Technical Papers
May 24, 2016

Evaluation of Sunflower Oil as a Rejuvenator and Its Microencapsulation as a Healing Agent

Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 11

Abstract

Self-healing microencapsulation in asphalt concrete is an emerging technology that would allow this particular material to resist cracking damage caused by vehicular and environmental loading. The objectives of this study were to evaluate the effects of asphalt rejuvenators on asphalt binder, to select a suitable healing agent for asphaltic materials, and to develop a synthesis procedure for the production of microencapsulation of asphalt rejuvenators. Produced microcapsules were characterized using scanning electron microscopy (SEM) to assess the effects of preparation parameters on the size and morphology of the microcapsules. Based on the results of the experimental program, it was concluded that the use of sunflower oil as a rejuvenator was effective in reversing the aging of asphalt binder and to positively affect both the high-temperature and low-temperature grades of the binder. In contrast, the use of PennzSuppress as a rejuvenator was not effective in reversing the aging of asphalt binder and only marginally influenced the grades of the aged and extracted binders at both low and high temperatures. Based on these results, microencapsulation of sunflower oil was selected given its effectiveness in reversing the aging of asphalt binder. A synthesis procedure was developed for the preparation of microencapsulation of sunflower oil and to characterize microcapsule properties such as diameter and morphology.

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References

AASHTO. (2006). “Standard method of test for viscosity determination of asphalt binder using rotational viscometer.” AASHTO T316, Washington, DC.
AASHTO. (2009a). “Standard method of test for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR).” AASHTO T313, Washington, DC.
AASHTO. (2009b). “Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR).” AASHTO T315, Washington, DC.
AASHTO. (2009c). “Standard method of test for effect of heat and air on a moving film of asphalt binder (rolling thin film oven test).” AASHTO T240, Washington, DC.
AASHTO. (2011). “Standard practice for recovery of asphalt binder from solution by Abson method.” AASHTO R59, Washington, DC.
AASHTO. (2014). “Standard method of test for quantitative extraction of asphalt binder from hot mix asphalt HMA.” AASHTO T164, Washington, DC.
AASHTO. (2015). “Standard specification for performance-graded for asphalt binder.” AASHTO M320, Washington, DC.
Aissa, B., Therriault, D., Haddad, E., and Jamroz, W. (2012). “Self-healing materials systems: Overview of major approaches and recent developed technologies.” Adv. Mater. Sci. Eng., 2012, 17.
Boh, B., and Sumiga, B. (2008). “Microencapsulation technology and its applications in building construction materials.” Mater. Geoenviron., 55(3), 329–344.
Brown, E. N., Kesseler, M. R., Sottos, N. R., and White, S. R. (2003). “In situ poly (urea-formaldehyde) microencapsulation of dicyclopentadiene.” J. Microencapsulation, 20(6), 719–730.
Caruso, M., Blaiszik, B., and Jin, H. (2010). “Robust, double-walled microcapsules for self-healing polymeric materials.” ACS Appl. Mater. Interfaces, 2(4), 1195–1199.
Dry, C., and McMillan, W. (1996). “Three-part methylmethacrylate adhesive system as an internal delivery system for smart responsive concrete.” Smart Mater. Struct., 5(3), 297–300.
Ghosh, S. K. (2006). Functional coatings by polymer microencapsulation, Wiley, Weinheim, Germany.
Joseph, C., Jefferson, A., Isaacs, B., Lark, R., and Gardner, D. (2010). “Experimental investigation of adhesive-based self-healing of cementitious materials.” Mag. Concr. Res., 62(11), 831–843.
Naka, Y., Kaetsu, I., Yamamoto, Y., and Hayashi, K. (1992). “Preparation of microspheres by radiation-induced polymerization. II. Mechanism of microsphere growth.” J. Polym. Sci. Polym. Chem., 30(7), 1287–1298.
Ovez, B., Citak, B., Oztemel, D., Balbas, A., Peker, S., and Cakir, S. (1997). “Variation of droplet sizes during the formation of microspheres from emulsions.” J. Microencapsulation, 14(4), 489–499.
Park, S. J., Shin, Y. S., and Lee, J. R. (2001). “Preparation and characterization of microspheres containing lemon oil.” J. Colloid Interface Sci., 241(2), 502–508.
Petersen, J. C. (2009). “A review of the fundamentals of asphalt oxidation: Chemical, physicochemical, physical property, and durability relationships.” Transportation Research Circular, No. E-C140.
Samadzadeh, M., Hatami, S., Peikari, M., and Ashrafi, A. (2010). “A review on self healing coatings based on micro/nanocapsules.” Prog. Org. Coat., 68(3), 159–164.
Schlangen, E. (2012). “Synthesis and physicochemical properties of high compact microcapsules containing rejuvenator applied in asphalt.” Faculty of Civil Engineering and Geosciences, Delft Univ. of Technology, Netherlands.
Shen, J., Amirkhanian, S., and Miller, J. A. (2007). “Effects of rejuvenating agents on superpave mixtures containing reclaimed asphalt pavement.” J. Mater. Civ. Eng., 376–384.
Shulkin, A., and Stöver, H. D. D. (2002). “Polymer microcapsules by interfacial polyaddition between styrene-maleic anhydride copolyers and amines.” J. Membr. Sci., 209(2), 421–432.
Sun, G., and Zhang, Z. (2002). “Mechanical strength of microcapsules made of different wall materials.” Int. J. Pharm., 242(1–2), 307–311.
Thao, T., Johnson, T., Tong, Q., and Dai, P. (2009). “Implementation of self-healing in concrete—Proof of concept.” IES J. Part A: Civ. Struct. Eng., 2(2), 116–125.
Then, S., Seng, G., and Abo-Kassem, N. (2011). “Optimization of micro-encapsulation process for self healing polymetric material.” Sains Malysiana, 40(7), 795–802.
Yut, I., and Zofka, A. (2014). “Correlation between rheology and chemical composition of aged polymer-modified asphalts.” Constr. Build. Mater., 62(2014), 109–117.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 11November 2016

History

Received: Nov 17, 2015
Accepted: Feb 23, 2016
Published online: May 24, 2016
Discussion open until: Oct 24, 2016
Published in print: Nov 1, 2016

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Authors

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Sharareh Shirzad [email protected]
Graduate Research Assistant, Dept. of Construction Management, Louisiana State Univ., 235 Old Forestry Building, Baton Rouge, LA 70803. E-mail: [email protected]
Marwa M. Hassan, M.ASCE [email protected]
CETF Distinguished Associate Professor, Dept. of Construction Managment, Louisiana State Univ., 214B Old Forestry Building, Baton Rouge, LA 70803 (corresponding author). E-mail: [email protected]
Max A. Aguirre [email protected]
Graduate Research Assistant, Dept. of Construction Management, Louisiana State Univ., 235 Old Forestry Building, Baton Rouge, LA 70803. E-mail: [email protected]
Louay N. Mohammad, M.ASCE [email protected]
Irma Louise Rush Stewart Distinguished Professor, Director, Dept. of Civil and Environmental Engineering, Louisiana State Univ., 4101 Gourrier Ave., Louisiana Transportation Research Center, Baton Rouge, LA 70808. E-mail: [email protected]
William H., Daly [email protected]
Alumni Professor Emeritus, Dept. of Chemistry, Louisiana State Univ., 712 Choppin Hall, Baton Rouge, LA 70803. E-mail: [email protected]

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