Technical Papers
Jul 7, 2021

Durability of Slag–Cement Paste Containing Polyaluminum Chloride

Publication: Journal of Materials in Civil Engineering
Volume 33, Issue 9

Abstract

The effect of polyaluminum chloride (PAC) on the durability, microstructure, and corrosion sensitivity of slag–cement pastes was investigated in this research. Various experimental tests were performed to assess the mechanical properties (compressive strength test), durability (rapid chloride migration test, water permeability test, capillary water absorption test, chloride binding test, accelerated carbonation test), microstructure (scanning electron microscopy, X-ray diffraction, mercury intrusion porosimetry), and corrosion sensitivity (accelerated corrosion sensitivity, initial chloride concentration). Experimental results showed that adding 1.5% PAC increased compressive strength by 77.0%, 53.8%, and 19.4% at 3, 7, and 28 days. Resistance to chloride migration, water permeation, capillary water absorption, and carbonation was improved. These results were consistent with the microstructural analysis, which showed that adding PAC facilitated the formation of Friedel’s salt and development of pore structure, which was the key factor for the improved durability of the slag–cement paste. Adding 1.5% PAC had a limited influence on the corrosion sensitivity despite introducing the additional chloride ions into the system. These results promote the further practical application of PAC.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The authors gratefully acknowledge the financial support provided by the Science and Technology Project of Shenzhen, China (Nos. JCYJ20180305124844894 and JCYJ20190808151011502) and the National Natural Science Foundation of China, NSFC-Shandong Joint Fund (No. U2006223).

References

Aperador, W., R. Mejia de Gutierrez, and D. M. Bastidas. 2009. “Steel corrosion behaviour in carbonated alkali-activated slag concrete.” Corros. Sci. 51 (9): 2027–2033. https://doi.org/10.1016/j.corsci.2009.05.033.
ASTM. 1999. Standard test method for water-soluble chloride in mortar and concrete. ASTM C1218/C1218M-99. West Conshohocken, PA: ASTM.
ASTM. 2004. Standard test method for measurement of rate of absorption of water by hydraulic-cement concretes. ASTM C1585-04. West Conshohocken, PA: ASTM.
ASTM. 2020. Standard practice for mechanical mixing of hydraulic cement pastes and mortars of plastic consistency. ASTM C305-20. West Conshohocken, PA: ASTM.
Balonis, M. 2019. “Thermodynamic modelling of temperature effects on the mineralogy of Portland cement systems containing chloride.” Cem. Concr. Res. 120: 66–76. https://doi.org/10.1016/j.cemconres.2019.03.011.
Balonis, M., B. Lothenbach, G. Le Saout, and F. P. Glasser. 2010. “Impact of chloride on the mineralogy of hydrated portland cement systems.” Cem. Concr. Res. 40 (7): 1009–1022. https://doi.org/10.1016/j.cemconres.2010.03.002.
Bastidas, D. M., M. Criado, S. Fajardo, A. La Iglesia, and J. M. Bastidas. 2015. “Corrosion inhibition mechanism of phosphates for early-age reinforced mortar in the presence of chlorides.” Cem. Concr. Compos. 61: 1–6. https://doi.org/10.1016/j.cemconcomp.2015.04.009.
Bignozzi, M. C., and S. Bondua. 2011. “Alternative blended cement with ceramic residues: Corrosion resistance investigation on reinforced mortar.” Cem. Concr. Res. 41 (9): 947–954. https://doi.org/10.1016/j.cemconres.2011.05.001.
Birnin-Yauri, U. A., and F. P. Glasser. 1998. “Friedel’s salt, Ca2Al(OH)6(Cl,OH)·2H2O: Its solid solutions and their role in chloride binding.” Cem. Concr. Res. 28 (12): 1713–1723. https://doi.org/10.1016/S0008-8846(98)00162-8.
Chen, W., B. Li, Q. Li, and J. Tian. 2016. “Effect of polyaluminum chloride on the properties and hydration of slag-cement paste.” Constr. Build. Mater. 124 (15): 1019–1027. https://doi.org/10.1016/j.conbuildmat.2016.08.154.
Chinese National Standard. 1999. Method of testing cement-determination of strength. GB/T 17671-1999. Beijing: Chinese National Standard.
Chinese National Standard. 2006. Test code for hydraulic concrete. SL 352-2006. Beijing: Chinese National Standard.
Chinese National Standard. 2007. Common portlandcement. GB 175-2007. Beijing: Chinese National Standard.
Chinese National Standard. 2009. Code for durability design of concrete structures. GB/T 50476-2008. Beijing: Chinese National Standard.
De Weerdt, K., D. Orsáková, and M. R. Geiker. 2014. “The impact of sulphate and magnesium on chloride binding in portland cement paste.” Cem. Concr. Res. 65: 30–40. https://doi.org/10.1016/j.cemconres.2014.07.007.
Edwin, R. S., M. Mushthofa, E. Gruyaert, and N. De Belie. 2019. “Quantitative analysis on porosity of reactive powder concrete based on automated analysis of back-scattered-electron images.” Cem. Concr. Compos. 96: 1–10. https://doi.org/10.1016/j.cemconcomp.2018.10.019.
Fu, Q., Y. Wu, N. Zhang, S. Hu, F. Yang, L. Lu, and J. Wang. 2020. “Durability and mechanism of high-salt resistance concrete exposed to sewage-contaminated seawater.” Constr. Build. Mater. 257 (Oct): 119534. https://doi.org/10.1016/j.conbuildmat.2020.119534.
Gu, P., J. J. Beaudoin, M. H. Zhang, and V. M. Malhotra. 2000. “Performance of reinforcing steel in concrete containing silica fume and blast-furnace slag ponded with sodium chloride solution.” ACI Mater. J. 97 (3): 254–262.
Gu, Y., R.-P. Martin, O. Omikrine Metalssi, T. Fen-Chong, and P. Dangla. 2019. “Pore size analyses of cement paste exposed to external sulfate attack and delayed ettringite formation.” Cem. Concr. Res. 123 (Sep): 105766. https://doi.org/10.1016/j.cemconres.2019.05.011.
Gupta, S. 2018. “Effect of presoaked superabsorbent polymer on strength and permeability of cement mortar.” Mag. Concr. Res. 70 (9): 473–486. https://doi.org/10.1680/jmacr.17.00120.
Hasholt, M. T., and O. M. Jensen. 2015. “Chloride migration in concrete with superabsorbent polymers.” Cem. Concr. Compo. 55: 290–297. https://doi.org/10.1016/j.cemconcomp.2014.09.023.
Hu, X., C. Shi, Z. Shi, and L. Zhang. 2019. “Compressive strength, pore structure and chloride transport properties of alkali-activated slag/fly ash mortars.” Cem. Concr. Compos. 104 (Nov): 103392. https://doi.org/10.1016/j.cemconcomp.2019.103392.
Juenger, M. C. G., R. Snellings, and S. A. Bernal. 2019. “Supplementary cementitious materials: New sources, characterization, and performance insights.” Cem. Concr. Res. 122: 257–273. https://doi.org/10.1016/j.cemconres.2019.05.008.
Kim, T. 2019. “The effects of polyaluminum chloride on the mechanical and microstructural properties of alkali-activated slag cement paste.” Cem. Concr. Compos. 96: 46–54. https://doi.org/10.1016/j.cemconcomp.2018.11.010.
Kim, T., C. Kang, S. Hong, and K. Y. Seo. 2019a. “Investigating the effects of polyaluminum chloride on the properties of ordinary portland cement.” Materials 12 (20): 3290. https://doi.org/10.3390/ma12203290.
Kim, T., I.-T. Kim, K.-Y. Seo, and H.-J. Park. 2019b. “Strength and pore characteristics of OPC-slag cement paste mixed with polyaluminum chloride.” Constr. Build. Mater. 223 (30): 616–628. https://doi.org/10.1016/j.conbuildmat.2019.07.009.
Koga, G. Y., B. Albert, and R. P. Nogueira. 2018. “Revisiting the ASTM C876 standard for corrosion of reinforcing steel: On the correlation between corrosion potential and polarization resistance during the curing of different cement mortars.” Electrochem. Commun. 94: 1–4. https://doi.org/10.1016/j.elecom.2018.07.017.
Leemann, A., P. Nygaard, J. Kaufmann, and R. Loser. 2015. “Relation between carbonation resistance, mix design and exposure of mortar and concrete.” Cem. Concr. Compos. 62: 33–43. https://doi.org/10.1016/j.cemconcomp.2015.04.020.
Li, K., Y. Zhang, S. Wang, and J. Zeng. 2018. “Impact of carbonation on the chloride diffusivity in concrete: Experiment, analysis and application.” Mater. Struct. 51 (6): 164. https://doi.org/10.1617/s11527-018-1295-8.
Long, W.-J., Y.-C. Gu, B.-X. Xiao, Q.-M. Zhang, and F. Xing. 2018. “Micro-mechanical properties and multi-scaled pore structure of graphene oxide cement paste: Synergistic application of nanoindentation, X-ray computed tomography, and SEM-EDS analysis.” Constr. Build. Mater. 179 (10): 661–674. https://doi.org/10.1016/j.conbuildmat.2018.05.229.
Luo, R., Y. Cai, C. Wang, and X. Huang. 2003. “Study of chloride binding and diffusion in GGBS concrete.” Cem. Concr. Res. 33 (1): 1–7. https://doi.org/10.1016/S0008-8846(02)00712-3.
Luping, T., and L.-O. Nilsson. 1993. “Chloride binding capacity and binding isotherms of OPC pastes and mortars.” Cem. Concr. Res. 23 (2): 247–253. https://doi.org/10.1016/0008-8846(93)90089-R.
Ma, B., X. Liu, H. Tan, T. Zhang, J. Mei, H. Qi, W. Jiang, and F. Zou. 2018. “Utilization of pretreated fly ash to enhance the chloride binding capacity of cement-based material.” Constr. Build. Mater. 175 (30): 726–734. https://doi.org/10.1016/j.conbuildmat.2018.04.178.
Mindess, S., J. F. Young, and D. Darwin. 2003. Concrete. Upper Saddle River, NJ: Prentice Hall.
Morandeau, A., M. Thiéry, and P. Dangla. 2015. “Impact of accelerated carbonation on OPC cement paste blended with fly ash.” Cem. Concr. Res. 67: 226–236. https://doi.org/10.1016/j.cemconres.2014.10.003.
Nestle, N., A. Kuehn, K. Friedemann, C. Horch, F. Stallmach, and G. Herth. 2009. “Water balance and pore structure development in cementitious materials in internal curing with modified superabsorbent polymer studied by NMR.” Microporous Mesoporous Mater. 125 (1–2): 51–57. https://doi.org/10.1016/j.micromeso.2009.02.024.
Ngala, V. T., and C. L. Page. 1997. “Effects of carbonation on pore structure and diffusional properties of hydrated cement pastes.” Cem. Concr. Res. 27 (7): 995–1007. https://doi.org/10.1016/S0008-8846(97)00102-6.
Nguyen, Q. D., and A. Castel. 2020. “Reinforcement corrosion in limestone flash calcined clay cement-based concrete.” Cem. Concr. Res. 132: 106051. https://doi.org/10.1016/j.cemconres.2020.106051.
Olsson, N., L.-O. Nilsson, M. Åhs, and V. Baroghel-Bouny. 2018. “Moisture transport and sorption in cement based materials containing slag or silica fume.” Cem. Concr. Res. 106: 23–32. https://doi.org/10.1016/j.cemconres.2018.01.018.
Sakai, Y. 2019. “Relationship between pore structure and chloride diffusion in cementitious materials.” Constr. Build. Mater. 229 (Dec): 116868. https://doi.org/10.1016/j.conbuildmat.2019.116868.
Scott, A., and M. G. Alexander. 2016. “Effect of supplementary cementitious materials (binder type) on the pore solution chemistry and the corrosion of steel in alkaline environments.” Cem. Concr. Res. 89: 45–55. https://doi.org/10.1016/j.cemconres.2016.08.007.
Sederholm, B., T. J. Ahlström, D. Boubitas, and L. Tang. 2018. New test methodology for determining the corrosion protection ability of binder in concrete. [In Swedish.]. Stockholm, Sweden: RISE CBI.
Sharma, R., and R. A. Khan. 2020. “Carbonation resistance of self-compacting concrete incorporating copper slag as fine aggregates.” J. Mater. Civ. Eng. 32 (6): 04020144. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003200.
Shi, C., and R. L. Day. 1995. “A calorimetric study of early hydration of alkali-slag cements.” Cem. Concr. Res. 25 (6): 1333–1346. https://doi.org/10.1016/0008-8846(95)00126-W.
Shi, C., and R. L. Day. 1996. “Some factors affecting early hydration of alkali-slag cements.” Cem. Concr. Res. 26 (3): 439–447. https://doi.org/10.1016/S0008-8846(96)85031-9.
Shi, Z., C. Shi, S. Wan, N. Li, and Z. Zhang. 2018. “Effect of alkali dosage and silicate modulus on carbonation of alkali-activated slag mortars.” Cem. Concr. Res. 113: 55–64. https://doi.org/10.1016/j.cemconres.2018.07.005.
Skibsted, J., and R. Snellings. 2019. “Reactivity of supplementary cementitious materials (SCMs) in cement blends.” Cem. Concr. Res. 124: 105799. https://doi.org/10.1016/j.cemconres.2019.105799.
Tang, H., F. Xiao, and D. Wang. 2015. “Speciation, stability, and coagulation mechanisms of hydroxyl aluminum clusters formed by PACl and alum: A critical review.” Adv. Colloid Interface Sci. 226: 78–85. https://doi.org/10.1016/j.cis.2015.09.002.
Thapa, V. B., D. Waldmann, and C. Simon. 2019. “Gravel wash mud, a quarry waste material as supplementary cementitious material (SCM).” Cem. Concr. Res. 124: 105833. https://doi.org/10.1016/j.cemconres.2019.105833.
Ukpata, J. O., P. A. M. Basheer, and L. Black. 2019. “Slag hydration and chloride binding in slag cements exposed to a combined chloride-sulphate solution.” Constr. Build. Mater. 195 (20): 238–248. https://doi.org/10.1016/j.conbuildmat.2018.11.055.
Wagner, C., B. Villmann, V. Slowik, and V. Mechtcherine. 2019. “Capillary absorption of cracked strain-hardening cement-based composites.” Cem. Concr. Compos. 97: 239–247. https://doi.org/10.1016/j.cemconcomp.2018.12.017.
Wei, N., Z. Zhang, D. Liu, Y. Wu, J. Wang, and Q. Wang. 2015. “Coagulation behavior of polyaluminum chloride: Effects of pH and coagulant dosage.” Chin. J. Chem. Eng. 23 (6): 1041–1046. https://doi.org/10.1016/j.cjche.2015.02.003.
Wu, Z., Y. Wei, S. Wang, and J. Chen. 2020. “Application of X-ray micro-CT for quantifying degree of hydration of slag-blended cement paste.” J. Mater. Civ. Eng. 32 (3): 04020008. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003082.
Wygocka-Domagałło, A., and H. Garbalińska. 2020. “The effect of pore structure on the water sorption coefficient of cement mortars reinforced with 12 mm polypropylene fibres.” Constr. Build. Mater. 248 (Jul): 116806. https://doi.org/10.1016/j.conbuildmat.2020.118606.
Yang, Z., B. Gao, Y. Wang, Q. Wang, and Q. Yue. 2011. “Aluminum fractions in surface water from reservoirs by coagulation treatment with polyaluminum chloride (PAC): Influence of initial pH and OH/Al3+ ratio.” Chem. Eng. J. 170 (1): 107–113. https://doi.org/10.1016/j.cej.2011.03.036.
Ye, H., L. Huang, and Z. Chen. 2019. “Influence of activator composition on the chloride binding capacity of alkali-activated slag.” Cem. Concr. Compos. 104: 103368. https://doi.org/10.1016/j.cemconcomp.2019.103368.
Ye, H., and A. Radlinska. 2016. “Quantitative analysis of phase assemblage and chemical shrinkage of alkali-activated slag.” J. Adv. Concr. Technol. 14 (5): 245–260. https://doi.org/10.3151/jact.14.245.
Yogarajah, E., T. Nawa, and K. Kurumisawa. 2018. “Influence of surface electrical properties of C-S-H on chloride binding in slag-blended cementitious materials.” J. Mater. Civ. Eng. 30 (5): 04018064. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002263.
Zhang, J., C. Lin, B. Dong, L. Tang, and S. Hong. 2020a. “Inverse modeling deduction of pore distribution in cement materials from capillary absorption features.” Cem. Concr. Compos. 109 (May): 103557. https://doi.org/10.1016/j.cemconcomp.2020.103557.
Zhang, Y., Z. Yang, and G. Ye. 2020b. “Dependence of unsaturated chloride diffusion on the pore structure in cementitious materials.” Cem. Concr. Res. 127 (Jan): 105919. https://doi.org/10.1016/j.cemconres.2019.105919.
Zheng, H., W. Li, F. Ma, and Q. Kong. 2012. “The effect of a surface-applied corrosion inhibitor on the durability of concrete.” Constr. Build. Mater. 37: 36–40. https://doi.org/10.1016/j.conbuildmat.2012.07.007.
Zhou, B., X. Gu, H. Guo, W. Zhang, and Q. Huang. 2018. “Polarization behavior of activated reinforcing steel bars in concrete under chloride environments.” Constr. Build. Mater. 164 (10): 877–887. https://doi.org/10.1016/j.conbuildmat.2018.01.187.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 33Issue 9September 2021

History

Received: Sep 1, 2020
Accepted: Jan 20, 2021
Published online: Jul 7, 2021
Published in print: Sep 1, 2021
Discussion open until: Dec 7, 2021

Permissions

Request permissions for this article.

Authors

Affiliations

Professor, Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen, Guangdong 518060, PR China; Professor, Durability Center for Civil Engineering, College of Civil and Transportation Engineering, Shenzhen Univ., Shenzhen, Guangdong 518060, PR China (corresponding author). ORCID: https://orcid.org/0000-0002-4760-0009. Email: [email protected]
Jun-kai Peng
Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen, Guangdong 518060, PR China; Durability Center for Civil Engineering, College of Civil and Transportation Engineering, Shenzhen Univ., Shenzhen, Guangdong 518060, PR China.
Yu-cun Gu, Ph.D.
Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen, Guangdong 518060, PR China; Durability Center for Civil Engineering, College of Civil and Transportation Engineering, Shenzhen Univ., Shenzhen, Guangdong 518060, PR China.
Assistant Professor, Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen, Guangdong 518060, PR China; Durability Center for Civil Engineering, College of Civil and Transportation Engineering, Shenzhen, Guangdong 518060, PR China. ORCID: https://orcid.org/0000-0002-0974-436X
Luping Tang
Professor, Dept. of Architecture and Civil Engineering, Charmers Univ. of Technology, Gothenburg SE-412 96, Sweden.
Feng Xing
Professor, Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen, Guangdong 518060, PR China; Durability Center for Civil Engineering, College of Civil and Transportation Engineering, Shenzhen, Guangdong 518060, PR China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

  • Investigation on chloride binding capacity and stability of Friedel's salt in graphene oxide reinforced cement paste, Cement and Concrete Composites, 10.1016/j.cemconcomp.2022.104603, 132, (104603), (2022).

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share