Technical Papers
Mar 26, 2024

Effect of Curing Temperature on the Strength Development of Magnesium Oxychloride Cement–Solidified Clay

Publication: International Journal of Geomechanics
Volume 24, Issue 6

Abstract

Magnesium oxychloride cement (MOC) is an environment-friendly cement often used for stabilizing soft soils because of its exceptional mechanical properties. In this study, the influence of curing temperature on the strength development of MOC-solidified clay is explored, considering different MgO/MgCl2 molar ratios. Different tests were carried out to study the corresponding effects. The results show that the effect of curing temperature on the strength of MOC-solidified clay differs greatly from that of cement-solidified soil. Increasing the curing temperature leads to strength reduction, whereas decreasing the curing temperature increases the corresponding strength. Scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses indicate that the variation in type and amount of hydration products of the solidified soil account for the strength development difference between MOC-solidified and cement-solidified soils. A model based on the experimental results is proposed to characterize the relationship between strength development and curing time. The strength influence factor (ηT) and the strength expedite factor (K) were introduced to demonstrate the relationship between strength development at a specific curing temperature as well as at room temperature.

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Data Availability Statement

All data, models, and codes generated or used during the study appear in the published article.

Acknowledgments

The authors gratefully acknowledge the National Natural Science Foundation of China (Grant Nos. 52009049 and 51709129).

References

Abdelli, K., W. Deboucha, N. Leklou, U. J. Alengaram, and M. N. Oudjit. 2022. “Effect of curing temperature on the early and later ages behaviour of Metakaolin blended cement mortars: Hydration heat and compressive strength.” Aust. J. Civil Eng. https://doi.org/10.1080/14488353.2022.2131949.
Aiken, T. A., M. Russell, D. McPolin, and L. Bagnall. 2020. “Magnesium oxychloride boards: Understanding a novel building material.” Mater. Struct. 53 (5): 118. https://doi.org/10.1617/s11527-020-01547-z.
Bi, J., and S. C. Chian. 2021. “Modelling strength development of cement-stabilised clay and clay with sand impurity cured under varying temperatures.” Bull. Eng. Geol. Environ. 80 (8): 6275–6302. https://doi.org/10.1007/s10064-021-02281-8.
Cai, G., and S. Liu. 2017. “Compaction and mechanical characteristics and stabilization mechanism of carbonated reactive MgO-stabilized silt.” KSCE J. Civ. Eng. 21 (7): 2641–2654. https://doi.org/10.1007/s12205-017-1145-1.
Cao, Y. P., J. Zhang, Z. F. Zhao, J. X. Liu, and H. Lin. 2022. “Strength properties of cement-solidified dredged sludge affected by curing temperature.” Buildings 12 (11): 1889. https://doi.org/10.3390/buildings12111889.
Chen, C. F., S. Q. Wei, and H. Cai. 2023. “Effect of temperature change on mechanical properties of cement soil.” [In Chinese.] J. Railway Sci. Eng. 20 (1): 1–13.
Chitambira, B. 2004. Accelerated ageing of cement stabilised/solidified contaminated soils with elevated temperatures. Cambridge, UK: University of Cambridge.
Chitambira, B., A. Al-Tabbaa, A. S. R. Perera, and X. D. Yu. 2007. “The activation energy of stabilised/solidified contaminated soils.” J. Hazard. Mater. 141 (2): 422–429. https://doi.org/10.1016/j.jhazmat.2006.05.080.
Deng, D., and Z. Chuanmei. 1999. “The formation mechanism of the hydrate phases in magnesium oxychloride cement.” Cem. Concr. Res. 29 (9): 1365–1371. https://doi.org/10.1016/S0008-8846(98)00247-6.
Guo, Y., Y. Zhang, K. Soe, and M. Pulham. 2018. “Recent development in magnesium oxychloride cement.” Struct. Concr. 19 (5): 1290–1300. https://doi.org/10.1002/suco.201800077.
Jianli, M., Z. Youcai, W. Jinmei, and W. Li. 2010. “Effect of magnesium oxychloride cement on stabilization/solidification of sewage sludge.” Constr. Build. Mater. 24 (1): 79–83. https://doi.org/10.1016/j.conbuildmat.2009.08.011.
Jirickova, A., M. Lojka, A. M. Lauermannova, F. Antonacik, D. Sedmidubsky, M. Pavlikova, M. Zaleska, Z. Pavlik, and O. Jankovsky. 2020. “Synthesis, structure, and thermal stability of magnesium oxychloride 5Mg(OH)2·MgCl2·8H2O.” Appl. Sci.-Basel 10 (5): 1683. https://doi.org/10.3390/app1005168310.
Li, C., and H. Yu. 2010. “Influence of fly ash and silica fume on water-resistant property of magnesium oxychloride cement.” J. Wuhan Univ. Technol.-Mater. Sci. Ed. 25 (4): 721–724. https://doi.org/10.1007/s11595-010-0079-y.
Li, Y., H. Yu, L. Zheng, J. Wen, C. Wu, and Y. Tan. 2013. “Compressive strength of fly ash magnesium oxychloride cement containing granite wastes.” Constr. Build. Mater. 38: 1–7. https://doi.org/10.1016/j.conbuildmat.2012.06.016.
Liu, W. H., Y. Sun, J. C. Zhang, W. G. Li, L. Wang, J. H. Yu, and X. H. Qin. 2023. “Influence of H2O/MgCl2 molar ratio on strength properties of the magnesium oxychloride cement solidified soft clay and its associated mechanisms.” Constr. Build. Mater. 393 (22): 132018. https://doi.org/10.1016/j.conbuildmat.2023.132018.
Liu, Z., M. Balonis, J. Huang, A. Sha, and G. Sant. 2017. “The influence of composition and temperature on hydrated phase assemblages in magnesium oxychloride cements.” J. Am. Ceram. Soc. 100 (7): 3246–3261. https://doi.org/10.1111/jace.14817.
MTC (Ministry of Transport of China). 2009. Test methods of materials stabilized with inorganic binders of highway engineering. [In Chinese.] JTG E51-2009. National Standards of People’s Republic of China. Beijing: China Communications Press.
Sglavo, V. M., F. De Genua, A. Conci, R. Ceccato, and R. Cavallini. 2011. “Influence of curing temperature on the evolution of magnesium oxychloride cement.” J. Mater. Sci. 46 (20): 6726–6733. https://doi.org/10.1007/s10853-011-5628-z.
Singh, A., R. Kumar, and P. Goel. 2021. “Factors influencing strength of magnesium oxychloride cement.” Constr. Build. Mater. 303: 124571. https://doi.org/10.1016/j.conbuildmat.2021.124571.
Tremblay, H., S. Leroueil, and J. Locat. 2001. “Mechanical improvement and vertical yield stress prediction of clayey soils from eastern Canada treated with lime or cement.” Can. Geotech. J. 38 (3): 567–579. https://doi.org/10.1139/t00-119.
Voottipruex, P., C. Teerawattanasuk, W. Sramoon, and I. Meepon. 2022. “Stabilization of soft clay using perlite geopolymer activated by sodium hydroxide.” Int. J. Geosynth. Ground Eng. 8 (1): 8. https://doi.org/10.1007/s40891-022-00350-w.
Walling, S. A., and J. L. Provis. 2016. “Magnesia-based cements: A journey of 150 years, and cements for the future?” Chem. Rev. 116 (7): 4170–4204. https://doi.org/10.1021/acs.chemrev.5b00463.
Wang, D. X., Z. G. Chen, and X. Y. Gao. 2022. “Sustainable improvement of magnesium oxychloride cement solidified waste sludge with fly-ash inclusion.” J. Mater. Civ. Eng. 34 (12).
Wang, D. X., S. J. Di, X. Y. Gao, R. H. Wang, and Z. G. Chen. 2020. “Strength properties and associated mechanisms of magnesium oxychloride cement–solidified urban river sludge.” Constr. Build. Mater. 250 (30): 118933.
Wang, D. X., X. Y. Gao, X. Q. Liu, and G. Zeng. 2021. “Strength, durability and microstructure of granulated blast furnace slag-modified magnesium oxychloride cement solidified waste sludge.” J. Cleaner Prod. 292 (10): 126072.
Wang, D. X., D. Yang, and Y. Yuan. 2023. “Strength improvement and micromechanism of inorganic/organic additive-modified magnesium oxychloride cement solidified sludge.” Constr. Build. Mater. 366 (22): 130159.
Wang, D. X., R. Zentar, and N. E. Abriak. 2017a. “Temperature-accelerated strength development in stabilized marine soils as road construction materials.” J. Mater. Civ. Eng. 29 (5): 12.
Wang, L., T. L. K. Yeung, A. Y. T. Lau, D. C. W. Tsang, and C.-S. Poon. 2017b. “Recycling contaminated sediment into eco-friendly paving blocks by a combination of binary cement and carbon dioxide curing.” J. Cleaner Prod. 164: 1279–1288. https://doi.org/10.1016/j.jclepro.2017.07.070.
Xu, B., H. Ma, C. Hu, S. Yang, and Z. Li. 2016. “Influence of curing regimes on mechanical properties of magnesium oxychloride cement–based composites.” Constr. Build. Mater. 102: 613–619. https://doi.org/10.1016/j.conbuildmat.2015.10.205.
Yang, P., X. Huang, J. Pi, and J. Yang. 2016. “Study on new cementitious materials used for pile and stabilized soil in super saline soil.” Jpn. Geotech. Soc. Spec. Publ. 2: 2111–2114. https://doi.org/10.3208/jgssp.CHN-33.
Yao, K., W. Wang, N. Li, C. Zhang, and L. Wang. 2019. “Investigation on strength and microstructure characteristics of nano-MgO admixed with cemented soft soil.” Constr. Build. Mater. 206: 160–168. https://doi.org/10.1016/j.conbuildmat.2019.01.221.
Ye, Q., W. Wang, W. Zhang, J. Li, and H. Chen. 2018. “Tuning the phase structure and mechanical performance of magnesium oxychloride cements by curing temperature and H2O/MgCl2 ratio.” Constr. Build. Mater. 179: 413–419. https://doi.org/10.1016/j.conbuildmat.2018.05.257.
Yi, Y., L. Gu, S. Liu, and F. Jin. 2016a. “Magnesia reactivity on activating efficacy for ground granulated blastfurnace slag for soft clay stabilisation.” Appl. Clay Sci. 126: 57–62. https://doi.org/10.1016/j.clay.2016.02.033.
Yi, Y., M. Liska, F. Jin, and A. Al-Tabbaa. 2016b. “Mechanism of reactive magnesia—ground granulated blastfurnace slag (GGBS) soil stabilization.” Can. Geotech. J. 53 (5): 773–782. https://doi.org/10.1139/cgj-2015-0183.
Yun, J.-M., Y.-S. Song, J.-H. Lee, and T.-H. Kim. 2006. “Strength characteristics of the cement-stabilized surface layer in dredged and reclaimed Marine Clay, Korea.” Mar. Georesour. Geotechnol. 24 (1): 29–45. https://doi.org/10.1080/10641190600559499.
Zaleska, M., M. Pavlikova, O. Jankovsky, M. Lojka, A. Pivak, and Z. Pavlik. 2018. “Experimental analysis of MOC composite with a waste-expanded polypropylene-based aggregate.” Materials 11 (6): 931. https://doi.org/10.3390/ma11060931.
Zhang, R. J., Y. T. Lu, T. S. Tan, K. K. Phoon, and A. M. Santoso. 2014. “Long-term effect of curing temperature on the strength behavior of cement-stabilized clay.” J. Geotech. Geoenviron. Eng. 140 (8): 12. https://doi.org/10.1061/(ASCE)GT.1943-5606.0001144.

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Go to International Journal of Geomechanics
International Journal of Geomechanics
Volume 24Issue 6June 2024

History

Received: Aug 29, 2023
Accepted: Dec 12, 2023
Published online: Mar 26, 2024
Published in print: Jun 1, 2024
Discussion open until: Aug 26, 2024

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Associate Professor, School of Environment and Civil Engineering, Jiangnan Univ., Wuxi 214122, China. Email: [email protected]
Master’s Candidate, School of Environment and Civil Engineering, Jiangnan Univ., Wuxi 214122, China (corresponding author). Email: [email protected]
Associate Research Fellow, School of Environment and Civil Engineering, Jiangnan Univ., Wuxi 214122, China. Email: [email protected]
Master’s Candidate, School of Environment and Civil Engineering, Jiangnan Univ., Wuxi 214122, China. Email: [email protected]

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