Technical Papers
May 28, 2019

Evaluating Effect of GGBFS in Alkali–Silica Reaction in Geopolymer Mortar with Accelerated Mortar Bar Test

Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 8

Abstract

This paper presents the effect of ground granulated blast-furnace slag (GGBFS) content on the alkali–silica reaction (ASR) in geopolymer mortar using the accelerated mortar bar test and scanning electron microscope (SEM) analysis. Three geopolymer mixtures with different fly ash/GGBFS weight ratios (9, 4, and 1) along with one ordinary portland cement (OPC) mixture were considered in this study. Other parameters of the geopolymer mixtures were kept constant. Mortar bar prisms were prepared in accordance with accelerated mortar bar test standards for expansion measurements, and SEM analysis was performed after 21 and 150 days of immersion in 1 M NaOH solution at 80°C. In addition, compressive strengths of mortar cubes were measured up to 29 days. Silica dissolution of the reactive aggregate used in mortar was determined by immersing it in NaOH solutions with different pH values. This study’s results suggest that the ASR in geopolymer is lower than that of OPC and that expansions due to ASR in geopolymer mortar increase with the increase in the GGBFS content in the mix design. Finally, this paper also emphasizes that the standard accelerated mortar bar test needs to be modified before endorsing it for geopolymer mortar.

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Acknowledgments

This research is funded by the CRC for Low Carbon Living supported by the Cooperative Research Centres Program, an Australian Government initiative.

References

Adam, A. 2009. “Strength and durability properties of alkali activated slag and fly ash-based geopolymer concrete.” Ph.D. thesis, Dept. of Civil, Environmental and Chemical Engineering, RMIT Univ.
Aldred, J., and J. Day. 2012. “Is geopolymer concrete a suitable alternative to traditional concrete.” In Proc., 37th Conf. on our World in Concrete & Structures, 29–31, Singapore: CI-Premier Pte.
Bakharev, T., J. G. Sanjayan, and Y.-B. Cheng. 1999. “Alkali activation of Australian slag cements.” Cem. Concr. Res. 29 (1): 113–120.
Bakharev, T., J. Sanjayan, and Y.-B. Cheng. 2001. “Resistance of alkali-activated slag concrete to alkali–aggregate reaction.” Cem. Concr. Res. 31 (2): 331–334. https://doi.org/10.1016/S0008-8846(00)00483-X.
Barneyback, R., Jr., and S. Diamond. 1981. “Expression and analysis of pore fluids from hardened cement pastes and mortars.” Cem. Concr. Res. 11 (2): 279–285. https://doi.org/10.1016/0008-8846(81)90069-7.
Bernal, S. A., and J. L. Provis. 2014. “Durability of alkali-activated materials: Progress and perspectives.” J. Am. Ceram. Soc. 97 (4): 997–1008. https://doi.org/10.1111/jace.12831.
Brady, P. V., and J. V. Walther. 1989. “Controls on silicate dissolution rates in neutral and basic pH solutions at 25°C.” Geochim. Cosmochim. Acta 53 (11): 2823–2830. https://doi.org/10.1016/0016-7037(89)90160-9.
Castel, A., and S. J. Foster. 2015. “Bond strength between blended slag and Class F fly ash geopolymer concrete with steel reinforcement.” Cem. Concr. Res. 72 (1): 48–53. https://doi.org/10.1016/j.cemconres.2015.02.016.
Chappex, T., and K. L. Scrivener. 2012. “The influence of aluminium on the dissolution of amorphous silica and its relation to alkali silica reaction.” Cem. Concr. Res. 42 (12): 1645–1649. https://doi.org/10.1016/j.cemconres.2012.09.009.
Dang, J., X. Shen, A. Castel, and J. Aldred. 2016. “Monitoring apparent pH value in geopolymer concrete using glass electrode.” In Proc., Int. Symp. on Automation and Robotics in Construction, 1. Waterloo, Canada: IAARC Publications.
Davidovits, J. 1994. “Properties of geopolymer cements.” In Proc., 1st Int. Conf. on Alkaline Cements and Concretes, 131–149. Kiev, Ukraine: Vipol Stock Company.
Davidovits, J. 2005. “Geopolymer chemistry and sustainable development: The poly (sialate) terminology: A very useful and simple model for the promotion and understanding of green-chemistry.” In Proc., 2005 Geopolymer Conf., 9–15. Saint-Quentin, France: Geopolymer Institute.
Davidovits, J. 2011. Geopolymer chemistry and applications. Saint-Quentin, France: Geopolymer Institute.
Diamond, S. 1976. “A review of alkali-silica reaction and expansion mechanisms 2: Reactive aggregates.” Cem. Concr. Res. 6 (4): 549–560. https://doi.org/10.1016/0008-8846(76)90083-1.
Duxson, P., A. Fernández-Jiménez, J. L. Provis, G. C. Lukey, A. Palomo, and J. van Deventer. 2007. “Geopolymer technology: The current state of the art.” J. Mater. Sci. 42 (9): 2917–2933. https://doi.org/10.1007/s10853-006-0637-z.
Fadhil Nuruddin, M., and S. N. A. Razak. 2014. “Effects of geopolymer concrete fly ash based on alkali silica reaction (ASR).” Appl. Mech. Mater. 567: 405–410.
Fang, G., W. K. Ho, W. Tu, and M. Zhang. 2018. “Workability and mechanical properties of alkali-activated fly ash-slag concrete cured at ambient temperature.” Constr. Build. Mater. 172 (1): 476–487. https://doi.org/10.1016/j.conbuildmat.2018.04.008.
Fernández-Jiménez, A., I. Garcia-Lodeiro, and A. Palomo. 2007. “Durability of alkali-activated fly ash cementitious materials.” J. Mater. Sci. 42 (9): 3055–3065.
Fernández-Jiménez, A., and F. Puertas. 2002. “The alkali-silica reaction in alkali-activated granulated slag mortars with reactive aggregate.” Cem. Concr. Res. 32 (7): 1019–1024. https://doi.org/10.1016/S0008-8846(01)00745-1.
Fernandez-Jimenez, A. M., A. Palomo, and C. Lopez-Hombrados. 2006. “Engineering properties of alkali-activated fly ash concrete.” ACI Mater. J. 103 (2): 106–112.
Fournier, B., and M.-A. Bérubé. 2000. “Alkali-aggregate reaction in concrete: A review of basic concepts and engineering implications.” Can. J. Civ. Eng. 27 (2): 167–191. https://doi.org/10.1139/l99-072.
Gaboriaud, F., A. Nonat, D. Chaumont, and A. Craievich. 1999. “Aggregation and gel formation in basic silico–calco–alkaline solutions studied: A SAXS, SANS, and ELS study.” J. Phys. Chem. B 103 (28): 5775–5781. https://doi.org/10.1021/jp990151s.
García-Lodeiro, I., A. Palomo, and A. Fernández-Jiménez. 2007. “Alkali–aggregate reaction in activated fly ash systems.” Cem. Concr. Res. 37 (2): 175–183. https://doi.org/10.1016/j.cemconres.2006.11.002.
Gunasekara, C. 2016. “Influence of properties of fly ash from different sources on the mix design and performance of geopolymer concrete.” Ph.D. thesis, Dept. of Civil and Infrastructure Engineering, RMIT Univ.
Hardjito, D., S. E. Wallah, D. M. Sumajouw, and B. V. Rangan. 2004. “On the development of fly ash-based geopolymer concrete.” ACI Mater. J. 101 (6): 467–472.
Hobbs, D. W. 1988. Alkali-silica reaction in concrete. London: Thomas Telford.
Hou, X., R. J. Kirkpatrick, L. J. Struble, and P. J. Monteiro. 2005. “Structural investigations of alkali silicate gels.” J. Am. Ceram. Soc. 88 (4): 943–949. https://doi.org/10.1111/j.1551-2916.2005.00145.x.
Hou, X., L. J. Struble, and R. J. Kirkpatrick. 2004. “Formation of ASR gel and the roles of CSH and portlandite.” Cem. Concr. Res. 34 (9): 1683–1696. https://doi.org/10.1016/j.cemconres.2004.03.026.
House, W. A., and D. R. Orr. 1992. “Investigation of the pH dependence of the kinetics of quartz dissolution at 25°C.” J. Chem. Soc. Faraday Trans. 88 (2): 233–241. https://doi.org/10.1039/FT9928800233.
Ichikawa, T., and M. Miura. 2007. “Modified model of alkali-silica reaction.” Cem. Concr. Res. 37 (9): 1291–1297. https://doi.org/10.1016/j.cemconres.2007.06.008.
Khan, M., A. Castel, and A. Noushini. 2016. “Carbonation of a low-calcium fly ash geopolymer concrete.” Mag. Concr. Res. 69 (1): 24–34.
Kim, T., and J. Olek. 2014a. “Chemical sequence and kinetics of alkali-silica reaction part I. Experiments.” J. Am. Ceram. Soc. 97 (7): 2195–2203. https://doi.org/10.1111/jace.12992.
Kim, T., and J. Olek. 2014b. “Chemical sequence and kinetics of alkali-silica reaction part II. A thermodynamic model.” J. Am. Ceram. Soc. 97 (7): 2204–2212. https://doi.org/10.1111/jace.12830.
Krivenko, P., R. Drochytka, A. Gelevera, and E. Kavalerova. 2014. “Mechanism of preventing the alkali-aggregate reaction in alkali activated cement concretes.” Cem. Concr. Compos. 45 (Jan): 157–165. https://doi.org/10.1016/j.cemconcomp.2013.10.003.
Kupwade-Patil, K., and E. N. Allouche. 2013. “Impact of alkali silica reaction on fly ash-based geopolymer concrete.” J. Mater. Civ. Eng. 25 (1): 131–139. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000579.
Law, D. W., A. A. Adam, T. K. Molyneaux, I. Patnaikuni, and A. Wardhono. 2015. “Long term durability properties of class F fly ash geopolymer concrete.” Mater. Struct. 48 (3): 721–731. https://doi.org/10.1617/s11527-014-0268-9.
Leemann, A., T. Katayama, I. Fernandes, and M. A. Broekmans. 2016. “Types of alkali–aggregate reactions and the products formed.” Proc. Inst. Civ. Eng. Constr. Mater. 169 (3): 128–135. https://doi.org/10.1680/jcoma.15.00059.
Leemann, A., G. Le Saout, F. Winnefeld, D. Rentsch, and B. Lothenbach. 2011. “Alkali-silica reaction: The influence of calcium on silica dissolution and the formation of reaction products.” J. Am. Ceram. Soc. 94 (4): 1243–1249. https://doi.org/10.1111/j.1551-2916.2010.04202.x.
Leemann, A., and P. Lura. 2013. “E-modulus of the alkali-silica-reaction product determined by micro-indentation.” Constr. Build. Mater. 44 (1): 221–227. https://doi.org/10.1016/j.conbuildmat.2013.03.018.
Leemann, A., and C. Merz. 2013. “An attempt to validate the ultra-accelerated microbar and the concrete performance test with the degree of AAR-induced damage observed in concrete structures.” Cem. Concr. Res. 49: 29–37. https://doi.org/10.1016/j.cemconres.2013.03.014.
Lloyd, N., and V. Rangan. 2010. “Geopolymer concrete with fly ash.” In Proc., 2nd Int. Conf. on Sustainable Construction Materials and Technologies, 1493–1504. Milwaukee, WI: UWM Center for By-Products Utilization.
Nath, P. 2014. “Study of fly ash based geopolymer concrete cured in ambient condition.” Ph.D. thesis, School of Civil and Mechanical Engineering, Curtin Univ.
Noushini, A., F. Aslani, A. Castel, R. I. Gilbert, B. Uy, and S. Foster. 2016. “Compressive stress-strain model for low-calcium fly ash-based geopolymer and heat-cured portland cement concrete.” Cem. Concr. Compos. 73 (Oct): 136–146. https://doi.org/10.1016/j.cemconcomp.2016.07.004.
Pan, Z., J. G. Sanjayan, and B. V. Rangan. 2011. “Fracture properties of geopolymer paste and concrete.” Mag. Concr. Res. 63 (10): 763–771. https://doi.org/10.1680/macr.2011.63.10.763.
Phoo-ngernkham, T., P. Chindaprasirt, V. Sata, S. Pangdaeng, and T. Sinsiri. 2013. “Properties of high calcium fly ash geopolymer pastes with portland cement as an additive.” Int. J. Miner. Metall. Mater. 20 (2): 214–220. https://doi.org/10.1007/s12613-013-0715-6.
Provis, J. L. 2014. “Geopolymers and other alkali activated materials: Why, how, and what?” Mater. Struct. 47 (1): 11–25. https://doi.org/10.1617/s11527-013-0211-5.
Rajabipour, F., E. Giannini, C. Dunant, J. H. Ideker, and M. D. A. Thomas. 2015. “Alkali-silica reaction: Current understanding of the reaction mechanisms and the knowledge gaps.” Cem. Concr. Res. 76 (Oct): 130–146. https://doi.org/10.1016/j.cemconres.2015.05.024.
Shafaatian, S. 2012. “Innovative methods to mitigate alkali-silica reaction in concrete materials containing recycled glass aggregates.” Ph.D. thesis, Dept. of Civil Engineering, The Pennsylvania State Univ.
Shi, C., Z. Shi, X. Hu, R. Zhao, and L. Chong. 2015a. “A review on alkali-aggregate reactions in alkali-activated mortars/concretes made with alkali-reactive aggregates.” Mater. Struct. 48 (3): 621–628. https://doi.org/10.1617/s11527-014-0505-2.
Shi, Z., C. Shi, R. Zhao, and S. Wan. 2015b. “Comparison of alkali-silica reactions in alkali-activated slag and portland cement mortars.” Mater. Struct. 48 (3): 743–751. https://doi.org/10.1617/s11527-015-0535-4.
Singh, B., G. Ishwarya, M. Gupta, and S. Bhattacharyya. 2015. “Geopolymer concrete: A review of some recent developments.” Constr. Build. Mater. 85 (Jun): 78–90. https://doi.org/10.1016/j.conbuildmat.2015.03.036.
Sofi, M., J. van Deventer, P. Mendis, and G. Lukey. 2007. “Bond performance of reinforcing bars in inorganic polymer concrete (IPC).” J. Mater. Sci. 42 (9): 3107–3116. https://doi.org/10.1007/s10853-006-0534-5.
Standards Australia. 2014. Methods for sampling and testing aggregates method 60.1: Potential alkali-silica reactivity-Accelerated mortar bar method. AS 1141.60.1. Sydney, Australia: Standards Australia.
Struble, L., and S. Diamond. 1981a. “Unstable swelling behaviour of alkali silica gels.” Cem. Concr. Res. 11 (4): 611–617. https://doi.org/10.1016/0008-8846(81)90091-0.
Struble, L. J., and S. Diamond. 1981b. “Swelling properties of synthetic alkali silica gels.” J. Am. Ceram. Soc. 64 (11): 652–655. https://doi.org/10.1111/j.1151-2916.1981.tb15864.x.
Thaulow, N., U. H. Jakobsen, and B. Clark. 1996. “Composition of alkali silica gel and ettringite in concrete railroad ties: SEM-EDX and X-ray diffraction analyses.” Cem. Concr. Res. 26 (2): 309–318. https://doi.org/10.1016/0008-8846(95)00219-7.
Thomas, M. 2001. “The role of calcium hydroxide in alkali recycling in concrete.” In Materials science of concrete: Calcium hydroxide in concrete, edited by J. Skalny, J. Gebauer, and I. Odler, 225–236. Westerville, OH: American Ceramic Society.
van Deventer, J., J. Provis, P. Duxson, and G. Lukey. 2007. “Reaction mechanisms in the geopolymeric conversion of inorganic waste to useful products.” J. Hazard. Mater. 139 (3): 506–513. https://doi.org/10.1016/j.jhazmat.2006.02.044.
van Deventer, J. S., J. L. Provis, P. Duxson, and D. G. Brice. 2010. “Chemical research and climate change as drivers in the commercial adoption of alkali activated materials.” Waste Biomass Valorization 1 (1): 145–155. https://doi.org/10.1007/s12649-010-9015-9.
Wang, H., and J. Gillott. 1991. “Mechanism of alkali-silica reaction and the significance of calcium hydroxide.” Cem. Concr. Res. 21 (4): 647–654. https://doi.org/10.1016/0008-8846(91)90115-X.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 8August 2019

History

Received: Jul 10, 2018
Accepted: Feb 28, 2019
Published online: May 28, 2019
Published in print: Aug 1, 2019
Discussion open until: Oct 28, 2019

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D. Mahanama [email protected]
Ph.D. Candidate, Centre for Infrastructure Engineering and Safety, School of Civil and Environmental Engineering, Univ. of New South Wales, Sydney, NSW 2052, Australia (corresponding author). Email: [email protected]
P. De Silva, Ph.D. [email protected]
Associate Professor, National School of Behavioural and Health Sciences, Australian Catholic Univ., 40 Edward St, North Sydney, NSW 2060, Australia. Email: [email protected]
Lecturer, Centre for Infrastructure Engineering and Safety, School of Civil and Environmental Engineering, Univ. of New South Wales, Sydney, NSW 2052, Australia. ORCID: https://orcid.org/0000-0003-4371-7178. Email: [email protected]
A. Castel, Ph.D. [email protected]
Associate Professor, Centre for Infrastructure Engineering and Safety, School of Civil and Environmental Engineering, Univ. of New South Wales, Sydney, NSW 2052, Australia. Email: [email protected]
M. S. H. Khan, Ph.D. [email protected]
Research Associate, Centre for Infrastructure Engineering and Safety, School of Civil and Environmental Engineering, Univ. of New South Wales, Sydney, NSW 2052, Australia. Email: [email protected]

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