Technical Papers
Nov 10, 2016

Flame Resistance of Asphalt Mixtures with Flame Retardants through a Comprehensive Testing Program

Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 4

Abstract

As tunnels are now longer and built more frequently, fire safety in tunnels has become a major issue throughout the world. The objective of this study is to investigate the flame resistance of warm-mix asphalt mixtures with flame retardants through a comprehensive testing program. In this study, a compound flame retardant (FR) was added to the asphalt and warm-mix asphalt. The comprehensive testing program included the flash point test and oxygen index test of the asphalt binder, the combustion test of loose and compacted mixtures, and a bench scale apparatus for combustion testing of asphalt mixtures in order to understand the flame resistance of the asphalt and mixtures. The results of the asphalt binder tests indicate that FR has no significant effect on the flash point but has an obvious effect on the fire point, and FR asphalt requires more oxygen because the FR prevents it from burning. During various combustion tests, the FR reduced the flame, lessened the smoke, and lowered the temperature but noticeably increased the burning time. It was noticed that the structural integrity of the burned FR mixture samples is preferable to the mixture without FR. The bench scale apparatus for combustion testing shows that the ignition time is extended, both the heat release and smoke for the FR mixtures are noticeably decreased, and both the carbon monoxide (CO) and carbon dioxide (CO2) emissions are reduced. This means FR mixtures have better flame resistance and will have less potential for environmental pollution. Moreover, the results also show that a warm-mix asphalt additive has little effect on the flash point, fire point, or oxygen index of the asphalt. It also has little effect on the burning time and the flame height of loose mixtures. Because the warm-mix asphalt additive aids combustion, it decreases the maximum temperature and mass loss of the compacted mixtures during the firing process. It also shortens the ignition time and decreases the released heat, the total smoke, and the release of CO and CO2. Thus, the flame resistance of warm-mix asphalt with FR is the best due to the combined effect of the FR and the warm-mix asphalt additive, which means that the combination of modified asphalt is preferable for asphalt pavement in tunnels.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 51308075, 51378084, 51478053), Foundation of Hu’nan Educational Committee (No. 15C0044), the China Scholarship Council (No. 201508430200), and Open Fund of State Engineering Laboratory of Highway Maintenance Technology (Changsha University of Science and Technology) (No. kfj140104).

References

ASTM. (2013). “Standard test method for measuring the minimum oxygen concentration to support candle-like combustion of plastics (oxygen index).” ASTM D2863, West Conshohocken, PA.
Babrauskas, V. (1984). “Development of the cone calorimeter-A bench-scale heat release rate apparatus based on oxygen consumption.” Fire Mater., 8(2), 81–95.
Babrauskas, V., and Peacock, R. D. (1992). “Heat release rate: The single most important variable in fire hazard.” Fire Saf. J., 18(3), 255–272.
Beard, A. N. (2016). “Major fire spread in a tunnel with water mist: A theoretical model.” Tunnelling Underground Space Technol., 53, 22–32.
Cheng, Y., Nan, X., and Song, X. (2013). “Study on application of flame-retardant warm-mixed asphalt mixture in tunnel pavement of Dan-Tong highway project.” J. Liaoning Provincial Coll. Commun., 15(4), 11–14.
Colwell, S. (2006). “Test methodologies for reaction to fire of pavement materials.” Document SAM-04-D20, SAMARIS (Sustainable and Advanced MAterials for Road InfraStructure) Research Project.
Colwell, S., and Rock, C. (2007). “Reaction to fire behaviour of pavement surfaces.” Proc., 11th Int. Fire Science and Engineering Conf., Interscience Communications, London, 123–133.
Comprehensive Planning Division of Transportation Department. (2015). “Statistical bulletin of transportation industry in 2015.” ⟨http://zizhan.mot.gov.cn/zfxxgk/bnssj/zhghs/201605/t20160506_2024006.html⟩ (Jul., 2016) (in Chinese).
Cong, P., Chen, S., Yu, J., and Wu, S. (2010). “Effects of aging on the properties of modified asphalt binder with flame retardants.” Constr. Build. Mater., 24(12), 2554–2558.
Enright, P. A., and Fleischmann, C. M. (1999). “Uncertainty of heat release rate calculation of the ISO5660-1 cone calorimeter standard test method.” Fire Technol., 35(2), 153–169.
Hirschler, M. M. (1993). Carbon monoxide and human lethality: Fire and non-fire studies, CRC, Rocky River, OH.
ISO. (2002). “Reaction-to-fire tests—Heat release, smoke production and mass loss rate. Part 1: Heat release rate (cone calorimeter method).” ISO5660-1, Geneva.
Jamshidi, A., Hamzah, M. O., and You, Z. (2013). “Performance of warm mix asphalt containing Sasobit®: State-of-the-art.” Constr. Build. Mater., 38, 530–553.
Jianying, Y. (1995). “Development and research of overseas flame-resistant linoleum.” Chem. Build. Mater., 11(6), 271–272.
Jianying, Y., Peiliang, C., and Shaopeng, W. (2009). “Investigation of the properties of asphalt and its mixtures containing flame retardant modifier.” Constr. Build. Mater., 23(6), 2277–2282.
JTG. (2011). “Standard test methods of bitumen and bituminous mixtures for highway engineering.”, Ministry of Transport of China, Beijing.
JTG. (2004). “Technical specification for construction of highway asphalt pavements.”, Ministry of Transport of China, Beijing.
Li, X., Zhou, Z., and You, Z. (2016). “Compaction temperatures of Sasobit produced warm mix asphalt mixtures modified with SBS.” Constr. Build. Mater., 123, 357–364.
Noumowe, A. (2004). “Asphalt ignition in case of fire in civil engineering structures: Chemical analysis.” Proc., 10th Fire Science and Engineering Conf., Edinburgh, Scotland, 1551–1560.
Puente, E., Lázaro, D., and Alvear, D. (2016). “Study of tunnel pavements behaviour in fire by using coupled cone calorimeter-FTIR analysis.” Fire Saf. J., 81, 1–7.
Rubio, M. C., Martínez, G., Baena, L., and Moreno, F. (2012). “Warm mix asphalt: An overview.” J. Cleaner Prod., 24, 76–84.
Su, X. (2012). Study of the warm mixed and flame retardant modified technology of mix asphalt, Chang’an Univ., Xi’an, China (in Chinese).
Tanaka, F., Kawabata, N., and Ura, F. (2016). “Effects of a transverse external wind on natural ventilation during fires in shallow urban road tunnels with roof openings.” Fire Saf. J., 79, 20–36.
Wang, H. Q., Zhao, L., and Tian, B. (2012). “Experiment research on asphalt pavement performance with different flame retarding systems.” Appl. Mech. Mater., 184, 967–970.
Weng, M.-C., Lu, X.-L., Liu, F., and Du, C.-X. (2016). “Study on the critical velocity in a sloping tunnel fire under longitudinal ventilation.” Appl. Therm. Eng., 94, 422–434.
Wu, S., Cong, P., Yu, J., Luo, X., and Mo, L. (2006). “Experimental investigation of related properties of asphalt binders containing various flame retardants.” Fuel, 85(9), 1298–1304.
Wu, S., Mo, L., Cong, P., Yu, J., and Luo, X. (2008). “Flammability and rheological behavior of mixed flame retardant modified asphalt binders.” Fuel, 87(1), 120–124.
Xu, T., Huang, X., and Zhao, Y. (2011). “Investigation into the properties of asphalt mixtures containing magnesium hydroxide flame retardant.” Fire Saf. J., 46(6), 330–334.
You, Z., and Goh, S. W. (2008). “Laboratory evaluation of warm mix asphalt: A preliminary study.” Int. J. Pavement Res. Technol., 1(1), 34–40 (in Chinese).
Yu, W., and Li, C. (2010). “Performance and application of antiflaming and warm-mix asphalt mixture.” Highway, 1, 129–134 (in Chinese).
Zhang, S., Cong, P., Cheng, S., and Yu, J. (2008). “Research on super-pave design and properties of flame retardanted asphalt mixtures with aluminium hydroxide.” J. Wuhan Univ. Technol., 12, 55–57 (in Chinese).
Zhang, Y., Liang, N., Li, L., and Liao, W. (2009). “Technical investigation on application of warm-mixed flame retardant asphalt mixture in tunnel pavement.” Technol. Highway Transport, 4, 111–114 (in Chinese).
Zhu, S., Li, Z., and Chen, S. (2015). “Dynamic mechanical characterizations and road performances of flame retardant asphalt mortars and concretes.” J. Wuhan Univ. Technol. Mater. Sci. Ed., 30(5), 908–913.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 4April 2017

History

Received: May 24, 2016
Accepted: Aug 16, 2016
Published online: Nov 10, 2016
Published in print: Apr 1, 2017
Discussion open until: Apr 10, 2017

Permissions

Request permissions for this article.

Authors

Affiliations

Associate Professor, State Engineering Laboratory of Highway Maintenance Technology, Changsha Univ. of Science and Technology, 960, 2nd Section, Wanjiali South Rd., Changsha 410004, China (corresponding author). ORCID: https://orcid.org/0000-0001-6644-2088. E-mail: [email protected]
Zhigang Zhou [email protected]
School of Traffic and Transportation Engineering, Changsha Univ. of Science and Technology, 960, 2nd Section, Wanjiali South Rd., Changsha 410004, China. E-mail: [email protected]
Master Student, School of Traffic and Transportation Engineering, Changsha Univ. of Science and Technology, 960, 2nd Section, Wanjiali South Rd., Changsha 410004, China. E-mail: [email protected]
Zhanping You, M.ASCE [email protected]
Professor, Dept. of Civil and Environmental Engineering, Michigan Technological Univ., 1400 Townsend Dr., Houghton, MI 49931-1295. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share