Case Studies
Jan 16, 2013

Effects of Firing Conditions on the Properties of Calcareous Clay Roofing Tiles

Publication: Journal of Materials in Civil Engineering
Volume 26, Issue 1

Abstract

The effects of firing conditions on the microstructure and physical properties of clay roofing tiles are studied. This research presents the effects of oxidizing and reducing atmosphere on Kanjiža clay material with carbonate content up to 22% by weight and the characterization of the final products. The firing was done both in the laboratory and under industrial conditions. The Fe2+/Fetotal ratio played a decisive role in the sintering process under a reducing atmosphere. The formed glassy phase, with the presence of Fe2+, attacked the earth-alkali oxides after the carbonate decomposition and more effectively filled smaller pores. The obtained results justified the benefits of the reducing firing atmosphere with 5% CO, lower porosity, higher frost resistance values, and changed microstructural characteristics

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Acknowledgments

The authors would like to express their gratitude to Company “Eisenmann” for enabling them to use the chamber kiln for reducing atmosphere firing. The first author is also grateful to the Domus Hungarica Scientarium et Artium foundation, which provides the funding for his specialization at the Laboratory of Nuclear Chemistry, Institute of Chemistry of the Eötvös Loránd Univ., Budapest, Hungary. The financial support given to the Ministry of education, science, and technological development of the Republic of Serbia (project III 45008) is also appreciated.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 26Issue 1January 2014
Pages: 175 - 183

History

Received: Jul 29, 2012
Accepted: Jan 14, 2013
Published online: Jan 16, 2013
Discussion open until: Jun 16, 2013
Published in print: Jan 1, 2014

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Authors

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Research Assistant, Potisje-Kanjiza Kanjiza-Tondach Group, Suboticki put 57, 24420 Kanjiza, Serbia (corresponding author). E-mail: [email protected]
J. Ranogajec [email protected]
Fulltime Professor, Univ. of Novi Sad, Bulevar Cara Lazara 1, 21000 Novi Sad, Serbia. E-mail: [email protected]
Assistant Professor, Dept. of Physical Chemistry and Materials Science, Univ. of Szeged, Aradi vt. 1, H-6720 Szeged, Hungary. E-mail: [email protected]
Fulltime Professor, Laboratory of Nuclear Chemistry, Institute of Chemistry, Eötvös Loránd Univ., Pázmány Péter Sétány 1/A, H-1117 Budapest, Hungary. E-mail: [email protected]

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