Abstract

In order to mitigate the effects of thermal-oxidative and ultraviolet (UV) aging on asphalt pavements during service, we explored the influence law of rare earth compounds on the aging properties of asphalt and the antiaging mechanism. The asphalt was subjected to thermal-oxidative and UV aging tests by using a thin-film aging oven as well as a UV aging oven. The changes of macroscopic and microscopic properties of three rare earth–modified asphalts before and after aging with base asphalt were studied by using basic physical property tests, dynamic shear rheology tests, and Fourier infrared spectroscopy comparisons. The results showed that the rare earth–modified asphalt had significantly improved in deformation resistance and high-temperature stability compared with the base asphalt. After aging, the change of carbonyl and sulfoxide functional group indexes of rare earth–modified asphalt was significantly slowed down compared with the base asphalt. It showed that the incorporation of rare earth compounds has a direct effect on the improvement of the aging resistance of asphalt. Regarding the three types of rare earth–modified asphalt, cerium oxide–modified asphalt showed better improvement in thermal-oxidative and UV aging resistance.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The authors gratefully acknowledge financial support from National Key research and development Program and Transportation Science and Technology Development Plan of Tianjin (No. 2019-14).

References

Chinese Standards. 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering. JTG E20-2011. Beijing: Ministry of Communications of the People’s Republic of China.
Cong, P. L., J. Wang, K. Li, and S. F. Chen. 2012. “Physical and rheological properties of asphalt binders containing various antiaging agents.” Fuel 97 (Jul): 678–684. https://doi.org/10.1016/j.fuel.2012.02.028.
Cong, P. L., X. Wang, P. J. Xu, J. F. Liu, R. He, and S. F. Chen. 2013. “Investigation on properties of polymer modified asphalt containing various antiaging agents.” Polym. Degrad. Stab. 98 (12): 2627–2634. https://doi.org/10.1016/j.polymdegradstab.2013.09.024.
Cong, P. L., P. J. Xu, and S. F. Chen. 2014. “Effects of carbon black on the anti aging, rheological and conductive properties of SBS/asphalt/carbon black composites.” Constr. Build. Mater. 52 (Feb): 306–313. https://doi.org/10.1016/j.conbuildmat.2013.11.061.
Cortizo, M. S., D. O. Larsen, H. Bianchetto, and J. L. Alessandrini. 2004. “Effect of the thermal degradation of SBS copolymers during the ageing of modified asphalts.” Polym. Degrad. Stab. 86 (2): 275–282. https://doi.org/10.1016/j.polymdegradstab.2004.05.006.
Fan, X. 2009. “Spot price of rare earth.” Accessed January 13, 2022. https://hq.smm.cn/xt.
Fang, C. Q., R. Yu, S. L. Liu, and Y. Li. 2013. “Nanomaterials applied in asphalt modification: A review.” J. Mater. Sci. Technol. 29 (7): 589–594. https://doi.org/10.1016/j.jmst.2013.04.008.
Fang, J. M., and J. S. Tu. 2019. “Effect of ultraviolet (UV) aging on rheology properties and microstructure of polyurethane (PU) modified asphalt.” Mater. Res. Express 6 (12): 125318. https://doi.org/10.1088/2053-1591/ab558f.
Feng, Z. G., H. J. Bian, X. J. Li, and J. Y. Yu. 2016. “FTIR analysis of UV aging on bitumen and its fractions.” Mater. Struct. 49 (4): 1381–1389. https://doi.org/10.1617/s11527-015-0583-9.
Feng, Z. G., S. J. Wang, H. J. Bian, Q. L. Guo, and X. J. Li. 2013a. “FTIR and rheology analysis of aging on different ultraviolet absorber modified bitumens.” Constr. Build. Mater. 115 (Jul): 48–53. https://doi.org/10.1016/j.conbuildmat.2016.04.040.
Feng, Z. G., J. Y. Yu, H. L. Zhang, D. L. Kuang, and L. H. Xue. 2013b. “Effect of ultraviolet aging on rheology, chemistry and morphology of ultraviolet absorber modified bitumen.” Mater. Struct. 46 (7): 1123–1132. https://doi.org/10.1617/s11527-012-9958-3.
Ghavibazoo, A., M. Abdelrahman, and M. Ragab. 2013. “Effect of crumb rubber modifier dissolution on storage stability of crumb rubber–modified asphalt.” Transp. Res. Record. 2370 (1): 109–115. https://doi.org/10.3141/2370-14.
Glombitza, C., K. Mangelsdorf, and B. Horsfield. 2016. “Differences in bitumen and kerogen-bound fatty acid fractions during diagenesis and early catagenesis in a maturity series of New Zealand coals.” Int. J. Coal Geol. 153 (Jan): 28–36. https://doi.org/10.1016/j.coal.2015.11.009.
Hong, F., D. H. Chen, and M. M. Mikhail. 2010. “Long-term performance evaluation of recycled asphalt pavement results from Texas: Pavement studies category 5 sections from the long-term pavement performance program.” Transp. Res. Record. 2180 (1): 58–66. https://doi.org/10.3141/2180-07.
Jahanbakhsh, H., M. M. Karimi, F. Moghadas Nejad, and B. Jahangiri. 2016. “Viscoelastic-based approach to evaluate low temperature performance of asphalt binders.” Constr. Build. Mater. 128 (Dec): 384–398. https://doi.org/10.1016/j.conbuildmat.2016.10.073.
Jiang, W., P. F. Li, W. L. Ye, J. H. Shan, Y. P. Li, and J. J. Xiao. 2020. “The effect and mechanism of La2O3 on the anti-ultraviolet aging characteristics of virgin bitumen.” Constr. Build. Mater. 230 (Jan): 116967. https://doi.org/10.1016/j.conbuildmat.2019.116967.
Jin, J., L. Liu, R. H. Liu, H. Wei, G. P. Qian, J. L. Zheng, W. Xie, F. P. Lin, and J. Xie. 2019a. “Preparation and thermal performance of binary fatty acid with diatomite as form-stable composite phase change material for cooling asphalt pavements.” Constr. Build. Mater. 226 (Nov): 616–624. https://doi.org/10.1016/j.conbuildmat.2019.07.305.
Jin, J., Y. Q. Tan, R. H. Liu, J. L. Zheng, and J. H. Zhang. 2019b. “Synergy effect of attapulgite, rubber, and diatomite on organic montmorillonite-modified asphalt.” J. Mater. Civ. Eng. 31 (2): 04018388. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002601.
Li, Y. Y., S. P. Wu, Q. T. Liu, S. Nie, H. C. Li, Y. Dai, L. Pang, C. M. Li, and A. M. Zhang. 2019. “Field evaluation of LDHs effect on the aging resistance of asphalt concrete after four years of road service.” Constr. Build. Mater. 208 (May): 192–203. https://doi.org/10.1016/j.conbuildmat.2019.02.174.
Liu, C. H., H. L. Zhang, S. Li, and C. Z. Zhu. 2014. “The effect of surface-modified nano-titania on the ultraviolet aging properties of bitumen.” Pet. Sci. Technol. 32 (24): 2995–3001. https://doi.org/10.1080/10916466.2014.938825.
Liu, Z. G., J. W. Fan, J. M. Feng, M. Li, Y. H. Hu, W. Hao, and F. S. Feng. 2020. “Study on the use of rare earth stabilizer as poly(vinyl chloride) stabilizer.” J. Vinyl Addit. Technol. 26 (4): 536–547. https://doi.org/10.1002/vnl.21768.
Morian, N., E. Y. Hajj, and P. E. Sebaaly. 2013. “Significance of mixture parameters on binder aging in hot-mix asphalt mixtures.” Transp. Res. Rec. 2370 (1): 116–127. https://doi.org/10.3141/2370-15.
Nian, T. F., P. Li, Y. Mao, G. H. Zhang, and Y. Liu. 2018. “Connections between chemical composition and rheology of aged base asphalt binders during repeated freeze-thaw cycles.” Constr. Build. Mater. 159 (Jan): 338–350. https://doi.org/10.1016/j.conbuildmat.2017.10.097.
Ouyang, C., S. F. Wang, Y. Zhang, and Y. X. Zhang. 2005. “Improving the aging resistance of styrene–butadiene–styrene tri-block copolymer modified asphalt by addition of antioxidants.” Polym. Degrad. Stab. 91 (4): 795–804. https://doi.org/10.1016/j.polymdegradstab.2005.06.009.
Parvez, M. A., M. Al-Mehthel, H. I. A. Wahhab, and I. A. Hussein. 2014. “Utilization of sulfur and crumb rubber in asphalt modification.” J. Appl. Polym. Sci. 131 (7): 40046. https://doi.org/10.1002/app.40046.
Qian, G. P., C. D. Yang, H. D. Huang, X. B. Gong, and H. N. Yu. 2020. “Resistance to ultraviolet aging of Nano-SiO2 and rubber powder compound modified asphalt.” Materials (Basel) 13 (22): 5067. https://doi.org/10.3390/ma13225067.
Rasool, R. T., H. R. Yao, A. Hassan, S. F. Wang, and H. Y. Zhang. 2018. “In-field aging process of high content SBS modified asphalt in porous pavement.” Constr. Build. Mater. 155 (Sep): 220–229. https://doi.org/10.1016/j.polymdegradstab.2018.07.023.
Saleh, N. F., B. Keshavarzi, F. Y. Rad, D. Mocelin, M. Elwardany, C. Castorena, B. S. Underwood, and Y. R. Kim. 2020. “Effects of aging on asphalt mixture and pavement performance.” Constr. Build. Mater. 258 (Oct): 120309. https://doi.org/10.1016/j.conbuildmat.2020.120309.
Valcheva-Traykova, M., L. Saso, and I. Kostova. 2014. “Involvement of lanthanides in the free radicals homeostasis.” Curr. Top. Med. Chem. 14 (22): 2508–2519. https://doi.org/10.2174/1568026614666141203123620.
Wang, F., Y. Xiao, P. D. Cui, J. T. Lin, M. L. Li, and Z. W. Chen. 2020a. “Correlation of asphalt performance indicators and aging degrees: A review.” Constr. Build. Mater. 250 (Jul): 118824. https://doi.org/10.1016/j.conbuildmat.2020.118824.
Wang, H. P., X. Y. Liu, P. Apostolidis, M. van de Ven, S. Erkens, and A. Skarpas. 2020b. “Effect of laboratory aging on chemistry and rheology of crumb rubber modified bitumen.” Mater. Struct. 53 (2): 147–153. https://doi.org/10.1617/s11527-020-1451-9.
Wang, Y. Y., L. Sun, and Y. X. Qin. 2015. “Aging mechanism of SBS modified asphalt based on chemical reaction kinetics.” Constr. Build. Mater. 91 (Aug): 47–56. https://doi.org/10.1016/j.conbuildmat.2015.05.014.
Xie, X. B., H. X. Li, J. C. Duan, G. H. Li, and S. J. Tong. 2020. “Influence of the mineral powder content on the asphalt aging resistance in high-altitu-de areas based on indoor ultraviolet light tests.” Materials (Basel) 13 (3): 754. https://doi.org/10.3390/ma13030754.
Xu, G. J., H. Wang, and H. Z. Zhu. 2017. “Rheological properties and anti-aging performance of asphalt binder modified with wood lignin.” Constr. Build. Mater. 151 (Oct): 801–808. https://doi.org/10.1016/j.conbuildmat.2017.06.151.
Yang, J., Y. Muhammad, C. Yang, Y. Liu, Z. B. Su, Y. H. Wei, and J. Li. 2021. “Preparation of TiO2/PS-rGO incorporated SBS modified asphalt with enhanced resistance against ultraviolet aging.” Constr. Build. Mater. 276 (Mar): 121461. https://doi.org/10.1016/j.conbuildmat.2020.121461.
Yu, H. N., X. P. Bai, G. P. Qian, H. Wei, X. B. Gong, J. Jin, and Z. J. Li. 2019. “Impact of ultraviolet radiation on the aging properties of SBS-modified asphalt binders.” Polymers (Basel) 11 (7): 1111. https://doi.org/10.3390/polym11071111.
Yu, T., H. Zhang, and Y. Wang. 2020. “Interaction of asphalt and water betwe-en porous asphalt pavement voids with different aging stage and its significance to drainage.” Constr. Build. Mater. 252 (Aug): 119085. https://doi.org/10.1016/j.conbuildmat.2020.119085.
Zhang, F., J. Y. Yu, and J. Han. 2010. “Effects of thermal oxidative ageing on dynamic viscosity, TG/DTG, DTA and FTIR of SBS- and SBS/sulfur-modified asphalts.” Constr. Build. Mater. 25 (1): 129–137. https://doi.org/10.1016/j.conbuildmat.2010.06.048.
Zhang, Y. H., H. Wei, and Y. H. Dai. 2020. “Influence of different aging environments on rheological behavior and structural properties of rubber asphalt.” Materials (Basel) 13 (15): 3376. https://doi.org/10.3390/ma13153376.
Zhao, Z. J., S. Xu, W. F. Wu, J. Y. Yu, and S. P. Wu. 2015. “The aging resistance of asphalt containing a compound of LDHs and antioxidant.” Pet. Sci. Technol. 33 (7): 787–793. https://doi.org/10.1080/10916466.2015.1014965.
Zheng, W., L. Liu, X. Y. Zhao, J. W. He, A. Wang, T. W. Chan, and S. Z. Wu. 2015. “Effects of lanthanum complex on the thermo-oxidative aging of natural rubber.” Polym. Degrad. Stab. 120 (Oct): 377–383. https://doi.org/10.1016/j.polymdegradstab.2015.07.024.
Zou, Y. K., J. W. He, Z. H. Tang, L. X. Zhu, and F. Liu. 2019. “A novel rare-earth complex containing hindered phenol and thioether groups for styrene-butadiene rubber/silica composites with improved antioxidative properties.” Polym. Degrad. Stab. 166 (Aug): 99–107. https://doi.org/10.1016/j.polymdegradstab.2019.05.029.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 34Issue 10October 2022

History

Received: Nov 16, 2021
Accepted: Feb 17, 2022
Published online: Jul 29, 2022
Published in print: Oct 1, 2022
Discussion open until: Dec 29, 2022

Permissions

Request permissions for this article.

Authors

Affiliations

Master’s Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]
Professor, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China (corresponding author). ORCID: https://orcid.org/0000-0002-4805-2462. Email: [email protected]
Yongke Zhao [email protected]
Lecturer, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]
Senior Engineer, Comprehensive Traffic Research Center, Tianjin Institute of Transportation Science, Hexi District, Tianjin 300060, PR China. Email: [email protected]
Senior Engineer, Tianjin Traffic Science and Testing Technology Co., Tianjin Institute of Transportation Science, Dongli District, Tianjin 300399, PR China. Email: [email protected]
Master’s Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]
Master’s Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]
Master’s Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]
Master’s Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]
Master’s Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]
Pengbing Guan [email protected]
Master’s Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Xiqing District, Tianjin 300384, PR China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share