TECHNICAL PAPERS
Feb 6, 2010

Effect of Various Organomodified Montmorillonites on the Properties of Montmorillonite/Bitumen Nanocomposites

Publication: Journal of Materials in Civil Engineering
Volume 22, Issue 8

Abstract

Three kinds of organomodified montmorillonites (OMMTs), OMMT1, OMMT2, and OMMT3, were prepared by using different organic modifiers. Nanocomposites of bitumen and three kinds of OMMTs were prepared by melt blending. X-ray diffraction (XRD) analysis was used to evaluate the degree of intercalation or exfoliation of OMMT and its dispersion in the bitumen. The effect of OMMTs on the physical and aging properties of the modified bitumen was studied. XRD results show that OMMT1-modified bitumen had an intercalated nanostructure, while OMMT2- and OMMT3-modified bitumens formed an exfoliated nanostructure. Compared with OMMT1-modified bitumen, the OMMT2- and OMMT3-modified bitumens showed a higher value of softening point and viscosity, and the better resistance to aging was due to the formation of exfoliated structure in the OMMT2- and OMMT3-modified bitumens. OMMT2 improved the aging resistance more remarkably than OMMT3, which can be attributed to the physical differences of the organic modifiers.

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Acknowledgments

This work is part of a research, Project 50773061, supported by the National Natural Science Foundation of China. The writers gratefully acknowledge its financial support.NNSFC

References

Ahmed, R., and Nehal, S. (2005). “Nanocomposite materials based on polyurethane intercalated into montmorillonite clay.” Mater. Sci. Eng., A, 399, 368–376.
Airey, G. D., Singleton, T. M., Collop, A. C., and Mater, J. (2002). “Properties of polymer modified bitumen after rubber-bitumen interaction.” J. Mater. Civ. Eng., 14(4), 344–354.
Akelah, A., Kelly, P., Qutubuddin, S., and Moet, A. (1994). “Synthesis and characterization of epoxyphilic montmorillonites.” Clay Miner., 29, 169–178.
Causin, V., Marega, C., Marigo, A., Ferrara, G., Idiyatullina, G., and Fantinel, F. (2006). “Morphology, structure and properties of a poly (1-butene)/montmorillonite nanocomposites.” Polymer (Guildf.), 47(13), 4773–4780.
Fu, Y., Yu, J. Y., and Feng, P. C. (2007). “Preparation and properties of montmorillonite modified asphalt.” J. Wuhan. Univ. Technol, 29(9), 51–54.
Gao, J. P., Li, Y., Luan, G. G., and Wang, Y. M. (2005). “Preparation and characterization of organophilic montmorillonite.” Synth. Technol. Appli, 20(13), 15–17.
Gawel, I., and Baqinska, K. (2004). “Effect of chemical nature on the susceptibility of asphalt to aging.” Pet. Sci. Technol., 22(9), 1261–1271.
Gultek, A., Seckin, T., and Onal, Y. (2001). “Preparation and phenol captivating properties of polyvinylpyrolidone montmorillonite hybrid materials.” J. Appl. Polym. Sci., 81, 512–519.
Hossain, M., Swartz, S., Hoque, E., and Mater, J. (1999). “Development of a crumb-rubber asphalt mix design.” J. Mater. Civ. Eng., 11, 287–294.
Jiang, H. T., Wu, S. P., and Kuang, D. L. (2007). “Aging properties of organo-modified montmorillonite modified asphalts.” J. Wuhan. Univ. Technol, 29(9), 41–43.
Lamontagne, J., Dumas, P., Mouillet, V., and Kister, J. (2001a). “Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: Application to road bitumens.” Fuel, 80(4), 483–488.
Lamontagne, J., Durrieu, F., Planche, J. P., Mouillet, V., and Kister, J. (2001b). “Direct and continuous methodological approach to study the ageing of fossil organic material by infrared microspectrometry imaging: Application to polymer modified bitumen.” Anal. Chim. Acta, 444, 241–250.
Mull, M. A., Stuart, K., and Yehia, A. J. (2002). “Fracture resistance characterization of chemically modified crumb rubber asphalt pavement.” J. Mater. Sci., 37, 557–566.
Ray, S. S., Bousmina, M., and Okamoto, K. (2005). “Structure and properties of nano composites based on poly (butylenes succinate-co-adipate) and organically modified montmorillonite.” Macromol. Mater. Eng., 290(8), 759–768.
Tien, Y. I., and Wei, K. H. (2002). “The effect of nano-sized silicate layers from montmorillonite on glass transition, dynamic mechanical and thermal degradation.” J. Appl. Polym. Sci., 86, 1741–1748.
Wan, C. Y., Qiao, X. Y., Zhang, Y., and Zhang, Y. X. (2003). “Effect of different clay treatment on morphology and mechanical properties of PVC-clay nanocomposites.” Polym. Test., 22, 453–461.
Wanjale, S. D., and Jog, J. P. (2003). “Effect of modified layered silicates and compatibilizer on properties of PMP/clay nanocomposites.” J. Appl. Polym. Sci., 90, 3233–3238.
Yu, J. Y., Wang, L., and Zeng, X. (2007a). “Effect of montmorillonite on properties of SBS modified bitumen.” Polym. Eng. Sci., 47(9), 1289–1295.
Yu, J. Y., Zeng, X., Wu, S. P., Wang, L., and Liu, G. (2007b). “Preparation and properties of montmorillonite modified asphalts.” Mater. Sci. Eng., A, 447, 233–238.
Zhang, Z. Q., Liang, X. L., and Li, P. (2005). “Evaluation method of asphalt aging properties.” J. Traffic Transp. Eng., 5(1), 1–5.
Zilg, C., Dietsche, F., and Hoffmann, B. (2001). “Nanofillers based upon organophilic layered silicates.” Macromol. Symp., 169, 65–77.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 22Issue 8August 2010
Pages: 788 - 793

History

Received: May 15, 2009
Accepted: Oct 6, 2009
Published online: Feb 6, 2010
Published in print: Aug 2010

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Authors

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Jianying Yu [email protected]
Professor, Key Laboratory for Silicate Material and Engineering of Ministry of Education, Wuhan Univ. of Technology, Wuhan 430070, People’s Republic of China (corresponding author). E-mail: [email protected]
Doctor, Key Laboratory for Silicate Material and Engineering of Ministry of Education, Wuhan Univ. of Technology, Wuhan 430070, People’s Republic of China. E-mail: [email protected]
Master, Key Laboratory for Silicate Material and Engineering of Ministry of Education, Wuhan Univ. of Technology, Wuhan 430070, People’s Republic of China. E-mail: [email protected]
Yuanyuan Tao [email protected]
Master, Key Laboratory for Silicate Material and Engineering of Ministry of Education, Wuhan Univ. of Technology, Wuhan 430070, People’s Republic of China. E-mail: [email protected]

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