Abstract

The production of rice-husk ash without controlled burning results in pozzolans with different physicochemical characteristics. The amorphous content of residual rice-husk ash (RRHA) is related to the temperature and exposure time during burning, whereas the BET specific surface area depends on the siliceous structure formed during plant growth, in addition to burning and grinding methods. In this study, amorphous content was quantified by X-ray diffraction (Rietveld refinement) in three RRHA samples randomly collected from rice mills located in southern Brazil, in which the burning process was not controlled. Pozzolanic activity evolution of RRHA samples in lime paste was monitored by thermogravimetry for 182 days in order to determine the influence of the lime:pozzolan ratio, BET specific surface area, and average particle size. The results show that lime consumption is not significantly affected by the BET specific surface area or average particle size of RRHA samples with a high amorphous content (>66%). The reaction rate of RRHA depends on the lime:pozzolan ratio. Lime consumption per unit surface area of RRHA declines with an increase in the BET specific surface area. Because the proposed shape factor connects the BET specific surface area and average particle size of RRHA and indirectly includes the amorphous content of RRHA samples, it can therefore be used as an indicator of RRHA reactivity.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

Authors would like to acknowledge the financial support provided by CNPq—Conselho Nacional de Desenvolvimento Científico e Tecnológico—National Counsel of Technological and Scientific Development.

References

Antiohos, S. K., Papadakis, V. G., and Tsimas, S. (2014). “Rice husk ash (RHA) effectiveness in cement and concrete as a function of reactive silica and fineness.” Cem. Concr. Res., 61–62, 20–27.
Antiohos, S. K., Tapali, J. G., Zervaki, M., Sousa-Coutinho, J., Tsimas, S., and Papadakis, V. G. (2013). “Low embodied energy cement containing untreated RHA: A strength development and durability study.” Constr. Build. Mater., 49, 455–463.
ASTM. (2012) “Standard specification for portland cement.” ASTM C150/150M–12, West Conshohoken, PA.
Barata, M. S., Hasparyk, N. P., and Lima, F. S. S. (2006). “Evaluation of pozzolanic activity and inhibition of the alkali-aggregate reaction in highly reactivity pozzolans.” Ibracon Mater. J., 2(1), 1–8.
Chandrasekhar, S., Pramada, P. M., and Majeed, J. (2006). “ Effect of calcination temperature and heating rate on the optical properties and reactivity of rice husk ash.” J. Mater. Sci., 41(23), 7926–7933.
Cordeiro, G. C., Toledo Filho, R. D., and Fairbairn, E. M. R. (2009). “Use of ultrafine rice husk ash with high-carbon content as pozzolan in high performance concrete.” Mater. Struct., 42(7), 983–992.
Cordeiro, G. C., Toledo Filho, R. D., Tavares, L. M., and Fairbairn, E. M. R. (2012). “Experimental characterization of binary and ternary blended-cement concretes containing ultrafine residual rice husk and sugar cane bagasse ashes.” Constr. Build. Mater., 29, 641–646.
Cordeiro, G. C., Toledo Filho, R. D., Tavares, L. M., Fairbairn, E. M. R., and Hempel, S. (2011). “Influence of particle size and specific surface area on the pozzolanic activity of residual rice husk ash.” Cem. Concr. Compos., 33(5), 529–534.
Feng, Q., Yamamichi, H., Shoya, M., and Sugita, S. (2004). “Study on the pozzolanic properties of rice husk ash by hydrochloric acid pretreatment.” Cem. Concr. Res., 34(3), 521–526.
Ganesan, K., Rajagopal, K., and Thangavel, K. (2008). “Rice husk ash blended cement: Assessment of optimal level of replacement for strength and permeability properties of concrete.” Constr. Build. Mater., 22(8), 1675–1683.
Gobbo, L. A., Sant’agostino, L. M., and D’agostino, L. Z. (2007). “XRD-Rietveld quantitative analysis of glass-containing by-products used in the Brazilian cement industry.” Proc., 12th Int. Congress on the Chemistry of Cement (ICCC), National Research Council of Canada and the Cement Association of Canada, Ottawa.
Hoppe Filho, J. (2008). “Sistemas cimento, cinza volante e cal hidratada: mecanismo de hidratação, microestrutura e carbonatação do concreto (in Portuguese).” Ph.D. thesis, Escola Politécnica–Univ. of São Paulo, São Paulo, Brazil.
Jamil, M., Kaish, A. B. M. A., Raman, S. N., and Zain, M. F. M. (2013). “Pozzolanic contribution of rice husk ash in cementitious system.” Constr. Build. Mater., 47, 588–593.
Nair, D. G., Fraaij, A., Klaassen, A. A. K., and Kentgens, A. P. M. (2008). “A structural investigation relating to the pozzolanic activity of rice husk ashes.” Cem. Concr. Res., 38(6), 861–869.
Pavía, S., Walker, R., Veale, P., and Wood, A. (2014). “Impact of the properties and reactivity of rice husk ash on lime mortar properties.” J. Mater. Civ. Eng., .
Quarcioni, V. A., Chotoli, F. F., Coelho, A. C. V., and Cincotto, M. A. (2015). “Indirect and direct Chapelle’s methods for the determination of lime consumption in pozzolanic materials.” Ibracon Struct. Mater. J., 8(1), 1–7.
Raverdy, M., Brivot, F., Paillere, A. M., and Dron, R. (1980). “Appreciation of pozzolanic reactivity of minor components.” Proc., 7th Int. Congress on the Chemistry of Cement (ICCC), Vol. 3, Institut Francais des Sciences et Technologies des Transports, de l’Aménagement et des Réseaux (IFSTTAR), Champs-sur-Marne, France.
Rêgo, J. H. S., Nepomuceno, A. A., Figueiredo, E. P., and Hasparyk, N. P. (2015a). “Microstructure of cement pastes with residual rice husk ash of low amorphous silica content.” Constr. Build. Mater., 80, 56–68.
Rêgo, J. H. S., Nepomuceno, A. A., Figueiredo, E. P., Hasparyk, N. P., and Borges, L. D. (2015b). “Effect of particle size of residual rice-husk ash in consumption of Ca(OH)2.” J. Mater. Civ. Eng., .
Rukzon, S., Chindaprasirt, P., and Mahachai, R. (2009). “Effect of grinding on chemical and physical properties of rice husk ash.” Int. J. Miner., Metall. Mater., 16(2), 242–247.
Sensale, G. R. (2010). “Effect of rice-husk ash on durability of cementitious materials.” Cem. Concr. Compos., 32(9), 718–725.
Souza, M. F., Batista, P. S., Regiani, I., Libório, J. B. L., and Souza, D. P. F. (2000). “Rice hull-derived silica: Applications in portland cement and mullite whiskers.” Mater. Res., 3(2), 25–30.
Taylor, H. F. W. (1997). Cement chemistry, Thomas Telford Publishing, London.
Wansom, S., Janjaturaphan, S., and Sinthupinyo, S. (2010). “Characterizing pozzolanic activity of rice husk ash by impedance spectroscopy.” Cem. Concr. Res., 40(12), 1714–1722.
Zain, M. F. M., Islam, N. M., Mahmud, F., and Jamil, M. (2011). “Production of rice husk ash for use in concrete as a supplementary cementitious material.” Constr. Build. Mater., 25(2), 798–805.
Zerbino, R., Giaccio, G., Batic, O. R., and Isaia, G. C. (2012). “Alkali-silica reaction in mortars and concretes incorporating natural rice husk ash.” Constr. Build. Mater., 36, 796–806.
Zerbino, R., Giaccio, G., and Isaia, G. C. (2011). “Concrete incorporating rice-husk ash without processing.” Constr. Build. Mater., 25(1), 371–378.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 6June 2017

History

Received: Feb 16, 2016
Accepted: Sep 14, 2016
Published online: Jan 23, 2017
Published in print: Jun 1, 2017
Discussion open until: Jun 23, 2017

Permissions

Request permissions for this article.

Authors

Affiliations

J. Hoppe Filho [email protected]
Adjunct Professor, Dept. of Civil Engineering, CCET, Federal Univ. of Western Bahia, Campus of Barreiras, Rua Prof. José Seabra de Lemos, 316, BA 47 808-021, Barreiras, Brazil (corresponding author). E-mail: [email protected]
M. R. Garcez [email protected]
Adjunct Professor, Dept. of Interdisciplinary, Federal Univ. of Rio Grande do Sul, North Coast Campus, km 92, RS 030, 11.700, RS 95 590-000, Tramandaí, Brazil. E-mail: [email protected]
M. H. F. Medeiros [email protected]
Adjunct Professor, Dept. of Civil Construction, Polytechnic Center, Federal Univ. of Paraná, P. O. Box 19.011, PR 81 531-980, Curitiba, Brazil. E-mail: [email protected]
L. C. P. Silva Filho [email protected]
Associate Professor, Dept. of Civil Engineering, School of Engineering, Federal Univ. of Rio Grande do Sul, Avenida Osvaldo Aranha, 99, RS 90 135-190, Porto Alegre, Brazil. E-mail: [email protected]
G. C. Isaia [email protected]
Titular Professor, Dept. of Structures and Civil Construction, Center of Technology, Federal Univ. of Santa Maria, Avenida Roraima, 100, RS 97 105-900, Santa Maria, Brazil. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share