Technical Papers
May 27, 2020

Effects of Curing Method and Glass Transition Temperature on the Unconfined Compressive Strength of Acrylic Liquid Polymer–Stabilized Kaolinite

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 8

Abstract

Polymers have been widely known as nontraditional soil stabilizers capable of replacing common soil additives to reach superior soil stabilization outcomes. While numerous studies represent the efficiency of polymers as one of the soil additives, there is still ambiguity about the optimum condition of curing, soil-polymer interaction, and effect of each property of the polymer on the final mixture. In this study, to investigate the effect of sample preparation on the strength of the clay, five different curing methods were examined to assess the unconfined compressive strength (UCS) of the stabilized clay with acrylic polymers. Since the glass transition temperature (Tg) is one of the most important characteristics of polymers that influences various mechanical properties of the polymer such as elastic modulus, in this study, it is considered by choosing two similar acrylic polymers with different glass transition temperatures. Two acrylic polymers with Tg above and below the ambient temperature (i.e., 13°C and +33°C) were used as soil stabilizers. Different curing variables including polymer concentration (0%–10%), curing time (immediately to 1 week), and curing temperature (ambient to 100°C) may control the clay-polymer composite behavior and were analyzed in this work. For Method I, samples were prepared, compacted, and tested immediately. For methods II and III, samples were oven-dried at 100°C for 1 day, air-dried at room temperature for 7 days, respectively, and subjected to UCS testing. Method IV consisted of curing the remolded samples in a double vinyl bag for 1 day before the UCS test. For Method V, the treated soil mix was oven-dried and then remoistened (using the original liquid: i.e., water or polymer solution) to reach the target moisture content followed by a UCS test. Samples cured at 100°C in the oven showed a significant increase in the UCS due to a complete moisture loss. There was no considerable difference between the samples cured in a vinyl bag and noncured samples. The results also showed that the polymer with a higher Tg is more effective for soil improvement given all other conditions are kept unchanged.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

References

Adam, J.-L., and X. Zhang. 2014. Chalcogenide glasses: Preparation, properties and applications. Cambridge, UK: Elsevier Science.
Ali, H., and M. Mohamed. 2018. “The effects of lime content and environmental temperature on the mechanical and hydraulic properties of extremely high plastic clays.” Appl. Clay Sci. 161 (Sep): 203–210. https://doi.org/10.1016/j.clay.2018.04.012.
Al-Khanbashi, A., and S. W. Abdalla. 2006. “Evaluation of three waterborne polymers as stabilizers for sandy soil.” Geotech. Geol. Eng. 24 (6): 1603–1625. https://doi.org/10.1007/s10706-005-4895-3.
Al-Khanbashi, A., and M. El-Gamal. 2003. “Modification of sandy soil using water-borne polymer.” J. Appl. Polym. Sci. 88 (10): 2484–2491. https://doi.org/10.1002/app.12066.
Anagnostopoulos, C. A. 2005. “Laboratory study of an injected granular soil with polymer grouts.” Tunnelling Underground Space Technol. 20 (6): 525–533. https://doi.org/10.1016/j.tust.2005.04.005.
Andry, H., T. Yamamoto, T. Irie, S. Moritani, M. Inoue, and H. Fujiyama. 2009. “Water retention, hydraulic conductivity of hydrophilic polymers in sandy soil as affected by temperature and water quality.” J. Hydrol. 373 (1–2): 177–183. https://doi.org/10.1016/j.jhydrol.2009.04.020.
Arasan, S., F. Işik, R. K. Akbulut, A. Ş. Zaimoğlu, and O. Nasirpur. 2015. “Rapid stabilization of sands with deep mixing method using polyester.” Periodica Polytech. Civ. Eng. 59 (3): 405–411. https://doi.org/10.3311/PPci.7956.
ASTM. 2012. Standard test methods for laboratory compaction characteristics of soil using standard effort (12400 ftl-bf/ft3 (600 kN-m/m3)). ASTM D698. West Conshohocken, PA: ASTM.
ASTM. 2016. Standard test method for unconfined compressive strength of cohesive soil. ASTM D2166. West Conshohocken, PA: ASTM.
ASTM. 2017a. Standard test methods for liquid limit, plastic limit, and plasticity index of soils. ASTM D4318. West Conshohocken, PA: ASTM.
ASTM. 2017b. Standard test method for particle-size distribution (gradation) of fine-grained soils using the sedimentation (hydrometer) analysis. ASTM D7928. West Conshohocken, PA: ASTM.
ASTM. 2017c. Standard test methods for particle-size distribution (gradation) of soils using sieve analysis. ASTM D6913. West Conshohocken, PA: ASTM.
Azzam, W. R. 2011. “Reduction of the shrinkage- swelling potential with polymer nanocomposite stabilization.” Appl. Polym. Sci. 123 (1): 299–306. https://doi.org/10.1002/app.33642.
Baghini, M. S., A. Ismail, S. S. Naseralavi, and A. A. Firoozi. 2016. “Performance evaluation of road base stabilized with styrene–butadiene copolymer latex and portland cement performance evaluation of road base.” Int. J. Pavement Res. Technol. 9 (4): 321–336. https://doi.org/10.1016/j.ijprt.2016.08.006.
Bai, W., H. Zhang, B. Liu, Y. Wu, and J. Q. Song. 2010. “Effects of super-absorbent polymers on the physical and chemical properties of soil following different wetting and drying cycles.” Soil Use Manage. 26 (3): 253–260. https://doi.org/10.1111/j.1475-2743.2010.00271.x.
Bekkouche, S. R., and G. Boukhatem. 2016. “Experimental characterization of clay soils behavior stabilized by polymers.” J. Fundam. Appl. Sci. 8 (3): 1193–1205. https://doi.org/10.4314/jfas.v8i3.30.
Bu, F., J. Liu, Y. Bai, D. P. Kanungo, Z. Song, and F. Kong. 2019. “Effects of the preparation conditions and reinforcement mechanism of polyvinyl acetate soil stabilizer.” Polymers 11 (3): 506. https://doi.org/10.3390/polym11030506.
Callebaut, F., D. Gabriels, and M. De Boodt. 1979. “The effect of polymer structure on soil physico-chemical properties and soil water evaporation.” J. Chem. Technol. Biotechnol. 29 (12): 723–729. https://doi.org/10.1002/jctb.503291203.
Cameron, D., C. Hopkins, and M. Rahman. 2016. “Hydrophobic polymer additive for stabilization of aggregates in local government roads.” Procedia Eng. 143: 26–33. https://doi.org/10.1016/j.proeng.2016.06.004.
David, A. L. 1997. “Bonding between polyacrylamide and clay mineral surfaces.” Soil Sci. 162 (11): 826–832. https://doi.org/10.1097/00010694-199711000-00006.
Deng, Y., J. B. Dixon, G. N. White, R. H. Loeppert, and A. S. R. Juo. 2006. “Bonding between polyacrylamide and smectite.” Colloids Surf. A 281: 82–91. https://doi.org/10.1016/j.colsurfa.2006.02.030.
De Rosa, J., D. M. Pontolillo, C. Di Maio, and R. Vassallo. 2016. “Chemical clay soil improvement: From laboratory to field test.” Procedia Eng. 158: 284–289. https://doi.org/10.1016/j.proeng.2016.08.443.
Estabragh, A. 2010. “Effect of resin on the strength of soil-cement mixture.” J. Mater. Civ. Eng. 23 (Jul): 969–976. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000252.
Farzi, G. A., and M. Mortezaei. 2016. “Acrylic latexes prepared via miniemulsion polymerization technique for improvement of soil behavior.” J. Nanosci. Technol. 2 (1): 50–54.
Fungaroli, A. A., and S. R. Prager. 1969. “Evaluation of some acrylic polymers as soil stabilizers.” Ind. Eng. Chem. Prod. Res. Dev. 8 (4): 450–453. https://doi.org/10.1021/i360032a026.
Geiman, C. M., T. L. Brandon, and R. H. Plaut. 2005. “Stabilization of soft clay subgrades in Virginia phase I laboratory study.” Ph.D. dissertation, Dept. of Civil Engineering, Virginia Polytechnic Institute, State Univ.
Ghasemzadeh, H., and F. Akbari. 2019. “Determining the bearing capacity factor due to non-linear matric suction distribution in the soil.” Can. J. Soil Sci. 99 (4): 434–446. https://doi.org/10.1139/cjss-2019-0071.
Ghasemzadeh, H., and E. A. Jalalabad. 2011. “Computing the compressive strength of carbon nanotube/cement composite.” Int. J. Civ. Eng. 9 (3): 223–229.
Ghasemzadeh, H., and M. Tabaiyan. 2017. “The effect of diesel fuel pollution on the efficiency of soil stabilization method.” Geotech. Geol. Eng. 35 (1): 475–484. https://doi.org/10.1007/s10706-016-0121-8.
Hamdan, N., and E. Kavazanjian. 2016. “Enzyme-induced carbonate mineral precipitation for fugitive dust control.” Géotechnique 66 (7): 546–555. https://doi.org/10.1680/jgeot.15.P.168.
Hirkane, S. P., N. G. Gore, and P. J. Salunke. 2014. “Ground improvement techniques.” Int. J. Inventive Eng. Sci. (IJIES) 2 (2): 11–13.
Ingles, O. G., and J. B. Metcalf. 1973. Soil stabilization: Principles and practice. New York: Wiley.
Kolay, P. K., B. Dhakal, S. Kumar, and V. K. Puri. 2016. “Effect of liquid acrylic polymer on geotechnical properties of fine-grained soils.” Int. J. Geosynthetics Ground Eng. 2 (4): 29. https://doi.org/10.1007/s40891-016-0071-5.
Lahalih, S. M., and N. Ahmed. 1998. “Effect of new soil stabilizers on the compressive strength of dune sand.” Constr. Build. Mater. 12 (6–7): 321–328. https://doi.org/10.1016/S0950-0618(98)00024-5.
Levy, G. J., and M. Agassi. 1995. “Polymer molecular weight and degree of drying effects on infiltration and erosion of three different soils.” Aust. J. Soil Res. 33 (6): 1007–1018. https://doi.org/10.1071/SR9951007.
Li, Y., M. Shao, and R. Horton. 2011. “Effect of polyacrylamide applications on soil hydraulic characteristics and sediment yield of sloping land.” Procedia Environ. Sci. 11 (PART B): 763–773. https://doi.org/10.1016/j.proenv.2011.12.118.
Majeed, Z. H., and M. R. Taha. 2013. “A review of stabilization of soils by using nanomaterials.” Aust. J. Basic Appl. Sci. 7 (2): 576–581.
Mirzababaei, M., A. Arulrajah, and M. Ouston. 2017. “Polymers for stabilization of soft clay soils.” Procedia Eng. 189 (May): 25–32. https://doi.org/10.1016/j.proeng.2017.05.005.
Mirzababaei, M., S. Yasrobi, and A. Al-Rawas. 2009. “Effect of polymers on swelling potential of expansive soils.” Proc. Inst. Civ. Eng. Ground Improv. 162 (3): 111–119. https://doi.org/10.1680/grim.2009.162.3.111.
Mitchell, J. K., and K. Soga. 2005. Fundamentals of soil behavior. New York: Wiley.
Mohammed, A. S., and C. Vipulanandan. 2014. “Compressive and tensile behavior of polymer treated sulfate contaminated CL soil.” Geotech. Geol. Eng. 32 (1): 71–83. https://doi.org/10.1007/s10706-013-9692-9.
Mousavi, F., E. Abdi, and H. Rahimi. 2014. “Effect of polymer stabilizer on swelling potential and CBR of forest road material.” KSCE J. Civ. Eng. 18 (7): 2064–2071. https://doi.org/10.1007/s12205-014-0137-7.
Naeini, S. A., B. Naderinia, and E. Izadi. 2012. “Unconfined compressive strength of clayey soils stabilized with waterborne polymer.” KSCE J. Civ. Eng. 16 (6): 943–949. https://doi.org/10.1007/s12205-012-1388-9.
Newman, K., and J. S. Tingle. 2004. Emulsion polymers for soil stabilization. Washington, DC: Federal Aviation Administration.
Nicholson, J. W. 1997. The chemistry of polymers. London: Royal Society of Chemistry.
Nielsen, E. L., and R. F. Landel. 1993. Mechanical properties of polymers and composites. Boca Raton, FL: CRC Press.
Orts, W. J., R. E. Sojka, G. M. Glenn, and R. A. Gross. 1999. “Preventing soil erosion with polymer additives.” Polymer News 24: 406–413.
Pethrick, R. A. 2007. Polymer structure characterization: From nano to macro organization. London: Royal Society of Chemistry.
Purwana, Y., P. Jitsangiam, H. Nikraz, and A. Jotisankasa. 2011. “Experimental studies of suction-monitored direct shear apparatus on Perth poorly graded sand.” In Proc., Int. Conf. on Advances in Geotechnical Engineering. Perth, Australia: Curtin Univ.
Qing-wen, Y., P. Xiang-jun, and H. Run-qiu. 2019. “Impact of polymer mixtures on the stabilization and erosion control of silty sand slope.” J. Mt. Sci. 16 (2): 470–485. https://doi.org/10.1007/s11629-018-4905-6.
Rauch, A. F., J. S. Harmon, L. E. Katz, and H. M. Liljestrand. 2002. “Liquid soil stabilizers: Measured effects on engineering properties of clay.” Transp. Res. Rec. 1787 (1): 33–41. https://doi.org/10.3141/1787-04.
Rezaeimalek, S., J. Huang, and S. Bin-shafique. 2017. “Mixing methods evaluation of a styrene-acrylic based liquid polymer for sand and clay stabilization.” In Proc., Int. Conf. on Transportation Infrastructure and Materials. Qingdao, China: Qingdao Univ. of Technology.
Rezaeimalek, S., J. Huang, and S. Bin-shafique. 2018. “Mixing methods evaluation of a styrene-acrylic based liquid polymer for sand and clay stabilization.” J. Mater. Civ. Eng. 30 (9): 04018200. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002396.
Soltani, A., A. Deng, A. Taheri, and M. Mirzababaei. 2019. “A sulphonated oil for stabilisation of expansive soils.” Int. J. Pavement Eng. 20 (11): 1285–1298. https://doi.org/10.1080/10298436.2017.1408270.
Theng, B. K. G. 1982. “Clay-polymer interactions : Summary and perspectives.” Clays Clay Miner. 30 (1): 1–10. https://doi.org/10.1346/CCMN.1982.0300101.
Tingle, J., and R. Santoni. 2003. “Stabilization of clay soils with nontraditional additives.” Transp. Res. Rec. 1819 (1): 72–84. https://doi.org/10.3141/1819b-10.
Wallace, G. A., and A. Wallace. 1986. “Control of soil erosion by polymeric soil conditioners.” Soil Sci. 141 (5): 363–367. https://doi.org/10.1097/00010694-198605000-00012.
Wheeler, S. J., and V. Sivakumar. 1995. “An elasto plastic critical state framework for unsaturated soil.” Géotechnique 45 (1): 35–53. https://doi.org/10.1680/geot.1995.45.1.35.
Yang, Q., C. Zheng, and J. Huang. 2018. “Curing of sand stabilized with alkali lignin.” In Proc., GeoShanghai 2018 Int. Conf. on Ground Improvement and Geosynthetics, 157–168. Singapore: Springer.
Yazdandoust, F., and S. S. Yasrobi. 2010. “Effect of cyclic wetting and drying on swelling behavior of polymer-stabilized expansive clays.” Appl. Clay Sci. 50 (4): 461–468. https://doi.org/10.1016/j.clay.2010.09.006.
Zhan, Q., and C. Qian. 2017. “Stabilization of sand particles by bio-cement based on CO2 capture and utilization: Process, mechanical properties and microstructure.” Constr. Build. Mater. 133 (Feb): 73–80. https://doi.org/10.1016/j.conbuildmat.2016.12.058.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 8August 2020

History

Received: Mar 17, 2019
Accepted: Jan 27, 2020
Published online: May 27, 2020
Published in print: Aug 1, 2020
Discussion open until: Oct 27, 2020

Permissions

Request permissions for this article.

Authors

Affiliations

Associated Professor, Dept. of Civil Engineering, K.N. Toosi Univ. of Technology, P.O. Box: 15875-4416, Tehran, Iran (corresponding author). ORCID: https://orcid.org/0000-0001-6267-9619. Email: [email protected]; [email protected]
Aida Mehrpajouh
Ph.D. Candidate, Dept. of Civil Engineering, K.N. Toosi Univ. of Technology, P.O. Box: 15875-4416, Tehran, Iran.
Malihe Pishvaei
Assistant Professor, Dept. of Resin and Additives, Institute for Color Science and Technology, P.O. Box: 16765-654, Tehran, Iran.
Mehdi Mirzababaei
Senior Lecturer, Dept. of Civil Engineering, School of Engineering and Technology, Central Queensland Univ., Melbourne, VIC 3000, Australia.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share