Technical Papers
Sep 28, 2020

Sulfate Resistance and Drying Shrinkage of Self-Compacting Concrete Incorporating Copper Slag

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 12

Abstract

This research involved a detailed laboratory study of sulfate resistance and drying shrinkage of self-compacting concrete (SCC) mixes made with copper slag. After an initial curing of 28 days, SCC samples were subjected to a sulfate solution for a period of over 1 year. Changes in compressive strength, mass gain, and expansion measurements were reported for SCC samples. Comparative analysis of compressive strength was done with the respective water-cured samples for up to 1 year. Drying shrinkage of SCC was studied for up to 448 days. Statistical significance of the compressive strength of SCC mixes was determined using analysis of variance. No major catastrophic damage was reported. An improvement in compressive strength of SCC mixes was observed from 28 to 90 days. Peaks of Ca and Si under energy-dispersive spectroscopy analysis revealed the development of calcium silicate hydrate layers leading to a gain in strength. No major phase change under X-ray diffraction (XRD) was observed for SCC mixes under normal curing as well as under sulfate attack. Minute expansions were reported for SCC mixes with copper slag. SCC mixes containing up to 60% copper slag gave lower drying shrinkage values than control SCC mix. The results of compressive strength of SCC exposed to sulfate were found out to be statistically significant.

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Data Availability Statement

All data used during the study appear in the published article.

References

Afshoon, I., and Y. Sharifi. 2017. “Use of copper slag microparticles in self-consolidating concrete.” ACI Mater. J. 114 (5): 691–699.
Al-Swaidani, A. M. 2019. “Use of micro and nano volcanic scoria in the concrete binder: Study of compressive strength, porosity and sulfate resistance.” Case Stud. Constr. Mater. 11 (Dec): e00294. https://doi.org/10.1016/j.cscm.2019.e00294.
ASTM. 2003. Standard test method for length change of hardened hydraulic-cement mortar and concrete. ASTM C157. West Conshohocken, PA: ASTM.
ASTM. 2010. Standard test method for length change of hydraulic cement mortars exposed to a sulfate solution. ASTM C1012. West Conshohocken, PA: ASTM.
Ayano, T., and K. Sakata. 2000. “Durability of concrete with copper slag fine aggregate.” ACI Spec. Publ. 192: 141–158.
Barr, B., S. B. Hoseinian, and M. A. Beygi. 2003. “Shrinkage of concrete stored in natural environments.” Cem. Concr. Compos. 25 (1): 19–29. https://doi.org/10.1016/S0958-9465(01)00044-0.
BIS (Bureau of Indian Standards). 1959. Methods of test for strength of concrete. IS 516. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 1971. Specification for coarse and fine aggregates from natural sources for concrete. IS 383. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 2003. Pulverized fuel ash-specification. Part 1: For use as pozzolana in cement, cement mortar and concrete. IS 3812. New Delhi, India: BIS.
BIS (Bureau of Indian Standards). 2013. Ordinary portland cement, 43 grade: Specification. IS 8112. New Delhi, India: BIS.
EFNARC (European Federation of National Associations Representing Producers and Applicators of Specialist Building Products for Concrete). 2005. Specification and guidelines for self-compacting concrete. Surrey, UK: EFNARC.
Gesoğlu, M., E. Güneyisi, and E. Özbay. 2009. “Properties of self-compacting concretes made with binary, ternary, and quaternary cementitious blends of fly ash, blast furnace slag, and silica fume.” Constr. Build. Mater. 23 (5): 1847–1854. https://doi.org/10.1016/j.conbuildmat.2008.09.015.
Glasser, F. P., J. Marchand, and E. Samson. 2008. “Durability of concrete—Degradation phenomena involving detrimental chemical reactions.” Cement Concr. Res. 38 (2): 226–246. https://doi.org/10.1016/j.cemconres.2007.09.015.
Gorai, B., and R. K. Jana. 2003. “Characteristics and utilisation of copper slag-A review.” Resour. Conser. Recycl. 39 (4): 299–313. https://doi.org/10.1016/S0921-3449(02)00171-4.
Gupta, N., and R. Siddique. 2019. “Strength and micro-structural properties of self-compacting concrete incorporating copper slag.” Constr. Build. Mater. 224 (Nov): 894–908. https://doi.org/10.1016/j.conbuildmat.2019.07.105.
Gupta, N., and R. Siddique. 2020. “Durability characteristics of self-compacting concrete made with copper slag.” Constr. Build. Mater. 247 (Jun): 118580. https://doi.org/10.1016/j.conbuildmat.2020.118580.
Hwang, C. L., and J. C. Laiw. 1989. “Properties of concrete using copper slag as a substitute for fine aggregate.” ACI Spec. Publ. 114: 1677–1696.
International Copper Study Group. 2018. The world copper fact book. Lisbon Portugal: International Copper Study Group.
Mehta, P. K. 1980. “Durability of concrete in marine environment—A review.” ACI Spec. Publ. 65: 1–20.
Mindess, S., J. F. Young, and D. Darwin. 2003. Concrete. 2nd ed., 644. Upper Saddle River, NJ: Prentice Hall.
Mithun, B. M., and M. C. Narasimhan. 2016. “Performance of alkali activated slag concrete mixes incorporating copper slag as fine aggregate.” J. Cleaner Prod. 112 (1): 837–844. https://doi.org/10.1016/j.jclepro.2015.06.026.
Najimi, M., J. Sobhani, and A. R. Pourkhorshidi. 2011. “Durability of copper slag contained concrete exposed to sulfate attack.” Constr. Build. Mater. 25 (4): 1895–1905. https://doi.org/10.1016/j.conbuildmat.2010.11.067.
Neville, A. 2004. “The confused world of sulfate attack on concrete.” Cem. Concr. Res. 34 (8): 1275–1296. https://doi.org/10.1016/j.cemconres.2004.04.004.
Roy, D. M., and G. M. Idorn. 1982. “Hydration, structure, and properties of blast furnace slag cements, mortars, and concrete.” ACI J. 79 (6): 444–457.
Scherer, G. W. 1999. “Crystallization in pores.” Cem. Concr. Res. 29 (8): 1347–1358. https://doi.org/10.1016/S0008-8846(99)00002-2.
Sharma, R., and R. A. Khan. 2017. “Durability assessment of self-compacting concrete incorporating copper slag as fine aggregates.” Constr. Build. Mater. 155 (Nov): 617–629. https://doi.org/10.1016/j.conbuildmat.2017.08.074.
Tam, C. M., V. W. Y. Tam, and K. M. Ng. 2012. “Assessing drying shrinkage and water permeability of reactive powder concrete produced in Hong Kong.” Constr. Build. Mater. 26 (1): 79–89. https://doi.org/10.1016/j.conbuildmat.2011.05.006.
Thomas, B. S., A. Damare, and R. C. Gupta. 2013. “Strength and durability characteristics of copper tailing concrete.” Constr. Build. Mater. 48 (Nov): 894–900. https://doi.org/10.1016/j.conbuildmat.2013.07.075.
Tian, B., and M. D. Cohen. 2000. “Does gypsum formation during sulfate attack on concrete lead to expansion?” Cem. Concr. Res. 30 (1): 117–123. https://doi.org/10.1016/S0008-8846(99)00211-2.
Wong, A. C. L., P. A. Childs, R. Berndt, T. Macken, G. D. Peng, and N. Gowripalan. 2007. “Simultaneous measurement of shrinkage and temperature of reactive powder concrete at early-age using fibre Bragg grating sensors.” Cem. Concr. Compos. 29 (6): 490–497. https://doi.org/10.1016/j.cemconcomp.2007.02.003.
Yu, C., W. Sun, and K. Scrivener. 2013. “Mechanism of expansion of mortars immersed in sodium sulfate solutions.” Cem. Concr. Res. 43 (Jan): 105–111. https://doi.org/10.1016/j.cemconres.2012.10.001.
Zhang, J., Y. D. Han, and Y. Gao. 2013. “Effects of water-binder ratio and coarse aggregate content on interior humidity, autogenous shrinkage, and drying shrinkage of concrete.” J. Mater. Civ. Eng. 26 (1): 184–189. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000799.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 12December 2020

History

Received: Jan 21, 2020
Accepted: Jun 16, 2020
Published online: Sep 28, 2020
Published in print: Dec 1, 2020
Discussion open until: Feb 28, 2021

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Authors

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Ph.D. Student, Dept. of Civil Engineering, Thapar Institute of Engineering and Technology, Deemed Univ., Patiala, Punjab 147004, India (corresponding author). ORCID: https://orcid.org/0000-0002-3142-1997. Email: [email protected]
Rafat Siddique, M.ASCE
Senior Professor, Dept. of Civil Engineering, Thapar Institute of Engineering and Technology, Deemed Univ., Patiala, Punjab 147004, India.

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