Abstract

Polyurethane resins are often used in the geotechnical domain to fill fine fissures, small underground cavities, or soil pores to reduce soil permeability, improve the bearing capacity of a shallow foundation, limit the compressibility of the foundation soil, reinforce road embankments, or obtain a lifting effect of structures that have suffered differential settlements. Polyurethane resins have been widely investigated from the mechanical point of view, but the effect of long-term aging on mechanical behavior is not yet well documented. This paper aims to investigate mechanical, physical, and chemical variations following an artificial aging treatment of polyurethane resin specimens with different densities, obtained under different expansion conditions. Artificial aging was obtained in several ways, such as soaking samples in different chemical solutions or subjecting them to different environmental conditions, to simulate the long-term effect of staying in the underground environment. Besides verifying the volume stability of specimens before and after aging, uniaxial compression tests have been performed on samples with and without aging treatment to verify maintenance or any change in the mechanical properties. Accelerated aging does not seem to affect volume change or mechanical behavior of the tested polyurethane resins. Comparison of both physical and mechanical properties before and after aging allows the deduction of useful information for practical geotechnical applications. The tested polyurethane resins showed (1) very high durability under several wetting-drying cycles, (2) high stability if exposed to aggressive chemical agents, and (3) practically unchanged deformability and strength in conditions very similar to those present in the ground. Moreover, the samples that underwent the highest volume change when soaked in chemical solutions revealed no any chemical degradation under infrared spectroscopy.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

This work has benefited from the equipment and framework of the COMP-HUB Initiative, funded by the Departments of Excellence program of the Italian Ministry for Education, University and Research (MIUR, 2018–2022). The authors thank Novatek s.r.l. for kindly providing the HDR specimens. The authors also thank Maria Grazia Zanoni and Alessandro Canali for technical support in the execution of laboratory tests. The authors are grateful to the two reviewers, who made it possible to improve the paper.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 5May 2023

History

Received: Nov 30, 2021
Accepted: Aug 10, 2022
Published online: Feb 21, 2023
Published in print: May 1, 2023
Discussion open until: Jul 21, 2023

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Associate Professor, Dept. of Chemistry, Life Sciences and Environmental Sustainability, Univ. of Parma, Parco Area delle Scienze 11/A, Parma 43124, Italy (corresponding author). ORCID: https://orcid.org/0000-0002-2331-5545. Email: [email protected]
Associate Professor, Dept. of Chemistry, Life Sciences and Environmental Sustainability, Univ. of Parma, Parco Area delle Scienze 11/A, Parma 43124, Italy. ORCID: https://orcid.org/0000-0001-9165-0356. Email: [email protected]
Associate Professor, Dept. of Engineering and Architecture, Univ. of Parma, Parco Area delle Scienze 181/A, Parma 43124, Italy. ORCID: https://orcid.org/0000-0001-5387-1246. Email: [email protected]

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