Technical Papers
Dec 26, 2022

Evaluation of the Microstructure and Mechanical Properties of Biopolymer-Based Cementitious Composites with Silver Nanoparticles

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 3

Abstract

This study investigated the effects of using silver nanoparticles (Ag NPs) on the microstructure and mechanical properties of cementitious composites. Ag NPs were synthesized with an ultrasonic irradiation method using konjac gum–polyethylene glycol (KG/PEG) and locust gum–polyethylene glycol (LG/PEG) and characterized using scanning electron microscopy (SEM), energy dispersive X-ray (EDX), high-resolution transmission electron microscopy (TEM), and Fourier-transform infrared (FTIR) analyses. To identify the effect of the Ag NPs on the mechanical properties of mortar, four different cement mortar mixtures were prepared with varying percentages of Ag NPs (0%, 0.5%, 1%, 2%, 3%, 4%, and 5% by weight). Clear improvements were observed in the 7- and 28-day compressive and flexural strengths of nanocomposites with Ag NPs. A thorough microstructure investigation using SEM, EDS, XRD, and thermogravimetric analysis (TGA) was presented, and the relationship between microstructure and the mechanical properties of cementitious composites including Ag NPs was discussed.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

References

Aly, M., M. S. J. Hashmi, A. G. Olabi, M. Messeiry, E. F. Abadir, and A. I. Hussain. 2012. “Effect of colloidal nano-silica on the mechanical and physical behaviour of waste-glass cement mortar.” Mater. Des. 33 (1): 127–135. https://doi.org/10.1016/j.matdes.2011.07.008.
Antoni, M., J. Rossen, F. Martirena, and K. Scrivener. 2012. “Cement substitution by a combination of metakaolin and limestone.” Cem. Concr. Res. 42 (12): 1579–1589. https://doi.org/10.1016/j.cemconres.2012.09.006.
ASTM. 2013. Standard test method for flow of hydraulic cement mortar. ASTM C1437. West Conshohocken, PA: ASTM.
Atiq Orakzai, M. 2021. “Hybrid effect of nano-alumina and nano-titanium dioxide on mechanical properties of concrete.” Case Stud. Constr. Mater. 14 (Jun): e00483. https://doi.org/10.1016/j.cscm.2020.e00483.
Balapour, M., A. Joshaghani, and F. Althoey. 2018. “Nano-SiO2 contribution to mechanical, durability, fresh and microstructural characteristics of concrete: A review.” Constr. Build. Mater. 181 (Aug): 27–41. https://doi.org/10.1016/j.conbuildmat.2018.05.266.
Balapour, M., A. A. Ramezanianpour, and E. Hajibandeh. 2017. “An investigation on mechanical and durability properties of mortars containing nano and micro RHA.” Constr. Build. Mater. 132 (Feb): 470–477. https://doi.org/10.1016/j.conbuildmat.2016.12.017.
Baomin, W., and D. Shuang. 2019. “Effect and mechanism of graphene nanoplatelets on hydration reaction, mechanical properties and microstructure of cement composites.” Constr. Build. Mater. 228 (Dec): 116720. https://doi.org/10.1016/j.conbuildmat.2019.116720.
Barak, S., and D. Mudgil. 2014. “Locust bean gum: Processing, properties and food applications—A review.” Int. J. Biol. Macromol. 66 (May): 74–80. https://doi.org/10.1016/j.ijbiomac.2014.02.017.
Behfarnia, K., and N. Salemi. 2013. “The effects of nano-silica and nano-alumina on frost resistance of normal concrete.” Constr. Build. Mater. 48 (Nov): 580–584. https://doi.org/10.1016/j.conbuildmat.2013.07.088.
Belattmania, Z., F. Bentiss, C. Jama, M. Barakate, C. Katif, A. Reani, and B. Sabour. 2018. “Biosynthesis and characterization of silver nanoparticles using sodium alginate from the invasive macroalga Sargassum muticum.” Bionanoscience 8 (2): 617–623. https://doi.org/10.1007/s12668-018-0518-3.
Ceran, Ö. B., B. Şimşek, S. Doruk, T. Uygunoğlu, and O. N. Şara. 2019. “Effects of dispersed and powdered silver nanoparticles on the mechanical, thermal, electrical and durability properties of cementitious composites.” Constr. Build. Mater. 222 (Oct): 152–167. https://doi.org/10.1016/j.conbuildmat.2019.06.138.
Chandran, S., V. Ravichandran, S. Chandran, J. Chemmanda, and B. Chandarshekar. 2016. “Biosynthesis of PVA encapsulated silver nanoparticles.” J. Appl. Res. Technol. 14 (5): 319–324. https://doi.org/10.1016/j.jart.2016.07.001.
Chen, J., Q. Zhao, J. Peng, X. Yang, D. Yu, and W. Zhao. 2020. “Antibacterial and mechanical properties of reduced graphene-silver nanoparticle nanocomposite modified glass ionomer cements.” J. Dent. 96 (May): 103332. https://doi.org/10.1016/j.jdent.2020.103332.
El-Dein, M. M. N., Z. A. Baka, M. I. Abou-Dobara, A. K. A. El-Sayed, and M. M. El-Zahed. 2021. “Extracellular biosynthesis, optimization, characterization and antimicrobial potential of Escherichia coli D8 silver nanoparticles.” J. Microbiol. Biotechnol. Food Sci. 10 (4): 648–656. https://doi.org/10.15414/jmbfs.2021.10.4.648-656.
Felix da Silva, D., C. Y. L. Ogawa, F. Sato, A. M. Neto, F. H. Larsen, and P. T. Matumoto-Pintro. 2020. “Chemical and physical characterization of Konjac glucomannan-based powders by FTIR and 13C MAS NMR.” Powder Technol. 361 (Feb): 610–616. https://doi.org/10.1016/j.powtec.2019.11.071.
Huang, Q., Z. Liu, Y. Pei, J. Li, and B. Li. 2021. “Gelation behaviors of the konjac gum from different origins: A. guripingensis and A. rivirei.” Food Hydrocolloids 111 (Feb): 106152. https://doi.org/10.1016/j.foodhyd.2020.106152.
Ibrahim, H. M. M. 2015. “Green synthesis and characterization of silver nanoparticles using banana peel extract and their antimicrobial activity against representative microorganisms.” J. Radiat. Res. Appl. Sci. 8 (3): 265–275. https://doi.org/10.1016/j.jrras.2015.01.007.
Islam, M. A., M. V. Jacob, and E. Antunes. 2021. “A critical review on silver nanoparticles: From synthesis and applications to its mitigation through low-cost adsorption by biochar.” J. Environ. Manage. 281 (Mar): 111918. https://doi.org/10.1016/j.jenvman.2020.111918.
Karakuş, S., N. Taşaltın, C. Taşaltın, and N. B. Üllen. 2021. “Ultrasonic synthesized konjac gum/PEG-silver nanoparticles for colorimetric detection of hydrogen peroxide.” J. Inorg. Organomet. Polym. Mater. 31: 3726–3739. https://doi.org/10.21203/RS.3.RS-212902/V1.
Kartik, A., D. Akhil, D. Lakshmi, K. Panchamoorthy Gopinath, J. Arun, R. Sivaramakrishnan, and A. Pugazhendhi. 2021. “A critical review on production of biopolymers from algae biomass and their applications.” Bioresour. Technol. 329 (Jun): 124868. https://doi.org/10.1016/j.biortech.2021.124868.
Katsumiti, A., D. Gilliland, I. Arostegui, and M. P. Cajaraville. 2015. “Mechanisms of toxicity of Ag nanoparticles in comparison to bulk and ionic Ag on mussel hemocytes and gill cells.” PLoS One 10 (6): e0129039. https://doi.org/10.1371/journal.pone.0129039.
Kruk, J., K. Kaczmarczyk, A. Ptaszek, U. Goik, and P. Ptaszek. 2017. “The effect of temperature on the colligative properties of food-grade konjac gum in water solutions.” Carbohydr. Polym. 174 (Oct): 456–463. https://doi.org/10.1016/j.carbpol.2017.06.116.
Kunther, W., S. Ferreiro, and J. Skibsted. 2017. “Influence of the Ca/Si ratio on the compressive strength of cementitious calcium-silicate-hydrate binders.” J. Mater. Chem. A 5 (33): 17401–17412. https://doi.org/10.1039/C7TA06104H.
Lau, D., W. Jian, Z. Yu, and D. Hui. 2018. “Nano-engineering of construction materials using molecular dynamics simulations: Prospects and challenges.” Composites, Part B 143 (Jun): 282–291. https://doi.org/10.1016/j.compositesb.2018.01.014.
Li, K., Y. Lei, J. Liao, and Y. Zhang. 2021. “A facile synthesis of graphene oxide/locust bean gum hybrid aerogel for water purification.” Carbohydr. Polym. 254 (Feb): 117318. https://doi.org/10.1016/j.carbpol.2020.117318.
Li, Z., S. Ding, X. Yu, B. Han, and J. Ou. 2018. “Multifunctional cementitious composites modified with nano titanium dioxide: A review.” Composites, Part A 111 (Aug): 115–137. https://doi.org/10.1016/j.compositesa.2018.05.019.
Lin, Y., and H. Du. 2020. “Graphene reinforced cement composites: A review.” Constr. Build. Mater. 265 (Dec): 120312. https://doi.org/10.1016/j.conbuildmat.2020.120312.
Liu, J., Q. Li, and S. Xu. 2015. “Influence of nanoparticles on fluidity and mechanical properties of cement mortar.” Constr. Build. Mater. 101 (Part 1): 892–901. https://doi.org/10.1016/j.conbuildmat.2015.10.149.
Ma, B., H. Li, J. Mei, X. Li, and F. Chen. 2015. “Effects of nano-TiO2 on the toughness and durability of cement-based material.” Adv. Mater. Sci. Eng. 2015: 583106. https://doi.org/10.1155/2015/583106.
Meddah, M. S., T. R. Praveenkumar, M. M. Vijayalakshmi, S. Manigandan, and R. Arunachalam. 2020. “Mechanical and microstructural characterization of rice husk ash and Al2O3 nanoparticles modified cement concrete.” Constr. Build. Mater. 255 (Sep): 119358. https://doi.org/10.1016/j.conbuildmat.2020.119358.
Mohseni, E., B. M. Miyandehi, J. Yang, and M. A. Yazdi. 2015. “Single and combined effects of nano-SiO2, nano-Al2O3 and nano-TiO2 on the mechanical, rheological and durability properties of self-compacting mortar containing fly ash.” Constr. Build. Mater. 84 (Jun): 331–340. https://doi.org/10.1016/j.conbuildmat.2015.03.006.
Moradi, F., S. Sedaghat, O. Moradi, and S. Arab Salmanabadi. 2021. “Review on green nano-biosynthesis of silver nanoparticles and their biological activities: With an emphasis on medicinal plants.” Inorg. Nano-Metal Chem. 51 (1): 133–142. https://doi.org/10.1080/24701556.2020.1769662.
Mu, R. J., L. Wang, Y. Du, Y. Yuan, Y. Ni, C. Wu, and J. Pang. 2018. “Synthesis of konjac glucomannan-silica hybrid materials with honeycomb structure and its application as activated carbon support for Cu(II) adsorption.” Mater. Lett. 226 (Sep): 75–78. https://doi.org/10.1016/j.matlet.2018.04.133.
Myers, R. J., E. L’Hôpital, J. L. Provis, and B. Lothenbach. 2015. “Effect of temperature and aluminium on calcium (alumino)silicate hydrate chemistry under equilibrium conditions.” Cem. Concr. Res. 68 (Feb): 83–93. https://doi.org/10.1016/j.cemconres.2014.10.015.
Nasrollahzadeh, M., N. Shafiei, F. Soleimani, Z. Nezafat, and N. S. Soheili Bidgoli. 2021. “Physicochemical characterization of biopolymer-based metal nanoparticles.” Biopolym. Met. Nanoparticle Chem. Sustainable Appl. 1: 317–478. https://doi.org/10.1016/b978-0-12-822108-2.00017-x.
Nisticò, R., M. Barrasso, G. A. Carrillo Le Roux, M. M. Seckler, W. Sousa, M. Malandrino, and G. Magnacca. 2015. “Biopolymers from composted biowaste as stabilizers for the synthesis of spherical and homogeneously sized silver nanoparticles for textile applications on natural fibers.” ChemPhysChem 16 (18): 3902–3909. https://doi.org/10.1002/cphc.201500721.
Nivethitha, D., and S. Dharmar. 2016. “Effect of zinc oxide nanoparticle on strength of cement mortar.” Int. J. Sci. Technol. Eng. 3 (5): 1–5.
Noori, A. J., and F. A. Kareem. 2020. “Setting time, mechanical and adhesive properties of magnesium oxide nanoparticles modified glass-ionomer cement.” J. Mater. Res. Technol. 9 (2): 1809–1818. https://doi.org/10.1016/j.jmrt.2019.12.012.
Oltulu, M., and R. Şahin. 2011. “Single and combined effects of nano-SiO2, nano-Al2O3 and nano-Fe2O3 powders on compressive strength and capillary permeability of cement mortar containing silica fume.” Mater. Sci. Eng., A 528 (22–23): 7012–7019. https://doi.org/10.1016/j.msea.2011.05.054.
Oltulu, M., and R. Şahin. 2013. “Effect of nano-SiO2, nano-Al2O3 and nano-Fe2O3 powders on compressive strengths and capillary water absorption of cement mortar containing fly ash: A comparative study.” Energy Build. 58 (Mar): 292–301. https://doi.org/10.1016/j.enbuild.2012.12.014.
Özsoy Özbay, A. E., I. S. Karapınar, A. U. Yazgan, A. O. Pehlivan, S. Karakuş, N. Taşaltın, and A. Kilislioğlu. 2022. “Mechanical properties of cement mortars incorporating zero-valent iron nanoparticles.” J. Mater. Civ. Eng. 34 (1): 1–10. https://doi.org/10.1061/(asce)mt.1943-5533.0004030.
Pathak, A., and A. Tiwari. 2017. “Effect of zinc oxide nanoparticle on compressive strength and durability of concrete.” Int. J. Res. Appl. Sci. Eng. Technol. 5 (8): 683–687. https://doi.org/10.22214/ijraset.2017.8098.
Pei, A. U. E., P. C. Huai, M. A. A. Masimen, W. I. W. Ismail, I. Idris, and N. A. Harun. 2020. “Biosynthesis of gold nanoparticles (AuNPs) by marine baitworm Marphysa moribidii idris, hutchings and arshad 2014 (annelida: polychaeta) and its antibacterial activity.” Adv. Nat. Sci.: Nanosci. Nanotechnol. 11 (1): 015001.
Richardson, I. G. 2014. “Model structures for C-(A)-S-H(I).” Acta Crystallogr., Sect. B: Struct. Sci. 70 (6): 903–923. https://doi.org/10.1107/S2052520614021982.
Schneible, J. D., M. A. Daniele, and S. Menegatti. 2021. Biopolymers for Biomedical and Biotechnological Applications: Natural and synthetic biopolymers in drug delivery and tissue engineering. New York: Wiley.
Scrivener, K. L., T. Füllmann, E. Gallucci, G. Walenta, and E. Bermejo. 2004. “Quantitative study of Portland cement hydration by X-ray diffraction/Rietveld analysis and independent methods.” Cem. Concr. Res. 34 (9): 1541–1547. https://doi.org/10.1016/j.cemconres.2004.04.014.
Singh, L. P., D. Ali, I. Tyagi, U. Sharma, R. Singh, and P. Hou. 2019. “Durability studies of nano-engineered fly ash concrete.” Constr. Build. Mater. 194 (Jan): 205–215. https://doi.org/10.1016/j.conbuildmat.2018.11.022.
Slane, J., J. Vivanco, W. Rose, H. L. Ploeg, and M. Squire. 2015. “Mechanical, material, and antimicrobial properties of acrylic bone cement impregnated with silver nanoparticles.” Mater. Sci. Eng., C 48 (Mar): 188–196. https://doi.org/10.1016/j.msec.2014.11.068.
TSI (Turkish Standard Institute). 2016. Methods of testing cement: Part 1: Determination of strength. TS EN 196-1. Ankara, Turkey: TSI.
Uygunoğlu, T., B. Şimşek, Ö. B. Ceran, and Ö. Eryeşil. 2021. “Novel hybrid fiber reinforced mortar production using polyvinyl alcohol with a blend of graphene oxide and silver nanoparticles.” J. Build. Eng. 44 (Dec): 102641. https://doi.org/10.1016/j.jobe.2021.102641.
Varadavenkatesan, T., R. Selvaraj, and R. Vinayagam. 2019. “Dye degradation and antibacterial activity of green synthesized silver nanoparticles using Ipomoea digitata Linn. flower extract.” Int. J. Environ. Sci. Technol. 16 (5): 2395–2404. https://doi.org/10.1007/s13762-018-1850-4.
Vinayagam, R., S. Pai, T. Varadavenkatesan, M. K. Narasimhan, S. Narayanasamy, and R. Selvaraj. 2020. “Structural characterization of green synthesized α-Fe2O3 nanoparticles using the leaf extract of Spondias dulcis.” Surf. Interfaces 20 (Sep): 100618. https://doi.org/10.1016/j.surfin.2020.100618.
Wang, Z., Z. Ma, J. Sun, Y. Yan, M. Bu, Y. Huo, Y. F. Li, and N. Hu. 2021. “Recent advances in natural functional biopolymers and their applications of electronic skins and flexible strain sensors.” Polym. Basel 13 (5): 813. https://doi.org/10.3390/polym13050813.
Wei, L., J. Lu, H. Xu, A. Patel, Z. S. Chen, and G. Chen. 2015. “Silver nanoparticles: Synthesis, properties, and therapeutic applications.” Drug Discovery Today 20 (5): 595–601. https://doi.org/10.1016/j.drudis.2014.11.014.
Xu, X., B. Li, J. F. Kennedy, B. J. Xie, and M. Huang. 2007. “Characterization of konjac glucomannan–gellan gum blend films and their suitability for release of nisin incorporated therein.” Carbohydr. Polym. 70 (2): 192–197. https://doi.org/10.1016/j.carbpol.2007.03.017.
Yazgan, A. U., S. Karakuş, A. O. Pehlivan, I. S. Karapınar, A. E. Özsoy Özbay, N. Taşaltın, and A. Kilislioğlu. 2022. “Improvement of mechanical strength of mortars by different morphological zinc oxide nanoparticles.” Mag. Concr. Res. 74 (16): 836–849. https://doi.org/10.1680/jmacr.21.00117.
Zarzuela, R., M. Luna, L. M. Carrascosa, M. P. Yeste, I. Garcia-Lodeiro, M. T. Blanco-Varela, M. A. Cauqui, J. M. Rodríguez-Izquierdo, and M. J. Mosquera. 2020. “Producing C-S-H gel by reaction between silica oligomers and portlandite: A promising approach to repair cementitious materials.” Cem. Concr. Res. 130 (Apr): 106008. https://doi.org/10.1016/j.cemconres.2020.106008.
Zhang, A., Y. Ge, W. Yang, X. Cai, and Y. Du. 2019. “Comparative study on the effects of nano-SiO2, nano-Fe2O3 and nano-NiO on hydration and microscopic properties of white cement.” Constr. Build. Mater. 228 (Dec): 116767. https://doi.org/10.1016/j.conbuildmat.2019.116767.
Zhao, Z., S. Gao, Y. Li, F. Wu, and C. Shen. 2021. “Gelation of konjac glucomannan crosslinked by organotitanium chelated with different ligands.” J. Sol-Gel Sci. Technol. 98 (2): 401–410. https://doi.org/10.1007/s10971-021-05517-x.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 3March 2023

History

Received: Dec 10, 2021
Accepted: Jun 30, 2022
Published online: Dec 26, 2022
Published in print: Mar 1, 2023
Discussion open until: May 26, 2023

Permissions

Request permissions for this article.

Authors

Affiliations

Assistant Professor, Dept. of Civil Engineering, Maltepe Univ., Istanbul 34857, Turkey (corresponding author). ORCID: https://orcid.org/0000-0002-6296-4126. Email: [email protected]
Işıl Sanrı Karapınar, Ph.D. [email protected]
Assistant Professor, Dept. of Civil Engineering, Maltepe Univ., Istanbul 34857, Turkey. Email: [email protected]
Selcan Karakuş, Ph.D. [email protected]
Assistant Professor, Dept. of Chemistry, Istanbul Univ.-Cerrahpaşa, Istanbul 34320, Turkey. Email: [email protected]
Ayşe Elif Özsoy Özbay, Ph.D. [email protected]
Assistant Professor, Dept. of Civil Engineering, Maltepe Univ., Istanbul 34857, Turkey. Email: [email protected]
Ahmet Utku Yazgan, Ph.D. [email protected]
Assistant Professor, Dept. of Civil Engineering, Maltepe Univ., Istanbul 34857, Turkey. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share