Thermal Storage Stability of Bio-Oil Modified Asphalt
Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 4
Abstract
This study investigates and evaluates the storage stability of asphalt binder modified by bio-oil at high temperature. Five bio-asphalts are prepared by adding 10, 15, 20, 25, and 30% bio-oil into 70# petroleum asphalt. The bioasphalts are statically stored for 48 h at four different temperatures: 120, 140, 160, and 180°C. The softening point test, rotational viscosity test, dynamic shear rheometer (DSR) test, and Fourier transform infrared spectroscopy (FTIR) test are applied. The top and bottom sections of samples after thermal storage are analyzed for thermal storage stability from three aspects: physical properties, rheological properties, and functional group composition. The results show that after thermal storage, the bioasphalts segregated and the softening point, viscosity, and antirutting factor of the bottom sections are larger than those of the top sections. The viscosities of the top and bottom sections of bioasphalt with 20% bio-oil are 0.507 and , respectively, under the storage temperature of 140°C. Moreover, the thermal storage stability of bioasphalts decreases with an increase in bio-oil content and storage temperature. Furthermore, based on rheological properties and functional group analysis, it is found that physical segregation and chemical reactions occurred, such as carbonation reactions, reactions between the oligomers, and volatilization of aromatic compounds. Overall, it is recommended that the storage temperature should be kept below 160°C and the bio-oil content should be less than 25%.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
This research is supported by the National Natural Science Foundation of China (NSFC) (Nos. 51378074 and 51578075), the Fundamental and Applied Research Project of the Chinese National Transportation Department (2014 319 812 180), and the Special Fund for Basic Scientific Research of Central Colleges, Chang’an University (CHD310821153503).
References
AASHTO. (2013a). “Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR).” AASHTO T315-12-UL, Washington, DC.
AASHTO. (2013b). “Standard method of test for viscosity determination of asphalt binder using rotational viscometer.” AASHTO T316-13-UL, Washington, DC.
Airey, G. D., and Mohammed, M. H. (2008). “Rheological properties of polyacrylates used as synthetic road binders.” Rheologica Acta, 47(7), 751–763.
ASTM. (2012a). “Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer.” ASTM D4402/D4402M-12, West Conshohocken, PA.
ASTM. (2012b). “Test method for softening point of bitumen (ring-and-ball apparatus).” ASTM D36/D36 M, West Conshohocken, PA.
Azahar, W., et al. (2016). “The potential of waste cooking oil as bio-asphalt for alternative binder—An overview.” Jurnal Teknologi, 78(4), 111–116.
Ba, T., Chaala, A., Garcia-Perez, M., and Roy, C. (2004). “Colloidal properties of bio-oils obtained by vacuum pyrolysis of softwood bark. Storage stability.” Energy Fuels, 18(1), 188–201.
Bowers, B. F., Huang, B., Shu, X., and Miller, B. C. (2014). “Investigation of reclaimed asphalt pavement blending efficiency through GPC and FTIR.” Constr. Build. Mater., 50, 517–523.
Bridgwater, A. V. (2012). “Review of fast pyrolysis of biomass and product upgrading.” Biomass Bioenergy, 38, 68–94.
Carpenter, D., Westover, T. L., Czernik, S., and Jablonski, W. (2014). “Biomass feedstocks for renewable fuel production: A review of the impacts of feedstock and pretreatment on the yield and product distribution of fast pyrolysis bio-oils and vapors.” Green Chem., 16(2), 384–406.
Chailleux, E., Audo, M., Bujoli, B., Queffelec, C., Legrand, J., and Lepine, O. (2012). “Alternative binder from microalgae: Algoroute project.” Workshop Alternative Binders for Sustainable Asphalt Pavements, France.
Chen, D., Zhou, J., Zhang, Q., and Zhu, X. (2014). “Evaluation methods and research progresses in bio-oil storage stability.” Renewable Sustainable Energy Rev., 40, 69–79.
Chinese Standards. (2004). “Technical specifications for construction of highway asphalt pavements.” JTG F40-2004, Ministry of Communications of the People’s Republic of China, Beijing.
Chinese Standards. (2011). “Standard test methods of bitumen and bituminous mixture for highway engineering.” JTG E20-2011, Ministry of Communications of the People’s Republic of China, Beijing.
Colbert, B., Hasan, M. R. M., and You, Z. (2016). “A hybrid strategy in selecting diverse combinations of innovative sustainable materials for asphalt pavements.” J. Traffic Transp. Eng., 3(2), 89–103.
Czernik, S., and Bridgwater, A. (2004). “Overview of applications of biomass fast pyrolysis oil.” Energy Fuels, 18(2), 590–598.
Diebold, J. P. (2000). “A review of the chemical and physical mechanisms of the storage stability of fast pyrolysis bio-oils.”, National Renewable Energy Laboratory, Golden, CO.
Eide, I., Zahlsen, K., Kummernes, H., and Neverdal, G. (2006). “Identification and quantification of surfactants in oil using the novel method for chemical fingerprinting based on electrospray mass spectrometry and chemometrics.” Energy Fuels, 20(3), 1161–1164.
Fini, E. H., Hosseinnezhad, S., Oldham, D. J., Chailleux, E., and Gaudefroy, V. (2017). “Source dependency of rheological and surface characteristics of bio-modified asphalts.” Road Mater. Pavement Des., 18(2), 408–424.
Fini, E. H., Oldham, D., and Buabeng, F. S. (2015). “Investing the aging susceptibility of bio-modified asphalts.” Airfield Highway Pavements, 62–73.
Fini, E. H., Yang, S.-H., and Xiu, S. (2010). “Characterization and application of manure-based bio-binder in asphalt industry.” Transportation Research Board 89th Annual Meeting, Washington, DC.
Haarlemmer, G., Guizani, C., Anouti, S., Déniel, M., Roubaud, A., and Valin, S. (2016). “Analysis and comparison of bio-oils obtained by hydrothermal liquefaction and fast pyrolysis of beech wood.” Fuel, 174, 180–188.
Hasan, M. R. M., and You, Z. (2016). “Ethanol based foamed asphalt as potential alternative for low emission asphalt technology.” J. Traffic Transp. Eng., 3(2), 116–126.
Hill, B., Oldham, D., Behnia, B., Fini, E. H., Buttlar, W. G., and Reis, H. (2016). “Evaluation of low temperature viscoelastic properties and fracture behavior of bio-asphalt mixtures.” Int. J. Pavement Eng., 1–8.
Javaid, A., et al. (2010). “Removal of char particles from fast pyrolysis bio-oil by microfiltration.” J. Membr. Sci., 363(1), 120–127.
Jiang, X., Zhong, Z., Ellis, N., and Wang, Q. (2011). “Aging and thermal stability of the mixed product of the ether-soluble fraction of bio-oil and bio-diesel.” Chem. Eng. Technol., 34(5), 727–736.
Kim, K. H., Bai, X., Cady, S., Gable, P., and Brown, R. (2015). “Quantitative investigation of free radicals in bio-oil and their potential role in condensed-phase polymerization.” ChemSusChem, 8(5), 894–900.
Lei, Z., Bahia, H., and Yi-Qiu, T. (2015). “Effect of bio-based and refined waste oil modifiers on low temperature performance of asphalt binders.” Constr. Build. Mater., 86, 95–100.
Metwally, M., and Raouf, M. A. (2010). Development of non-petroleum binders derived from fast pyrolysis bio-oils for use in flexible pavement, Iowa State Univ., Ames, IA.
Mills-Beale, J., You, Z., Fini, E., Zada, B., Lee, C. H., and Yap, Y. K. (2012). “Aging influence on rheology properties of petroleum-based asphalt modified with biobinder.” J. Mater. Civ. Eng., 358–366.
Mohammad, L., Elseifi, M., Cooper, S., Challa, H., and Naidoo, P. (2013). “Laboratory evaluation of asphalt mixtures that contain biobinder technologies.” Transp. Res. Rec., 2371, 58–65.
Mohan, D., Kumar, H., Sarswat, A., Alexandre-Franco, M., and Pittman, C. U. (2014). “Cadmium and lead remediation using magnetic oak wood and oak bark fast pyrolysis bio-chars.” Chem. Eng. J., 236, 513–528.
Mohan, D., Pittman, C. U., and Steele, P. H. (2006). “Pyrolysis of wood/biomass for bio-oil: A critical review.” Energy Fuels, 20(3), 848–889.
Onochie, A., Fini, E., Yang, X., Mills-Beale, J., and You, Z. (2013). “Rheological characterization of nano-particle based bio-modified binder.” Transportation Research Board 92nd Annual Meeting, Washington, DC.
Raouf, M. A., and Williams, R. C. (2009). “Determination of pre-treatment procedure required for developing bio-binders from bio-oils.” Proc. Mid-Continent Transportation Research Symp., Ames, IA.
Raouf, M. A., and Williams, R. C. (2010a). “Rheology of fractionated cornstover bio-oil as a pavement material.” Int. J. Pavements, 9(1–3), 58–69.
Raouf, M. A., and Williams, R. C. (2010b). “Temperature susceptibility of non-petroleum binders derived from bio-oils.” 7th Asia Pacific Conf. on Transportation and the Environment, Semarang, Indonesia.
Sun, Z., Yi, J., Huang, Y., Feng, D., and Guo, C. (2016). “Properties of asphalt binder modified by bio-oil derived from waste cooking oil.” Constr. Build. Mater., 102, 496–504.
Tripathi, M. M., El Barbary, M. H., Yueh, F.-Y., Singh, J. P., Steele, P. H., and Ingram, L. L. (2009). “Reflection–absorption-based near infrared spectroscopy for predicting water content in bio-oil.” Sens. Actuators, B, 136(1), 20–25.
Wang, H., Zhang, R., Chen, Y., You, Z., and Fang, J. (2016). “Study on microstructure of rubberized recycled hot mix asphalt based X-ray CT technology.” Constr. Build. Mater., 121, 177–184.
Wang, H. G., and Junfeng, Z. Y. (2014). “Advances in bio-binder application on road pavement.” J. Wuhan Univ. Technol., 36(7), 4 (in Chinese).
Yang, X., Mills-Beale, J., and You, Z. (2017). “Chemical characterization and oxidative aging of bio-asphalt and its compatibility with petroleum asphalt.” J. Cleaner Prod., 142, 1837–1847.
Yang, X., You, Z., Dai, Q., and Mills-Beale, J. (2014). “Mechanical performance of asphalt mixtures modified by bio-oils derived from waste wood resources.” Constr. Build. Mater., 51, 424–431.
Yang, X., You, Z.-P., and Dai, Q.-L. (2013). “Performance evaluation of asphalt binder modified by bio-oil generated from waste wood resources.” Int. J. Pavement Res. Technol., 6(4), 431–439.
Yu, J., Zeng, X., Wu, S., Wang, L., and Liu, G. (2007). “Preparation and properties of montmorillonite modified asphalts.” Mater. Sci. Eng. A, 447(1), 233–238.
Zhang, R., Wang, H., Gao, J., You, Z., and Yang, X. (2017). “High temperature performance of SBS modified bio-asphalt.” Constr. Build. Mater., 144, 99–105.
Zhao, X. (2014). Preliminary study on the preparation technology and rheology property of bio-asphalt binders, Chang’an Univ., Xi’an, Shaanxi, China (in Chinese).
Information & Authors
Information
Published In
Copyright
©2018 American Society of Civil Engineers.
History
Received: Jul 12, 2017
Accepted: Oct 11, 2017
Published online: Feb 10, 2018
Published in print: Apr 1, 2018
Discussion open until: Jul 10, 2018
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.