Microstructural and Mineralogical Characterization of Artificially Produced Pellets for Civil Engineering Applications
Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 2
Abstract
Most hazardous, industrial waste from thermal coal-fired power plants has found utilization opportunities in different civil engineering applications by various treatment operations in recent years. Such initiatives provide improvements in economy, environmental protection, and health safety. One of the techniques used in treatment of powdered wastes is to make pellets by pelletization discs. These artificial pellets are mainly used in many structural applications as aggregate in concrete, filling material for roads and foundations, drainage and infiltration material, and so on. In this study, artificially produced pellets from mixtures of fly ash, bentonite, and powdered window glass were sintered at different temperatures to obtain desirable properties. Microstructure of these sintered pellets were investigated in order to understand the changes due to the sintering agent type, content, and sintering temperature. For this purpose, thermal, mineralogical, and microstructural studies were performed. It was noted that sintering temperature and the type and amount of the sintering agent had a remarkable effect on the changes in the microstructure of the pellets. X-ray diffraction (XRD) patterns also showed that sintering produced new crystalline phases not found in the raw materials which was also detected in differential thermal analysis (DTA). Thus, the dissimilar sintering behavior is attributed to the combined effect of crystal structure, morphological characteristics, and oxide compositions of the powder materials used in the production of the pellets.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
The support of Bogazici University Research Fund is gratefully acknowledged through Project 07A402.
References
Adell, V., Cheeseman, C. R., Doel, A., Beattie, A., and Boccaccini, A. R. (2008). “Comparison of rapid and slow sintered pulverised fuel ash.” Fuel, 87(2), 187–195.
Aineto, M., Acosta, A., Rincon, J. M., and Romero, M. (2006). “Thermal expansion of slag and fly ash from coal gasification in IGCC power plant.” Fuel, 85(16), 2352–2358.
Baykal, G., and Döven, A. G. (2000). “Utilization of fly ash by pelletization process; theory, application areas and research results.” Resour. Conserv. Recycl., 30(1), 59–77.
Biernacki, J. J., Vazrala, A. K., and Leimer, H. W. (2008). “Sintering of a class F fly ash.” Fuel, 87(6), 782–792.
Cheng, T. W. (2004). “Effect of additional materials on the properties of glass-ceramic produced from ıncinerator fly ashes.” Chemosphere, 56(2), 127–131.
Cheng, T. W., and Chen, Y. S. (2003). “On formation of ––glass–ceramics by vitrification of incinerator fly ash.” Chemosphere, 51(9), 817–824.
Dong, Y., Feng, X., Ding, Y., Liu, X., and Meng, G. (2008). “Preparation of low cost mullite ceramics from natural bauxite and industrial waste fly ash.” J. Alloys Compd., 460(1–2), 599–606.
Duvarcı, Ö. Ç., Akdeniz, Y., Özmıhçı, F., Ülkü, S., Balköse, D., and Çiftçioğlu, M. (2007). “Thermal behaviour of a zeolitic tuff.” Ceram. Int., 33(5), 795–801.
Erol, M., Küçükbayrak, S., and Ersoy-Meriçboyu, A. (2008). “Characterization of sintered coal fly ashes.” Fuel, 87(7), 1334–1340.
Foletto, E. L., Volzone, C., and Porto, L. M. (2003). “Performance of an Argentinian acid-activated bentonite in the bleaching of soybean oil.” Braz. J. Chem. Eng., 20(2), 139–145.
Harakrsihnan, K. I., and Ramamurthy, K. (2006). “Influence of pelletization process on the properties of fly ash aggregates.” Waste Manage., 26(8), 846–852.
Karamanova, A., Pelinoa, M., Salvo, M., and Metekovits, I. (2003). “Sintered glass-ceramics from incinerator fly ashes. Part II: The influence of the particle size and heat-treatment on the properties.” J. Eur. Ceram. Soc., 23(10), 1609–1615.
Kayali, O. (2008). “Fly ash lightweight aggregates in high performance concrete.” Constr. Build. Mater., 22(12), 2393–2399.
Kockal, N. U. (2012a). “Properties and microstructure of porous ceramic bodies containing fly ash.” J. Build. Phys., 35(4), 338–352.
Kockal, N. U. (2012b). “Utilisation of different types of coal fly ash in the production of ceramic tiles.” Bol. Soc. Esp. Ceram. Vidrio, 51(5), 297–304.
Kockal, N. U., and Ozturan, T. (2011a). “Characteristics of lightweight fly ash aggregates produced with different binders and heat treatments.” Cem. Concr. Compos., 33(1), 61–67.
Kockal, N. U., and Ozturan, T. (2011b). “Optimization of properties of fly ash aggregates for high strength lightweight concrete production.” Mater. Des., 32(6), 3586–3593.
Li, R., Wang, L., Yang, T., and Raninger, B. (2007). “Investigation of MSWI fly ash melting characteristic by DSC-DTA.” Waste Manage., 27(10), 1383–1392.
Li, Y., et al. (2000). “Measurement and statistics of single pellet mechanical strength of differently shaped catalysts.” Powder Technol., 113(1–2), 176–184.
Li-Xiong, G., Yan, Y., and Ling, W. (2004). “Research on sintered fly ash aggregate of high strength and low absorption of water.” Proc., Int. Workshop on Sustainable Development and Concrete Technology, K. Wang, ed., Iowa State Univ., Ames, IA, 151–157.
Mun, K. J. (2007). “Development and tests of lightweight aggregate using sewage sludge for nonstructural concrete.” Constr. Build. Mater., 21(7), 1583–1588.
Onal, M., Sarıkaya, Y., Alemdaroğlu, T., and Bozdoğan, İ. (2002). “The effect of acid activation on some physicochemical properties of a bentonite.” Turk. J. Chem., 26, 409–416.
Pontes, J., Santos Silva, A., and Faria, P. (2012). “Evaluation of pozzolanic reactivity of artificial pozzolans.” Mater. Sci. Forum, 730–732, 433–438.
Ramamurthy, K., and Harikrishnan, K. I. (2006). “Influence of binders on properties of sintered fly ash aggregate.” Cem. Concr. Compos., 28(1), 33–38.
Riley, C. M. (1951). “Relation of chemical properies to the bloating of clays.” J. Am. Ceram. Soc., 34(4), 121–128.
Show, K., Lee, D., Tay, J., Hong, S., and Chien, C. (2005). “Lightweight aggregates from industrial sludge—Marine clay mixes.” J. Environ. Eng., 1106–1113.
Turkish Standards. (2008). “Fly ash for concrete—Part 1: Definitions, specifications and conformity criteria.”, Turkish Standards Institute, Ankara, Turkey.
Wasserman, R., and Bentur, A. (1997). “Effect of lightweight fly ash aggregate microstructure on the strength of concretes.” Cem. Concr. Res., 27(4), 525–537.
Information & Authors
Information
Published In
Copyright
© 2016 American Society of Civil Engineers.
History
Received: Mar 9, 2016
Accepted: Jun 28, 2016
Published online: Sep 2, 2016
Published in print: Feb 1, 2017
Discussion open until: Feb 2, 2017
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.