Technical Papers
Jun 22, 2016

Strength Development and Microfabric Structure of Construction and Demolition Aggregates Stabilized with Fly Ash–Based Geopolymers

Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 11

Abstract

The reuse of recycled construction and demolition (C&D) aggregates in civil engineering infrastructure applications has been considered a low-carbon solution to replace conventional pavement aggregates. Evaluating the strength development mechanism and interparticle flow of forces in geopolymer stabilized C&D aggregates will provide fundamental understanding of the behavior of stabilized C&D aggregates. The C&D aggregates studied are reclaimed asphalt pavement (RAP), recycled concrete aggregate (RCA), and crushed brick (CB). The performance of alkali-activated fly ash (geopolymer) on the stabilization of C&D aggregates, under different curing conditions and sample preparation methods were studied. Fly ash was used as the precursor for the alkali-activated binder that was used to stabilize the C&D aggregates. The effect of low and high content of fly ash–based geopolymers on strength development of recycled materials is investigated for the first time. Sodium silicate and sodium hydroxide were used, with different ratios, to intensify the alkaline environment for fly ash to accelerate the strength development of the mixture. The effect of static and dynamic compaction on the density and strength development was investigated for both low-content fly ash and high-content fly ash. Temperature treatment of geopolymer stabilized C&D aggregates up to 40°C and humidity curing in the moisture chamber for 7 days indicated improvement of the strength development of the mixture. The results of unconfined compressive strength (UCS) and resilient modulus testing of geopolymer-stabilized C&D aggregates indicate that alkali-activated fly ash is a viable binder for the stabilization of C&D aggregates.

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Acknowledgments

This research was supported under Australian Research Council’s Linkage Projects funding scheme (project number LP120100107).

References

AASHTO. (2007). “Standard method of test for determining the resilient modulus of soils and aggregate materials.” AASHTO T 307-99, Washington, DC.
Ashtiani, R., Little, D., and Masad, E. (2007). “Evaluation of the impact of fines on the performance of lightly cement-stabilized aggregate systems.” Transp. Res. Rec., 2026, 81–88.
ASTM. (2006). “Standard test method for resistance to degradation of small-size coarse aggregate by abrasion and impact in the Los Angeles machine.” ASTM C131, West Conshohocken, PA.
ASTM. (2007). “Standard test methods for moisture, ash, and organic matter of peat and other organic soils.” ASTM D2974-07, West Conshohocken. PA, 1520.
ASTM. (2009). “Standard test method for unconfined compressive strength of compacted soil-lime mixtures.” ASTM D5102, West Conshohocken, PA.
Banfill, P., Carter, R., and Weaver, P. (1991). “Simultaneous rheological and kinetic measurements on cement pastes.” Cem. Concr. Res., 21(6), 1148–1154.
British Standards. (2000). “Method for determination of particle shape: Flakiness index.” BS 812-105.1, London.
Criado, M., Palomo, A., Fernández-Jiménez, A., and Banfill, P. F. G. (2009). “Alkali activated fly ash: Effect of admixtures on paste rheology.” Rheol Acta, 48(4), 447–455.
Crispim, F. A., et al. (2011). “The influence of laboratory compaction methods on soil structure: Mechanical and micromorphological analyses.” Soils Rocks, 34(1), 91–98.
Damtoft, J., Lukasik, J., Herfort, D., Sorrentino, D., and Gartner, E. (2008). “Sustainable development and climate change initiatives.” Cem. Concr. Res., 38(2), 115–127.
Davidovits, J. (1991). “Geopolymers.” J. Therm. Anal. Calorim., 37(8), 1633–1656.
Dept. for Transport, Energy and Infrastructure (DTEI). (1991). “Resilient modulus characterisation of granular unbound pavement materials.” Adelaide, Australia.
Dhir, R., Munday, J., and Ong, L. (1986). “Investigations of the engineering properties of OPC/pulverised-fuel ash concrete: Deformation properties.” Struct. Eng. Part B, 64(14), 36–42.
DSEWPaC (Department of Sustainability Environment Water Population and Communities). (2012). “Construction and demolition waste guide—Recycling and re-use across the supply chain.” Environmental Protection Agency of Victoria, Dept. of Sustainability Environment Water Population and Communities, Edge Environment Pty Ltd., Canberra, Australia.
Du, Y.-J., Jiang, N.-J., Liu, S.-Y., Jin, F., Singh, D. N., and Puppala, A. J. (2013). “Engineering properties and microstructural characteristics of cement-stabilized zinc-contaminated kaolin.” Can. Geotech. J., 51(3), 289–302.
Du, Y.-J., Jiang, N.-J., Shen, S.-L., and Jin, F. (2012). “Experimental investigation of influence of acid rain on leaching and hydraulic characteristics of cement-based solidified/stabilized lead contaminated clay.” J. Hazard. Mater., 225, 195–201.
Du, Y.-J., Wei, M.-L., Reddy, K. R., Liu, Z.-P., and Jin, F. (2014). “Effect of acid rain pH on leaching behavior of cement stabilized lead-contaminated soil.” J. Hazard. Mater., 271, 131–140.
Duxson, P., Provis, J. L., Lukey, G. C., Separovic, F., and van Deventer, J. S. (2005). “29Si NMR study of structural ordering in aluminosilicate geopolymer gels.” Langmuir, 21(7), 3028–3036.
Ebrahimi, A., Kootstra, B. R., Edil, T. B., and Benson, C. H. (2012). “Practical approach for designing flexible pavements using recycled roadway materials as base course.” Road Mater. Pavement Des., 13(4), 731–748.
Fernández-Jiménez, A., and Palomo, A. (2005a). “Composition and microstructure of alkali activated fly ash binder: Effect of the activator.” Cem. Concr. Res., 35(10), 1984–1992.
Fernández-Jiménez, A., and Palomo, A. (2005b). “Mid-infrared spectroscopic studies of alkali-activated fly ash structure.” Microporous Mesoporous Mater., 86(1), 207–214.
Fernández-Jiménez, A., Palomo, A., Sobrados, I., and Sanz, J. (2006). “The role played by the reactive alumina content in the alkaline activation of fly ashes.” Microporous Mesoporous Mater., 91(1), 111–119.
Haider, G. M., Sanjayan, J., and Ranjith, P. (2014). “Complete triaxial stress-strain curves for geopolymer.” Constr. Build. Mater., 69, 196–202.
Hoyos, L. R., Puppala, A. J., and Ordonez, C. A. (2011). “Characterization of cement fiber-treated reclaimed asphalt pavement aggregates: Preliminary investigation.” J. Mater. Civ. Eng., 977–989.
Jitsangiam, P., Boonserm, K., Phenrat, T., Chummuneerat, S., Chindaprasirt, P., and Nikraz, H. (2015). “Recycled concrete aggregates in roadways: Laboratory examination of self-cementing characteristics.” J. Mater. Civ. Eng., 04014270.
Kayhanian, M., et al. (2010). “Water quality evaluation of leachate produced from pavement specimens under controlled laboratory conditions.” Road Mater. Pavement Des., 11(1), 9–28.
Mohammadinia, A., Arulrajah, A., Sanjayan, J., Disfani, M., Bo, M., and Darmawan, S. (2014). “Laboratory evaluation of the use of cement-treated construction and demolition materials in pavement base and subbase applications.” J. Mater. Civ. Eng., 04014186.
Mohammadinia, A., Arulrajah, A., Sanjayan, J., Disfani, M. M., Win Bo, M., and Darmawan, S. (2016). “Stabilization of demolition materials for pavement base/subbase applications using fly ash and slag geopolymers: Laboratory investigation.” J Mater. Civ. Eng., 04016033.
Nematollahi, B., and Sanjayan, J. (2014). “Effect of different superplasticizers and activator combinations on workability and strength of fly ash based geopolymer.” Mater. Des., 57, 667–672.
Palomo, A., Grutzeck, M., and Blanco, M. (1999). “Alkali-activated fly ashes: A cement for the future.” Cem. Concr. Res., 29(8), 1323–1329.
Phetchuay, C., Horpibulsuk, S., Suksiripattanapong, C., Chinkulkijniwat, A., Arulrajah, A., and Disfani, M. M. (2014). “Calcium carbide residue: Alkaline activator for clay-fly ash geopolymer.” Constr. Build. Mater., 69, 285–294.
Puppala, A. J., Hoyos, L. R., and Potturi, A. K. (2011). “Resilient moduli response of moderately cement-treated reclaimed asphalt pavement aggregates.” J. Mater. Civ. Eng., 990–998.
Rahman, M., Arulrajah, A., Piratheepan, J., Bo, M., and Imteaz, M. (2013). “Resilient modulus and permanent deformation responses of geogrid-reinforced construction and demolition materials.” J. Mater. Civ. Eng, 512–519.
Rahman, M. A., Imteaz, M., Arulrajah, A., and Disfani, M. M. (2014). “Suitability of recycled construction and demolition aggregates as alternative pipe backfilling materials.” J. Clean. Prod., 66, 75–84.
Snellings, R., Mertens, G., and Elsen, J. (2012). “Supplementary cementitious materials.” Rev. Mineral. Geochem., 74(1), 211–278.
Standards Australia. (1997). “Soil chemical tests—Determination of the pH value of a soil—Electrometric method.” AS 1289.4.3.1, Sydney, Australia.
Standards Australia. (2000a). “Particle density and water absorption of coarse aggregate—Weighing-in-water method.” AS 1141.6.1.” Sydney, Australia.
Standards Australia. (2000b). “Particle density and water absorption of fine aggregate.” AS 1141.5.1, Sydney, Australia.
Standards Australia. (2003). “Soil compaction and density tests—Determination of the dry density/moisture content relation of a soil using modified compactive effort.” AS 1289.5.2.1, Sydney, Australia.
Suksiripattanapong, C., Horpibulsuk, S., Chanprasert, P., Sukmak, P., and Arulrajah, A. (2015). “Compressive strength development in fly ash geopolymer masonry units manufactured from water treatment sludge.” Constr. Build. Mater., 82, 20–30.
Tam, V. W., and Tam, C. (2006). “A review on the viable technology for construction waste recycling.” Resour. Conserv. Recycl., 47(3), 209–221.
Tennakoon, C., De Silva, P., Sagoe-Crentsil, K., and Sanjayan, J. G. (2015). “Influence and role of feedstock Si and Al content in Geopolymer synthesis.” J. Sustainable Cem. Mater., 4(2), 129–139.
Texas Department of Transportation. (2010). “Cement treatment (plant-mixed), Item 276.” Austin, TX.
Texas Department of Transportation. (2013). “(TxDOT) Test procedure for soil-cement testing.” Tex-120-E, Austin, TX.
Thomas, M. (2007). Optimizing the use of fly ash in concrete, Portland Cement Association, Skokie, IL.
Wei, M. L., Du, Y. J., Reddy, K. R., and Wu, H. L. (2015). “Effects of freeze-thaw on characteristics of new KMP binder stabilized Zn- and Pb-contaminated soils.” Environ. Sci. Pollut. Res., 22(24), 19473–19484.
Xu, H., and Van Deventer, J. (2000). “The geopolymerisation of alumino-silicate minerals.” Int. J. Mineral Process., 59(3), 247–266.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 11November 2016

History

Received: Oct 16, 2015
Accepted: Mar 24, 2016
Published online: Jun 22, 2016
Published in print: Nov 1, 2016
Discussion open until: Nov 22, 2016

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Authors

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Alireza Mohammadinia [email protected]
Ph.D. Student, Dept. of Civil and Construction Engineering, Swinburne Univ. of Technology, P.O. Box 218, Hawthorn, Melbourne, VIC 3122, Australia. E-mail: [email protected]
Arul Arulrajah [email protected]
Professor, Dept. of Civil and Construction Engineering, Swinburne Univ. of Technology, P.O. Box 218, Hawthorn, Melbourne, VIC 3122, Australia (corresponding author). E-mail: [email protected]
Jay Sanjayan [email protected]
Professor, Dept. of Civil and Construction Engineering, Swinburne Univ. of Technology, P.O. Box 218, Hawthorn, Melbourne, VIC 3122, Australia. E-mail: [email protected]
Mahdi M. Disfani [email protected]
Lecturer, Dept. of Civil and Construction Engineering, Univ. of Melbourne, Melbourne, VIC 3010, Australia. E-mail: [email protected]
Myint Win Bo [email protected]
President and COO, Sarafinchin Associates Ltd., Toronto, Canada, M9W 5R8. E-mail: [email protected]
Stephen Darmawan [email protected]
Director, Geotesta Pty Ltd., Notting Hill, VIC 3168, Australia. E-mail: [email protected]

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