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Research Article
Aug 1981

Halogenated Byproduct Formation by ClO2 and Cl2

Publication: Journal of the Environmental Engineering Division
Volume 107, Issue 4

Abstract

The formation of halogenated organic byproducts, resulting from treating wastewater effluents with chlorine dioxide and chlorine, was studied in laboratory experiments. Total trihalomethanes (TTHM) and total organic halogen (TOX) were measured as criteria for halogenated organic byproduct formation. Chlorine dioxide and chlorine were compared at equal mass doses. Two wastewater effluents were studied—one containing substantial amounts of ammonia nitrogen and another containing less. Chlorine formed significant amounts of halogenated organics in both effluents. The amount of TOX produced by chlorine corresponded to 5 to 20 times the halogen content indicated by TTHM determinations.

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Journal of the Environmental Engineering Division
Volume 107Issue 4August 1981
Pages: 609 - 618

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Published in print: Aug 1981
Published online: Feb 11, 2021

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Bruce M. Chow
Engr., James M. Montgomery, Consulting Engrs., Inc., 555 East Walnut Street, Pasadena, Calif. 91101
Paul V. Roberts, M.ASCE
Adjunct Prof., Dept. of Civ. Engrg., Stanford Univ., Stanford, Calif. 94305

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