Technical Papers
Aug 29, 2016

Improvement of Problematic Soils with Biopolymer—An Environmentally Friendly Soil Stabilizer

Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 2

Abstract

Problematic soils with high compressibility and low shear strength are often treated with traditional chemical stabilizing additives such as cement and lime to improve their engineering properties. These additives are generally recognized as having less than ideal environmental impacts—in particular, the high quantity of greenhouse gases that are generally created during their production. With an increasing focus on the use of more environmentally friendly and sustainable materials in the built and natural environments, alternative eco-friendly additives to traditional chemical stabilizers have the potential to significantly change the field of soil improvement worldwide. The current study illustrates the viability of xanthan gum as an environmentally friendly stabilizer that can improve the engineering properties of both low- and high-swelling clays. Experimental mechanical tests were performed on both untreated and xanthan gum–stabilized montmorillonite and kaolinite clays at various curing times, including unconfined compression strength (UCS) tests, direct shear tests, and one-dimensional (1D) consolidation tests. Various microscopic techniques were also performed to characterize the microstructure of the stabilized soil matrix, including field emission scanning electron microscopy (FESEM) tests, Brunauer, Emmett, and Teller (N2-BET) surface area analysis tests, and particle size analysis (PSA) tests using a laser diffraction approach. From the results of the strength and compressibility testing, 1 and 1.5% xanthan gum contents were found to be optimum levels of additive use for the montmorillonite and kaolinite clays, respectively. The microstructural analysis tests performed indicated the formation of new cementitious products that result from chemical reactions between the xanthan gum and soil particles at the microlevel, which improved the soil structure by welding soil particles together and filling the pore space in the soil matrix. Significant engineering property improvement was observed during the first 28 days of curing; this improvement corresponded to significant changes in the soil’s microstructure that occurred over the same period of time.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The authors would like to acknowledge financial support provided by the Ministry of Education Malaysia under the Fundamental Research Grants (PDRU).Q.J130000.21A2.02E82, and support from Universiti Teknologi Malaysia (UTM), as well as support from the Institute for Smart Infrastructure and Innovative Construction (ISIIC) at UTM. The second author is grateful for financial support from the Thailand Research Fund under the TRF Senior Research Scholar program (Grant No. RTA5680002).

References

Arulrajah, A., Abdullah, A., Bo, M. W., and Bouazza, A. (2009). “Ground improvement techniques for railway embankments.” Ground Improv., 162(1), 3–14.
Arulrajah, A., Kua, T. A., Phetchuay, C., Horpibulsuk, S., Mahghoolpilehrood, F., and Disfani, M. M. (2015). “Spent coffee grounds–fly ash geopolymer used as an embankment structural fill material.” J. Mater. Civ. Eng., 04015197.
Arulrajah, A., Mohammadinia, A., Phummiphan, I., Horpibulsuk, S., and Samingthong, W. (2016). “Stabilization of recycled demolition aggregates by geopolymers comprising calcium carbide, fly ash and slag precursors.” Constr. Build. Mater., 114, 864–873.
Awad, Y. M., Blagodatskaya, E., Ok, Y. S., and Kuzyakov, Y. (2013). “Effects of polyacrylamide, biopolymer and biochar on the decomposition of 14C-labelled maize residues and on their stabilization in soil aggregates.” Eur. J. Soil Sci., 64(4), 488–499.
Bergmann, D., Furth, G., and Mayer, C. (2008). “Binding of bivalent cations by Xanthan in aqueous solution.” Int. J. Biol. Macromol., 43(3), 245–251.
Blanck, G., Cuisinier, O., and Masrouri, F. (2014). “Soil treatment with organic non-traditional additives for the improvement of earthworks.” Acta Geotech., 9(6), 1111–1122.
Bo, M. W., Arulrajah, A., Horpibulsuk, S., and Leong, M. (2015). “Quality management of prefabricated vertical drain materials in mega land reclamation projects: A case study.” Soils Found., 55(4), 895–905.
Bo, M. W., Arulrajah, A., Horpibulsuk, S., Leong, M., and Disfani, M. M. (2014). “Densification of land reclamation sands by deep vibratory compaction.” J. Mater. Civ. Eng., 06014016.
Bobet, A., Hwang, J., Johnston, C. T., and Santagata, M. (2011). “One-dimensional consolidation behavior of cement-treated organic soil.” Can. Geotech. J., 48(7), 1100–1115.
Brunauer, S., Emmett, P. H., and Teller, E. (1938). “Adsorption of gases in multimolecular layers.” J. Am. Chem. Soc., 60(2), 309–319.
BSI (British Standards Institution). (1990a). “British standard methods of test for soils for civil engineering purposes—Part 2: Classification tests.” BS1377, London.
BSI (British Standards Institution). (1990b). “British standard methods of test for soils for civil engineering purposes—Part 4: Compaction related tests.” BS1377, London.
BSI (British Standards Institution). (1990c). “British standard methods of test for soils for civil engineering purposes—Part 5: Compressibility, permeability and durability tests.” BS1377, Milton Keynes, U.K.
BSI (British Standards Institution). (1990d). “British standard methods of test for soils for civil engineering purposes—Part 7: Shear strength tests (total stress).” BS1377, Milton Keynes, U.K.
Cadmus, M. C., Jackson, L. K., Burton, K. A., Plattner, R. D., and Slodki, M. E. (1982). “Biodegradation of Xanthan gum by Bacillus sp.” Appl. Environ. Microbiol., 44(1), 5–11.
Casas, J. A., Santos, V. E., and Garcia-Ochoa, F. (2000). “Xanthan gum production under several operational conditions: Molecular structure and rheological properties.” Enzyme Microb. Technol., 26(2–4), 282–291.
Chai, J. C., Horpibulsuk, S., Shen, S. L., and Carter, J. P. (2014). “Consolidation analysis of clayey deposits under vacuum pressure with horizontal drains.” Geotext. Geomembr., 42(5), 437–444.
Chang, I., and Cho, G. C. (2012). “Strengthening of Korean residual soil with β-1, 3/1, 6-glucan biopolymer.” Constr. Build. Mater., 30, 30–35.
Chang, I., Im, J., Prasidhi, A. K., and Cho, G. C. (2015). “Effects of Xanthan gum biopolymer on soil strengthening.” Constr. Build. Mater., 74, 65–72.
Chang, Y. J., Lee, S., Yoo, M. A., and Lee, H. G. (2006). “Structural and biological characterization of sulfated-derivatized oat β-glucan.” J. Agric. Food Chem., 54(11), 3815–3818.
Chen, J. F., and Yu, S. B. (2011). “Centrifugal and numerical modelling of a reinforced lime treated soil embankment on soft clay with wick drains.” Int. J. Geomech., 167–173.
Chenu, C., and Stotzky, G. (2002). “Interactions between microorganisms and soil particles: An overview.” Interactions between soil particles and microorganisms: Impact on the terrestrial ecosystem, Wiley, Manchester, U.K., 1–40.
Chinkulkijniwat, A., and Horpibulsuk, S. (2012). “Field strength development of repaired pavement using the recycling technique.” Q. J. Eng. Geol. Hydrogeol., 45(2), 221–229.
Chu, J., Bo, M. W., and Arulrajah, A. (2009). “Reclamation of a slurry pond in Singapore.” Geotech. Eng., 162(1), 13–20.
Comba, S., and Sethi, R. (2009). “Stabilization of highly concentrated suspensions of iron nanoparticles using shear-thinning gels of Xanthan gum.” Water Res., 43(15), 3717–3726.
Cristelo, N., Glendinning, S., Fernandes, L., and Pinto, A. T. (2013). “Effects of alkaline-activated fly ash and portland cement on soft soil stabilisation.” Acta Geotech., 8(4), 395–405.
Dash, S. K., and Hussain, M. (2011). “Lime stabilization of soils: Reappraisal.” J. Mater. Civ. Eng., 707–714.
de Brito Galvão, T. C., Elsharief, A., and Simões, G. F. (2004). “Effects of lime on permeability and compressibility of two tropical residual soils.” J. Environ. Eng., 881–885.
DeJong, J. T., et al. (2013). “Biogeochemical processes and geotechnical applications: Progress, opportunities and challenges.” Geotechnique, 63(4), 287.
Du, Y. J., Horpibulsuk, S., Wei, M. L., Suksiripattanapong, C., and Liu, M. D. (2014). “Modeling compression behavior of cement-treated zinc-contaminated clayey soils.” Soils Found., 54(5), 1018–1026.
Eisazadeh, A., and Eisazadeh, H. (2015). “N2-BET surface area and FESEM studies of lime-treated montmorillonitic and kaolinitic soils.” Environ. Earth Sci., 74(1), 377–384.
Gregory, J., and Barany, S. (2011). “Adsorption and flocculation by polymers and polymer mixtures.” Adv. Colloid Interface Sci., 169(1), 1–12.
Ho, M. H., and Chan, C. M. (2011). “Some mechanical properties of cement treated Malaysian soft clay.” World Acad. Sci. Eng. Technol., 74, 24–31.
Horpibulsuk, S., Katkan, W., and Apichatvullop, A. (2008a). “An approach for assessment of compaction curves of fine-grained soils at various energies using a one point test.” Soils Found., 48(1), 115–125.
Horpibulsuk, S., Katkan, W., and Naramitkornburee, A. (2009). “Modified Ohio’s curves: A rapid estimation of compaction curves for coarse- and fine-grained soils.” Geotech. Test. J., 32(1), 64–75.
Horpibulsuk, S., Kumpala, A., and Katkan, W. (2008e). “A case history on underpinning for a distressed building on hard residual soil underneath non-uniform loose sand.” Soils Found., 48(2), 267–285.
Horpibulsuk, S., Miura, N., and Bergado, D. T. (2004). “Undrained shear behavior of cement admixed clay at high water content.” J. Geotech. Geoenviron. Eng., 1096–1105.
Horpibulsuk, S., and Niramitkornburee, A. (2010). “Pullout resistance of bearing reinforcement embedded in sand.” Soils Found., 50(2), 215–226.
Horpibulsuk, S., Phetchuay, C., and Chinkulkijniwat, A. (2012). “Soil stabilization by calcium carbide residue and fly ash.” J. Mater. Civ. Eng., 184–193.
Horpibulsuk, S., Rachan, R., Suddeepong, A., and Chinkulkijniwat, A. (2011a). “Strength development in cement admixed Bangkok clay: Laboratory and field investigations.” Soils Found., 51(2), 239–251.
Horpibulsuk, S., Shibuya, S., Fuenkajorn, K., and Katkan, W. (2007). “Assessment of engineering properties of Bangkok clay.” Can. Geotech. J., 44(2), 173–187.
Horpibulsuk, S., Suddeepong, A., Suksiripattanapong, C., Chinkulkijniwat, A., Arulrajah, A., and Disfani, M. M. (2014). “Water-void to cement ratio identity of lightweight cellular-cemented material.” J. Mater. Civ. Eng., 06014021.
Horpibulsuk, S., Suksiripattanapong, C., Samingthong, W., Rachan, R., and Arulrajah, A. (2015). “Durability against wetting-drying cycles of water treatment sludge-fly ash geopolymer and water treatment sludge-cement and silty clay-cement systems.” J. Mater. Civ. Eng., 04015078.
Horpibulsuk, S., Yangsukaseam, N., Chinkulkijniwat, A., and Du, Y. J. (2011b). “Compressibility and permeability of Bangkok clay compared with kaolinite and bentonite.” Appl. Clay Sci., 52(1), 150–159.
ISO. (2009). “Particle size analysis-laser diffraction methods.” 13320:2009, Geneva.
Ivanov, V., and Chu, J. (2008). “Applications of microorganisms to geotechnical engineering for bioclogging and biocementation of soil in situ.” Rev. Environ. Sci. Bio/Technol., 7(2), 139–153.
Jamsawang, P., Voottipruex, P., and Horpibulsuk, S. (2014). “Flexural strength characteristics of compacted cement-polypropylene fiber sand.” J. Mater. Civ. Eng., 27(904014243.
Joel, M., and Agbede, I. O. (2010). “Mechanical-cement stabilization of laterite for use as flexible pavement material.” J. Mater. Civ. Eng., 146–152.
Kampala, A., Horpibulsuk, S., Prongmanee, N., and Chinkulkijniwat, A. (2014). “Influence of wet-dry cycles on compressive strength of calcium carbide residue-fly ash stabilized clay.” J. Mater. Civ. Eng., 633–643.
Labille, J., Thomas, F., Milas, M., and Vanhaverbeke, C. (2004). “Flocculation of colloidal clay by bacterial polysaccharides: Effect of macromolecule charge and structure.” J. Colloid Interface Sci., 284(1), 149–156.
Laneuville, S. I., Turgeon, S. L., Sanchez, C., and Paquin, P. (2006). “Gelation of native betalactoglobulin induced by electrostatic attractive interaction with Xanthan gum.” Langmuir, 22(17), 7351–7357.
Latifi, N., Eisazadeh, A., and Marto, A. (2014). “Strength behavior and microstructural characteristics of tropical laterite soil treated with sodium silicate-based liquid stabilizer.” Environ. Earth Sci., 72(1), 91–98.
Latifi, N., Marto, A., and Eisazadeh, A. (2013). “Structural characteristics of laterite soil treated by SH-85 and TX-85 (non-traditional) stabilizers.” Electron. J. Geotech. Eng., 18, 1707–1718.
Latifi, N., Marto, A., and Eisazadeh, A. (2015a). “Analysis of strength development in non-traditional liquid additive-treated laterite soil from macro-and micro-structural considerations.” Environ. Earth Sci., 73(3), 1133–1141.
Latifi, N., Marto, A., and Eisazadeh, A. (2015b). “Physicochemical behavior of tropical laterite soil treated with non-traditional additive.” Acta Geotech., 11(2), 433–443.
Latifi, N., Marto, A., and Eisazadeh, A. (2016a). “Experimental investigations on behaviour of strip footing placed on chemically stabilised backfills and flexible retaining walls.” Arabian J. Sci. Eng., 1–12.
Latifi, N., Marto, A., Rashid, A. S. A., and Yii, J. L. J. (2015c). “Strength and physico-chemical characteristics of fly ash-bottom ash mixture.” Arabian J. Sci. Eng., 40(9), 2447–2455.
Latifi, N., Rashid, A., Siddiqua, S., and Horpibulsuk, S. (2015d). “Micro-structural analysis of strength development in low- and high-swelling clays stabilized with magnesium chloride solution—A green soil stabilizer.” Appl. Clay Sci., 118, 195–206.
Latifi, N., Rashid, A. S. A., Ecemis, N., Tahir, M. M., and Marto, A. (2016b). “Time-dependent physicochemical characteristics of Malaysian residual soil stabilized with magnesium chloride solution.” Arabian J. Geosci., 9(1), 1–12.
Latifi, N., Rashid, A. S. A., Marto, A., and Tahir, M. M. (2016c). “Effect of magnesium chloride solution on the physico-chemical characteristics of tropical peat.” Environ. Earth Sci., 75, 220.
Liu, J., Shi, B., Jiang, H., Huang, H., Wang, G., and Kamai, T. (2011). “Research on the stabilization treatment of clay slope topsoil by organic polymer soil stabilizer.” Eng. Geol., 117(1), 114–120.
Marto, A., Latifi, N., and Eisazadeh, A. (2014). “Effect of non-traditional additives on engineering and microstructural characteristics of laterite soil.” Arabian J. Sci. Eng., 39(10), 6949–6958.
Marto, A., Latifi, N., and Sohaei, H. (2013). “Stabilization of laterite soil using GKS soil stabilizer.” Electron. J. Geotech. Eng., 18, 521–532.
Meo, S. A. (2004). “Health hazards of cement dust.” Saudi Med. J., 25(9), 1153–1159.
Miranda-Trevino, J. C., and Coles, C. A. (2003). “Kaolinite properties, structure and influence of metal retention on pH.” Appl. Clay Sci., 23(1), 133–139.
Mitchell, J. K., and Santamarina, J. C. (2005). “Biological considerations in geotechnical engineering.” J. Geotech. Geoenviron. Eng., 1222–1233.
Mohammadinia, A., Arulrajah, A., Sanjayan, J., Disfani, M. M., Bo, M. W., and Darmawan, S. (2014). “Laboratory evaluation of the use of cement-treated construction and demolition materials in pavement base and subbase applications.” J. Mater. Civ. Eng., 04014186.
Orts, W. J., Roa-Espinosa, A., Sojka, R. E., Glenn, G. M., Imam, S. H., and Erlacher, K. (2007). “Use of synthetic polymers and biopolymers for soil stabilization in agricultural, construction, and military applications.” J. Mater. Civ. Eng., 58–66.
Particle Expert V5.12 [Computer software]. Particle Expert, Medford, OR.
Phetchuay, C., Horpibulsuk, S., Arulrajah, A., Suksiripattanapong, C., and Udomchai, A. (2016). “Strength development in soft marine clay stabilized by fly ash and calcium carbide residue based geopolymer.” Appl. Clay Sci., 127, 134–142.
Plank, J. (2004). “Applications of biopolymers and other biotechnological products in building materials.” Appl. Microbiol. Biotechnol., 66(1), 1–9.
Rehm, B. H. (2010). “Bacterial polymers: Biosynthesis, modifications and applications.” Nat. Rev. Microbiol., 8(8), 578–592.
Rosalam, S., and England, R. (2006). “Review of Xanthan gum production from unmodified starches by Xanthomonas comprestris sp.” Enzyme Microb. Technol., 39(2), 197–207.
Shen, S. L., Han, J., and Du, Y. J. (2008). “Deep mixing induced property changes in surrounding sensitive marine clays.” J. Geotech. Geoenviron. Eng., 845–854.
Shen, S. L., Wang, Z. F., Sun, W. J., Wang, L. B., and Horpibulsuk, S. (2013). “A field trial of horizontal jet grouting using the composite-pipe method in soft deposit of Shanghai.” Tunnelling Underground Space Technol., 35, 142–151.
Sukmak, K., Sukmak, P., Horpibulsuk, S., Han, J., Shen, S. L., and Arulrajah, A. (2015a). “Effect of fine content on the pullout resistance mechanism of bearing reinforcement embedded in cohesive-frictional soils.” Geotext. Geomembr., 43(2), 107–117.
Sukmak, P., Silva, P. D., Horpibulsuk, S., and Chindaprasirt, P. (2015b). “Sulfate resistance of clay-portland cement and clay-high calcium fly ash geopolymer.” J. Mater. Civ. Eng., 04014158-1–04014158-11.
Thangaraj, R., and Thenmozhi, R. (2013). “Sustainable concrete using high volume fly ash from thermal power plants.” Ecol. Environ. Conserv., 19(2), 461–466.
Tingle, J. S., and Santoni, R. L. (2003). “Stabilization of clay soils with nontraditional additives.” Transp. Res. Rec., 1819(1), 72–84.
Wu, H. N., Shen, S. L., Ma, L., Yin, Z. Y., and Horpibulsuk, S. (2015). “Evaluation of the strength increase of marine clay under seawall construction: A case study.” Mar. Georesour. Geotechnol., 33(6), 532–541.
Zohuriaan, M. J., and Shokrolahi, F. (2004). “Thermal studies on natural and modified gums.” Polym. Test., 23(5), 575–579.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 2February 2017

History

Received: Jan 28, 2016
Accepted: Jun 7, 2016
Published online: Aug 29, 2016
Discussion open until: Jan 29, 2017
Published in print: Feb 1, 2017

Permissions

Request permissions for this article.

Authors

Affiliations

Nima Latifi, Ph.D. [email protected]
Postdoctoral Research Fellow, Dept. of Civil and Environmental Engineering, Univ. of Delaware, 301 DuPont Hall, Newark, DE 19716 (corresponding author). E-mail: [email protected]; [email protected]
Suksun Horpibulsuk, Ph.D.
P.E.
Professor and Chair, School of Civil Engineering and Director, Center of Excellence in Innovation for Sustainable Infrastructure Development, Suranaree Univ. of Technology, Nakhon Ratchasima 30000, Thailand.
Christopher L. Meehan, Ph.D.
P.E.
Bentley Systems Incorporated Chair of Civil Engineering and Associate Professor, Dept. of Civil and Environmental Engineering, Univ. of Delaware, 301 DuPont Hall, Newark, DE 19716.
Muhd Zaimi Abd Majid, Ph.D.
P.E.
Professor, Institute for Smart Infrastructure and Innovative Construction (ISIIC), Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia.
Mahmood Md Tahir, Ph.D.
Professor, Construction Research Centre (CRC), Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia.
Edy Tonnizam Mohamad, Ph.D.
Associate Professor, Dept. of Geotechnic and Transportation, Faculty of Civil Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share