Technical Papers
Oct 24, 2019

Aging Evaluation of Amorphous Carbon-Modified Asphalt Binders Using Rheological and Chemical Approach

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 1

Abstract

Like every other organic compound, asphalt binder experiences aging over time, which significantly affects its chemical and physical properties. This study was the extension of a series of previous research studies in an attempt to evaluate the amorphous carbon-modified binders as a byproduct of paraffin factory when added in asphalt binder. A novel approach was taken in this research study to evaluate the aging properties of amorphous powder. Historically, it is believed that carbon powder can improve the aging of asphalt binder; however, the methods for such a claim are not designed well for long-term evaluation. This study used a time-temperature-aging superposing principle that added an aging component to the well-known time-temperature superposition principle to evaluate the aging properties of amorphous-modified binders comprehensively. This methodology was verified with a chemical test, Fourier-transform infrared (FTIR) spectroscopy. The master curve results, along with chemical properties, showed as binder aged, the rate of aging decreased. The chemical results indicated the benefits of amorphous powder against aging to some extent; however, due to added stiffness of this powder that acted as filler in binder, the master curve of aging showed higher stiffness values for samples modified with 10% amorphous carbon compared to 5% and 0% binders.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The authors wish to acknowledge the Rose Polymer Company for providing the financial support and providing the amorphous carbon powder. The authors also acknowledge the Monash Centre for Electron Microscopy for testing the carbon powder.

References

Akbari Nasrekani, A. A., M. Nakhaei, K. Naderi, E. Fini, and S. Aflaki. 2017. “Improving moisture sensitivity of asphalt concrete using natural bitumen (Gilsonite).” In Proc., Transportation Research Board 96th Annual Meeting Conf. Washington, DC: Transportation Research Board.
Ameri, M., S. Nowbakht, M. Molayem, and M. R. M. Aliha. 2016. “Investigation of fatigue and fracture properties of asphalt mixtures modified with carbon nanotubes.” Fatigue Fract. Eng. Mater. Struct. 39 (7): 896–906. https://doi.org/10.1111/ffe.12408.
Anderson, D. A., D. W. Christensen, and H. Bahia. 1991. “Physical properties of asphalt cement and the development of performance-related specifications.” J. Assoc. Asphalt Paving Technol. 60: 437–475.
Apeagyei, A. K. 2011. “Laboratory evaluation of antioxidants for asphalt binders.” Constr. Build. Mater. 25 (1): 47–53. https://doi.org/10.1016/j.conbuildmat.2010.06.058.
Asgharzadeh, S. M., N. Tabatabaee, K. Naderi, and M. Partl. 2013. “An empirical model for modified bituminous binder master curves.” Mater. Struct. 46 (9): 1459–1471. https://doi.org/10.1617/s11527-012-9988-x.
Asgharzadeh, S. M., N. Tabatabaee, K. Naderi, and M. N. Partl. 2015. “Evaluation of rheological master curve models for bituminous binders.” Mater. Struct. 48 (1–2): 393–406. https://doi.org/10.1617/s11527-013-0191-5.
Baek, C., B. Underwood, and Y. Kim. 2012. “Effects of oxidative aging on asphalt mixture properties.” Transp. Res. Rec. 2296 (1): 77–85. https://doi.org/10.3141/2296-08.
Baqersad, M., H. Ali, F. Haddadi, and I. Khakpour. 2019. “Short- and long-term rheological and chemical characteristics of nanomodified asphalt binder.” Pet. Sci. Technol. 37 (15): 1788–1799. https://doi.org/10.1080/10916466.2019.1602635.
Behbahani, H., M. J. Ayazi, and A. Moniri. 2017. “Laboratory investigation of rutting performance of warm mix asphalt containing high content of reclaimed asphalt pavement.” Pet. Sci. Technol. 35 (15): 1556–1561. https://doi.org/10.1080/10916466.2017.1316738.
Bradshaw, R. D., and L. C. Brinson. 1997. “Physical aging in polymers and polymer composites: An analysis and method for time-aging time superposition.” Polym. Eng. Sci. 37 (1): 31–44. https://doi.org/10.1002/pen.11643.
Brown, E. R., P. S. Kandhal, F. L. Roberts, Y. R. Kim, D.-Y. Lee, and T. W. Kennedy. 2009. Hot mix asphalt materials, mixture design and construction. Lanham, MD: NAPA Research and Education Foundation.
Cong, P., P. Xu, and S. Chen. 2014. “Effects of carbon black on the anti aging, rheological and conductive properties of SBS/asphalt/carbon black composites.” Constr. Build. Mater. 52 (Feb): 306–313. https://doi.org/10.1016/j.conbuildmat.2013.11.061.
de Melo, J. V. S., G. Trichês, and L. T. de Rosso. 2018. “Experimental evaluation of the influence of reinforcement with multi-walled carbon nanotubes (MWCNTs) on the properties and fatigue life of hot mix asphalt.” Constr. Build. Mater. 162 (Feb): 369–382. https://doi.org/10.1016/j.conbuildmat.2017.12.033.
Faramarzi, M., M. Arabani, A. K. Haghi, and V. Mottaghitalab. 2015. “Carbon nanotubes-modified asphalt binder: Preparation and characterization.” Int. J. Pavement Res. Technol. 8 (1): 29–37. https://doi.org/10.6135/ijprt.org.tw/2015.8(1).29.
Jafari, M., A. A. Nasrekani, M. Nakhaei, and A. Babazadeh. 2017. “Evaluation of rutting resistance of asphalt binders and asphalt mixtures modified with polyphosphoric acid.” Pet. Sci. Technol. 35 (2): 141–147. https://doi.org/10.1080/10916466.2016.1248776.
Januszke, R. M. 1971. “Paving asphalt. Additives in durability determination.” Ind. Eng. Chem. Prod. Res. Dev. 10 (2): 209–214. https://doi.org/10.1021/i360038a021.
Korayem, A. H., H. Ziari, M. Hajiloo, and A. Moniri. 2018. “Rutting and fatigue performance of asphalt mixtures containing amorphous carbon as filler and binder modifier.” Constr. Build. Mater. 188 (Nov): 905–914. https://doi.org/10.1016/j.conbuildmat.2018.08.179.
Lamontagne, J., P. Dumas, V. Mouillet, and J. Kister. 2001. “Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: Application to road bitumens.” Fuel 80 (4): 483–488. https://doi.org/10.1016/S0016-2361(00)00121-6.
Majidifard, H., B. Jahangiri, W. G. Buttlar, and A. H. Alavi. 2018a. “New machine learning-based prediction models for fracture energy of asphalt mixtures.” Measurement 135 (Mar): 438–451. https://doi.org/10.1016/j.measurement.2018.11.081.
Majidifard, H., N. Tabatabaee, and W. Buttlar. 2018b. “Effect of bio-based oil on performance of high-rap mixtures.” In Proc., Transportation Research Board 96th Annual Meeting Conf. Washington, DC: Transportation Research Board.
Mamun, A. A., and M. Arifuzzaman. 2018. “Nano-scale moisture damage evaluation of carbon nanotube-modified asphalt.” Constr. Build. Mater. 193 (Dec): 268–275. https://doi.org/10.1016/j.conbuildmat.2018.10.155.
Mamun, A. A., M. Arifuzzaman, and R. Taha. 2018. “Nano scale aging characterization of carbon nanotube modified asphalt binders.” In Proc., Advances in Materials and Pavement Prediction: Papers from the International Conference on Advances in Materials and Pavement Performance Prediction 403. London: Taylor & Francis.
Marsac, P., et al. 2014. “Potential and limits of FTIR methods for reclaimed asphalt characterization.” Mater. Struct. 47 (8): 1273–1286. https://doi.org/10.1617/s11527-014-0248-0.
Mirzaiyan, D., A. Amini, and F. Jalali. 2019. “Investigating the influence of SBS and Gilsonite on the rheological properties of asphalt binder using statistical analysis.” Int. J. Sci. Tech. Res. Eng. 4 (1): 31–41.
Naderi, K., F. M. Nejad, and A. Khodaii. 2017. “Time-temperature-age superposition validation for linear viscoelastic properties of bituminous materials.” J. Mater. Civ. Eng. 30 (2): 04017292. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002162.
Nakhaei, M., K. Naderi, A. A. Nasrekani, and D. H. Timm. 2018. “Moisture resistance study on PE-wax and EBS-wax modified warm mix asphalt using chemical and mechanical procedures.” Constr. Build. Mater. 189 (Nov): 882–889. https://doi.org/10.1016/j.conbuildmat.2018.08.216.
Nazari, H., K. Naderi, and F. M. Nejad. 2018. “Improving aging resistance and fatigue performance of asphalt binders using inorganic nanoparticles.” Constr. Build. Mater. 170 (May): 591–602. https://doi.org/10.1016/j.conbuildmat.2018.03.107.
Petersen, J. C. 1993. “Asphalt oxidation--AH overview including a new model for oxidation proposing that physicochemical factors dominate the oxidation kinetics.” Fuel sci. Technol. Int. 11 (1): 57–87. https://doi.org/10.1080/08843759308916058.
Petersen, J. C., J. F. Branthaver, R. E. Robertson, P. M. Harnsberger, J. J. Duvall, and E. K. Ensley. 1993. “Effects of physicochemical factors on asphalt oxidation kinetics.” Transp. Res. Rec. (1391): 1–10.
Sabouri, M., D. Mirzaeian, and A. Moniri. 2018. “Effectiveness of linear amplitude sweep (LAS) asphalt binder test in predicting asphalt mixtures fatigue performance.” Constr. Build. Mater. 171 (May): 281–290. https://doi.org/10.1016/j.conbuildmat.2018.03.146.
Saghafi, M., N. Tabatabaee, and S. Nazarian. 2019. “Performance evaluation of slurry seals containing reclaimed asphalt pavement.” Transp. Res. Rec. 2673 (1): 358–368. https://doi.org/10.1177/0361198118821908.
Shafabakhsh, G., M. Taghipoor, M. Sadeghnejad, and S. A. Tahami. 2015. “Evaluating the effect of additives on improving asphalt mixtures fatigue behavior.” Constr. Build. Mater. 90 (Aug): 59–67. https://doi.org/10.1016/j.conbuildmat.2015.04.046.
Smith, B. T., I. L. Howard, W. S. Jordan III, C. Daranga, and G. L. Baumgardner. 2018. “Comparing pressure aging vessel time to field aging of binder as a function of pavement depth and time.” Transp. Res. Rec. 2672 (28): 223–234. https://doi.org/10.1177/0361198118790836.
Wang, P., Z.-J. Dong, Y.-Q. Tan, and Z.-Y. Liu. 2017. “Effect of multi-walled carbon nanotubes on the performance of styrene–butadiene–styrene copolymer modified asphalt.” Mater. Struct. 50 (1): 17 https://doi.org/10.1617/s11527-016-0890-9.
Xiao, F., S. N. Amirkhanian, M. Karakouzian, and M. Khalili. 2015. “Rheology evaluations of WMA binders using ultraviolet and PAV aging procedures.” Constr. Build. Mater. 79 (Mar): 56–64. https://doi.org/10.1016/j.conbuildmat.2015.01.046.
Ziari, H., A. Amini, A. Goli, and D. Mirzaeiyan. 2018. “Predicting rutting performance of carbon nano tube (CNT) asphalt binders using regression models and neural networks.” Constr. Build. Mater. 160 (Jan): 415–426. https://doi.org/10.1016/j.conbuildmat.2017.11.071.
Ziari, H., A. H. Korayem, M. Hajiloo, M. Nakhaei, A. Razmjou, and H. Divandari. 2017a. “Evaluating the effect of amorphous carbon powder on moisture susceptibility and mechanical resistance of asphalt mixtures.” Constr. Build. Mater. 152 (Oct): 182–191. https://doi.org/10.1016/j.conbuildmat.2017.06.036.
Ziari, H., A. Moniri, R. Imaninasab, and M. Nakhaei. 2017b. “Effect of copper slag on performance of warm mix asphalt.” Int. J. Pavement Eng. 20 (7): 1–7.
Ziari, H., M. Nakhaei, A. A. Nasrekani, and A. Moniri. 2016. “Characterization of rutting resistance of EBS-modified asphalt mixtures.” Pet. Sci. Technol. 34 (13): 1107–1112. https://doi.org/10.1080/10916466.2016.1181655.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 1January 2020

History

Received: Feb 4, 2019
Accepted: Jun 19, 2019
Published online: Oct 24, 2019
Published in print: Jan 1, 2020
Discussion open until: Mar 24, 2020

Permissions

Request permissions for this article.

Authors

Affiliations

Ph.D. Student, National Center for Asphalt Technology, Auburn Univ., Auburn, AL 36830 (corresponding author). ORCID: https://orcid.org/0000-0001-5046-7133. Email: [email protected]
Hassan Ziari [email protected]
Professor, School of Civil Engineering, Iran Univ. of Science and Technology, Narmak, Tehran 1684613114, Iran. Email: [email protected]
Asghar Habibnejad Korayem [email protected]
Professor, School of Civil Engineering, Iran Univ. of Science and Technology, Narmak, Tehran 1684613114, Iran. Email: [email protected]
Mojtaba Hajiloo [email protected]
Ph.D. Student, School of Civil Engineering, Iran Univ. of Science and Technology, Narmak, Tehran 1684613114, Iran. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share