Mechanical Properties of Fly Ash–Slag Based Alkali-Activated Materials under the Low-Energy Consummation-Sealed Curing Condition
Publication: Journal of Materials in Civil Engineering
Volume 33, Issue 10
Abstract
The effect of curing conditions (sealed and standard) on the mechanical properties of fly ash (FA) and ground-granulated blast-furnace slag (GGBFS)–based alkali-activated materials with NaOH and waterglass alkali activators are investigated in this study. The results show the highest 28-day compressive strength of samples was obtained in the A-3 samples and researched to 59.8 MPa under sealed curing conditions. Using scanning electron microscopy (SEM), it was found that samples with sealed curing condition have higher mechanical properties associating to the denser microstructure and low crack width. Under the sealed curing condition, lower carbonation degree of samples has higher content of to form the Si-O-Na bond resulting in the higher content of amorphous gel and geopolymerization degree based on the experiments results of electron paramagnetic resonance (EPR), Fourier transform infrared (FTIR) spectrometer, X-ray photoelectron spectroscopy (XPS), chemical bond water, and selective dissolution.
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Data Availability Statement
No data, models, or code were generated or used during the study.
Acknowledgments
This study was funded by National Natural Science Foundation of China (Grant No. 52002307).
References
Abeer, A. M., J. L. Provis, and A. Cwirzen. 2019. “Effect of curing condition on shrinkage of alkali-activated high-MgO Swedish slag concrete.” Frontiers Mater. 6 (Nov): 1–10. https://doi.org/10.3389/fmats.2019.00287.
Al Bakri Abdullah, M. M., M. F. Mohd Tahir, K. Hussin, M. Binhussain, and J. J. Ekaputri. 2016. “Effect of microwave curing to the compressive strength of fly ash based geopolymer mortar.” In Proc., Materials Science Forum, 193–199. Stafa-Zurich, Switzerland: Trans Tech Publications. https://doi.org/10.4028/www.scientific.net/MSF.841.193.
Bakharev, T. 2005. “Resistance of geopolymer materials to acid attack.” Cem. Concr. Res. 35 (4): 658–670. https://doi.org/10.1016/j.cemconres.2004.06.005.
Bilim, C., O. Karahan, and L. Serhan. 2015. “Effects of chemical admixtures and curing conditions on some properties of alkali-activated cementless slag mixtures.” J. Civ. Eng. 19 (3): 733–741. https://doi.org/10.1007/s12205-015-0629-0.
Chindaprasirt, P. 2013. “Role of microwave radiation in curing the fly ash geopolymer.” Adv. Powder Technol. 24 (3): 703–707. https://doi.org/10.1016/j.apt.2012.12.005.
Chinese National Standards. 2012. Methods for testing uniformity of concrete admixture. GB/T 8077-2012. Beijing: American National Standards Institute.
Davidovits, J. 1991. “Geopolymers: Inorganic polymeric new materials.” Therm. Anal. 37 (8): 1633–1656. https://doi.org/10.1007/BF01912193.
Duxson, P., J. L. Provis, and G. C. Lukey. 2007. “The role of inorganic polymer technology in the development of ‘green concrete.’” Cem. Concr. Res. 37 (12): 1590–1597. https://doi.org/10.1016/j.cemconres.2007.08.018.
Habert, G., and C. Ouellet-Plamondo. 2016. “Recent update on the environmental impact of geopolymers.” RLEM Tech. Lett. 1 (2): 17–23. https://doi.org/10.21809/rilemtechlett.2016.6.
Han, S., Y. Cui, H. Huang, M. An, and Z. Yu. 2018. “Effect of curing conditions on the shrinkage of ultra high-performance fiber-reinforced concrete.” Adv. Civ. Eng. 2018 (Jan): 1–8. https://doi.org/10.1155/2018/5238278.
Jiang, W., and D. M. Roy. 1992. “Hydrothermal processing of new fly ash cement.” Am. Ceram. Soc. Bull. 71 (4): 642–647. https://doi.org/10.1007/BF00796258.
Kani, E. N., and H. Mehdizadeh. 2017. “Investigating gel molecular structure and its relation with mechanical strength in geopolymer cement based on natural pozzolan using in situ ATR-FTIR spectroscopy.” J. Mater. Civ. Eng. 29 (8): 04017078. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001917.
Kovalchuk, G., and A. Palomol. 2006. “Alkali-activated fly ash: Effect of thermal curing conditions on mechanical and microstructural development—Part II.” Fuel 86 (3): 315–322. https://doi.org/10.1016/j.fuel.2006.07.010.
Narayanan, A., and P. Shanmugasundaram. 2017. “An experimental investigation on flyash-based geopolymer mortar under different curing regime for thermal analysis.” Energy Build. 138 (Mar): 539–545. https://doi.org/10.1016/j.enbuild.2016.12.079.
Nedeljković, M., B. Ghiassi, S. V. D. Laan, Z. Li, and G. Ye. 2019. “Effect of curing conditions on the pore solution and carbonation resistance of alkali-activated fly ash and slag pastes.” Cem. Concr. Res. 116 (Feb): 146–158. https://doi.org/10.1016/j.cemconres.2018.11.011.
Noushini, A., and A. Castel. 2016. “The effect of heat-curing on transport properties of low-calcium fly ash-based geopolymer concrete.” Constr. Build. Mater. 112 (3): 464–477. https://doi.org/10.1016/j.conbuildmat.2016.02.210.
Park, S., and M. Pour-Ghaz. 2018. “What is the role of water in the geopolymerization of metakaolin?” Constr. Build. Mater. 182 (Sep): 360–370. https://doi.org/10.1016/j.conbuildmat.2018.06.073.
Provis, J. L., and S. A. Bernal. 2014. “Geopolymers and related alkali-activated materials.” Annu. Rev. Mater. Res. 44 (4): 299–327. https://doi.org/10.1146/annurev-matsci-070813-113515.
Ranjbar, N., A. Kashefi, and M. R. Maheri. 2018. “Hot-pressed geopolymer dual effects of heat and curing time.” Cem. Concr. Compos. 86 (Feb): 1–8. https://doi.org/10.1016/j.cemconcomp.2017.11.004.
Rattanasak, U., K. Pankhet, and P. Chindaprasirt. 2011. “Effect chemical admixtures on properties of high-calcium fly ash geopolymer.” Int. J. Miner. Metall. 18 (3): 364–369. https://doi.org/10.1007/s12613-011-0448-3.
Rimer, J. D., R. F. Lobo, and D. G. Vlachos. 2005. “Physical basis for the formation and stability of silica nanoparticles in basic solutions of monovalent cations.” Langmuir ACS J. Surfaces Colloids 21 (19): 8960–8971. https://doi.org/10.1021/la0511384.
Shi, C. J., A. F. Jimenez, and A. Palomo. 2011. “New cements for the 21st century: The pursuit of an alternative to portland cement.” Cem. Concr. Res. 41 (7): 750–763. https://doi.org/10.1016/j.cemconres.2011.03.016.
Somna, K., J. Chai, P. Kajitvichyanukul, and P. Chindaprasrit. 2011. “NaOH-activated ground fly ash geopolymer cured at ambient temperature.” Fuel 90 (6): 2118–2124. https://doi.org/10.1016/j.fuel.2011.01.018.
Struble, L. 2013. “Overview of geopolymer cement.” In Proc., Symp. on Geopolymer Binder Systems, edited by L. Struble and J. Hicks. West Conshohocken, PA: ASTM. https://doi.org/10.1520/STP156620120106.
Suwan, T., M. Fan, and N. Braimah. 2016. “Micro-mechanisms and compressive strength of geopolymer-portland cementitious system under various curing temperatures.” Mater. Chemis. Phys. 180 (Sep): 219–225. https://doi.org/10.1016/j.matchemphys.2016.05.069.
Wan, Q., R. Feng, and S. X. Song. 2017. “Geopolymerization reaction, microstructure and simulation of metakaolin-based geopolymers at extended Si/Al ratios.” Cem. Concr. Compos. 79 (May): 45–52. https://doi.org/10.1016/j.cemconcomp.2017.01.014.
Zhang, W., X. Yao, T. Yang, and Z. Zhang. 2018. “Effect of calcined dolomite addition on sodium carbonate cements with different curing methods.” Adv. Cem. Res. 31 (8): 1–11. https://doi.org/10.1680/jadcr.17.00204.
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© 2021 American Society of Civil Engineers.
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Received: Sep 1, 2020
Accepted: Mar 5, 2021
Published online: Jul 30, 2021
Published in print: Oct 1, 2021
Discussion open until: Dec 30, 2021
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