New Polymer Concrete with Superior Ductility and Fracture Toughness Using Alumina Nanoparticles
Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 8
Abstract
This study investigates the effect of alumina nanoparticles (ANPs) on tension and fracture characteristics of polymer concrete (PC). ANPs with a maximum particle size of 50 nm were used at 0.5, 1.0, 2.0, and 3.0 wt.% of epoxy resin. Tensile strength, tensile failure strain, and fracture toughness (, , and ) were determined experimentally. A PC with superior ductility showing a tensile failure strain of 4.89% (compared with 2.56% for neat PC) was observed at ANP content of 3.0 wt.%. Using ANPs in producing epoxy PC can significantly improve ductility () and fracture toughness () compared with neat PC. Scanning electron microscope (SEM), dynamic mechanical analyzer (DMA), and Fourier transform infrared (FTIR) observations were conducted to understand the role ANPs play to manifest the observed improvements in tension and fracture characteristics of PC.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
Southern Plains Transportation Center (SPTC) has funded this research work. The authors greatly acknowledge this support. The first author acknowledges financial support from the Scientific and Technological Research Council of Turkey (TUBITAK) BIDEB-2219 Postdoctoral Research program. Finally, support to the fourth author by the Egyptian Science and Technology Fund (STDF-CSE 5213) is also appreciated.
References
ACI (American Concrete Institute). (2009a). “Fracture toughness testing of concrete.” ACI 446, Farmington Hills, MI.
ACI (American Concrete Institute). (2009b). “Guide for the use of polymers in concrete.” ACI 548.1 R-92, Farmington Hills, MI.
ASTM. (2013). “Standard test method for flow of hydraulic cement mortar.” ASTM C1437, West Conshohocken, PA.
ASTM. (2014). “Standard test method for tensile properties of plastics.” ASTM D638-14, West Conshohocken, PA.
Byczyński, Ł., Dutkiewicz, M., and Maciejewski, H. (2015). “Synthesis and properties of high-solids hybrid materials obtained from epoxy functional urethanes and siloxanes.” Prog. Org. Coat., 84, 59–69.
Campillo, I., Guerrero, A., Dolado, J. S., Porro, A., Ibáñez, J. A., and Goñi, S. (2007). “Improvement of initial mechanical strength by nanoalumina in belite cements.” Mater. Lett., 61(8–9), 1889–1892.
Cristea, M., Ibanescu, S., Cascaval, C. N., and Rosu, D. (2009). “Dynamic mechanical analysis of polyurethane-epoxy interpenetrating polymer networks.” High Perform. Polym., 21(5), 608–623.
Dorigato, A., and Pegoretti, A. (2011). “The role of alumina nanoparticles in epoxy adhesives.” J. Nanoparticle Res., 13(6), 2429–2441.
Ferdous, W., Manalo, A., Aravinthan, T., and Van Erp, G. (2016). “Properties of epoxy polymer concrete matrix: Effect of resin-to-filler ratio and determination of optimal mix for composite railway sleepers.” Constr. Bldg. Mater., 124, 287–300.
Gopalaratnam, V., Gettu, R., Carmona, S., and Jamet, D. (1995). “Characterization of the toughness of fiber reinforced concretes using the load-CMOD response.” Proc., FRAMCOS-2, F. H. Wittmann, ed., AED1FICATIO, Freiburg, Germany, 769–782.
Gopalaratnam, V. S., and Gettu, R. (1995). “On the characterization of flexural toughness in fiber reinforced concretes.” Cem. Conc. Comput., 17(3), 239–254.
Gu, H., et al. (2012). “Polyaniline stabilized magnetite nanoparticle reinforced epoxy nanocomposites.” ACS App. Mater. Interfaces, 4(10), 5613–5624.
Hosseini, P., Hosseinpourpia, R., Pajum, A., Khodavirdi, M. M., Izadi, H., and Vaezi, A. (2014). “Effect of nano-particles and aminosilane interaction on the performances of cement-based composites: An experimental study.” Constr. Build. Mater., 66, 113–124.
Hu, C., Xu, G., Shen, X., Shao, C., and Yan, X. (2010). “The epoxy-siloxane/Al composite coatings with low infrared emissivity for high temperature applications.” App. Surf. Sci., 256(11), 3459–3463.
Jung, K.-C., Roh, I.-T., and Chang, S.-H. (2015). “Stress analysis of runway repaired using compliant polymer concretes with consideration of cure shrinkage.” Compos. Struct., 119, 13–23.
Kwon, Y., Yim, B.-s., Kim, J.-m., and Kim, J. (2011). “Mechanical and wetting properties of epoxy resins: Amine-containing epoxy-terminated siloxane oligomer with or without reductant.” Microelectron. Relia., 51(4), 819–825.
Li, Z., Wang, H., He, S., Lu, Y., and Wang, M. (2006). “Investigations on the preparation and mechanical properties of the nano-alumina reinforced cement composite.” Mater. Lett., 60(3), 356–359.
Liu, T., Phang, I. Y., Shen, L., Chow, S. Y., and Zhang, W.-D. (2004). “Morphology and mechanical properties of multiwalled carbon nanotubes reinforced nylon-6 composites.” Macromolecules, 37(19), 7214–7222.
Luo, J., Li, Q., Zhao, T., Gao, S., and Sun, S. (2013). “Bonding and toughness properties of PVA fibre reinforced aqueous epoxy resin cement repair mortar.” Constr. Build. Mater., 49(0), 766–771.
Martínez-Barrera, G., Menchaca-Campos, C., and Gencel, O. (2013). “Polyester polymer concrete: Effect of the marble particle sizes and high gamma radiation doses.” Constr. Bldg. Mater., 41(0), 204–208.
Mikhaylova, Y., Adam, G., Häussler, L., Eichhorn, K. J., and Voit, B. (2006). “Temperature-dependent FTIR spectroscopic and thermoanalytic studies of hydrogen bonding of hydroxyl (phenolic group) terminated hyperbranched aromatic polyesters.” J. Molecular Struct., 788(1–3), 80–88.
Ohama, Y. (1995). Handbook of polymer-modified concrete and mortars: Properties and process technology, William Andrew Publishing, Park Ridge, NJ.
Pallant, J. (2007). SPSS survival manual: A step by step guide to data analysis using SPSS, Allen & Unwin, NSW, Australia.
Quanfu, Y., Weijun, Y., Chengjun, S., and Mingwei, D. (2012). “Preparation and properties of lingin-epoxy resin composite.” BioResources, 7(4), 5737–5748.
Rashad, A. M. (2013). “A synopsis about the effect of nano-Al2O3, nano-Fe2O3, nano-Fe3O4 and nano-clay on some properties of cementitious materials—A short guide for civil engineer.” Mater. Des., 52, 143–157.
Reda Taha, M. M., Xiao, X., Yi, J., and Shrive, N. G. (2002). “Evaluation of flexural fracture toughness for quasi-brittle structural materials using a simple test method.” Can. J. Civ. Engin., 29(4), 567–575.
Reis, J. M. L., and Ferreira, A. J. M. (2004). “A contribution to the study of the fracture energy of polymer concrete and fibre reinforced polymer concrete.” Polymer Test., 23(4), 437–440.
Sanchez, F., and Sobolev, K. (2010). “Nanotechnology in concrete—A review.” Constr. Build. Mater., 24(11), 2060–2071.
Sun, W., Vassilopoulos, A. P., and Keller, T. (2014). “Effect of thermal lag on glass transition temperature of polymers measured by DMA.” Int. J. Adhes. Adhes., 52, 31–39.
Susilorini, R. M. I. R., et al. (2014). “The advantage of natural polymer modified mortar with seaweed: Green construction material innovation for sustainable concrete.” Procedia Engin., 95(0), 419–425.
Toufigh, V., Hosseinali, M., and Shirkhorshidi, S. M. (2016). “Experimental study and constitutive modeling of polymer concrete’s behavior in compression.” Const. Build. Mater., 112, 183–190.
Van Gemert, D., et al. (2005). “Cement concrete and concrete–polymer composites: Two merging worlds: A report from 11th ICPIC congress in Berlin, 2004.” Cem. Concr. Comp., 27(9–10), 926–933.
Wang, S., et al. (2011). “Preparation of a durable superhydrophobic membrane by electrospinning poly(vinylidene fluoride) (PVDF) mixed with epoxy-siloxane modified SiO2 nanoparticles: A possible route to superhydrophobic surfaces with low water sliding angle and high water contact angle.” J. Colloid Interface Sci., 359(2), 380–388.
Zabihi, O., Omrani, A., and Rostami, A. A. (2012). “Thermo-oxidative degradation kinetics and mechanism of the system epoxy nanocomposite reinforced with nano-Al2O3.” J. Therm. Anal. Calorimetry, 108(3), 1251–1260.
Zhu, J., Wei, S., Ryu, J., Budhathoki, M., Liang, G., and Guo, Z. (2010). “In situ stabilized carbon nanofiber (CNF) reinforced epoxy nanocomposites.” J. Mater. Chem., 20(23), 4937–4948.
Information & Authors
Information
Published In
Copyright
©2017 American Society of Civil Engineers.
History
Received: Sep 17, 2016
Accepted: Nov 22, 2016
Published online: Apr 3, 2017
Published in print: Aug 1, 2017
Discussion open until: Sep 3, 2017
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.