Characterization of Alkali-Activated Nonwood Biomass Ash–Based Geopolymer Concrete
Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 4
Abstract
The combustion ash of a common nonwood biomass (wheat straw) was evaluated for value-added use in production of geopolymer concrete where alkali aluminosilicate hydrates are the primary binder constituents. The wheat straw ash was supplemented with other raw materials in order to achieve a desired chemical balance. The binder composition that performed well in experimental work comprised wheat straw ash:coal fly ash:metakaolin:gypsum at 0.50:0.25:0.25:0.05 weight ratios. The wheat straw ash–based concrete as well as a control portland cement concrete were subjected to a comprehensive experimental investigation. The workability, set time, compressive strength, residual compressive strength after immersion in boiling water, flexural strength, density, moisture absorption, voids content, capillary sorptivity, and acid and fire resistance of concrete materials were evaluated. The experimental results indicated that the nonwood biomass ash–based geopolymer concrete materials with proper binder formulation can provide desired mechanical attributes, moisture barrier qualities, durability, and fire resistance when compared with normal portland cement concrete.
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Acknowledgments
The authors wish to acknowledge the support of the U.S. Department of Agriculture (SBIR Award No. 2014-33610-21903) for the work reported herein. The authors declare that they have no conflict of interest.
References
Abdollahnejad, Z., Torgal, F. P., Aguiar, J. L., and Jesus, C. M. G. (2014). “Performance of fly ash based one-part geopolymer mortars in durability tests.” Congresso Luso-Brasileiro de Materiais de Construção Sustentáveis, Vol. 1, Universidade do Minho, Braga, Portugal.
Abdulkareem, O. A., Al Bakri, A. M. M., Kamarudin, H., and Nizar, I. K. (2013a). “Fire resistance evaluation of lightweight geopolymer concrete system exposed to elevated temperatures of 100–800°C.” Key Eng. Mater., 594–595, 427–432.
Abdulkareem, O. A., Mustafa Al Bakri, A. M., Kamarudin, H., and Khairul Nizar, I. (2013b). “Alteration in the microstructure of fly ash geopolymers upon exposure to elevated temperatures.” Adv. Mater. Res., 795, 201–205.
Ariffin, M. A. M., Bhutta, M. A. R., Hussin, M. W., Mohd Tahir, M., and Aziah, N. (2013). “Sulfuric acid resistance of blended ash geopolymer concrete.” Constr. Build. Mater., 43, 80–86.
Arioz, O. (2007). “Effects of elevated temperatures on properties of concrete.” Fire Saf. J., 42(8), 516–522.
ASTM. (2008). “Standard test method for time of setting of concrete mixtures by penetration resistance.” ASTM C403/C403M-08, West Conshohocken, PA.
ASTM. (2013a). “Standard test method for density, absorption, and voids in hardened concrete.” ASTM C642-13, West Conshohocken, PA.
ASTM. (2013b). “Standard test method for measurement of rate of absorption of water by hydraulic-cement concretes.” ASTM C1585-13, West Conshohocken, PA.
ASTM. (2014). “Standard specification for flow table for use in tests of hydraulic cement.” ASTM C230/C230M-14, West Conshohocken, PA.
ASTM. (2016a) “Standard specification for concrete aggregates.” ASTM C33/C33M-16, West Conshohocken, PA.
ASTM. (2016b) “Standard specification for portland cement.” ASTM C150/C150M-16e1, West Conshohocken, PA.
ASTM. (2016c). “Standard test method for flexural strength of concrete (using simple beam with third-point loading).” ASTM C78/C78M-16, West Conshohocken, PA.
ASTM. (2016d) “Standard test methods for fineness of hydraulic cement by air-permeability apparatus.” ASTM C204-16, West Conshohocken, PA.
Autef, A., Joussein, E., Gasgnier, G., and Rossignol, S. (2012). “Role of the silica source on the geopolymerization rate.” J. Non-Cryst. Solids, 358(21), 2886–2893.
Bakharev, T. (2005). “Resistance of geopolymer materials to acid attack.” Cem. Concr. Res., 35(4), 658–670.
Ban, C. C., and Ramli, M. (2011). “The implementation of wood waste ash as a partial cement replacement material in the production of structural grade concrete and mortar: An overview.” Resour. Conserv. Recycl., 55(7), 669–685.
Berra, M., et al. (2011). Reuse of woody biomass fly ash in cement-based materials: Leaching tests, Springer, Berlin.
Capablo, J., et al. (2009). “Ash properties of alternative biomass.” Energy Fuels, 23(4), 1965–1976.
Cheah, C. B., and Ramli, M. (2012). “Mechanical strength, durability and drying shrinkage of structural mortar containing HCWA as partial replacement of cement.” Constr. Build. Mater., 30, 320–329.
Chindaprasirt, P., Rattanasak, U., and Taebuanhuad, S. (2013). “Resistance to acid and sulfate solutions of microwave-assisted high calcium fly ash geopolymer.” Mater. Struct., 46(3), 375–381.
Feng, D. W., Provis, J. L., and van Deventer, J. S. J. (2012). “Thermal activation of albite for the synthesis of one-part mix geopolymers.” J. Am. Ceram. Soc., 95(2), 565–572.
Giannopoulou, I., and Panias, D. (2010). “Hydrolytic stability of sodium silicate gels in the presence of aluminum.” J. Mater. Sci., 45(19), 5370–5377.
Hajimohammadi, A., Provis, J. L., and Van Deventer, J. S. (2008). “One-part geopolymer mixes from geothermal silica and sodium aluminate.” Ind. Eng. Chem. Res., 47(23), 9396–9405.
James, A., Thring, R., Helle, S., and Ghuman, H. (2012). “Ash management review—Applications of biomass bottom ash.” Energies, 5(12), 3856–3873.
Kong, D. L., and Sanjayan, J. G. (2010). “Effect of elevated temperatures on geopolymer paste, mortar and concrete.” Cem. Concr. Res., 40(2), 334–339.
Marín-López, C., et al. (2009). “Synthesis and characterization of a concrete based on metakaolin geopolymer.” Inorg. Mater., 45(12), 1429–1432.
Matalkah, F., Soroushian, P., Abideen, S. U., and Peyvandi, A. (2016). “Use of non-wood biomass combustion ash in development of alkali-activated concrete.” Constr. Build. Mater., 121, 491–500.
Panwar, N. L. (2009). “Design and performance evaluation of energy efficient biomass gasifier based cookstove on multi fuels.” Mitigation Adaptation Strategies Global Change, 14(7), 627–633.
Pels, J. R., and Saraber, A. J. (2011). “Utilization of biomass ashes.” Solid biofuels for energy: A lower greenhouse gas alternative, P. Grammelis, ed., Springer, London, 219–235.
Peng, M. X., Wang, Z. H., Shen, S. H., and Xiao, Q. G. (2015). “Synthesis, characterization and mechanisms of one-part geopolymeric cement by calcining low-quality kaolin with alkali.” Mater. Struct., 48(3), 699–708.
Perlack, R. D., Wright, L. L., Turhollow, A. F., Graham, R. L., Stokes, B. J., and Erbach, D. C. (2005). “Biomass as feedstock for a bioenergy and bioproducts industry: The technical feasibility of a billion-ton annual supply.” Oak Ridge National Lab, Oak Ridge, TN.
Rajamma, R., Labrincha, J. A., and Ferreira, V. M. (2012). “Alkali activation of biomass fly ash-metakaolin blends.” Fuel, 98, 265–271.
Redden, R., and Neithalath, N. (2014). “Microstructure, strength, and moisture stability of alkali activated glass powder-based binders.” Cem. Concr. Compos., 45, 46–56.
Sarker, P. K., Haque, R., and Ramgolam, K. V. (2013). “Fracture behaviour of heat cured fly ash based geopolymer concrete.” Mater. Des., 44, 580–586.
Shaikh, F. U. A. (2014). “Effects of alkali solutions on corrosion durability of geopolymer concrete.” Adv. Concr. Constr., 2(2), 109–123.
Songpiriyakij, S., Kubprasit, T., Jaturapitakkul, C., and Chindaprasirt, P. (2010). “Compressive strength and degree of reaction of biomass- and fly ash-based geopolymer.” Constr. Build. Mater., 24(3), 236–240.
Thokchom, S. (2014). “Fly ash geopolymer pastes in sulphuric acid.” Int. J. Eng. Innovation Res., 3(6), 943–947.
Wallah, S., and Rangan, B. V. (2006). “Low-calcium fly ash-based geopolymer concrete: Long-term properties.”, Curtin Univ., Perth, Australia.
Wang, S.-D., Scrivener, K. L., and Pratt, P. (1994). “Factors affecting the strength of alkali-activated slag.” Cem. Concr. Res., 24(6), 1033–1043.
Yost, J. R., Radlinska, A., Ernst, S., Salera, M., and Martignetti, N. J. (2013). “Structural behavior of alkali activated fly ash concrete. Part 2: Structural testing and experimental findings.” Mater. Struct., 46(3), 449–462.
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Published In
Journal of Materials in Civil Engineering
Volume 29 • Issue 4 • April 2017
Copyright
©2016 American Society of Civil Engineers.
History
Received: May 23, 2016
Accepted: Aug 29, 2016
Published online: Nov 11, 2016
Published in print: Apr 1, 2017
Discussion open until: Apr 11, 2017
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