Technical Papers
Jan 27, 2023

Strength, Deformation Behavior, and Microstructure of Cement Paste Backfill with Calcium Chloride in Subzero Environments

Publication: Journal of Cold Regions Engineering
Volume 37, Issue 2

Abstract

This manuscript presents and discusses the results of an experimental study on the deformation behavior, strength, and microstructural development of cemented paste backfill (CPB) with chloride-bearing antifreeze (calcium chloride, CaCl2) in subzero environments. CPB samples with CaCl2 at various concentrations (0, 5, 15, and 35 g/L) were cured at different subzero temperatures (−1, −6, and −12°C) that represent temperatures to which CPBs may be exposed in mines located in permafrost or cold regions. Unconfined compressive strength (UCS) tests were conducted after specific curing time (7, 28, 60, and 90 days). Moreover, microstructural analyses and monitoring experiments (for volumetric water content and matric suction) were performed. The results showed that the addition of calcium chloride antifreeze reduced the strength of CPB and had a significant impact on its stress–strain behavior and microstructural characteristics. Furthermore, it was also found that the strength of CPB decreased with an increase of calcium chloride concentration and subzero curing temperature. These findings provide important guidance for mine backfilling work of CPB with chloride-bearing antifreeze additives and productivity improvement in subzero environments.

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Acknowledgments

The authors gratefully acknowledge the support of the Natural Sciences and Engineering Research Council of Canada (NSERC), China Scholarship Council, and the University of Ottawa.

References

Alarcon-Ruiz, L., G. Platret, E. Massieu, and A. Ehrlacher. 2005. “The use of thermal analysis in assessing the effect of temperature on a cement paste.” Cem. Concr. Res. 35 (3): 609–613. https://doi.org/10.1016/j.cemconres.2004.06.015.
Ali, G., M. Fall, and I. Alainachi. 2021. “Time-and temperature-dependence of rheological properties of cemented tailings backfill with sodium silicate.” J. Mater. Civ. Eng. 33 (3): 04020498. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003605.
Alzaza, A., K. Ohenoja, I. Langås, B. Arntsen, M. Poikelispää, and M. Illikainen. 2022. “Low-temperature (−10°C) curing of Portland cement paste—Synergetic effects of chloride-free antifreeze admixture, C–S–H seeds, and room-temperature pre-curing.” Cem. Concr. Compos. 125: 104319. https://doi.org/10.1016/j.cemconcomp.2021.104319.
Arakawa, M., and N. Maeno. 1997. “Mechanical strength of polycrystalline ice under uniaxial compression.” Cold Reg. Sci. Technol. 26 (3): 215–229. https://doi.org/10.1016/S0165-232X(97)00018-9.
Banin, A., and D. M. Anderson. 1974. “Effects of salt concentration changes during freezing on the unfrozen water content of porous materials.” Water Resour. Res. 10 (1): 124–128. https://doi.org/10.1029/WR010i001p00124.
Behera, S. K., C. N. Ghosh, D. P. Mishra, P. Singh, K. Mishra, J. Buragohain, and P. K. Mandal. 2020. “Strength development and microstructural investigation of lead-zinc mill tailings based paste backfill with fly ash as alternative binder.” Cem. Concr. Compos. 109: 103553. https://doi.org/10.1016/j.cemconcomp.2020.103553.
Cao, S., E. Yilmaz, Z. Yin, G. Xue, W. Song, and L. Sun. 2021. “CT scanning of internal crack mechanism and strength behavior of cement-fiber-tailings matrix composites.” Cem. Concr. Compos. 116: 103865. https://doi.org/10.1016/j.cemconcomp.2020.103865.
Cao, W., Y. Sheng, Y. Qin, J. Li, and J. Wu. 2011. “An application of a new method in permafrost environment assessment of Muli mining area in Qinghai-Tibet Plateau, China.” Environ. Earth Sci. 63 (3): 609–616. https://doi.org/10.1007/s12665-010-0728-7.
Chamberlain, E. 1983. “Frost heave of saline soils.” In Proc., 4th Int. Conf., on Permafrost, 121–126. Washington, DC: National Academy Press.
Chang, S., and M. Fall. 2022. “Strength, microstructure and deformation behavior of frozen cemented tailings materials.” J. Cold Reg. Eng. 36 (1): 04021017. https://doi.org/10.1061/(ASCE)CR.1943-5495.0000265.
Chatterji, S. 1999. “Aspects of the freezing process in a porous material–water system: Part 1. Freezing and the properties of water and ice.” Cem. Concr. Res. 29 (4): 627–630. https://doi.org/10.1016/S0008-8846(99)00035-6.
Chatterji, S. 2003. “Freezing of air-entrained cement-based materials and specific actions of air-entraining agents.” Cem. Concr. Compos. 25 (7): 759–765. https://doi.org/10.1016/S0958-9465(02)00099-9.
Dharmawardhana, C. C., A. Misra, S. Aryal, P. Rulis, and W. Y. Ching. 2013. “Role of interatomic bonding in the mechanical anisotropy and interlayer cohesion of CSH crystals.” Cem. Concr. Res. 52: 123–130. https://doi.org/10.1016/j.cemconres.2013.05.009.
Ercikdi, B., T. Yılmaz, and G. Külekci. 2014. “Strength and ultrasonic properties of cemented paste backfill.” Ultrasonics 54 (1): 195–204. https://doi.org/10.1016/j.ultras.2013.04.013.
Fall, M., D. Adrien, J. C. Celestin, M. Pokharel, and M. Touré. 2009. “Saturated hydraulic conductivity of cemented paste backfill.” Miner. Eng. 22 (15): 1307–1317. https://doi.org/10.1016/j.mineng.2009.08.002.
Fall, M., J. Célestin, and H. F. Sen. 2010a. “Potential use of densified polymer-pastefill mixture as waste containment barrier materials.” Waste Manage. (Oxford) 30 (12): 2570–2578. https://doi.org/10.1016/j.wasman.2010.07.016.
Fall, M., J. C. Célestin, M. Pokharel, and M. Touré. 2010b. “A contribution to understanding the effects of curing temperature on the mechanical properties of mine cemented tailings backfill.” Eng. Geol. 114 (3): 397–413. https://doi.org/10.1016/j.enggeo.2010.05.016.
Falmagne, V., and N. St-Onge. 2019. “Ground support challenges in Arctic mining conditions.” In Proc., 9th Int. Symp. on Ground Support in Mining and Underground Construction, 139–154. Crawley, Western Australia: Australian Centre for Geomechanics.
Fang, K., and M. Fall. 2018. “Effects of curing temperature on shear behavior of cemented paste backfill-rock interface.” Int. J. Rock Mech. Min. Sci. 112: 184–192. https://doi.org/10.1016/j.ijrmms.2018.10.024.
Gabrovšek, R., T. Vuk, and V. Kaučič. 2006. “Evaluation of the hydration of Portland cement containing various carbonates by means of thermal analysis.” Acta Chim. Slov. 53: 159–165.
Hajkowicz, S. A., S. Heyenga, and K. Moffat. 2011. “The relationship between mining and socio-economic well being in Australia’s regions.” Resour. Policy 36 (1): 30–38. https://doi.org/10.1016/j.resourpol.2010.08.007.
Haruna, S., and M. Fall. 2021. “Strength development of cemented tailings materials containing polycarboxylate ether-based superplasticizer: Experimental results on the effect of time and temperature.” Can. J. Civ. Eng. 48 (4): 429–442. https://doi.org/10.1139/cjce-2019-0809.
Hassani, F., and J. Archibald. 1998. Mine backfill, CD-Rom. Montreal: Canadian Institute of Mine, Metallurgy and Petroleum.
Hassani, F., M. Scoble, and T. Yu. 2021. Innovations in mining backfill technology. Boca Raton, FL: CRC Press.
Hivon, E. G., and D. C. Sego. 1995. “Strength of frozen saline soils.” Can. Geotech. J. 32 (2): 336–354. https://doi.org/10.1139/t95-034.
Hivon, E.G. 1993. Behavior of saline frozen soils. Ph.D. Dissertation, Dept. of Civil Engineering, Univ. of Alberta, Edmonton, Canada.
Hou, C., W. Zhu, B. Yan, K. Guan, and J. Du. 2020. “The effects of temperature and binder content on the behavior of frozen cemented tailings backfill at early ages.” Constr. Build. Mater. 239: 117752. https://doi.org/10.1016/j.conbuildmat.2019.117752.
Jiang, H., and M. Fall. 2017a. “Yield stress and strength of saline cemented tailings in sub-zero environments: Portland cement paste backfill.” Int. J. Miner. Process. 160: 68–75. https://doi.org/10.1016/j.minpro.2017.01.010.
Jiang, H., and M. Fall. 2017b. “Yield stress and strength of saline cemented tailings in sub-zero environments: Portland cement paste backfill.” Int. J. Miner. Process. 160: 68–75. https://doi.org/10.1016/j.minpro.2017.01.010.
Jiang, H. Q., and M. Fall. 2017c. “Yield stress and strength of saline cemented tailings materials in sub-zero environments: Slag-paste backfill.” J. Sustain. Cem-Based 6 (5): 314–331.
Jiang, H., M. Fall, and L. Cui. 2016. “Yield stress of cemented paste backfill in sub-zero environments: Experimental results.” Miner. Eng. 92: 141–150. https://doi.org/10.1016/j.mineng.2016.03.014.
Jiang, H., M. Fall, and L. Cui. 2017. “Freezing behavior of cemented paste backfill material in column experiments.” Constr. Build. Mater. 147: 837–846. https://doi.org/10.1016/j.conbuildmat.2017.05.002.
Jiang, H., M. Fall, Y. Li, and J. Han. 2019. “An experimental study on compressive behavior of cemented rockfill.” Constr. Build. Mater. 213: 10–19. https://doi.org/10.1016/j.conbuildmat.2019.04.061.
John, M., M. Suominen, O.-V. Sormunen, M. Hasan, E. Kurvinen, P. Kujala, A. Mikkola, and M. Louhi-Kultanen. 2018. “Purity and mechanical strength of naturally frozen ice in wastewater basins.” Water Res. 145: 418–428. https://doi.org/10.1016/j.watres.2018.08.063.
Joshi, R. C., and H. Wijeweera. 1990. “Post peak axial compressive strength and deformation behavior of fine-grained frozen soils.” In Proc., 5th Canadian Permafrost Conf., 317–325. Quebec: Centre d'études Nordiques, University of Laval.
Juenger, M. C. G., P. J. M. Monteiro, E. M. Gartner, and G. P. Denbeaux. 2005. “A soft X-ray microscope investigation into the effects of calcium chloride on tricalcium silicate hydration.” Cem. Concr. Res. 35 (1): 19–25. https://doi.org/10.1016/j.cemconres.2004.05.016.
Karlsson, J. O. M., E. G. Cravalho, and M. Toner. 1994. “A model of diffusion-limited ice growth inside biological cells during freezing.” J. Appl. Phys. 75 (9): 4442–4455. https://doi.org/10.1063/1.355959.
Kesimal, A., E. Yilmaz, and B. Ercikdi. 2004. “Evaluation of paste backfill mixtures consisting of sulphide-rich mill tailings and varying cement contents.” Cem. Concr. Res. 34 (10): 1817–1822. https://doi.org/10.1016/j.cemconres.2004.01.018.
Li, W., and M. Fall. 2018. “Strength and self-desiccation of slag-cemented paste backfill at early ages: Link to initial sulphate concentration.” Cem. Concr. Compos. 89: 160–168. https://doi.org/10.1016/j.cemconcomp.2017.09.019.
Li, Z., F. Hu, S. Qi, and R. Hu. 2020. “Strain-softening failure mode after the post-peak as a unique mechanism of ruptures in a frozen soil-rock mixture.” Eng. Geol. 274: 105725. https://doi.org/10.1016/j.enggeo.2020.105725.
Liu, L., Z. Fang, M. Wang, C. Qi, Y. Zhao, and C. Huan. 2020. “Experimental and numerical study on rheological properties of ice-containing cement paste backfill slurry.” Powder Technol. 370: 206–214. https://doi.org/10.1016/j.powtec.2020.05.024.
McIntosh, J. D. 1956. “The effects of low-temperature curing on the compressive strength of concrete. Gen. Report of Session BII.” In Proc., of RILEM Symp. Winter Concreting, Danish Institute for Building Research Copenhagen. Cogenhagen, Danemark: Danish National Institute of Building Research.
Ogata, N., M. Yasuda, and T. Kataoka. 1983. “Effects of salt concentration on strength and creep behavior of artificially frozen soils.” Cold Reg. Sci. Technol. 8 (2): 139–153. https://doi.org/10.1016/0165-232X(83)90005-8.
Orejarena, L., and M. Fall. 2008. “Mechanical response of a mine composite material to extreme heat.” Bull. Eng. Geol. Environ. 67 (3): 387–396. https://doi.org/10.1007/s10064-008-0148-z.
Pharr, G. M., and J. E. Merwin. 1985. “Effects of brine content on the strength of frozen Ottawa sand.” Cold Reg. Sci. Technol. 11 (3): 205–212. https://doi.org/10.1016/0165-232X(85)90044-8.
Powers, T. C., and R. Helmuth. 1953. “Theory of volume changes in hardened Portland-cement paste during freezing.” In Proc., Highway Research Board. Washington, DC: Transportation Research Board of the National Academy of Sciences, National Academy of Sciences.
Qi, C., and A. Fourie. 2019. “Cemented paste backfill for mineral tailings management: Review and future perspectives.” Miner. Eng. 144: 106025. https://doi.org/10.1016/j.mineng.2019.106025.
Raoult, F.-M. 1887. “Loi générale des tensions de vapeur des dissolvants.” CR Hebd. Seances Acad. Sci. 104: 1430–1433.
Richardson, I. G. 1999. “The nature of CSH in hardened cements.” Cem. Concr. Res. 29 (8): 1131–1147. https://doi.org/10.1016/S0008-8846(99)00168-4.
Roshani, A., and M. Fall. 2020. “Rheological properties of cemented paste backfill with nano-silica: Link to curing temperature.” Cem. Concr. Compos. 114: 103785. https://doi.org/10.1016/j.cemconcomp.2020.103785.
Sellevold, E. J., and T. Farstad. 1991. “Frost/salt-testing of concrete: Effect of test parameters and concrete moisture history.” In Freeze–thaw and deicing resistance of concrete, research seminar held in Lund, edited by G. Fagerlund, and M. J. Setzer, 83–100. Oslo, Norway: Norwegian Institute of Technology.
Taylor, H. 1990. Cement chemistry. London: Academic Press.
Tian, X., and M. Fall. 2021. “Non-isothermal evolution of mechanical properties, pore structure and self-desiccation of cemented paste backfill.” Constr. Build. Mater. 297: 123657. https://doi.org/10.1016/j.conbuildmat.2021.123657.
Timco, G. W., and W. F. Weeks. 2010. “A review of the engineering properties of sea ice.” Cold Reg. Sci. Technol. 60 (2): 107–129. https://doi.org/10.1016/j.coldregions.2009.10.003.
Ting, J. M., R. Torrence Martin, and C. C. Ladd. 1983. “Mechanisms of strength for frozen sand.” J. Geotech. Eng. 109 (10): 1286–1302. https://doi.org/10.1061/(ASCE)0733-9410(1983)109:10(1286).
Verbeck, G., and P. Klieger. 1958. “Calorimeter-strain apparatus for study of freezing and thawing concrete Highw.” Res. Board Bull. 176: 9–22.
von Helmholtz, R. 1886. “Untersuchungen über Dämpfe und Nebel, besonders über solche von Lösungen.” Annalen der Physik und Chemie 263 (4): 508–543. https://doi.org/10.1002/andp.18862630403.
Wijeweera, H., and R. C. Joshi. 1990. “Compressive strength behavior of fine-grained frozen soils.” Can. Geotech. J. 27 (4): 472–483. https://doi.org/10.1139/t90-062.
Wu, D., M. Fall, and S.-j. Cai. 2012. “Coupled modeling of temperature distribution and evolution in cemented tailings backfill structures that contain mineral admixtures.” Geotech. Geol. Eng. 30 (4): 935–961. https://doi.org/10.1007/s10706-012-9518-1.
Xiapeng, P., M. Fall, and S. Haruna. 2019. “Sulphate induced changes of rheological properties of cemented paste backfill.” Miner. Eng. 141: 105849. https://doi.org/10.1016/j.mineng.2019.105849.
Xu, W., W. Chen, M. Tian, and L. Guo. 2021. “Effect of temperature on time-dependent rheological and compressive strength of fresh cemented paste backfill containing flocculants.” Constr. Build. Mater. 267: 121038. https://doi.org/10.1016/j.conbuildmat.2020.121038.
Xu, W., M. Tian, and Q. Li. 2020a. “Time-dependent rheological properties and mechanical performance of fresh cemented tailings backfill containing flocculants.” Miner. Eng. 145: 106064. https://doi.org/10.1016/j.mineng.2019.106064.
Xu, W., Y. Zhang, X. Zuo, and M. Hong. 2020b. “Time-dependent rheological and mechanical properties of silica fume modified cemented tailings backfill in low temperature environment.” Cem. Concr. Compos. 114: 103804. https://doi.org/10.1016/j.cemconcomp.2020.103804.
Yilmaz, E., and M. Fall. 2017. Paste tailings management. New York: Springer Cham.
Yoshikawa, K., and P. P. Overduin. 2005. “Comparing unfrozen water content measurements of frozen soil using recently developed commercial sensors.” Cold Reg. Sci. Technol. 42 (3): 250–256. https://doi.org/10.1016/j.coldregions.2005.03.001.
Zhang, G., Y. Yang, H. Yang, and H. Li. 2020. “Calcium sulphoaluminate cement used as mineral accelerator to improve the property of Portland cement at sub-zero temperature.” Cem. Concr. Compos. 106: 103452. https://doi.org/10.1016/j.cemconcomp.2019.103452.
Zhao, Y., A. Taheri, M. Karakus, Z. Chen, and A. Deng. 2020. “Effects of water content, water type and temperature on the rheological behavior of slag-cement and fly ash-cement paste backfill.” Int. J. Min. Sci. Technol. 30 (3): 271–278. https://doi.org/10.1016/j.ijmst.2020.03.003.
Zhou, X., J. Zhou, W. Kinzelbach, and F. Stauffer. 2014. “Simultaneous measurement of unfrozen water content and ice content in frozen soil using gamma ray attenuation and TDR.” Water Resour. Res. 50: 9630–9655. https://doi.org/10.1002/2014WR015640.
Zhou, Y., M. Fall, and S. Haruna. 2022. “Flow ability of cemented paste backfill with chloride-free antifreeze additives in sub-zero environments.” Cem. Concr. Compos. 126: 104359. https://doi.org/10.1016/j.cemconcomp.2021.104359.

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Journal of Cold Regions Engineering
Volume 37Issue 2June 2023

History

Received: May 27, 2022
Accepted: Nov 16, 2022
Published online: Jan 27, 2023
Published in print: Jun 1, 2023
Discussion open until: Jun 27, 2023

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Ph.D. Student, Dept. of Civil Engineering, Univ. of Ottawa, 161 Louis Pasteur, Ottawa K1N 6N5; Canada and School of Energy and Mining Engineering, China Univ. of Mining and Technology (Beijing), Beijing 100083, China. Email: [email protected]
Mamadou Fall [email protected]
Full Professor and Chair, Dept. of Civil Engineering, Univ. of Ottawa, 161 Louis Pasteur, Ottawa K1N 6N5, ON, Canada (corresponding author). Email: [email protected]

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