Diffusion and Rheological Properties of Asphalt Modified by Bio-Oil Regenerant Derived from Waste Wood
Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 2
Abstract
To decrease the usage of energy and improve waste recovery, dynamic simulations are conducted to understand the diffusion mechanism and rheological properties of bio-oil regenerated asphalt. A new simplified model of bio-oil modified asphalt (BMA) is built to calculate diffusion coefficients, diffusion driving force, viscosity, solubility parameters, and ductility. The calculated diffusion coefficients of bio-oil, asphaltenes, saturates, and resins are , , , and at 298 K, respectively. Results indicate that the bio-oil diffuses faster than asphaltenes, saturates, and resins, and that it can increase the ductility of asphalt and improve asphalt’s elastic property. Moreover, potential energy is the key driving force of diffusion. There is no chemical reaction involved in the diffusion process of BMA and bio-oil can both reduce the viscosity of asphalt and soften it.
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Acknowledgments
The authors are supported by the National Natural Science Foundation of China (No. 51308329), the Science and Technology Department of Shanxi Province International Cooperation (Nos. 201603D421027 and 201703D42111474), the Shanxi Provincial Key Research and Development Program (No. 201603D321118), and the Science and Technology Planning Project of Transport Department of Shanxi Province (Nos. 2017-1-16 and 2016-1-14). The author would like to thank Shiyanjia Lab.
References
Asli, H., Ahmadinia, E., and Zargar, M. (2012). “Investigation on physical properties of waste cooking oil: Rejuvenated bitumen binder.” Constr. Build. Mater., 37(12), 398–405.
ASTM. (1999). “Standard test method for ductility of bituminous materials.” ASTM D113, West Conshohocken, PA.
ASTM. (2009) “Standard test method for softening point of bitumen (Ring-and-ball apparatus).” ASTM D36-76, West Conshohocken, PA.
ASTM. (2013). “Standard test method for penetration of bituminous materials.” ASTM D5, West Conshohocken, PA.
Bai, F., Yang, X., and Zeng, G. (2016). “A stochastic viscoelastic-viscoplastic constitutive model and its application to crumb rubber modified asphalt mixtures.” Mater. Des., 89(1), 802–809.
Barton, A. F. M. (1975). Solubility parameters, Vol. 75, Springer, New York, 289–303.
Burke, K., and Hesp, S. A. M. (2011). “Penetration testing of waste engine oil modified asphalt cements.” Conf. Transportation Research Group of India, Schindler, Ebikon, Switzerland, 46–52.
Chemdraw [Computer software]. PerkinElmer, Waltham, MA.
Chen, M., Leng, B., Wu, S., and Sang, Y. (2014a). “Physical, chemical and rheological properties of waste edible vegetable oil rejuvenated asphalt binders.” Constr. Build. Mater., 66(36), 286–298.
Chen, M., Xiao, F., and Putman, B. (2014b). “High temperature properties of rejuvenating recovered binder with rejuvenator, waste cooking and cotton seed oils.” Constr. Build. Mater., 59(3), 10–16.
Ding, Y., Huang, B., and Xiang, S. (2016). “Use of molecular dynamics to investigate diffusion between virgin and aged asphalt binders.” Fuel, 174(6), 267–273.
Fini, E. H., Kalberer, E. W., and Shahbazi, A. (2011). “Chemical characterization of bio-binder from swine manure: Sustainable modifier for asphalt binder.” J. Mater. Civ. Eng., 1506–1513.
Groenzin, H., and Mullins, C. O. (2000). “Molecular size and structure of asphaltenes from various sources.” Energy Fuels, 14(3), 677–684.
Hansen, C. M. (2000). Hansen solubility parameters: A user’s handbook, CRC Press, London, 25–43.
Hansen, C. M. (2004a). “50 years with solubility parameters: Past and future.” Prog. Org. Coat., 51(1), 77–84.
Hansen, C. M. (2004b). “Aspects of solubility, surfaces, and diffusion in polymers.” Prog. Org. Coat., 51(1), 55–66.
Hansen, C. M., and Smith, A. L. (2004). “Using Hansen solubility parameters to correlate solubility of C60 fullerene in organic solvents and in polymers.” Carbon, 42(8), 1591–1597.
Harman-Ware, A. E., Morgan, T., and Wilson, M. (2013). “Microalgae as a renewable fuel source: Fast pyrolysis of Scenedesmus sp.” Renewable Energy, 60(12), 625–632.
Hildebrand, J., and Scott, R. L. (1950). The solubility of nonelectrolytes, 3rd Ed., Reinhold, New York.
Hui, Y., Dai, Q., and You, Z. (2016). “Molecular dynamics simulation of physicochemical properties of the asphalt model.” Fuel, 164(1), 83–93.
Kim, S. W., Koo, B. S., and Dong, H. L. (2014). “A comparative study of bio-oils from pyrolysis of microalgae and oil seed waste in a fluidized bed.” Bioresour. Technol., 162(162C), 96–102.
Materials Studio [Computer software]. BIOVIA, San Diego.
Mills-Beale, J., You, Z., and Fini, E. (2012). “Aging influence on rheology properties of petroleum-based asphalt modified with bio-binder.” J. Mater. Civ. Eng., 358–366.
Mohan, D., Pittman, C. U., and Steele, P. H. (2006). “Pyrolysis of wood/biomass for bio-oil: A critical review.” Energy Fuels, 20(3), 848–889.
Nicolet Omnic [Computer software]. Thermo Fisher Scientific, Waltham, MA.
Onochie, A., Fini, E., and Yang, X. (2013). “Rheological characterization of nano-particle based bio-modified binder.” Transportation Research Board 92nd Annual Meeting, Transportation Research Board, Washington, DC, 125–131.
Raouf, M. A., and Williams, R. C. (2009). “Determination of pre-treatment procedure required for developing bio-binders from bio-oils.” Proc., 2009 Mid-Continent Transportation Research Symp., Transportation Research Board, Washington, DC, 12–18.
Su, J. F., Qiu, J., and Schlangen, E. (2015). “Investigation the possibility of a new approach of using micro-capsules containing waste cooking oil: In situ, rejuvenation for aged bitumen.” Constr. Build. Mater., 74, 83–92.
Sun, D., Lin, T., and Zhu, X. (2016a). “Indices for self-healing performance assessments based on molecular dynamics simulation of asphalt binders.” Comput. Mater. Sci., 114(3), 86–93.
Sun, H. (1998). “COMPASS: An ab initio force-field optimized for condensed-phase applications overview with details on alkane and benzene compounds.” J. Phys. Chem. B, 102(38), 7338–7364.
Sun, Z., Yi, J., Huang, Y., and Guo, C. (2016c). “Properties of asphalt binder modified by bio-oil derived from waste cooking oil.” Constr. Build. Mater., 102(1), 496–504.
Vicente, L., Soto, C., and Pacheco-Sánchez, H. (2006). “Application of molecular simulation to calculate miscibility of a model asphaltene molecule.” Fluid Phase Equilib., 239(1), 100–106.
Xu, G., and Wang, H. (2016). “Study of cohesion and adhesion properties of asphalt concrete with molecular dynamics simulation.” Comput. Mater. Sci., 112(2), 161–169.
Xue, Y., Wu, S., and Cai, J. (2014). “Effects of two biomass ashes on asphalt binder: Dynamic shear rheological characteristic analysis.” Constr. Build. Mater., 56(4), 7–15.
Yang, S. H., and Suciptan, T. (2016). “Rheological behavior of Japanese cedar-based bio-binder as partial replacement for bituminous binder.” Constr. Build. Mater., 114(7), 127–133.
Yang, X., You, Z., and Dai, Q. (2013). “Performance evaluation of asphalt binder modified by bio-oil generated from waste wood resources.” Int. J. Pavement Res. Technol., 6(4), 431–439.
Yang, X., You, Z., and Dai, Q. (2014). “Mechanical performance of asphalt mixtures modified by bio-oils derived from waste wood resources.” Constr. Build. Mater., 51(31), 424–431.
Yao, H., Dai, Q., and You, Z. (2015). “Chemo-physical analysis and molecular dynamics (MD) simulation of moisture susceptibility of nano hydrated lime modified asphalt mixtures.” Constr. Build. Mater., 101(1), 536–547.
Zhao, Z., Wu, S., and Zhou, X. (2016). “Molecular simulations of properties changes on nano-layered double hydroxides-modified bitumen.” Mater. Res. Innovations, 19(S8), 556–560.
Zhou, X., Wu, S., and Liu, G. (2016a). “Molecular simulations and experimental evaluation on the curing of epoxy bitumen.” Mater. Struct., 49(1–2), 241–247.
Zhou, X., Wu, S., and Liu, Q. (2016b). “Effect of surface active agents on the rheological properties and solubility of layered double hydroxides-modified asphalt.” Mater. Res. Innovations, 19(S5), 978–982.
Zhou, X., Zhang, X., and Xu, S. (2017). “Evaluation of thermo-mechanical properties of graphene/carbon-nanotubes modified asphalt with molecular simulation.” Mol. Simul., 43(4), 312–319.
Zofka, A., and Yut, I. (2012). “Investigation of rheology and aging properties of asphalt binder modified with waste coffee grounds.” Transportation Research Board, Alternative Binders for Sustainable Asphalt Pavements, Transportation Research Board, Washington, DC, 112–116.
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©2017 American Society of Civil Engineers.
History
Received: May 5, 2017
Accepted: Jul 19, 2017
Published online: Nov 27, 2017
Published in print: Feb 1, 2018
Discussion open until: Apr 27, 2018
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