Technical Papers
Sep 9, 2014

Activation of Pozzolanic and Latent-Hydraulic Reactions by Alkalis in Order to Repair Concrete Cracks

Publication: Journal of Materials in Civil Engineering
Volume 27, Issue 7

Abstract

The low degree of hydration of fly ash (FA) and slag (BFS) particles in high-volume FA and BFS concrete offers the possibility to activate the unreacted particles upon crack formation to close the crack. In this paper, a preliminary study is performed to evaluate the use of alkaline activators to stimulate the formation of reaction products in the crack. First, the reaction rates of crushed pastes mixed with alkaline solutions or water were monitored by calorimetry. These tests showed that alkaline activators stimulate the reactions more than water. Secondly, cracked mortar beams were stored in different alkaline solutions or water and the crack self-closing ratio was calculated after microscopic investigation at different time intervals. The results indicated that reference mixes, containing only ordinary portland cement as binder, heal very well autogenously, while a solution of Ca(OH)2+Na2CO3 seems to be the most suitable activator to stimulate crack closing of BFS concrete. Thirdly, the regain in strength due to healing of the cracks was determined. Compared to other self-healing techniques, strength regain is limited (about 10–40%).

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Acknowledgments

This research under the program SHE (Engineered Self-Healing materials) (project SECEMIN: Self-healing CEmentitious and MINeral building materials) was funded by SIM (Strategic Initiative Materials) in Flanders. The authors would like to thank the foundation for their financial support. The authors thank Brenda Debbaut for her help with data processing.

References

Arjunan, P., Silsbee, M. R., and Roy, D. M. (2001). “Chemical activation of low calcium fly ash. Part 1: Identification of suitable activators and their dosage.” Int. Ash Utilization Symp., KY.
Baert, G. (2009). “Physico-chemical interactions in portland cement—(High volume) fly ash binders.” Ph.D. dissertation, Ghent Univ., Ghent, Belgium.
Bernal, S. A., Mejia de Gutierrez, R., Pedraza, A. L., Provis, J. L., Rodriguez, E. D., and Delvasto, S. (2011). “Effect of binder content on the performance of alkali-activated slag concretes.” Cem. Concr. Res., 41(1), 1–8.
Buchwald, A., Vanooteghem, M., Gruyaert, E., Hilbig, H., and De Belie, N. (2013). “Purdocement: Application of alkali-activated slag cement in Belgium in the 1950s.” Mater. Struct.
Dennis Lee, H. X., Wong, H. S., and Buenfeld, N. (2010). “Self-sealing cement-based materials using superabsorbent polymers.” Int. RILEM Conf. on Use of Superabsorbent Polymers and Other New Additives in Concrete, O. M. Jensen, M. Hasholt, T. Laustsen, and S. Lyngby, eds., RILEM Publications, Bagneux, France, 171–178.
Deschner, F., et al. (2013). “Quantification of fly ash in hydrated, blended portland cement pastes by back-scattered electron imaging.” J. Microsc., 251(2), 188–204.
Dry, C., and McMillan, W. (1996). “Three-part methylmethacrylate adhesive system as an internal delivery system for smart responsive concrete.” Smart Mater. Struct., 5(3), 297–300.
Gruyaert, E. (2011). “Effect of blast-furnace slag as cement replacement on hydration, microstructure, strength and durability of concrete.” Ph.D. dissertation, Ghent Univ., Ghent, Belgium.
Gruyaert, E., Robeyst, N., and De Belie, N. (2010). “Study of the hydration of portland cement blended with blast-furnace slag by calorimetry and thermogravimetry.” J. Therm. Anal. Calorim., 102(3), 941–951.
Jaroenratanapirom, D., and Sahamitmongkol, R. (2011). “Self-crack closing ability of mortar with different additives.” J. Metals Mater. Miner., 21(1), 9–17.
Kim, J. S., and Schlangen, E. (2010). “Super absorbent polymers to stimulate self healing in ECC.” 2nd Int. Symp. on Service Life Design for Infrastructure, RILEM Publications, Bagneux, France.
Kocaba, V., Gallucci, E., and Scrivener, K. (2012). “Methods for determination of degree of reaction of slag in blended cement pastes.” Cem. Concr. Res., 42(3), 511–525.
Lumley, J. S., Gollop, R. S., Moir, G. K., and Taylor, H. F. W. (1996). “Degrees of reaction of the slag in some blends with portland cements.” Cem. Concr. Res., 26(1), 139–151.
NBN. (2005). “Methods of testing cement—Part 1: Determination of strength.” EN 196-1, Brussels, Belgium.
NBN. (2011). “Cement—Composition, specifications and conformity criteria for common cements.” EN 197-1, Brussels, Belgium.
Provis, J., and van Deventer, J., eds. (2014). Alkali activated materials, state-of-the-art report TC 224-AAM, Springer, Dordrecht, Netherlands.
Purdon, A. O. (1940). “The action of alkalis on blast-furnace slag.” J. Soc. Chem. Ind.: Trans. Commun., 59, 191–202.
Shi, C., Krivenko, P. V., and Roy, D. (2006). Alkali-activated cements and concretes, Taylor and Francis, Abingdon, U.K.
Snoeck, D., and De Belie, N. (2012). “Mechanical and self-healing properties of cementitious composites reinforced with flax and cottonised flax, and compared with polyvinyl alcohol fibres.” Biosyst. Eng., 111(4), 325–335.
Snoeck, D., Van Tittelboom, K., Steuperaert, S., Dubruel, P., and De Belie, N. (2013). “Self-healing cementitious materials by the combination of microfibers and superabsorbent polymers.” J. Intell. Mater. Syst. Struct., 25(1), 13–24.
ter Heide, N. (2005). “Crack healing in hydrating concrete.” M.Sc. thesis, Delft Univ. of Technology, Delft, Netherlands.
Thao, T. D. P., Johnson, T., Tong, Q., and Dai, P. (2009). “Implementation of self-healing in concrete—Proof of concept.” IES J. Part A: Civ. Struct. Eng., 2(2), 116–125.
Van Tittelboom, K., De Belie, N., De Muynck, W., and Verstraete, W. (2010). “Use of bacteria to repair cracks in concrete.” Cem. Concr. Res., 40(1), 157–166.
Van Tittelboom, K., De Belie, N., Lehmann, F., and Grosse, C. U. (2012a). “Acoustic emission analysis for the quantification of autonomous crack healing in concrete.” Constr. Build. Mater., 26(1), 532–540.
Van Tittelboom, K., De Belie, N., Van Loo, D., and Jacobs, P. (2011). “Self-healing efficiency of cementitious materials containing tubular capsules filled with healing agent.” Cem. Concr. Compos., 33(4), 497–505.
Van Tittelboom, K., Gruyaert, E., and De Belie, N. (2012b). “Influence of mix composition on the autogenous crack healing efficiency.” Constr. Build. Mater., 37, 349–359.
Wang, J., Van Tittelboom, K., De Belie, N., and Verstraete, W. (2012). “Use of silica gel or polyurethane immobilized bacteria for self-healing concrete.” Constr. Build. Mater., 26(1), 532–540.
Wiktor, V., and Jonkers, H. M. (2011). “Quantification of crack-healing in novel bacteria-based self-healing concrete.” Cem. Concr. Compos., 33(7), 763–770.

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Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 27Issue 7July 2015

History

Received: Jan 14, 2014
Accepted: Jul 16, 2014
Published online: Sep 9, 2014
Discussion open until: Feb 9, 2015
Published in print: Jul 1, 2015

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Authors

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Elke Gruyaert, Ph.D. [email protected]
Magnel Laboratory for Concrete Research, Dept. of Structural Engineering, Faculty of Engineering and Architecture, Ghent Univ., Technologiepark-Zwijnaarde 904, 9052 Ghent, Belgium; and SIM vzw, Technologiepark-Zwijnaarde 935, 9052 Ghent, Belgium. E-mail: [email protected]
Kim Van Tittelboom, Ph.D. [email protected]
Magnel Laboratory for Concrete Research, Dept. of Structural Engineering, Faculty of Engineering and Architecture, Ghent Univ., Technologiepark-Zwijnaarde 904, 9052 Ghent, Belgium. E-mail: [email protected]
Hubert Rahier, Ph.D. [email protected]
Professor, FYSC, Dept. Materials and Chemistry, Faculty of Engineering, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels, Belgium. E-mail: [email protected]
Nele De Belie, Ph.D. [email protected]
Professor, Magnel Laboratory for Concrete Research, Dept. of Structural Engineering, Faculty of Engineering and Architecture, Ghent Univ., Technologiepark-Zwijnaarde 904, 9052 Ghent, Belgium (corresponding author). E-mail: [email protected]

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