Technical Notes
Aug 28, 2019

Effect of Municipal Solid Waste Incineration Fly Ash on Properties of Magnesium Potassium Phosphate Paste

Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 11

Abstract

This paper studied the effect of municipal solid waste incineration fly ash (MSWI FA) on properties of magnesium potassium phosphate cement (MKPC) paste. MKPC pastes containing different contents of MSWI FA were prepared. Initial setting time and hydration temperature of fresh MKPC paste were tested. Compressive strength and shrinkage deformation of hardened MKPC paste were determined. Phase composition [via X-ray diffraction (XRD), energy dispersive spectrometry (EDS)], pore structure [via mercury intrusion porosimetry (MIP)], and morphology [via scanning electron microscopy (SEM)] of hardened MKPC paste were analyzed. Leaching concentrations of Pb and Cd from hardened MKPC pastes were detected. Compared with MKPC paste containing no MSWI FA, MKPC paste containing 10% MSWI FA had 20% higher 60-day compressive strength and 20% less 60-day shrinkage deformation. This was due to the higher early hydration degree and denser structure of MKPC paste containing MSWI FA. When the curing time was no less than 7 d, the leaching concentrations of Pb and Cd from MKPC pastes containing 5%–20% MSWI FA met the leaching requirement in the relevant Chinese national standard.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No. 51578475).

References

Abdelrazig, B. E. I., J. H. Sharp, and B. El-Jazairi. 1988. “The chemical composition of mortars made from magnesia-phosphate cement.” Cem. Concr. Res. 18 (3): 415–425. https://doi.org/10.1016/0008-8846(88)90075-0.
Abdelrazig, B. E. I., J. H. Sharp, and B. El-Jazairi. 1989. “The microstructure and mechanical properties of mortars made from magnesia-phosphate cement.” Cem. Concr. Res. 19 (2): 247–258.
ASTM. 2001. Standard test method for compressive strength of hydraulic cement mortars. ASTM C109/C109M. West Conshohocken, PA: ASTM.
ASTM. 2007. Standard test method for flow of hydraulic cement mortar. ASTM C1437. West Conshohocken, PA: ASTM.
ASTM. 2013. Standard test methods for time of setting of hydraulic cement by Vicat needle. ASTM C191. West Conshohocken, PA: ASTM.
Buj, I., J. Torras, D. Casellas, M. Rovira, and J. de Pablo. 2009. “Effect of heavy metals and water content on the strength of magnesium phosphate cements.” J. Hazard. Mater. 170 (1): 345–350. https://doi.org/10.1016/j.jhazmat.2009.04.091.
Buj, I., J. Torras, M. Rovira, and J. de Pablo. 2010. “Leaching behaviour of magnesium phosphate cements containing high quantities of heavy metals.” J. Hazard. Mater. 175 (1–3): 789–794. https://doi.org/10.1016/j.jhazmat.2009.10.077.
Chang, Y., C. Shi, N. Yang, and J. Yang. 2013. “Effect of fineness of magnesium oxide on properties of magnesium potassium phosphate cement.” [In Chinese.] J. Chin. Ceram. Soc. 41 (4): 492–499. https://doi.org/10.1016/j.jhazmat.2009.10.077.
Chau, C. K., F. Qiao, and Z. Li. 2011. “Microstructure of magnesium potassium phosphate cement.” Constr. Build. Mater. 25 (6): 2911–2917. https://doi.org/10.1016/j.conbuildmat.2010.12.035.
Chinese Standard. 1995. Environmental quality standard for soils. GB 15618. Beijing: Chinese Standard.
Chinese Standard. 2007a. Identification standards for hazardous wastes—Identification for extraction. GB5085.3. Beijing: Chinese Standard.
Chinese Standard. 2007b. Solid waste-extraction procedure for leaching toxicity-sulphuric acid & nitric acid method. HJ/T299. Beijing: Chinese Standard.
Ding, Z., and Z. Li. 2005. “High-early-strength magnesium phosphate cement with fly ash.” ACI Mater. J. 102 (6): 375–381.
Gardner, L. J., S. A. Bernal, S. A. Walling, C. L. Corkhill, J. L. Provis, and N. C. Hyatt. 2015. “Characterisation of magnesium potassium phosphate cements blended with fly ash and ground granulated blast furnace slag.” Cem. Concr. Res. 74: 78–87. https://doi.org/10.1016/j.cemconres.2015.01.015.
Hall, D. A., R. Stevens, and B. El-Jazairi. 2001. “The effect of retarders on the microstructure and mechanical properties of magnesia-phosphate cement mortar.” Cem. Concr. Res. 31 (3): 455–465. https://doi.org/10.1016/S0008-8846(00)00501-9.
ISO. 2009. Testing of concrete. Determination of the drying shrinkage of concrete for samples prepared in the field or in the laboratory. BS ISO 1920-8. Geneva: ISO.
Li, J., W. Zhang, and Y. Cao. 2014. “Laboratory evaluation of magnesium phosphate cement paste and mortar for rapid repair of cement concrete pavement.” Constr. Build. Mater. 58 (May): 122–128. https://doi.org/10.1016/j.conbuildmat.2014.02.015.
Malviya, R., and R. Chaudhary. 2006. “Factors affecting hazardous waste solidification/stabilization: A review.” J. Hazard. Mater. 137 (1): 267–276. https://doi.org/10.1016/j.jhazmat.2006.01.065.
Mehta, P. K. 1980. “Pore size distribution and permeability of hardened cement pastes.” In Proc., 7th Int. Congress on the Chemistry of Cement, VII-1–VII-5. Paris: Editions Septima.
Paria, S., and P. K. Yuet. 2006. “Solidification-stabilization of organic and inorganic contaminants using portland cement: A literature review.” Environ. Rev. 14 (4): 217–255. https://doi.org/10.1139/a06-004.
Randall, P. M., and S. Chattopadhyay. 2010. “Bench-scale evaluation of chemically bonded phosphate ceramic technology to stabilize mercury waste mixtures.” J. Environ. Eng. 136 (3): 265–273. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000144.
Ribeiro, D. V., and M. R. Morelli. 2009. “Influence of the addition of grinding dust to a magnesium phosphate cement matrix.” Constr. Build. Mater. 23 (9): 3094–3102. https://doi.org/10.1016/j.conbuildmat.2009.03.013.
Shi, H., and L. Yuan. 2003. “Cementitious reactivity of municipal solid waste incineration fly ash and immobilization effect by cement.” [In Chinese.] J. Chin. Ceram. Soc. 31 (11): 1021–1025.
Singh, D., A. S. Wagh, M. Tlustochowicz, and S. Y. Jeong. 1998. “Phosphate ceramic process for macroencapsulation and stabilization of low-level debris wastes.” Waste Manage. 18 (2): 135–143. https://doi.org/10.1016/S0956-053X(98)00018-X.
Wagh, A. S. 2016. Chemically bonded phosphate ceramics: Twenty-first century materials with diverse applications. Amsterdam, Netherlands: Elsevier.
Wagh, A. S., S. Y. Jeong, and D. Singh. 1997. “High strength phosphate cement using industrial byproduct ashes.” In Proc., 1st Int. Conf. on High Strength Concrete, edited by A. Azizinamini, D. Darwin, and C. French, 542–553. Reston, VA: ASCE.
Wagh, A. S., R. Strain, S. Y. Jeong, D. Reed, T. Krause, and D. Singh. 1999. “Stabilization of Rocky Flats Pu-contaminated ash within chemically bonded phosphate ceramics.” J. Nucl. Mater. 265 (3): 295–307. https://doi.org/10.1016/S0022-3115(98)00650-3.
Yang, J. M., C. J. Shi, Y. Chang, and N. Yang. 2013a. “Hydration and hardening characteristics of magnesium potassium phosphate cement paste containing composite retarders.” [In Chinese.] J. Build. Mater. 16 (1): 43–49. https://doi.org/10.3969/j.issn.1007-9629.2013.01.008.
Yang, J. H., J. M. Shin, C. H. Lee, C. M. Heo, M. K. Jeon, and K. H. Kang. 2013b. “Stabilization of Cs/Re trapping filters using magnesium phosphate ceramics.” J. Radioanal. Nucl. Chem. 295 (1): 211–219. https://doi.org/10.1007/s10967-012-1774-2.
Yang, Q., and X. Wu. 1999. “Factors influencing properties of phosphate cement-based binder for rapid repair of concrete.” Cem. Concr. Res. 29 (3): 389–396. https://doi.org/10.1016/S0008-8846(98)00230-0.
Yang, Q., B. Zhu, and X. Wu. 2000. “Characteristics and durability test of magnesium phosphate cement-based material for rapid repair of concrete.” Mater. Struct. 33 (4): 229–234. https://doi.org/10.1007/BF02479332.
You, C., J. Qian, J. Qin, H. Wang, Q. Wang, and Z. Ye. 2015. “Effect of early hydration temperature on hydration product and strength development of magnesium phosphate cement (MPC).” Cem. Concr. Res. 78 (Dec): 179–189. https://doi.org/10.1016/j.cemconres.2015.07.005.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 11November 2019

History

Received: Feb 4, 2017
Accepted: May 29, 2019
Published online: Aug 28, 2019
Published in print: Nov 1, 2019
Discussion open until: Jan 28, 2020

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Authors

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Jianming Yang [email protected]
Professor, Jiangsu Collaborative Innovation Center for Ecological Building Materials and Environmental Protection, College of Civil Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China (corresponding author). Email: [email protected]
Shucong Zhen [email protected]
Associate Professor, College of Civil Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China. Email: [email protected]
Professor, Jiangsu Collaborative Innovation Center for Ecological Building Materials and Environmental Protection, College of Materials Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China. Email: [email protected]

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