Technical Papers
May 7, 2015

Evaluation of Slag-Blended Alkaline-Activated Palm Oil Fuel Ash Mortar Exposed to the Sulfuric Acid Environment

Publication: Journal of Materials in Civil Engineering
Volume 27, Issue 12

Abstract

The performance of alkaline activated ground slag/ultrafine palm oil fuel ash (AAGU) mortars upon their exposure to 6% of H2SO4aq (acid) for 60 days was investigated. The mortars were prepared with NaOHaq of varied concentrations and Na2SiO3aq (Ms-SiO2/Na2O=3.3) activators and then cured at a temperature of 60°C for 24 h. The findings through strength, microstructural examination, and product characterization revealed that sulfuric acid attack could cause the disintegration of microstructure through the removal of the key elements—Ca, Mg, Na and Al—which resulted in the formation of gypsum, expansive shrinkage cracks, and a reduction in strength retention. Maintaining the slag content, concentration of NaOHaq, Na2SO3aq/NaOHaq ratio, and the mixing water content in the range of 20–40 wt.%, 8–10 M, 1.0–2.5, 5–10 wt.% of the pozzolanic materials (PMs), respectively could enhance the resistance of AAGU mortar subjected to sulfuric acid attack.

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Acknowledgments

The authors gratefully acknowledge the Universiti Sains Malaysia for providing financial support for this research work through the Research University Grant Scheme (1001/PAWAM/814191). The support from the Centre for Engineering Research, Research Institute, and Project Department of King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia are specially acknowledged. Thanks are also due to United Palm Oil Industries and Southern Steel Company for providing the palm oil fuel ash and steel slag, respectively.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 27Issue 12December 2015

History

Received: Nov 12, 2014
Accepted: Feb 19, 2015
Published online: May 7, 2015
Discussion open until: Oct 7, 2015
Published in print: Dec 1, 2015

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Moruf Olalekan Yusuf [email protected]
School of Civil Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Pinang, Malaysia (corresponding author). E-mail: [email protected]; [email protected]
Megat Azmi Megat Johari
Associate Professor, School of Civil Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Pinang, Malaysia.
Zainal Arifin Ahmad
Professor, Structural Materials Niche Area, School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Pinang, Malaysia.
Mohammed Maslehuddin
Senior Research Engineer, Center for Engineering Research Institute, King Fahd Univ. of Petroleum and Minerals, Dhahran, Saudi Arabia 31261.

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