Technical Papers
Apr 20, 2021

Technoeconomic Study of Alkali-Activated Slag Concrete with a Focus on Strength, CO2 Emission, and Material Cost

Publication: Journal of Materials in Civil Engineering
Volume 33, Issue 7

Abstract

The present research evaluates the technoeconomic performance of alkali-activated slag (AAS) concrete in comparison with ordinary portland cement (OPC) concrete. Seventy-five AAS mixtures with a wide range of mixture proportions are produced, moist-cured, and tested for their workability (slump or slump flow) and compressive strength. The relative CO2 emission and material cost of the mixtures are also analyzed in comparison with OPC concrete. Regression analyses are carried out to model the mixtures’ consistency and compressive strength and relate them to the governing factors [i.e., (Na+K)/Si, Ca/Si, and (H2O/Solids)vol.]. The extent of the effects and the interactions of such factors on the strength and slump of AAS concrete is quantitatively determined. A multiresponse optimization method with the aim of maximizing the strength for a targeted slump range while minimizing the relative cost and CO2 emission is introduced, and the mixture proportions yielding such conditions are identified. The results suggest that at molar ratios (Na+K)/Si=0.55, Ca/Si=1.01, and volume ratio (H2O/Solids)vol.=1.0, workable AAS mixtures (slump=90  mm) could be produced with strength values exceeding twice the amount and CO2 emissions half that of OPC concrete while maintaining the material cost increase below 40%.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The authors gratefully acknowledge the financial support from Mr. Ali-Mohammad Houshangi, Mr. Amir-Hossein Houshangi, and the White-Damavand Co. The invaluable technical support of Mr. Mahdi Nofallah in preparing the experimental setups is greatly appreciated.

References

Al Bakri, A. M., H. Kamarudin, M. Bnhussain, I. K. Nizar, A. R. Rafiza, and Y. Zarina. 2012. “The processing, characterization, and properties of fly ash based geopolymer concrete.” Rev. Adv. Mater. Sci. 30 (1): 90–97.
Andrew, R. M. 2018. “Global CO2 emissions from cement production.” Earth Syst. Sci. Data 10 (1): 195–217. https://doi.org/10.5194/essd-10-195-2018.
Annadurai, A., and A. Ravichandran. 2014. “Development of mix design for high strength concrete with admixtures.” J. Mech. Civ. Eng. 10 (5): 22–27. https://doi.org/10.9790/1684-1052227.
Aperador Chaparro, W., D. Martínez Bastidas, B. Ruíz, and J. Hernando. 2012. “Mechanical properties and absorption of chlorides in alkali activated slag concrete and exposed to carbonation.” Revista Facultad de Ingeniería Universidad de Antioquia 62 (Mar): 189–195.
ASTM. 2018. Standard test method for slump flow of self-consolidating concrete. ASTM C1611/C1611M-18. West Conshohocken, PA: ASTM.
ASTM. 2020a. Standard test method for compressive strength of cylindrical concrete specimens. ASTM C39/C39M-20. West Conshohocken, PA: ASTM.
ASTM. 2020b. Standard test method for slump of hydraulic-cement concrete. ASTM C143/C143M-20. West Conshohocken, PA: ASTM.
Capitolaggregate.com. 2018a. “Coarse aggregates.” Accessed November 20, 2018. http://www.capitolaggregates.com/s/Products-Coarse-Aggregate.
Capitolaggregate.com. 2018b. “Fine aggregates.” Accessed November 20, 2018. http://www.capitolaggregates.com/s/Products-Fine-Aggregates.
Chidiac, S. E., F. Habibbeigi, and D. Chan. 2006. “Slump and slump flow for characterizing yield stress of fresh concrete.” ACI Mater. J. 103 (6): 413.
Chidiac, S. E., O. Maadani, A. G. Razaqpur, and N. P. Mailvaganam. 2000. “Controlling the quality of fresh concrete—A new approach.” Mag. Concr. Res. 52 (5): 353–363. https://doi.org/10.1680/macr.2000.52.5.353.
Collins, F., and J. G. Sanjayan. 1999. “Workability and mechanical properties of alkali activated slag concrete.” Cem. Concr. Res. 29 (3): 455–458. https://doi.org/10.1016/S0008-8846(98)00236-1.
Davidovits, J. 1994. “Global warming impact on the cement and aggregates industries.” World Resour. Rev. 6 (2): 263–278.
de Best, R. 2020. “Cement prices in the United States from 2007 to 2019 (in U.S. dollars per metric ton).” Accessed November 10, 2020. https://www.statista.com/statistics/219339/us-prices-of-cement/.
Derringer, G., and R. Suich. 1980. “Simultaneous optimization of several response variables.” J. Qual. Technol. 12 (4): 214–219. https://doi.org/10.1080/00224065.1980.11980968.
Flower, D. J., and J. G. Sanjayan. 2007. “Green house gas emissions due to concrete manufacture.” Int. J. Life Cycle Assess. 12 (5): 282. https://doi.org/10.1065/lca2007.05.327.
Frost, J. 2013. “Multiple regression analysis: Use adjusted R-squared and predicted R-squared to include the correct number of variables.” Minitab Blog 13 (6).
Glukhovsky, V. 1959. “Soil silicates.” In Gosstroyizdat. Kiev, Ukraine: Gosstroyizdat Ukrainy Publishing.
Gong, Z., and Z. Zhang. 2004. “A study on embodied environmental profile during the life cycle of cement.” [In Chinese.] China Civ. Eng. J. 37: 86–91.
Gunasekara, C., D. W. Law, S. Setunge, and J. G. Sanjayan. 2015. “Zeta potential, gel formation and compressive strength of low calcium fly ash geopolymers.” Constr. Build. Mater. 95 (Oct): 592–599. https://doi.org/10.1016/j.conbuildmat.2015.07.175.
Hadi, M., H. Zhang, and S. Parkinson. 2019. “Optimum mix design of geopolymer pastes and concretes cured in ambient condition based on compressive strength, setting time and workability.” J. Build. Eng. 23 (May): 301–313. https://doi.org/10.1016/j.jobe.2019.02.006.
Hardjito, D., and B. V. Rangan. 2005. Development and properties of low-calcium fly ash-based geopolymer concrete. Perth, Australia: Curtin Univ. of Technology.
ICIS (Independent Commodity Intelligence Services). 2018c. “Sodium silicates prices increase on energy costs.” Accessed November 20, 2018. https://www.icis.com/explore/resources/news/2004/09/10/611782/sodium-silicates-prices-increase-on-energy-costs/.
ICIS (Independent Commodity Intelligence Services). 2018d. “US caustic soda could push higher on restricted global supply.” Accessed November 20, 2018. https://www.icis.com/explore/resources/news/2018/01/03/10172550/outlook-18-us-caustic-soda-could-push-higher-on-restricted-global-supply/.
ISIRI (Institute of Standards and Industrial Research of Iran). 2013. Standard specifications for concrete aggregates. ISIRI 302. Tehran, Iran: ISIRI.
Ismailov, A., K. Baybolov, R. Ristavletov, B. Kopzhasarov, M. Kambarov, U. Ussipbayev, R. Kudabayev, and S. Mominova. 2018. “Effect of cost-effective alkaline additives on the hydration of slag-cement mixtures.” J. Adv. Concr. Technol. 16 (9): 429–440. https://doi.org/10.3151/jact.16.429.
Kalyoncu, R. S. 2001. Slag-iron and steel. Washington, DC: USGS.
Kazemian, A., A. G. Vayghan, and F. Rajabipour. 2015. “Quantitative assessment of parameters that affect strength development in alkali activated fly ash binders.” Constr. Build. Mater. 93 (Sep): 869–876. https://doi.org/10.1016/j.conbuildmat.2015.05.078.
Komura, R., Y. Tanigawa, H. Mori, and Y. Kurokawa. 1994. “Rheological study on slumping behavior of fresh concrete.” Trans. Jpn. Concr. Inst. 59 (462): 1–10. https://doi.org/10.3130/aijs.59.1_8.
Li, W., Z. Tang, V. Tam, X. Zhao, and K. F. Wang. 2019. “A review on durability of alkali-activated system from sustainable construction materials to infrastructures.” ES Mater. Manuf. 4 (Feb): 2–19. https://doi.org/10.30919/esmm5f204.
Pu, X., C. Gan, S. Wang, and C. Yang. 1988. Summary reports of research on alkali-activated slag cement and concrete. Chongqing, China: Chongqing Institute of Architecture and Engineering.
Puertas, F., B. González-Fonteboa, I. González-Taboada, M. Alonso, M. Torres-Carrasco, G. Rojo, and F. Martínez-Abella. 2018. “Alkali-activated slag concrete: Fresh and hardened behavior.” Cem. Concr. Compos. 85 (Jan): 22–31. https://doi.org/10.1016/j.cemconcomp.2017.10.003.
Shi, C., and J. Qian. 2000. “High performance cementing materials from industrial slags—A review.” Resour. Conserv. Recycl. 29 (3): 195–207. https://doi.org/10.1016/S0921-3449(99)00060-9.
Songpiriyakij, S., T. Kubprasit, C. Jaturapitakkul, and P. Chindaprasirt. 2010. “Compressive strength and degree of reaction of biomass-and fly ash-based geopolymer.” Constr. Build. Mater. 24 (3): 236–240. https://doi.org/10.1016/j.conbuildmat.2009.09.002.
Tang, Z., W. Li, Y. Hu, J. L. Zhou, and V. W. Tam. 2019. “Review on designs and properties of multifunctional alkali-activated materials (AAMs).” Constr. Build. Mater. 200 (Mar): 474–489. https://doi.org/10.1016/j.conbuildmat.2018.12.157.
Tanigawa, Y. 1986. “Rheological analysis of slumping behavior of fresh concrete.” In Proc., 29th Japan Congress on Materials Research. Oak Ridge, TN: DOE.
Van Gijlswijk, R., S. Pascale, and G. Urbano. 2015. “Carbon footprint of concrete based on secondary materials.” Heron J. 60 (1–2): 113–139.
Wang, S. 2009. Research on the EIA of ready-mixed concrete during the life cycle. Beijing, China: Tsinghua Univ.
Wang, S.-D., X.-C. Pu, K. Scrivener, and P. Pratt. 1995. “Alkali-activated slag cement and concrete: A review of properties and problems.” Adv. Cem. Res. 7 (27): 93–102. https://doi.org/10.1680/adcr.1995.7.27.93.
You, S., S. W. Ho, T. Li, T. Maneerung, and C.-H. Wang. 2019. “Techno-economic analysis of geopolymer production from the coal fly ash with high iron oxide and calcium oxide contents.” J. Hazard. Mater. 361 (Jan): 237–244. https://doi.org/10.1016/j.jhazmat.2018.08.089.
Zhang, Y., M. Liu, H. Xie, and Y. Wang. 2015. “Assessment of CO2 emissions and cost in fly ash concrete: Environment, energy and applied technology.” In Proc., 2014 Int. Conf. on Frontier of Energy and Environment Engineering (ICFEEE 2014). Boca Raton, FL: CRC Press.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 33Issue 7July 2021

History

Received: Jul 1, 2020
Accepted: Nov 19, 2020
Published online: Apr 20, 2021
Published in print: Jul 1, 2021
Discussion open until: Sep 20, 2021

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Postdoctoral Researcher, Sustainable Materials Management, Vlaamse Instelling voor Technologisch Onderzoek, 200 Boeretang, 2400 Mol, Belgium; Assistant Professor, Dept. of Civil Engineering, K. N. Toosi Univ. of Technology, 1346 Valiasr St., 15875 Tehran, Iran (corresponding author). ORCID: https://orcid.org/0000-0002-0130-4976. Email: [email protected]; [email protected]
Mohammad-Hossein Nofallah [email protected]
M.Sc. Graduate, Dept. of Civil Engineering, Islamic Azad Univ., Central Tehran Branch, Poonak Square, 14696 Tehran, Iran. Email: [email protected]
Professor, Dept. of Civil Engineering, Sharif Univ. of Technology, Azadi St., 11365 Tehran, Iran. ORCID: https://orcid.org/0000-0003-4450-0202. Email: [email protected]

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Cited by

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