Technical Papers
Jun 29, 2022

Performance Evolution Mechanism of Hot-Mix Epoxy Asphalt Binder and Mixture Based on Component Characteristics

Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 9

Abstract

In-depth exploration of the performance evolution process of hot-mix epoxy asphalt binder (HEAB) with different components can help control costs and facilitate its promotion and application in engineering. In this study, through the tensile test, viscosity test, laser scanning confocal microscope (LSCM), and Fourier transform infrared spectroscopy (FTIR), the properties of HEAB with different epoxy resin (EP) content were studied, the appropriate EP content was explored, and the curing degree was evaluated by the epoxy conversion rate. Meanwhile, the pavement performance of the HEAB mixture was studied and compared with the stone matrix asphalt (SMA) mixture. The results showed that the tensile properties of HEAB were significantly improved when the EP content reached 30% by weight, and the phase transition occurred when the EP content was 50% by weight. The appropriate content of EP in HEAB was recommended to be 40% by weight, and the mixing temperature of 160°C can ensure sufficient construction allowable time range. The epoxy conversion rate gradually rose with the increase of curing time, and the early curing reaction rate was faster than the later ones. The HEAB mixture had excellent comprehensive properties, and its high-temperature stability was particularly outstanding, but the water stability and skid resistance were inferior to the SMA mixture. Hence, an upper layer of SMA and lower layer of HEAB as a composite structure of a steel bridge deck pavement are worthy of further study in the future.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

This work was undertaken with funding from the National Key R&D Program of China (No. 2019YFE0116300) and the Outstanding Youth Foundation of Jiangsu Province of China (No. BK20211514).

References

Albayati, A. H., and E. T. Al-Azawee. 2018. “Properties of epoxy-asphalt pavement mixture for bridge decks.” Al-Nahrain J. Eng. Sci. 21 (1): 20–27. https://doi.org/10.29194/NJES21010020.
Al-Hadidy, A. I., and Y. Q. Tan. 2011. “Effect of styrene-butadiene-styrene on the properties of asphalt and stone-matrix-asphalt mixture.” J. Mater. Civ. Eng. 23 (4): 504–510. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000185.
Apostolidis, P., X. Liu, S. Erkens, and A. Scarpas. 2019. “Evaluation of epoxy modification in bitumen.” Constr. Build. Mater. 208 (May): 361–368. https://doi.org/10.1016/j.conbuildmat.2019.03.013.
Apostolidis, P., X. Liu, S. Erkens, and A. Scarpas. 2020a. “Characterization of epoxy-asphalt binders by differential scanning calorimetry.” Constr. Build. Mater. 249 (Jul): 118800. https://doi.org/10.1016/j.conbuildmat.2020.118800.
Apostolidis, P., X. Liu, S. Erkens, and T. Scarpas. 2020b. “Oxidative aging of epoxy asphalt.” Int. J. Pavement Eng. 1–11. https://doi.org/10.1080/10298436.2020.1806278.
ASTM. 2014. Standard test method for tensile properties of plastics. ASTM D638. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer. ASTM D4402. West Conshohocken, PA: ASTM.
Cabanelas, J. C., B. Serrano, M. G. Gonzalez, and J. Baselga. 2005. “Confocal microscopy study of phase morphology evolution in epoxy/polysiloxane thermosets.” Polymer 46 (17): 6633–6639. https://doi.org/10.1016/j.polymer.2005.05.017.
Cong, P., Y. Tian, N. Liu, and P. Xu. 2016. “Investigation of epoxy-resin-modified asphalt binder.” J. Appl. Polym. Sci. 133 (21): 43041. https://doi.org/10.1002/app.43401.
Cong, P., J. Yu, and S. Chen. 2010. “Effects of epoxy resin contents on the rheological properties of epoxy-asphalt blends.” J. Appl. Polym. Sci. 118 (6): 3678–3684. https://doi.org/10.1002/app.32440.
Cuadri, A. A., C. Delgado-Sánchez, F. J. Navarro, and P. Partal. 2020. “Short- and long-term epoxy modification of bitumen: Modification kinetics, rheological properties, and microstructure.” Polymers 12 (3): 508. https://doi.org/10.3390/polym12030508.
Esra’a, I. A., and S. A. Abo-Qudais. 2017. “Hot mix asphalt time-temperature shifting and fitting techniques: A comparative study.” Constr. Build. Mater. 146 (Aug): 514–523. https://doi.org/10.1016/j.conbuildmat.2017.03.213.
He, Q., H. Zhang, J. Li, and H. Duan. 2021. “Performance evaluation of polyurethane/epoxy resin modified asphalt as adhesive layer material for steel-UHPC composite bridge deck pavements.” Constr. Build. Mater. 291 (Jul): 123364. https://doi.org/10.1016/j.conbuildmat.2021.123364.
Herrington, P., and D. Alabaster. 2008. “Epoxy modified open-graded porous asphalt.” Road Mater. Pavement Des. 9 (3): 481–498. https://doi.org/10.1080/14680629.2008.9690129.
Hong, W. H., S. P. Wu, and J. Xie. 2010. “Ultraviolet radiation aging of TAFPACK-super modified porous asphalt concrete.” [In Chinese.] Wuhan Ligong Daxue Xuebao (J. Wuhan Univ. Technol.) 32 (17): 206–209.
Hou, X., F. Xiao, J. Wang, and S. Amirkhanian. 2018. “Identification of asphalt aging characterization by spectrophotometry technique.” Fuel 226 (Aug): 230–239. https://doi.org/10.1016/j.fuel.2018.04.030.
Hu, J., Z. Qian, Y. Xue, and Y. Yang. 2016. “Investigation on fracture performance of lightweight epoxy asphalt concrete based on microstructure characteristics.” J. Mater. Civ. Eng. 28 (9): 04016084. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001594.
Huang, S. C. 2008. “Rubber concentrations on rheology of aged asphalt binders.” J. Mater. Civ. Eng. 20 (3): 221–229. https://doi.org/10.1061/(ASCE)0899-1561(2008)20:3(221).
Jiao, Y., Y. Zhang, L. Fu, M. Guo, and L. Zhang. 2019. “Influence of crumb rubber and TAFPACK super on performances of SBS modified porous asphalt mixtures.” Supplement, Road Mater. Pavement Des. 20 (S1): S196–S216. https://doi.org/10.1080/14680629.2019.1590223.
Kang, Y., M. Song, L. Pu, and T. Liu. 2015. “Rheological behaviors of epoxy asphalt binder in comparison of base asphalt binder and SBS modified asphalt binder.” Constr. Build. Mater. 76 (Feb): 343–350. https://doi.org/10.1016/j.conbuildmat.2014.12.020.
Karayannidou, E. G., D. S. Achilias, and I. D. Sideridou. 2006. “Cure kinetics of epoxy–amine resins used in the restoration of works of art from glass or ceramic.” Eur. Polym. J. 42 (12): 3311–3323. https://doi.org/10.1016/j.eurpolymj.2006.08.025.
Kiselev, A., H. Zhang, and Z. Liu. 2021. “The effect of two-phase mixing on the functional and mechanical properties of TPS/SBS-modified porous asphalt concrete.” Constr. Build. Mater. 270 (Feb): 121841. https://doi.org/10.1016/j.conbuildmat.2020.121841.
Li, S., K. Huang, X. Yang, M. Li, and J. Xia. 2014. “Design, preparation and characterization of novel toughened epoxy asphalt based on a vegetable oil derivative for bridge deck paving.” RSC Adv. 4 (84): 44741–44749. https://doi.org/10.1039/C4RA07637K.
Liu, Y., J. Zhang, Y. J. Jiang, C. X. Li, Z. H. Xi, J. Cai, and H. F. Xie. 2018. “Investigation of secondary phase separation and mechanical properties of epoxy SBS-modified asphalts.” Constr. Build. Mater. 165 (Mar): 163–172. https://doi.org/10.1016/j.conbuildmat.2018.01.032.
Lu, Q., and J. Bors. 2015. “Alternate uses of epoxy asphalt on bridge decks and roadways.” Constr. Build. Mater. 78 (Mar): 18–25. https://doi.org/10.1016/j.conbuildmat.2014.12.125.
Luo, S., Z. Liu, X. Yang, Q. Lu, and J. Yin. 2019. “Construction technology of warm and hot mix epoxy asphalt paving for long-span steel bridge.” J. Constr. Eng. Manage. 145 (12): 04019074. https://doi.org/10.1061/(ASCE)CO.1943-7862.0001716.
Luo, S., Q. Lu, and Z. Qian. 2015. “Performance evaluation of epoxy modified open-graded porous asphalt concrete.” Constr. Build. Mater. 76 (Feb): 97–102. https://doi.org/10.1016/j.conbuildmat.2014.11.057.
Ministry of Transport of China. 2004. Technical specification for construction of highway asphalt pavements. JTG F40-2004. Beijing, China: China Communications Press.
Ministry of Transport of China. 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering. JTG E20-2011. Beijing, China: China Communications Press.
Ministry of Transport of China. 2019. Specifications for design and construction of pavement on highway steel deck bridge. JTG/T3364-02-2019. Beijing, China: China Communications Press.
Ministry of Transport of the People’s Republic of China. 2016. “Guiding opinions of the ministry of transport on promoting the construction of highway steel structure bridges.” [In Chinese.] Highway 61 (8): 271–272.
Otsu, N. 1979. “A threshold selection method from gray-level histograms.” IEEE Trans. Syst. Man Cybern. 9 (1): 62–66. https://doi.org/10.1109/TSMC.1979.4310076.
Serigos, P. A., A. De Fortier Smit, and J. A. Prozzi. 2014. “Incorporating surface microtexture in the prediction of skid resistance of flexible pavements.” Transp. Res. Rec. 2457 (1): 105–113. https://doi.org/10.3141/2457-11.
Shi, J., W. Fan, and C. Qian. 2020. “Effect of high viscosity modifier on rheological properties and microstructure of high viscosity asphalt.” In Vol. of 2258 Proc., 2nd Int. Symp. on Mechanics, Structures and Materials Science, 020011. Tianjin, China: AIP Conference. https://doi.org/10.1063/5.0014735.
Sureshkumar, M. S., S. Filippi, G. Polacco, I. Kazatchkov, J. Stastna, and L. Zanzotto. 2010. “Internal structure and linear viscoelastic properties of EVA/asphalt nanocomposites.” Eur. Polym. J. 46 (4): 621–633. https://doi.org/10.1016/j.eurpolymj.2009.12.024.
Ud Din, I. M., M. S. Mir, and M. A. Farooq. 2020. “Effect of freeze-thaw cycles on the properties of asphalt pavements in cold regions: A review.” [In Chinese.] Transp. Res. Procedia 48: 3634–3641. https://doi.org/10.1016/j.trpro.2020.08.087.
Vyrozhemskyi, V., I. Kopynets, S. Kischynskyi, and N. Bidnenko. 2017. “Epoxy asphalt concrete is a perspective material for the construction of roads.” In Vol. 236 of Proc., IOP Conf. Series: Materials Science and Engineering, 012022. Prague, Czech Republic: IOP Conference Series. https://doi.org/10.1088/1757-899X/236/1/012022.
Wang, C., Y. Fu, Q. Chen, B. Chen, and L. Zhou. 2018. “Application and research advances in epoxy asphalt concrete serving as deck pavement material.” [In Chinese.] Mater. Rep. 32 (17): 2992–3009.
Wei, J., and Y. Zhang. 2012. “Study on the curing process of epoxy asphalt.” J. Test. Eval. 40 (7): 1169–1176. https://doi.org/10.1520/JTE20120136.
Xiang, Q., and F. Xiao. 2020. “Applications of epoxy materials in pavement engineering.” Constr. Build. Mater. 235 (Feb): 117529. https://doi.org/10.1016/j.conbuildmat.2019.117529.
Xiao, F., N. Su, S. Yao, S. Amirkhanian, and J. Wang. 2019. “Performance grades, environmental and economic investigations of reclaimed asphalt pavement materials.” J. Cleaner Prod. 211 (Feb): 1299–1312. https://doi.org/10.1016/j.jclepro.2018.11.126.
Xu, W., G. Zhuang, Z. Chen, and J. Wei. 2020. “Experimental study on the micromorphology and strength formation mechanism of epoxy asphalt during the curing reaction.” Appl. Sci. 10 (7): 2610. https://doi.org/10.3390/app10072610.
Yang, G., C. Wang, H. Fu, Z. Yan, and W. Yin. 2019. “Waterborne epoxy resi-polyurethane-emulsified asphalt: Preparation and properties.” J. Mater. Civ. Eng. 31 (11): 04019265. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002904.
Yin, H., H. Jin, C. Wang, Y. Sun, Z. Yuan, H. Xie, Z. Wang, and R. Cheng. 2014. “Thermal, damping, and mechanical properties of thermosetting epoxy-modified asphalts.” J. Therm. Anal. Calorim. 115 (2): 1073–1080. https://doi.org/10.1007/s10973-013-3449-9.
Yin, H., Y. Zhang, Y. Sun, W. Xu, D. Yu, H. Xie, and R. Cheng. 2015. “Performance of hot mix epoxy asphalt binder and its concrete.” Mater. Struct. 48 (11): 3825–3835. https://doi.org/10.1617/s11527-014-0442-0.
Yu, X., F. Dong, G. Ding, S. Liu, and S. Shen. 2016. “Rheological and microstructural properties of foamed epoxy asphalt.” Constr. Build. Mater. 114 (Jul): 215–222. https://doi.org/10.1016/j.conbuildmat.2016.03.179.
Zeng, G. 2019. Evaluation of the mechanical behavior and fatigue performance of steel bridge deck pavement. Guangzhou, China: South China University of Technology.
Zeng, G., W. Xu, H. Huang, and X. Zhang. 2019. “Study on the microstructure and properties of hot-mix epoxy asphalt.” Int. J. Pavement Res. Technol. 12 (2): 147–153. https://doi.org/10.1007/s42947-019-0019-y.
Zhang, D., F. Ye, and J. Yuan. 2013. “Life-cycle cost analysis (LCCA) on steel bridge pavement structural composition.” Procedia—Soc. Behav. Sci. 96 (Nov): 785–789. https://doi.org/10.1016/j.sbspro.2013.08.089.
Zhang, F., and J. Yu. 2010. “The research for high-performance SBR compound modified asphalt.” Constr. Build. Mater. 24 (3): 410–418. https://doi.org/10.1016/j.conbuildmat.2009.10.003.
Zhang, Y., Y. Cheng, X. Dong, and N. Li. 2020a. “Study on the performance of new TPS high viscosity modifier on its modified asphalt.” In Vol. 587 of Proc., IOP Conf. Series: Earth and Environmental Science, 012023. Dalian, China: Academic Exchange Information Centre. https://doi.org/10.1088/1755-1315/587/1/012023.
Zhang, Z., J. Sun, Z. Huang, F. Wang, M. Jia, W. Lv, and J. Ye. 2021. “A laboratory study of epoxy/polyurethane modified asphalt binders and mixtures suitable for flexible bridge deck pavement.” Constr. Build. Mater. 274 (Mar): 122084. https://doi.org/10.1016/j.conbuildmat.2020.122084.
Zhang, Z., J. Sun, M. Jia, B. Qi, H. Zhang, W. Lv, Z. Mao, P. Chang, J. Peng, and Y. Liu. 2020b. “Study on a thermosetting polyurethane modified asphalt suitable for bridge deck pavements: Formula and properties.” Constr. Build. Mater. 241 (Apr): 118122. https://doi.org/10.1016/j.conbuildmat.2020.118122.
Zhong, K., M. Sun, and R. Chang. 2018. “Performance evaluation of high-elastic/salt-storage asphalt mixture modified with Mafilon and rubber particles.” Constr. Build. Mater. 193 (Dec): 153–161. https://doi.org/10.1016/j.conbuildmat.2018.10.185.
Zhou, X., S. Wu, G. Liu, and P. Pan. 2016. “Molecular simulations and experimental evaluation on the curing of epoxy bitumen.” Mater. Struct. 49 (1): 241–247. https://doi.org/10.1617/s11527-014-0491-4.
Zhu, J., B. Birgisson, and N. Kringos. 2014. “Polymer modification of bitumen: Advances and challenges.” Eur. Polym. J. 54 (May): 18–38. https://doi.org/10.1016/j.eurpolymj.2014.02.005.

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Journal of Materials in Civil Engineering
Volume 34Issue 9September 2022

History

Received: Oct 5, 2021
Accepted: Jan 14, 2022
Published online: Jun 29, 2022
Published in print: Sep 1, 2022
Discussion open until: Nov 29, 2022

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Professor, Intelligent Transportation System Research Center, Southeast Univ., Nanjing, Jiangsu 210096, PR China. Email: [email protected]
Ph.D. Candidate, School of Transportation, Southeast Univ., Nanjing, Jiangsu 210096, PR China (corresponding author). Email: [email protected]
Associate Professor, Intelligent Transportation System Research Center, Southeast Univ., Nanjing, Jiangsu 210096, PR China. Email: [email protected]
Shicheng Liu [email protected]
Nanjing Railway Construction Investment Co., Ltd., Xinjiekou St., Xuanwu District, Nanjing, Jiangsu 210005, PR China. Email: [email protected]

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