Technical Papers
Feb 22, 2022

Evaluation of Mechanical Performance of Compacted Magnesium Hydroxide after Carbonation Curing

Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 5

Abstract

In this study, the potential to directly use magnesium hydroxide as an alternative binder was investigated. A compaction molding technique was employed, where magnesium hydroxide powder was mixed with water at relatively low water-to-binder ratios, compacted in a mold, then subjected to accelerated CO2 curing at room temperature to form a carbonate binder. The influence of water-to-binder ratio and compaction pressure on the mechanical and microstructural properties of compacted magnesium hydroxide systems under accelerated CO2 curing was evaluated. Results showed that compaction pressure and water-to-binder ratio have a significant effect on CO2 uptake and strength development. An optimum compaction level was found to be 3 MPa in this study, where compressive strengths of 33.5±4.0 and 70.8±4.1  MPa were reached after 2 and 5 days of CO2 curing. Results highlight the potential to tailor the mechanical properties of magnesium hydroxide systems through processing, and to reach strengths comparable to those of magnesium oxide systems but with the advantage of skipping the calcination step and reducing water demand.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The authors would like to acknowledge Columbia University’s School of Engineering and Applied Science (SEAS) Interdisciplinary Research Seed (SIRS) Program for financial support, and technical support by the staff of Columbia University’s Carleton Laboratory. The first author is grateful for the financial support given by the Scientific and Technical Research Council of Turkey (TÜBİTAK). We would also like to thank Palash Badjatya and Roberto Interiano for their help with this work.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 34Issue 5May 2022

History

Received: Feb 28, 2021
Accepted: Sep 10, 2021
Published online: Feb 22, 2022
Published in print: May 1, 2022
Discussion open until: Jul 22, 2022

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Authors

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Researcher, Dept. of Civil Engineering, Yıldız Technical Univ., İstanbul 34220, Turkey. ORCID: https://orcid.org/0000-0003-1151-5520
Siwei Ma
Researcher, Dept. of Civil Engineering and Engineering Mechanics, Columbia Univ., New York, NY 10027.
Daniel Esposito
Associate Professor, Dept. of Chemical Engineering, Columbia Univ., New York, NY 10027.
Associate Professor, Dept. of Civil Engineering and Engineering Mechanics, Columbia Univ., New York, NY 10027 (corresponding author). ORCID: https://orcid.org/0000-0002-3332-3936. Email: [email protected]; [email protected]

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  • Carbon-negative cement manufacturing from seawater-derived magnesium feedstocks, Proceedings of the National Academy of Sciences, 10.1073/pnas.2114680119, 119, 34, (2022).

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