Evaluation of Mechanical Performance of Compacted Magnesium Hydroxide after Carbonation Curing
Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 5
Abstract
In this study, the potential to directly use magnesium hydroxide as an alternative binder was investigated. A compaction molding technique was employed, where magnesium hydroxide powder was mixed with water at relatively low water-to-binder ratios, compacted in a mold, then subjected to accelerated curing at room temperature to form a carbonate binder. The influence of water-to-binder ratio and compaction pressure on the mechanical and microstructural properties of compacted magnesium hydroxide systems under accelerated curing was evaluated. Results showed that compaction pressure and water-to-binder ratio have a significant effect on uptake and strength development. An optimum compaction level was found to be 3 MPa in this study, where compressive strengths of and were reached after 2 and 5 days of curing. Results highlight the potential to tailor the mechanical properties of magnesium hydroxide systems through processing, and to reach strengths comparable to those of magnesium oxide systems but with the advantage of skipping the calcination step and reducing water demand.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
The authors would like to acknowledge Columbia University’s School of Engineering and Applied Science (SEAS) Interdisciplinary Research Seed (SIRS) Program for financial support, and technical support by the staff of Columbia University’s Carleton Laboratory. The first author is grateful for the financial support given by the Scientific and Technical Research Council of Turkey (TÜBİTAK). We would also like to thank Palash Badjatya and Roberto Interiano for their help with this work.
References
Abanades, S., and L. Andre. 2018. “Design and demonstration of a high temperature solar-heated rotary tube reactor for continuous particles calcination.” Appl. Energy 212 (Feb): 1310–1320. https://doi.org/10.1016/j.apenergy.2018.01.019.
Ashraf, W., and J. Olek. 2018. “Carbonation activated binders from pure calcium silicates: Reaction kinetics and performance controlling factors.” Cem. Concr. Compos. 93 (Oct): 85–98. https://doi.org/10.1016/j.cemconcomp.2018.07.004.
Biernacki, J. J., et al. 2017. “Cements in the 21st century: Challenges, perspectives, and opportunities.” J. Am. Ceram. Soc. 100 (7): 2746–2773. https://doi.org/10.1111/jace.14948.
Botha, A., and C. A. Strydom. 2001. “Preparation of a magnesium hydroxy carbonate from magnesium hydroxide.” Hydrometallurgy 62 (3): 175–183. https://doi.org/10.1016/S0304-386X(01)00197-9.
Canterford, J. H., and G. Tsambourakis. 1984. “Some observations on the properties of dypingite , and related minerals.” Mineral. Mag. 48 (348): 437–442. https://doi.org/10.1180/minmag.1984.048.348.15.
De Silva, P., L. Bucea, D. R. Moorehead, and V. Sirivivatnanon. 2006. “Carbonate binders: Reaction kinetics, strength and microstructure.” Cem. Concr. Compos. 28 (7): 613–620. https://doi.org/10.1016/j.cemconcomp.2006.03.004.
De Silva, P., L. Bucea, and V. Sirivivatnanon. 2009. “Chemical, microstructural and strength development of calcium and magnesium carbonate binders.” Cem. Concr. Res. 39 (5): 460–465. https://doi.org/10.1016/j.cemconres.2009.02.003.
Devasahayam, S., and V. Strezov. 2018. “Thermal decomposition of magnesium carbonate with biomass and plastic wastes for simultaneous production of hydrogen and carbon avoidance.” J. Cleaner Prod. 174 (Feb): 1089–1095. https://doi.org/10.1016/j.jclepro.2017.11.017.
Dung, N. T., A. Lesimple, R. Hay, K. Celik, and C. Unluer. 2019. “Formation of carbonate phases and their effect on the performance of reactive MgO cement formulations.” Cem. Concr. Res. 125 (Nov): 105894. https://doi.org/10.1016/j.cemconres.2019.105894.
Dung, N. T., and C. Unluer. 2016. “Improving the performance of reactive MgO cement-based concrete mixes.” Constr. Build. Mater. 126 (Nov): 747–758. https://doi.org/10.1016/j.conbuildmat.2016.09.090.
Dung, N. T., and C. Unluer. 2018. “Development of MgO concrete with enhanced hydration and carbonation mechanisms.” Cem. Concr. Res. 103 (Jan): 160–169. https://doi.org/10.1016/j.cemconres.2017.10.011.
Eloundou, L., and T. Joffroy. 2013. “Earthen architecture in today’s world.” In Proc., UNESCO International Colloquium on the Conservation of World Heritage Earthen Architecture. Paris: UNESCO.
Frost, R. L., S. Bahfenne, J. Graham, and W. N. Martens. 2008. “Thermal stability of artinite, dypingite and brugnatellite—Implications for the geosequestration of greenhouse gases.” Thermochim. Acta 475 (1–2): 39–43. https://doi.org/10.1016/j.tca.2008.06.007.
Gartner, E., and T. Sui. 2018. “Alternative cement clinkers.” Cem. Concr. Res. 114 (Dec): 27–39. https://doi.org/10.1016/j.cemconres.2017.02.002.
Han, B., H. Qu, H. Niemi, Z. Sha, and M. Louhi-Kultanen. 2014. “Mass transfer and kinetics study of heterogeneous semi-batch precipitation of magnesium carbonate.” Chem. Eng. Technol. 37 (8): 1363–1368. https://doi.org/10.1002/ceat.201300855.
Hay, R., and K. Celik. 2020. “Hydration, carbonation, strength development and corrosion resistance of reactive MgO cement-based composites.” Cem. Concr. Res. 128 (Feb): 105941. https://doi.org/10.1016/j.cemconres.2019.105941.
Ho, L. S., K. Nakarai, Y. Ogawa, T. Sasaki, and M. Morioko. 2018. “Effect of internal water content on carbonation progress in cement-treated sand and effect of carbonation on compressive strength.” Cem. Concr. Compos. 85 (Jan): 9–21. https://doi.org/10.1016/j.cemconcomp.2017.09.016.
Huntzinger, D. N., and T. D. Eatmon. 2009. “A life-cycle assessment of portland cement manufacturing: Comparing the traditional process with alternative technologies.” J. Cleaner Prod. 17 (7): 668–675. https://doi.org/10.1016/j.jclepro.2008.04.007.
Kastiukas, G., X. Zhou, B. Neyazi, and K. T. Wan. 2019. “Sustainable calcination of magnesium hydroxide for magnesium oxychloride cement production.” J. Mater. Civ. Eng. 31 (7): 04019110. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002786.
Lehne, J., and F. Preston. 2018. Making concrete change innovation in low-carbon cement and concrete. London: Royal Institute of International Affairs—Chatham House.
Lowe, C. A., and M. W. Greenway. 2005. “Compaction processes in granular beds composed of different particle sizes.” J. Appl. Phys. 98 (12): 123519. https://doi.org/10.1063/1.2149167.
Lowe, C. A., and A. W. Longbottom. 2006. “Effect of particle distribution on the compaction behavior of granular beds.” Phys. Fluids 18 (6): 066101. https://doi.org/10.1063/1.2213641.
Mikulcic, H., J. J. Klemes, M. Vujanovic, K. Urbaniec, and N. Duić. 2016. “Reducing greenhouse gasses emissions by fostering the deployment of alternative raw materials and energy sources in the cleaner cement manufacturing process.” J. Cleaner Prod. 136 (Nov): 119–132. https://doi.org/10.1016/j.jclepro.2016.04.145.
Mo, L., Y. Hao, Y. Liu, F. Wang, and M. Deng. 2019. “Preparation of calcium carbonate binders via activation of magnesium slag.” Cem. Concr. Res. 121 (Jul): 81–90. https://doi.org/10.1016/j.cemconres.2019.04.005.
Oliveira, F. A. C., J. C. Fernandes, J. Galindo, J. Rodriguez, I. Canadas, V. Vermelhudo, A. Nunes, and L. G. Rosa. 2019. “Portland cement clinker production using concentrated solar energy—A proof-of-concept approach.” Sol. Energy 183 (May): 677–688. https://doi.org/10.1016/j.solener.2019.03.064.
Pacheco-Torgal, F., and S. Jalali. 2012. “Earth construction: Lessons from the past for future eco-efficient construction.” Constr. Build. Mater. 29 (Apr): 512–519. https://doi.org/10.1016/j.conbuildmat.2011.10.054.
Pacheco-Torgal, F., C. Shi, and A. P. Sanchez. 2018. Carbon dioxide sequestration in cementitious construction materials. Cambridge, UK: Woodhead Publishing.
Power, I. M., S. A. Wilson, J. M. Thom, G. M. Dipple, and G. Southam. 2007. “Biologically induced mineralization of dypingite by cyanobacteria from an alkaline wetland near Atlin, British Columbia, Canada.” Geochem. Trans. 8 (1): 1–16. https://doi.org/10.1186/1467-4866-8-13.
Ruan, S., and C. Unluer. 2017. “Influence of mix design on the carbonation, mechanical properties and microstructure of reactive MgO cement-based concrete.” Cem. Concr. Compos. 80 (Jul): 104–114. https://doi.org/10.1016/j.cemconcomp.2017.03.004.
Shen, W., L. Cao, Q. Li, Z. Wen, J. Wang, Y. Liu, R. Dong, Y. Tan, and R. Chen. 2016. “Is magnesia cement low carbon? Life cycle carbon footprint comparing with portland cement.” J. Cleaner Prod. 131 (Sep): 20–27. https://doi.org/10.1016/j.jclepro.2016.05.082.
Sivakrishna, A., A. Adesina, P. O. Awoyera, and K. R. Kumar. 2020. “Green concrete: A review of recent developments.” Mater. Today: Proc. 27 (1): 54–58. https://doi.org/10.1016/j.matpr.2019.08.202.
Teh, S. H., T. Wiedmann, A. Castel, and J. de Burgh. 2017. “Hybrid life cycle assessment of greenhouse gas emissions from cement, concrete and geopolymer concrete in Australia.” J. Cleaner Prod. 152 (May): 312–320. https://doi.org/10.1016/j.jclepro.2017.03.122.
Unluer, C., and A. Al-Tabbaa. 2013. “Impact of hydrated magnesium carbonate additives on the carbonation of reactive MgO cements.” Cem. Concr. Res. 54 (Dec): 87–97. https://doi.org/10.1016/j.cemconres.2013.08.009.
Unluer, C., and A. Al-Tabbaa. 2014. “Enhancing the carbonation of MgO cement porous blocks through improved curing conditions.” Cem. Concr. Res. 59 (May): 55–65. https://doi.org/10.1016/j.cemconres.2014.02.005.
Van Damme, H., and H. Houben. 2018. “Earth concrete. Stabilization revisited.” Cem. Concr. Res. 114 (Dec): 90–102. https://doi.org/10.1016/j.cemconres.2017.02.035.
Walling, S. A., and J. L. Provis. 2016. “Magnesia-based cements: A journey of 150 years, and cements for the future?” Chem. Rev. 116 (7): 4170–4204. https://doi.org/10.1021/acs.chemrev.5b00463.
Information & Authors
Information
Published In
Copyright
© 2022 American Society of Civil Engineers.
History
Received: Feb 28, 2021
Accepted: Sep 10, 2021
Published online: Feb 22, 2022
Published in print: May 1, 2022
Discussion open until: Jul 22, 2022
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.
Cited by
- Palash Badjatya, Abdullah H. Akca, Daniela V. Fraga Alvarez, Baoqi Chang, Siwei Ma, Xueqi Pang, Emily Wang, Quinten van Hinsberg, Daniel V. Esposito, Shiho Kawashima, Carbon-negative cement manufacturing from seawater-derived magnesium feedstocks, Proceedings of the National Academy of Sciences, 10.1073/pnas.2114680119, 119, 34, (2022).