Effect of Polycarboxylate Superplasticizer Modified by Sodium Hypophosphite on the Properties of -Calcium Sulfate Hemihydrate
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 1
Abstract
In this study, sodium hypophosphite (SHP) was used to modify polycarboxylate superplasticizer (P-PCE), and the properties of P-PCE on -calcium sulfate hemihydrate () were systematically investigated. The results showed that P-PCE could exhibit better fluidity and more retarding effect compared with the conventional polycarboxylate superplasticizer (C-PCE). The reason might be ascribed to the higher adsorption ability of P-PCE because of its stronger complexing capacity with calcium ion, which was induced by the phosphonate and phosphinate groups in the P-PCE molecule. Additionally, PCE played an important function in hindering the calcium sulfate dehydrate (DH) crystallization instead of the dissolution of , resulting in the retarding effect. This new type of PCE can show great potential in gypsum engineering.
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Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
This work was financially supported by the Taishan Scholars Program, Case-by-Case Project for Top Outstanding Talents of Jinan and the National Natural Science Foundation of China (Grant Nos. 51778269 and 51672106).
References
Ahmad, M. R., B. Chen, M. A. Haque, and S. Y. Oderji. 2020. “Multiproperty characterization of cleaner and energy-efficient vegetal concrete based on one-part geopolymer binder.” J. Cleaner Prod. 253 (Apr): 119916. https://doi.org/10.1016/j.jclepro.2019.119916.
Aranda, B., O. Guillou, C. Lanos, C. Daiguebonne, S. Freslon, C. Tessier, M. Laurans, and C. Baux. 2016. “Effect of multiphasic structure of binder particles on the mechanical properties of a gypsum-based material.” Constr. Build. Mater. 102 (Jan): 175–181. https://doi.org/10.1016/j.conbuildmat.2015.10.171.
Arikan, M., and K. Sobolev. 2002. “The optimization of a gypsum-based composite material.” Cem. Concr. Res. 32 (11): 1725–1728. https://doi.org/10.1016/S0008-8846(02)00858-X.
Birss, F., and T. Thorvaldson. 1955. “The hydration of plaster of Paris.” Can. J. Chem. 33 (5): 870–880. https://doi.org/10.1139/v55-105.
Chen, T., X. Gao, and L. Qin. 2019. “Mathematical modeling of accelerated carbonation curing of Portland cement paste at early age.” Cem. Concr. Res. 120 (Jun): 187–197. https://doi.org/10.1016/j.cemconres.2019.03.025.
Chernyshova, N., V. Lesovik, R. Fediuk, and R. Timokhin. 2020. “Enhancement of fresh properties and performances of the eco-friendly gypsum-cement composite (EGCC).” Constr. Build. Mater. 260 (Nov): 120462. https://doi.org/10.1016/j.conbuildmat.2020.120462.
China Building Materials Standards. 2010. α-high strength gypsum plaster. Beijing: China Building Materials Standards.
China National GB Standards. 1999a. Gypsum plasters-determination of mechanical properties of pure paste. Beijing: China National GB Standards.
China National GB Standards. 1999b. Gypsum plasters-determination of physical properties of pure paste. Beijing: China National GB Standards.
Ding, X., Z. Shan, Z. Long, and Z. Chen. 2020. “Utilization of collagen protein extracted from chrome leather scraps as a set retarders in gypsum.” Constr. Build. Mater. 237 (Mar): 117584. https://doi.org/10.1016/j.conbuildmat.2019.117584.
Eve, S., M. Gomina, A. Gmouh, A. Samdi, R. Moussa, and G. Orange. 2002. “Microstructural and mechanical behaviour of polyamide fibre-reinforced plaster composites.” J. Eur. Ceram. Soc. 22 (13): 2269–2275. https://doi.org/10.1016/S0955-2219(02)00014-6.
Eve, S., M. Gomina, J. Hamel, and G. Orange. 2006. “Investigation of the setting of polyamide fibre/latex-filled plaster composites.” J. Eur. Ceram. Soc. 26 (13): 2541–2546. https://doi.org/10.1016/j.jeurceramsoc.2005.07.063.
Garg, M., A. Pundir, and R. Singh. 2016. “Modifications in water resistance and engineering properties of -calcium sulphate hemihydrate plaster-superplasticizer blends.” Mater. Struct. 49: 3253–3263. https://doi.org/10.1617/s11527-015-0717-0.
Guan, B., Q. Ye, J. Zhang, W. Lou, and Z. Wu. 2010. “Interaction between -calcium sulfate hemihydrate and superplasticizer from the point of adsorption characteristics, hydration and hardening process.” Cem. Concr. Res. 40 (2): 253–259. https://doi.org/10.1016/j.cemconres.2009.08.027.
Guo, Y., B. Ma, Z. Zhi, H. Tan, M. Liu, S. Jian, and Y. Guo. 2017. “Effect of polyacrylic acid emulsion on fluidity of cement paste.” Colloids Surf., A 535 (Dec): 139–148. https://doi.org/10.1016/j.colsurfa.2017.09.039.
Hashemikia, S., and M. Montazer. 2012. “Sodium hypophosphite and nano inorganic catalysts along with citric acid on textile producing multi-functional properties.” Appl. Catal., A 417–418 (Feb): 200–208. https://doi.org/10.1016/j.apcata.2011.12.041.
Karni, J., and E. Y. Karni. 1995. “Gypsum in construction: Origin and properties.” Mater. Struct. 28: 92–100. https://doi.org/10.1007/BF02473176.
Lanzón, M., and P. A. García-Ruiz. 2012. “Effect of citric acid on setting inhibition and mechanical properties of gypsum building plasters.” Constr. Build. Mater. 28 (1): 506–511. https://doi.org/10.1016/j.conbuildmat.2011.06.072.
Lewry, A., and J. Williamson. 1994. “The setting of gypsum plaster—Part II The development of microstructure and strength.” J. Mater. Sci. 29 (3): 5524–5528. https://doi.org/10.1007/BF00349943.
Li, H., Z. Jiang, X. Yang, L. Yu, G. Zhang, J. Wu, and X. Liu. 2015. “Sustainable resource opportunity for cane molasses: Use of cane molasses as a grinding aid in the production of Portland cement.” J. Cleaner Prod. 93 (Apr): 56–64. https://doi.org/10.1016/j.jclepro.2015.01.027.
Lin, X., B. Liao, J. Zhang, S. Li, J. Huang, and H. Pang. 2019. “Synthesis and characterization of high-performance cross-linked polycarboxylate superplasticizers.” Constr. Build. Mater. 210 (Jun): 162–171. https://doi.org/10.1016/j.conbuildmat.2019.03.185.
Liu, Z., H. Fu, L. Zhang, H. Li, and X. Liu. 2016. “Synthesis of itaconic acid—Sodium allysulfonate—Sodium hypophosphite copolymer and evaluation of its scale and corrosion inhibition performance.” Desalin. Water Treat. 57 (13): 5740–5752. https://doi.org/10.1080/19443994.2015.1008580.
Magallanes-Rivera, R. X., C. A. Juarez-Alvarado, P. Valdez, and J. M. Mendoza-Rangel. 2012. “Modified gypsum compounds: An ecological–economical choice to improve traditional plasters.” Constr. Build. Mater. 37 (Dec): 591–596. https://doi.org/10.1016/j.conbuildmat.2012.07.054.
Nilles, V., and J. Plank. 2012. “Study of the retarding mechanism of linear sodium polyphosphates on -calcium sulfate hemihydrates.” Cem. Concr. Res. 42 (5): 736–744. https://doi.org/10.1016/j.cemconres.2012.02.008.
Peng, J., J. Qu, J. Zhang, M. Chen, and T. Wan. 2005. “Adsorption characteristics of water-reducing agents on gypsum surface and its effect on the rheology of gypsum plaster.” Cem. Concr. Res. 35 (3): 527–531. https://doi.org/10.1016/j.cemconres.2004.04.016.
Plank, J., and M. Gretz. 2008. “Study on the interaction between anionic and cationic latex particles and Portland cement.” Colloids Surf., A 330 (2–3): 227–233. https://doi.org/10.1016/j.colsurfa.2008.08.005.
Powell, D. A. 1958. “Transformation of the - and -forms of calcium sulphate hemihydrate to insoluble anhydrite.” Nature 182: 792. https://doi.org/10.1038/182792a0.
Pundir, A., M. Garg, and R. Singh. 2015. “Evaluation of properties of gypsum plaster-superplasticizer blends of improved performance.” J. Build. Eng. 4 (Dec): 223–230. https://doi.org/10.1016/j.jobe.2015.09.012.
Qi, H., B. Ma, H. Tan, Y. Su, Z. Jin, C. Li, X. Liu, Q. Yang, and Z. Luo. 2021. “Polycarboxylate superplasticizer modified by phosphate ester in side chain and its basic properties in gypsum plaster.” Constr. Build. Mater. 271 (Feb): 121566. https://doi.org/10.1016/j.conbuildmat.2020.121566.
Sakthieswaran, N., and M. Sophia. 2018. “Effect of superplasticizers on the properties of latex modified gypsum plaster.” Constr. Build. Mater. 179 (Aug): 675–691. https://doi.org/10.1016/j.conbuildmat.2018.05.150.
Singh, N. B., and B. Middendorf. 2007. “Calcium sulphate hemihydrate hydration leading to gypsum crystallization.” Prog. Cryst. Growth Charact. Mater. 53 (1): 57–77. https://doi.org/10.1016/j.pcrysgrow.2007.01.002.
Sowoidnich, T., T. Rachowski, C. Rößler, A. Völkel, and H.-M. Ludwig. 2015. “Calcium complexation and cluster formation as principal modes of action of polymers used as superplasticizer in cement systems.” Cem. Concr. Res. 73 (Jul): 42–50. https://doi.org/10.1016/j.cemconres.2015.01.016.
Tan, H., X. Deng, B. Gu, B. Ma, S. Luo, Z. Zhi, Y. Guo, and F. Zou. 2018. “Effect of borax and sodium tripolyphosphate on fluidity of gypsum paste plasticized by polycarboxylate superplasticizer.” Constr. Build. Mater. 176 (Jul): 394–402. https://doi.org/10.1016/j.conbuildmat.2018.05.005.
Tan, H., Y. Guo, B. Ma, X. Li, and B. Gu. 2017. “Adsorbing behavior of polycarboxylate superplasticizer in the presence of the ester group in side chain.” J. Dispersion Sci. Technol. 38 (5): 743–749. https://doi.org/10.1080/01932691.2016.1193814.
Thymotie, A., T. P. Chang, and H. A. Nguyen. 2020. “Improving properties of high-volume fly ash cement paste blended with -hemihydrate from flue gas desulfurization gypsum.” Constr. Build. Mater. 261 (Nov): 120494. https://doi.org/10.1016/j.conbuildmat.2020.120494.
Vimmrová, A., M. Keppert, L. Svoboda, and R. Černý. 2011. “Lightweight gypsum composites: Design strategies for multi-functionality.” Cem. Concr. Compos. 33 (1): 84–89. https://doi.org/10.1016/j.cemconcomp.2010.09.011.
Winnefeld, F., S. Becker, J. Pakusch, and T. Götz. 2007. “Effects of the molecular architecture of comb-shaped superplasticizers on their performance in cementitious systems.” Cem. Concr. Compos. 29 (4): 251–262. https://doi.org/10.1016/j.cemconcomp.2006.12.006.
Wu, H., Y. Xia, X. Hu, and X. Liu. 2014. “Improvement on mechanical strength and water absorption of gypsum modeling material with synthetic polymers.” Ceram. Int. 40 (9): 14899–14906. https://doi.org/10.1016/j.ceramint.2014.06.085.
Xu, G. 2001. Aqueous polymerization of ethylenically dicarboxylic acids and multicarboxylic acids studied by mass spectroscopy and nuclear magnetic resonance. Athens, GA: Univ. of Georgia.
Yang, C. Q., Q. He, and B. Voncina. 2011. “Cross-linking cotton cellulose by the combination of maleic acid and sodium hypophosphite. 2. Fabric fire performance.” Ind. Eng. Chem. Res. 50 (10): 5889–5897. https://doi.org/10.1021/ie1022892.
Yang, Z., M. Yu, Y. Liu, X. Chen, and Y. Zhao. 2019. “Synthesis and performance of an environmentally friendly polycarboxylate superplasticizer based on modified poly(aspartic acid).” Constr. Build. Mater. 202 (Mar): 154–161. https://doi.org/10.1016/j.conbuildmat.2018.12.148.
Yu, Q. L., and H. J. H. Brouwers. 2011. “Microstructure and mechanical properties of -hemihydrate produced gypsum: An insight from its hydration process.” Constr. Build. Mater. 25 (7): 3149–3157. https://doi.org/10.1016/j.conbuildmat.2010.12.005.
Zhao, H., W. Sun, X. Wu, and B. Gao. 2020. “Influence of addition of polycarboxylate-based superplasticizer on properties of high performance concrete.” J. Mater. Civ. Eng. 32 (3): 04020009. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003025.
Zhi, Z., B. Ma, H. Tan, Y. Guo, Z. Jin, H. Yu, and S. Jian. 2018. “Effect of competitive adsorption between polycarboxylate superplasticizer and hydroxypropylmethyl cellulose on rheology of gypsum paste.” J. Mater. Civ. Eng. 30 (7): 04018141. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002346.
Zingg, A., F. Winnefeld, L. Holzer, J. Pakusch, S. Becker, and L. Gauckler. 2008. “Adsorption of polyelectrolytes and its influence on the rheology, zeta potential, and microstructure of various cement and hydrate phases.” J. Colloid Interface Sci. 323 (2): 301–312. https://doi.org/10.1016/j.jcis.2008.04.052.
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Received: Dec 14, 2021
Accepted: Apr 22, 2022
Published online: Oct 19, 2022
Published in print: Jan 1, 2023
Discussion open until: Mar 19, 2023
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