. M. Krishnan. 2018. “Non-linear viscoelastic model based ranking of modified binders for their rutting performance.” Mater. Struct. 51 (4): 1–14. https://doi.org/10.1617/s11527-018-1227-7.
Padhan, R. K., Z. Leng, A. Sreeram, and X. Xu. 2020. “Compound modification of asphalt with styrene-butadiene-styrene and waste polyethylene terephthalate functionalized additives.” J. Cleaner Prod. 277 (Dec): 124286. https://doi.org/10.1016/j.jclepro.2020.124286.
Perzyna, P. 1966. “Fundamental problems in viscoplasticity.” Adv. Appl. Mech. 9 (Jan): 243–377. https://doi.org/10.1016/S0065-2156(08)70009-7.
Sadeq, M., E. Masad, H. Al-Khalid, O. Sirin, and L. Mehrez. 2018. “Linear and nonlinear viscoelastic and viscoplastic analysis of asphalt binders with warm mix asphalt additives.” Int. J. Pavement Eng. 19 (10): 857–864. https://doi.org/10.1080/10298436.2016.1213592.
Schapery, R. A. 1966. A theory of non-linear thermoviscoelasticity based on irreversible thermodynamics, 511–530. New York: American Society of Mechanical Engineers.
Schapery, R. A. 1969. “On the characterization of nonlinear viscoelastic materials.” Polym. Eng. Sci. 9 (4): 295–310. https://doi.org/10.1002/pen.760090410.
Shirodkar, P., Y. Mehta, A. Nolan, K. Dahm, R. Dusseau, and L. McCarthy. 2012. “Characterization of creep and recovery curve of polymer modified binder.” Constr. Build. Mater. 34 (Sep): 504–511. https://doi.org/10.1016/j.conbuildmat.2012.02.018.
Shirzad, S., I. I. Idris, M. Hassan, and L. N. Mohammad. 2023. “Self-healing capability and mechanical properties of asphalt mixtures prepared with light-activated polyurethane prepolymer modified asphalt binder.” Transp. Res. Rec. 2677 (1): 03611981221138522. https://doi.org/10.1177/03611981221138522.
Singh, B., and P. Kumar. 2022. “Rutting and fatigue performance of aged modified asphalt binders.” Int. J. Pavement Res. Technol. 15 (4): 789–802. https://doi.org/10.1007/s42947-021-00053-x.
Sun, Y., J. Chen, B. Huang, J. Liu, W. Wang, and B. Xu. 2020. “Novel procedure for accurately characterizing nonlinear viscoelastic and irrecoverable behaviors of asphalt binders.” Int. J. Geomech. 20 (3): 04019198. https://doi.org/10.1061/(ASCE)GM.1943-5622.0001582.
Sybilski, D. 1996. “Zero-shear viscosity of bituminous binder and its relation to bituminous mixture’s rutting resistance.” Transp. Res. Rec. 1535 (1): 15–21. https://doi.org/10.1177/0361198196153500103.
Tabatabaee, N., and H. A. Tabatabaee. 2010. “Multiple stress creep and recovery and time sweep fatigue tests: Crumb rubber modified binder and mixture performance.” Transp. Res. Rec. 2180 (1): 67–74. https://doi.org/10.3141/2180-08.
Tsantilis, L., S. B. Underwood, F. Miglietta, P. P. Riviera, O. Baglieri, and E. Santagata. 2021. “Ageing effects on the linear and nonlinear viscoelasticity of bituminous binders.” Road Mater. Pavement Des. 22 (S1): S37–S50. https://doi.org/10.1080/14680629.2021.1908406.
Walubita, L. F., M. Ling, L. M. R. Pianeta, L. Fuentes, J. J. Komba, and G. M. Mabrouk. 2022. “Correlating the asphalt-binder MSCR test results to the HMA HWTT and field rutting performance.” J. Transp. Eng. Part B Pavements 148 (3): 04022047. https://doi.org/10.1061/JPEODX.000038.
Zhang, Y., B. Birgisson, and R. L. Lytton. 2016. “Weak form equation–based finite-element modeling of viscoelastic asphalt mixtures.” J. Mater. Civ. Eng. 28 (2): 04015115. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001395.
Information & Authors
Information
Published In
Copyright
© 2023 American Society of Civil Engineers.
History
Received: Jan 7, 2023
Accepted: May 1, 2023
Published online: Jul 27, 2023
Published in print: Oct 1, 2023
Discussion open until: Dec 27, 2023
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.