Technical Papers
Feb 29, 2016

Assessment of Pozzolanicity of Clay Bricks Fired at Different Temperatures for Use in Repair Mortar

Publication: Journal of Materials in Civil Engineering
Volume 28, Issue 8

Abstract

Crushed bricks used in air lime mortars must show pozzolanic activity to obtain hydraulic products, and peak firing temperature is one of the main parameters for pozzolanicity of the fired clay bricks apart from clay type. In this study, solid clay mortars containing impurities as found in nature, which are used in the production of commercially sold bricks, were pulverized for a uniform firing process and then fired at nine different temperatures. The pozzolanic activity of the fired, pulverized clay was examined by commonly used direct and indirect test methods, and the results were discussed. Phase transformations of the clay and the reactions corresponding to temperature changes were also examined by X-ray diffraction (XRD) and thermogravimetric (TG) analyses. The common result of the methods reveals that clay treated at 850°C can be regarded as the best pozzolan, and the pozzolanicity of clay bricks significantly changes the mechanical properties of crushed brick-lime mortars.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was supported by research grants of The Scientific and Technological Research Council of Turkey (Project No. 111M568). The authors thank Yıldız Technical University Research Foundation for financial support (Project No. 2011-05-01-DOP01) and Işıklar Building Materials Inc. for supplying the clay mortars.

References

Adam, J. P. (2005). Roman building—Materials and techniques, Taylor and Francis, London.
Akman, M. S., Guner, A., and Aksoy, I. H. (1986). “The history and properties of khorasan mortar and concrete.” Proc., 2nd Int. Congress on the History of Turkish and Islamic Science and Technology, Vol. 1, Turkish and Islamic Science and Technology in the 16th Century, ITU Research Center of History of Science and Technology, Istanbul, Turkey, 101–112.
Al-Rawas, A. A., Hago, A. W., Corcoran, T. C., and Al-Ghafri, K. M. (1998). “Properties of Omani artificial pozzolana (sarooj).” Appl. Clay Sci., 13(4), 275–292.
ASTM. (2011). “Standard specification for fly ash and other pozzolans for use with lime for soil stabilization.” ASTM C593, West Conshohocken, PA.
ASTM. (2012). “Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete.” ASTM C618, West Conshohocken, PA.
ASTM. (2013a). “Standard test method for compressive strength of hydraulic cement mortars.” ASTM C109, West Conshohocken, PA.
ASTM. (2013b). “Standard test method for sampling and testing fly ash or natural pozzolans for use in portland-cement concrete.” ASTM C311, West Conshohocken, PA.
Baronio, G., and Binda, L. (1997). “Study of the pozzolanicity of some bricks and clays.” Constr. Build. Mater., 11(1), 41–46.
Boke, H., Akkurt, S., Ipekoglu, B., and Ugurlu, E. (2006). “Characteristics of brick used as aggregate in historic brick-lime mortars and plasters.” Cem. Concr. Res., 36(6), 1115–1122.
Budak, M., Akkurt, S., and Boke, H. (2010). “Evaluation of heat treated clay for potential use in intervention mortars.” Appl. Clay Sci., 49(4), 414–419.
CEN (European Committee for Standardization). (1998). “Methods of test for mortar for masonry—Part 2: Bulk sampling of mortars and preparation of test mortars.”, Brussels, Belgium.
CEN (European Committee for Standardization). (1999a). “Methods of test for mortar for masonry—Part 3: Determination of consistence of fresh mortar (by flow table).”, Brussels, Belgium.
CEN (European Committee for Standardization). (1999b). “Unbound and hydraulically bound mixtures—Part 43: Test method for the determination of the modulus of elasticity of hydraulically bound mixtures.”, Brussels, Belgium.
CEN (European Committee for Standardization). (2003). “Methods of test for mortar for masonry—Part 11: Determination of flexural and compressive strength of hardened mortar.”, Brussels, Belgium.
CEN (European Committee for Standardization). (2005). “Methods of testing cement—Part 1: Determination of strength.”, Brussels, Belgium.
CEN (European Committee for Standardization). (2011a). “Building lime—Part 1: Definitions, specifications and conformity criteria.”, Brussels, Belgium.
CEN (European Committee for Standardization). (2011b). “Cement—Part 1: Composition, specifications and conformity criteria for common cements.”, Brussels, Belgium.
CEN (European Committee for Standardization). (2011c). “Methods of testing cement—Part 5: Pozzolanicity test for pozzolanic cement.”, Brussels, Belgium.
Chakchouk, A., Trifi, L., Samet, B., and Bouaziz, S. (2009). “Formulation of blended cement: Effect of process variables on clay pozzolanic activity.” Constr. Build. Mater., 23(3), 1365–1373.
Cultrone, G., Sebastian, E., Elert, K., Torre, M. J., Cazalla, O., and Rodriguez-Navarro, C. (2004). “Influence of mineralogy and firing temperature on the porosity of bricks.” J. Eur. Ceram. Soc., 24(3), 547–564.
Donatello, S., Tyrer, M., and Cheeseman, C. R. (2010). “Comparison of test methods to assess pozzolanic activity.” Cem. Concr. Compos., 32(2), 121–127.
Fernandez, R., Martirena, F., and Scrivener, K. L. (2011). “The origin of the pozzolanic activity of calcined clay minerals: A comparison between kaolinite, illite and montmorillonite.” Cem. Concr. Res., 41(1), 113–122.
He, C., Makovicky, E., and Osbaeck, B. (1994). “Thermal stability and pozzolanic activity of calcined kaolin.” Appl. Clay Sci., 9(3), 165–187.
He, C., Osbaeck, B., and Makovicky, E. (1995). “Pozzolanic reactions of six principal clay minerals: Activation, reactivity assessments and technological effects.” Cem. Concr. Res., 25(8), 1691–1702.
Ispir, M., Demir, C., Ilki, A., and Kumbasar, N. (2010). “Material characterization of the historical unreinforced masonry akaretler row houses in Istanbul.” J. Mater. Civ. Eng., 702–713.
Lea, F. M. (1970). The chemistry of cement and concrete, 3rd Ed., Edward Arnold, London.
Luxan, M. P., Madruga, F., and Saavedra, J. (1989). “Rapid evaluation of pozzolanic activity of natural products by conductivity measurement.” Cem. Concr. Res., 19(1), 63–68.
Maniatis, Y., Simopoulos, A., and Kostikas, A. (1981). “Moessbauer study of the effect of calcium content on iron oxide transformations in fired clays.” J. Am. Ceram. Soc., 64 (5), 263–269.
Moropoulou, A., Cakmak, A. S., Biscontin, G., Bakolas, A., and Zendri, E. (2002). “Advanced byzantine cement based composites resisting earthquake stresses: The crushed brick/lime mortars of Justinian’s Hagia Sophia.” Constr. Build. Mater., 16(8), 543–552.
Mortureux, B., Hornain, H., Gautier, E., and Regourd, M. (1980). “Comparison de la reactivite de differentes pouzzolanes.” Proc., 7th Int. Congress on the Chemistry of Cement, Vol. 4, Septima, Paris, 110–115.
Paya, J., Borrachero, M. V., Monzo, J., Peris-Mora, E., and Amahjour, F. (2001). “Enhanced conductivity measurement techniques for evaluation of fly ash pozzolanic activity.” Cem. Concr. Res., 31(1), 41–49.
Rodriguez-Navarro, C., Cultrone, G., Sanchez Navas, A., and Sebastian, E. (2003). “TEM study of mullite growth after muscovite breakdown.” Am. Mineral., 88(5-6), 713–724.
Salvador, S. (1995). “Pozzolanic properties of flash-calcined kaolinite: A comparative study with soak-calcined products.” Cem. Concr. Res., 25(1), 102–112.
Tironi, A., Trezza, M. A., Scian, A. N. and Irassar, E. F. (2013). “Assessment of pozzolanic activity of different calcined clays”. Cem. Concr. Compos., 35(1), 319–327.
TS (Turkish Standard Institution). (2008). “Natural pozzolan for use in cement and concrete—Definitions, requirements and conformity criteria (in Turkish).”, Ankara, Turkey.
Vitruvius. (1960). The ten books on architecture, M. H. Morgan, ed., Dover, New York.
Wild, S., Gailius, A., Hansen, H., Pederson, L., and Szwabowski, J. (1997). “Pozzolanic properties of a variety of European clay bricks.” Build. Res. Inf., 25(3), 170–175.
Yu, Q., Sawayama, K., Sugita, S., Shoya, M., and Isojima, Y. (1999). “The reaction between rice husk ash and Ca(OH)2 solution and the nature of its product.” Cem. Concr. Res., 29(1), 37–43.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 28Issue 8August 2016

History

Received: Jul 20, 2015
Accepted: Dec 1, 2015
Published online: Feb 29, 2016
Discussion open until: Jul 29, 2016
Published in print: Aug 1, 2016

Permissions

Request permissions for this article.

Authors

Affiliations

Serhan Ulukaya [email protected]
Ph.D. Candidate, Dept. of Civil Engineering, Construction Materials Division, Yıldız Technical Univ., Davutpasa Campus, Esenler-Istanbul 34220, Turkey (corresponding author). E-mail: [email protected]
Nabi Yüzer, Ph.D. [email protected]
Professor, Dept. of Civil Engineering, Construction Materials Division, Yıldız Technical Univ., Davutpasa Campus, Esenler-Istanbul 34220, Turkey. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share