Technical Papers
Sep 28, 2019

Developing Renewable Agro-Based Anti-Icers for Sustainable Winter Road Maintenance Operations

Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 12

Abstract

This work evaluated the performance and impacts of several agro-based anti-icers along with two traditional chloride-based anti-icers (23% by weight NaCl brine and its beet juice blend). A statistical design of experiments (central composite design) was employed for developing anti-icing liquids consisting of cost-competitive chemicals such as renewable agro-based compounds (Concord grape extract and glycerin); sodium chloride; sodium metasilicate; and sodium formate. The following experimentally obtained parameters were examined as a function of the formulation design: ice-melting capacity at 3.9°C, splitting tensile strength of portland cement mortar samples after 10 freeze-thaw/deicer cycles, corrosion rate of C1010 carbon steel after 24-h immersion, and impact on low temperature performance of asphalt binder. One viable formula (the best performer) was tested for thermal properties by measuring its differential scanning calorimetry (DSC) thermograms and other properties (friction coefficient on anti-iced asphalt pavement, pH, oxygen demands). These laboratory data shed light on the selection and formulation of innovative agro-based snow and ice control chemicals that can significantly reduce the costs of winter road maintenance operations.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The authors acknowledge the financial support provided by the Center for Environmentally Sustainable Transportation in Cold Climates (CESTiCC), Washington State Department of Transportation (WSDOT), and the National Science Foundation (Award No. 1638384). The authors would also like to thank Sen Du, Taekil Oh, and Deborah Ave Okon for their assistance in running some of the laboratory experiments.

References

ASTM. 1998. Standard specification for steel, carbon (0.15 maximum, percent), hot-rolled sheet and strip commercial (Withdrawn 2000). ASTM A569: West Conshohocken, PA.
Bahia, H. U., and D. A. Anderson. 1993. “The pressure aging vessel (PAV): A test to simulate rheological changes due to field aging.” In Physical properties of asphalt cement binders. DFW Airport, TX: Dallas/Fort Worth International Airport.
Chappelow, C. C., A. D. McElroy, R. R. Blackburn, D. Darwin, F. G. de Noyelles, and C. E. Locke. 1992. Handbook of test methods for evaluating chemical deicers. Washington, DC: Strategic Highway Research Program.
Chen, J., R. Bharata, T. Yin, Q. Wang, H. Wang, and T. Zhang. 2016. “Assessment of sulfate attack and freeze-thaw cycle damage of cement-based materials by a nonlinear acoustic technique.” Mater. Struct. 50 (2): 105. https://doi.org/10.1617/s11527-016-0949-7.
Corsi, S. R., L. A. De Cicco, M. A. Lutz, and R. M. Hirsch. 2015. “River chloride trends in snow-affected urban watersheds: Increasing concentrations outpace urban growth rate and are common among all seasons.” Sci. Total Environ. 508 (Mar): 488–497. https://doi.org/10.1016/j.scitotenv.2014.12.012.
Corsi, S. R., D. Mericas, and G. T. Bowman. 2012. “Oxygen demand of aircraft and airfield pavement deicers and alternative freezing point depressants.” Water Air Soil Pollut. 223 (5): 2447–2461. https://doi.org/10.1007/s11270-011-1036-x.
Dang, Y., X. Shi, N. Xie, E. McVey, and A. Kessel. 2016. “Accelerated laboratory test suggests the importance of film integrity of sealers on the protection of concrete from deicer scaling.” J. Mater. Civ. Eng. 28 (9): 04016065. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001579.
Farnam, Y., S. Dick, A. Wiese, J. Davis, D. Bentz, and J. Weiss. 2015. “The influence of calcium chloride deicing salt on phase changes and damage development in cementitious materials.” Cem. Concr. Compos. 64 (Nov): 1–15. https://doi.org/10.1016/j.cemconcomp.2015.09.006.
Fay, L., and X. Shi. 2012. “Environmental impacts of chemicals for snow and ice control: State of the knowledge.” Water Air Soil Pollut. 223 (5): 2751–2770. https://doi.org/10.1007/s11270-011-1064-6.
Fay, L., X. Shi, and J. Huang. 2013. Strategies to mitigate the impacts of chloride roadway deicers on the natural environment. Washington, DC: Transportation Research Board.
Heikal, M. 2004. “Effect of calcium formate as an accelerator on the physicochemical and mechanical properties of pozzolanic cement pastes.” Cem. Concr. Res. 34 (6): 1051–1056. https://doi.org/10.1016/j.cemconres.2003.11.015.
Honarvar Nazari, M., F. Laura, S. Jungwirth, and X. Shi. 2015. “Water quality implications and the toxicological effects of chloride-based deicers.” Environ. Sustainability Transp. Infrastruct. 272–292. https://doi.org/10.1061/9780784479285.022.
Honarvar Nazari, M., X. Shi, E. Jackson, Z. Yan, and Y. Li. 2017. “Laboratory investigation of washing practices and bio-based additive for mitigating metallic corrosion by magnesium chloride deicer.” J. Mater. Civ. Eng. 29 (1): 04016187. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001727.
Hossain, S. M. K., L. Fu, and R. Lake. 2015. “Field evaluation of the performance of alternative deicers for winter maintenance of transportation facilities.” Can. J. Civ. Eng. 42 (7): 437–448. https://doi.org/10.1139/cjce-2014-0423.
Hosseini, F., S. M. K. Hossain, and L. Fu. 2016. “Bio-based materials for improving winter pavement friction.” Can. J. Civ. Eng. 44 (2): 99–105. https://doi.org/10.1139/cjce-2016-0460.
Li, Y., Y. Fang, N. Seeley, S. Jungwirth, E. Jackson, and X. Shi. 2013. “Corrosion by chloride deicers on highway maintenance equipment.” Transp. Res. Rec. 2361 (1): 106–113. https://doi.org/10.3141/2361-13.
Metal Samples. 2018. “Introduction to linear polarization resistance (LPR) monitoring.” Accessed May 10, 2018. http://www.alspi.com/lprintro.htm.
Nazari, M. H., and X. Shi. 2018. “Vehicle risks of winter road operations and best management practices.” Sustainable Winter Road Oper. 241–272. https://doi.org/10.1002/9781119185161.ch12.
Pan, T., X. He, and X. Shi. 2008. “Laboratory investigation of acetate-based deicing/anti-icing agents deteriorating airfield asphalt (with discussion).” J. Assoc. Pav. Technol. 77: 773–794.
Pieper, K. J., M. Tang, C. N. Jones, S. Weiss, A. Greene, H. Mohsin, J. Parks, and M. A. Edwards. 2018. “Impact of road salt on drinking water quality and infrastructure corrosion in private wells.” Environ. Sci. Technol. 52 (24): 14078–14087. https://doi.org/10.1021/acs.est.8b04709.
Pigeon, M., and R. Pleau. 2010. Durability of concrete in cold climates. New York: CRC Press.
Qiao, C., P. Suraneni, and J. Weiss. 2018. “Damage in cement pastes exposed to NaCl solutions.” Constr. Build. Mater. 171 (May): 120–127. https://doi.org/10.1016/j.conbuildmat.2018.03.123.
Real Tech Inc. 2017. “Biochemical oxygen demand (BOD).” Accessed February 2, 2019. https://realtechwater.com/parameters/biochemical-oxygen-demand/.
Refait, P., M. Abdelmoula, J.-M. Génin, and M. Jeannin. 2006. “Synthesis and characterisation of the Fe(II-III) hydroxy-formate green rust.” Hyperfine Interact. 167: 717–722 https://doi.org/10.1007/978-3-540-49853-7_2.
Shi, X., L. Fay, M. M. Peterson, and Z. Yang. 2010. “Freeze-thaw damage and chemical change of a portland cement concrete in the presence of diluted deicers.” Mater. Struct. 43 (7): 933–946. https://doi.org/10.1617/s11527-009-9557-0.
Shi, X., K. Fortune, R. Smithlin, M. Akin, and L. Fay. 2013. “Exploring the performance and corrosivity of chloride deicer solutions: Laboratory investigation and quantitative modeling.” Cold Regions Sci. Technol. 86 (Feb): 36–44. https://doi.org/10.1016/j.coldregions.2012.10.011.
Shi, X., S. M. Quilty, T. Long, A. Jayakaran, L. Fay, and G. Xu. 2017. “Managing airport stormwater containing deicers: Challenges and opportunities.” Front. Struct. Civ. Eng. 11 (1): 35–46. https://doi.org/10.1007/s11709-016-0366-6.
Sivrioğlu, Ö., and T. Yonar. 2015. “Determination of the acute toxicities of physicochemical pretreatment and advanced oxidation processes applied to dairy effluents on activated sludge.” J. Dairy Sci. 98 (4): 2337–2344. https://doi.org/10.3168/jds.2014-8278.
Triantaphyllou, E., and S. H. Mann. 1995. “Using the analytic hierarchy process for decision making in engineering applications: Some challenges.” Int. J. Ind. Eng. 2 (1): 35–44.
Waluś, K. J., and Z. Olszewski. 2011. “Analysis of tire-road contact under winter conditions.” In Vol. 3 Proc., World Congress on Engineering. London: International Association of Engineers.
Wang, L., L. Dai, H. Bian, Y. Ma, and J. Zhang. 2019. “Concrete cracking prediction under combined prestress and strand corrosion.” Struct. Infrastruct. Eng. 15 (3): 1–11. https://doi.org/10.1080/15732479.2018.1550519.
Xie, N., X. Shi, and Z. Zhang. 2017. “Impacts of potassium acetate and sodium-chloride deicers on concrete.” J. Mater. Civ. Eng. 29 (3): 04016229. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001754.
Xu, G., and X. Shi. 2018. “Impact of chemical deicers on roadway infrastructure.” In Sustainable winter road operations, 211–240. Hoboken, New Jersey: Wiley.
Yang, Z., Y. Zhang, and X. Shi. 2018. “Impact of nanoclay and carbon microfiber in combating the deterioration of asphalt concrete by non-chloride deicers.” Constr. Build. Mater. 160: 514–525.
Zandi Hanjari, K., P. Utgenannt, and K. Lundgren. 2011. “Experimental study of the material and bond properties of frost-damaged concrete.” Cem. Concr. Res. 41 (3): 244–254. https://doi.org/10.1016/j.cemconres.2010.11.007.
Zhang, X., L. Wang, and J. Zhang. 2017. “Mechanical behavior and chloride penetration of high strength concrete under freeze-thaw attack.” Cold Reg. Sci. Technol. 142 (Oct): 17–24. https://doi.org/10.1016/j.coldregions.2017.07.004.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 12December 2019

History

Received: Feb 3, 2019
Accepted: Jun 14, 2019
Published online: Sep 28, 2019
Published in print: Dec 1, 2019
Discussion open until: Feb 28, 2020

Permissions

Request permissions for this article.

Authors

Affiliations

Mehdi Honarvar Nazari, Ph.D., S.M.ASCE [email protected]
Graduate Research Assistant, Laboratory of Corrosion Science and Electrochemical Engineering, Dept. of Civil and Environmental Engineering, Washington State Univ., P.O. Box 642910, Pullman, WA 99164-2910. Email: [email protected]
Associate Professor, Laboratory of Corrosion Science and Electrochemical Engineering, Dept. of Civil and Environmental Engineering, Washington State Univ., P.O. Box 642910, Pullman, WA 99164-2910 (corresponding author). ORCID: https://orcid.org/0000-0003-3576-8952. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share