Technical Papers
Nov 23, 2016

Influences of Activity Index on Mechanical and Microstructural Characteristics of Carbonated Reactive Magnesia-Admixed Silty Soil

Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 5

Abstract

Carbonated reactive magnesia (MgO)-admixed soil is employed for stabilizing soft soil through absorbing gaseous CO2, which is an innovative and sustainable technique recently developed in the realm of ground improvement. With this in view, a systematic study that targets the influence of the MgO activity index (cA) on mechanical and microstructural characteristics of carbonated silty soil with different ratios of initial water content to MgO content (represented as w0/c) is initiated in this paper. In this context, the mechanical properties are investigated through unconfined compression tests, and the microstructural properties are obtained from X-ray diffraction, scanning electron microscopy, thermogravimetry, and mercury intrusion porosimetry analyses. The results demonstrate that cA and w0/c are the two crucial factors controlling the mechanical and microstructural characteristics of carbonated MgO-admixed soils. A simplified equation with combination of cA and w0/c is proposed for accurately predicting the unconfined compressive strength of carbonated MgO-admixed soils. The analyses of microstructural characteristics indicate that dypingite or hydromagnesite and plentiful crystalline nesquehonite play an important role in reducing the pore volume, and the latter is the primary micromechanistic reason for the strength gain of the carbonated MgO-admixed soils.

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Acknowledgments

This research is financially supported by the NSFC (51279032, 41330641, 51278100, and 41472258), the “Twelfth Five-Year” National Technology Support Program (2012BAJ01B02-01), the Natural Science Foundation of Jiangsu Province (BK2012022), and Project (KYLX_0147) supported by Graduate Student Scientific Research Innovation Projects of Jiangsu Province.

References

Arulrajah, A., Kua, T. A., Phetchuay, C., Horpibulsuk, S., Mahghoolpilehrood, F., and Disfani, M. M. (2016). “Spent coffee grounds-fly ash geopolymer used as an embankment structural fill material.” J. Mater. Civ. Eng., .
Arulrajah, A., Piratheepan, J., Bo, M. W., and Sivakugan, N. (2012). “Geotechnical characteristics of recycled crushed brick blends for pavement sub-base applications.” Can. Geotech. J., 49(7), 796–811.
Arulrajah, A., Piratheepan, J., Disfani, M. M., and Bo, M. W. (2013). “Geotechnical and geoenvironmental properties of recycled construction and demolition materials in pavement subbase applications.” J. Mater. Civ. Eng., 1077–1088.
ASTM. (2007). “Standard test method for pH of soils.” ASTM D4972, West Conshohocken, PA.
ASTM. (2008). “Standard test method for unconfined compressive strength index of chemical-grouted soils.” ASTM D4219, West Conshohocken, PA.
ASTM. (2010a). “Standard methods for specific gravity of soils by water pycnometer.” ASTM D854, West Conshohocken, PA.
ASTM. (2010b). “Standard test methods for liquid limit, plastic limit and plasticity index of soils.” ASTM D4318, West Conshohocken, PA.
ASTM. (2011). “Standard practice for classification of soils for engineering purposes (unified soil classification system).” ASTM D2487, West Conshohocken, PA.
ASTM. (2012). “Test methods for moisture-density relations of soils and soil-aggregate mixtures.” ASTM D698, West Conshohocken, PA.
Botha, A., and Strydom, C. A. (2003). “DTA and FT-IR analysis of the rehydration of basic magnesium carbonate.” J. Therm. Anal. Calorim., 71(3), 987–996.
Cai, G. H., Du, Y. J., Liu, S. Y., and Singh, D. N. (2015a). “Physical properties, electrical resistivity and strength characteristics of carbonated silty soil admixed with reactive magnesia.” Can. Geotech. J., 52(11), 1699–1713.
Cai, G. H., Liu, S. Y., Du, Y. J., Zhang, D. W., and Zheng, X. (2015b). “Strength and deformation characteristics of carbonated reactive magnesia treated silt soil.” J. Cent. South Univ., 22(5), 1859–1868.
Chinese Standard. (2006). “Test methods for chemical activity of caustic burned magnesia.” Black metallurgical industry standard of P.R.C., YB/T 4019–2006, Beijing (in Chinese).
Choudhary, V. R., Pataskar, S. G., Gunjikar, V. G., and Zope, G. B. (1994). “Influence of preparation conditions of basic magnesium carbonate on its thermal analysis.” Thermochim. Acta, 232(1), 95–110.
Delage, P., Marcial, D., Cui, Y. J., and Ruiz, X. (2006). “Ageing effects in a compacted bentonite: A microstructure approach.” Géotechnique, 56(5), 291–304.
Disfani, M., Arulrajah, A., Haghighi, H., Mohammadinia, A., and Horpibulsuk, S. (2014). “Flexural beam fatigue strength evaluation of crushed brick as a supplementary material in cement stabilized recycled concrete aggregates.” Constr. Build. Mater., 68, 667–676.
Du, Y. J., Bo, Y. L., Jin, F., and Liu, S. Y. (2015). “Durability of reactive magnesia-activated slag-stabilized low plasticity clay subjected to drying-wetting cycle.” Eur. J. Environ. Civ. Eng., 20(2), 215–230.
Du, Y. J., Jiang, N. J., Liu, S. Y., Horpibulski, S., and Arulrajah, A. (2016a). “Field evaluation of soft highway subgrade soil stabilized with calcium carbide residue.” Soils Found., 56(2), 301–314.
Du, Y. J., Jiang, N. J., Liu, S. Y., Jin, F., Singh, D. N., and Anand, J. P. (2014a). “Engineering properties and microstructural characteristics of cement-stabilized zinc-contaminated kaolin.” Can. Geotech. J., 51(3), 289–302.
Du, Y. J., Jiang, N. J., Shen, S. L., and Jin, F. (2012). “Experimental investigation of influence of acid rain on leaching and hydraulic characteristics of cement based solidified/stabilized lead contaminated clay.” J. Hazard Mater., 225-226, 195–201.
Du, Y. J., Wei, M. L., Jin, F., and Liu, Z. B. (2013). “Stress-strain relation and strength characteristics of cement treated zinc-contaminated clay.” Eng. Geol., 167, 20–26.
Du, Y. J., Wei, M. L., Reddy, K. R., Jin, F., Wu, H. L., and Liu, Z. P. (2014c). “New phosphate-based binder for stabilization of soils contaminated with heavy metals: Leaching, strength and microstructure characterization.” J. Environ. Manag., 146, 179–188.
Du, Y. J., Wei, M. L., Reddy, R. K., and Wu, H. L. (2016b). “Effect of carbonation on leachability, strength and microstructural characteristics of KMP binder stabilized Zn and Pb contaminated soils.” Chemosphere, 144, 1033–1042.
Földvári, M. (2011). Handbook of thermogravimetric system of minerals and its use in geological practice, Geological Institute of Hungary—Kiadja a Magyar Állami Földtani Intézet, Budapest, Hungary.
Giammar, D. E., Bruant, R. G., and Peters, C. A. (2005). “Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide.” Chem. Geol., 217(3), 257–276.
Gumaste, S. D., Iyer, K. R., Sharma, S., Channabasavaraj, W., and Singh, D. N. (2014). “Simulation of fabric in sedimented clays.” Appl. Clay Sci., 91-92, 117–126.
Horpibulsuk, S., Phetchuay, C., and Chinkulkijniwat, A. (2012a). “Soil stabilization by calcium carbide residue and fly ash.” J. Mater. Civ. Eng., 184–193.
Horpibulsuk, S., Rachan, R., Chinkulkijniwat, A., Raksachon, Y., and Suddeepong, A. (2010). “Analysis of strength development in cement-stabilized silty clay from microstructural considerations.” Constr. Build. Mater., 24(10), 2011–2021.
Horpibulsuk, S., Suddeepong, A., Chinkulkijniwat, A., and Liu, M. D. (2012b). “Strength and compressibility of lightweight cemented clays.” Appl. Clay Sci., 69, 11–21.
Jiang, N. J., Du, Y. J., Liu, S. Y., Horpibulsuk, S., and Arulrajah, A. (2016). “Multi-scale laboratory evaluation of the physical, mechanical and microstructural properties of soft highway subgrade soil stabilized with calcium carbide residue.” Can. Geotech. J., 53(3), 373–383.
Jin, F., and Al-Tabbaa, A. (2013). “Thermogravimetric study on the hydration of reactive magnesia and silica mixture at room temperature.” Thermochim. Acta, 566, 162–168.
Jin, F., and Al-Tabbaa, A. (2014). “Characterisation of different commercial reactive magnesia.” Adv. Cem. Res., 26(2), 101–113.
Jin, F., Gu, K., Abdollahzadeh, A., and Al-Tabbaa, A. (2015). “Effects of different reactive MgOs on the hydration of MgO-activated GGBS paste.” J. Mater. Civ. Eng., 27(7), B4014001.
Jin, F., Gu, K., and Al-Tabbaa, A. (2014). “Strength and drying shrinkage of reactive MgO modified alkali-activated slag paste.” Constr. Build. Mater., 51(1), 395–404.
Jitsangiam, P., Boonserm, K., Phenrat, T., Chummuneerat, S., Chindaprasirt, P., and Nikraz, H. (2015). “Recycled concrete aggregates in roadways: Laboratory examination of self-cementing characteristics.” J. Mater. Civ. Eng., 27(10), .
Kampala, A., and Horpibulsuk, S. (2013). “Engineering properties of silty clay stabilized with calcium carbide residue.” J. Mater. Civ. Eng., 632–644.
Lanas, J., and Alvarez, J. I. (2004). “Dolomitic lime: Thermal decomposition of nesquehonite.” Thermochim. Acta, 421(1), 123–132.
Latifi, N., Rashid, A. S. A., Siddiqua, S., and Horpibulsuk, S. (2015). “Micro-structural analysis of strength development in low-and high swelling clays stabilized with magnesium chloride solution—A green soil stabilizer.” Appl. Clay Sci., 118, 195–206.
Li, X., and Zhang, L. M. (2009). “Characterization of dual-structure pore-size distribution of soil.” Can. Geotech. J., 46(2), 129–141.
Liska, M., and Al-Tabbaa, A. (2008). “Performance of magnesia cements in pressed masonry units with natural aggregates: Production parameters optimisation.” Constr. Build. Mater., 22(8), 1789–1797.
Liska, M., and Al-Tabbaa, A. (2009). “Ultra-green construction: Reactive magnesia masonry products.” Proc. ICE Waste Res. Manag., 162(4), 185–196.
Liska, M., and Al-Tabbaa, A. (2012). “Performance of magnesia cements in porous blocks in acid and magnesium environments.” Adv. Cem. Res., 24(4), 221–232.
Liska, M., Al-Tabbaa, A., Carter, K., and Fifield, J. (2012a). “Scaled-up commercial production of reactive magnesium cement pressed masonry units. Part I: Production.” Proc. ICE Constr. Mater., 165(4), 211–223.
Liska, M., Al-Tabbaa, A., Carter, K., and Fifield, J. (2012b). “Scaled-up commercial production of reactive magnesium cement pressed masonry units. Part II: Performance.” Proc. ICE Constr. Mater., 165(4), 225–243.
Liska, M., Vandeperre, L. J., and Al-Tabbaa, A. (2008). “Influence of carbonation on the properties of reactive magnesia cement-based pressed masonry units.” Adv. Cem. Res., 20(2), 53–64.
Liu, S. Y., Du, Y. J., Yi, Y. L., and Puppala, A. J. (2012). “Field investigations on performance of T-shaped deep mixed soil cement column-supported embankments over soft ground.” J. Geotech. Geoenviron. Eng., 718–727.
Liu, S. Y., and Li, C. (2015). “Influence of MgO activity on the stabilization efficiency of carbonated mixing method.” Chin. J. Geotech. Eng., 37(1), 148–155 (in Chinese).
Lorenzo, G. A., and Bergado, D. T. (2006). “Fundamental characteristics of cement-admixed clay in deep mixing.” J. Mater. Civ. Eng., 161–174.
Mo, L. W., Liu, M., Al-Tabbaa, A., and Deng, M. (2015). “Deformation and mechanical properties of the expansive cements produced by inter-grinding cement clinker and MgOs with various reactivities.” Constr. Build. Mater., 80, 1–8.
Mo, L. W., and Panesar, D. K. (2012). “Effects of accelerated carbonation on the microstructure of Portland cement pastes containing reactive MgO.” Cem. Concr. Res., 42(6), 769–777.
Mo, L. W., and Panesar, D. K. (2013). “Accelerated carbonation: A potential approach to sequester CO2 in cement paste containing slag and reactive MgO.” Cem. Concr. Compos., 43, 69–77.
Mo, L. W., and Panesar, D. K. (2014). “Microstructure of reactive magnesia cement pastes subjected to high carbon dioxide concentration.” J. Chin. Ceramic Soc., 42(2), 142–149.
Mohammadinia, A., Arulrajah, A., Sanjayan, J., Disfani, M., Bo, M., and Darmawan, S. (2015). “Laboratory evaluation of the use of cement-treated construction and demolition materials in pavement base and subbase applications.” J. Mater. Civ. Eng., .
Mohammadinia, A., Arulrajah, A., Sanjayan, J., Disfani, M. M., Win Bo, M., and Darmawan, S. (2016). “Stabilization of demolition materials for pavement base/subbase applications using fly ash and slag geopolymers: Laboratory investigation.” J. Mater. Civ. Eng., .
Nagaraj, T. S., Griffiths, F. J., Joshi, R. C., Vatsala, A., and Murthy, B. R. S. (1990). “Change in pore-size distribution due to consolidation of clays—Discussion.” Géotechnique, 40(2), 303–309.
Panesar, D. K., and Mo, L. (2013). “Properties of binary and ternary reactive MgO mortar blends subjected to CO2 curing.” Cem. Concr. Compos., 38, 40–49.
Samtani, M., Dollimore, D., and Alexander, K. S. (2002). “Comparison of dolomite decomposition kinetics with related carbonates and the effect of procedural variables on its kinetic parameters.” Thermochim. Acta, 392, 135–145.
Shen, S. L., Han, J., and Du, Y. J. (2008). “Deep mixing induced property changes in surrounding sensitive marine clays.” J. Geotech. Geoenviron. Eng., 845–854.
Sukmak, P., De Silva, P., Horpibulsuk, S., and Chindaprasirt, P. (2015). “Sulfate resistance of clay-portland cement and clay high-calcium fly ash geopolymer.” J. Mater. Civ. Eng., 27(5), .
Sukmak, P., Horpibulsuk, S., Shen, S. L., Chindaprasirt, P., and Suksiripattanapong, C. (2013). “Factors influencing strength development in clay-fly ash geopolymer.” Constr. Build. Mater., 47, 1125–1136.
Thiery, M., Villain, G., Dangla, P., and Platret, G. (2007). “Investigation of the carbonation front shape on cementitious materials: Effects of the chemical kinetics.” Cem. Concr. Res., 37(7), 1047–1058.
Unluer, C., and Al-Tabbaa, A. (2013). “Impact of hydrated magnesium carbonate additives on the carbonation of reactive MgO cements.” Cem. Concr. Res., 54, 87–97.
Unluer, C., and Al-Tabbaa, A. (2014a). “Characterization of light and heavy hydrated magnesium carbonates using thermal analysis.” J. Therm. Anal. Calorim., 115(1), 595–607.
Unluer, C., and Al-Tabbaa, A. (2014b). “Enhancing the carbonation of MgO cement porous blocks through improved curing conditions.” Cem. Concr. Res., 59(5), 55–65.
Unluer, C., and Al-Tabbaa, A. (2015). “The role of brucite, ground granulated blastfurnace slag, and magnesium silicates in the carbonation and performance of MgO cements.” Constr. Build. Mater., 94, 629–643.
Vandeperre, L. J., and Al-Tabbaa, A. (2007). “Accelerated carbonation of reactive MgO cements.” Adv. Cem. Res., 19(2), 67–79.
Yi, Y., Li, C., and Liu, S. (2015). “Alkali-activated ground-granulated blast furnace slag for stabilization of marine soft clay.” J. Mater. Civ. Eng., .
Yi, Y., Liska, M., and Al-Tabbaa, A. (2014). “Properties of two model soils stabilized with different blends and contents of GGBS, MgO, lime, and PC.” J. Mater. Civ. Eng., 267–274.
Yi, Y. L., Liska, M., Unluer, C., and Al-Tabbaa, A. (2013). “Carbonating magnesia for soil stabilization.” Can. Geotech. J., 50(8), 899–905.
Yu, B. W., Du, Y. J., Jin, F., and Liu, C. Y. (2016). “Multiscale study of sodium sulfate soaking durability of low plastic clay stabilized by reactive magnesia-activated ground granulated blast-furnace slag.” J. Mater. Civ. Eng., .
Zhang, L. M., and Li, X. (2010). “Microporosity structure of coarse granular soils.” J. Geotech. Geoenviron. Eng., 1425–1436.
Zhang, T., Cheeseman, C. R., and Vandeperre, L. J. (2011). “Development of low pH cement systems forming magnesium silicate hydrate (MSH).” Cem. Concr. Res., 41(4), 439–442.
Zhang, T. W., Yue, X. B., Deng, Y. F., Zhang, D. W., and Liu, S. Y. (2015). “Mechanical behaviour and micro-structure of cement-stabilised marine clay with a metakaolin agent.” Constr. Build. Mater., 73, 51–57.
Zhang, Z., and Li, N. (2005). “Effect of polymorphism of Al2O3 on the synthesis of magnesium aluminate spinel.” Ceram. Int., 31(4), 583–589.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 5May 2017

History

Received: Dec 14, 2015
Accepted: Aug 16, 2016
Published online: Nov 23, 2016
Discussion open until: Apr 23, 2017
Published in print: May 1, 2017

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Guang-Hua Cai
Ph.D. Candidate, Institute of Geotechnical Engineering, Southeast Univ., Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Nanjing 210096, China.
Song-Yu Liu [email protected]
Professor, Institute of Geotechnical Engineering, Southeast Univ., Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Nanjing 210096, China (corresponding author). E-mail: [email protected]
Yan-Jun Du
Professor, Institute of Geotechnical Engineering, Southeast Univ., Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Nanjing 210096, China.
Jing-Jing Cao
Graduate Student, Institute of Geotechnical Engineering, Southeast Univ., Jiangsu Key Laboratory of Urban Underground Engineering and Environmental Safety, Nanjing 210096, China.

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