Abstract

In this work, the effect of pyrogenic silica and nanosilica on the properties of portland cement matrices is compared. Two chemically and mineralogically similar mineral additions (amorphous silica) with different particle size and specific surface area were used to prepare pastes and mortars with different solids substitutions of cement by silica. These samples were used to measure water and superplasticizer demand, setting time, hydration kinetics, water absorption by capillary suction, and compressive strength. It was found that specific surface area, rather than particle size, played a crucial role in the amount of water and superplasticizer necessary to obtain a desired workability in pastes and mortars. Such water and superplasticizer demands had a delaying effect on the setting time and hydration kinetics of pastes. Nevertheless, compressive strength results at different curing ages of mortars were found to have a direct correlation with the porous structure of the matrix, rather than with the specific surface area of the silica particles. It was concluded that regardless of its higher specific surface area and greater effect on the fresh state properties of pastes, pyrogenic silica was less efficient than nanosilica to increase the compressive strength of mortars, being considered a less efficient pozzolanic material.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 30Issue 10October 2018

History

Received: Nov 14, 2017
Accepted: Apr 26, 2018
Published online: Jul 26, 2018
Published in print: Oct 1, 2018
Discussion open until: Dec 26, 2018

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Jorge I. Tobón, Ph.D. [email protected]
Professor, Grupo del Cemento y Materiales de Construcción CEMATCO, Facultad de Minas, Universidad Nacional de Colombia, Calle 75 # 79A, 51 Bloque M17, Medellín 050041, Colombia (corresponding author). Email: [email protected]
Oscar Mendoza Reales [email protected]
D.Sc.
Postdoctoral Researcher, Federal Univ. of Rio de Janeiro, Ilha do Fundão, Centro de Tecnologia, Bloco I Sala 110, Av. Horácio Macedo, 2030-101-Cidade Universitária, Rio de Janeiro 21941-450, Brazil. Email: [email protected]
Oscar Jaime Restrepo, Ph.D. [email protected]
Professor, Grupo del Cemento y Materiales de Construcción CEMATCO, Facultad de Minas, Universidad Nacional de Colombia, Calle 75 # 79A, 51 Bloque M17, Medellín 050041, Colombia. Email: [email protected]
María Victoria Borrachero, Ph.D. [email protected]
Professor, Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València, Camino de Vera, s/n, Valencia 46071, Spain. Email: [email protected]
Jordi Payá, Ph.D. [email protected]
Professor, Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València, Camino de Vera, s/n, Valencia 46071, Spain. Email: [email protected]

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