Technical Papers
Oct 31, 2022

Flow and Transport Analysis and Suggested Optimal CAB Design Charts under Varying Hydraulic Conditions

Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 27, Issue 1

Abstract

This research presents a numerical investigation that employs a continuous adsorptive barrier (CAB) near heavily contaminated groundwater. The source is classified as a heavy metal finite point source that is found in landfills. A decision maker could benefit from the CAB design charts that are produced in this research in table and chart forms. Based on the results, the cost of the barrier installation (CCAB) and the estimated dimensions could be determined by a decision maker for a known finite source concentration at the site. To accomplish this, the problem is simplified and discretized using the finite-difference technique to solve a two-dimensional (2D) transport model, and the model’s accuracy is then tested against a variety of real-world scenarios. The established model (PRBFD) was used to simulate heavy metal pollution that used adsorption as the natural attenuation. Later, the required aquifer length and width for a 4-year simulation were plotted. Then, it was discovered that natural remediation took longer to reach the remediation goal, and therefore, to meet the requirements, a reactive barrier was considered. Zero-valent iron (ZVI), which is a reactive material, is introduced next to the contaminant to absorb heavy metals in a CAB. Subsequently, a plot of the maximum relative concentrations in the longitudinal and transverse directions is generated from the data for peak concentrations that are obtained at various time (t) intervals, and the requisite CAB dimensions [e.g., length (LB) and width (WB)] are computed where the cost incurred in the system is calculated. Finally, a sensitivity analysis is performed to determine the impact of sensitive hydraulic parameters on the barrier dimensions and its design cost, and various design charts are generated for the most probable cases, which could allow a decision maker to identify the barrier dimensions for any known source concentration value.

Practical Applications

A number of heavy metals, such as arsenic (As), lead (Pb), zinc (Zn), copper (Cu), and cadmium (Cd) adversely affect human health. Toxic metals could easily be transmitted to the human body by food or water, because heavy metals naturally transfer from the soil to crops and then into groundwater. This research was designed so that a decision maker could determine the size of the reactive barrier, along with the design cost, against known maximum concentrations of hazardous metals at the source; and permissible concentrations of the same metal contaminant at the barrier exit face without the use of mathematical modeling.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This research was fully supported by the Indian Institute of Technology Delhi, India. The corresponding author would like to express their thanks to the Ministry of Education, India, for providing financial support, a Ph.D. assistantship, and research facilities to establish this work.

References

Babel, S., and T. A. Kurniawan. 2003. “Low-cost adsorbents for heavy metals uptake from contaminated water: A review.” J. Hazard. Mater. 97 (1): 219–243. https://doi.org/10.1016/S0304-3894(02)00263-7.
Bilardi, S., P. S. Calabrò, and N. Moraci. 2021. “Optimal design of ZVI/lapillus mixtures for nickel removal in permeable reactive barriers.” Jpn. Geotech. Soc. Spec. Publ. 9 (7): 313–318. https://doi.org/10.3208/jgssp.v09.cpeg022.
Blowes, D. W., C. J. Ptacek, S. G. Benner, C. W. T. McRae, T. A. Bennett, and R. W. Puls. 2000. “Treatment of inorganic contaminants using permeable reactive barriers.” J. Contam. Hydrol. 45 (1): 123–137. https://doi.org/10.1016/S0169-7722(00)00122-4.
Bortone, I., S. Chianesea, A. Di Nardoa, M. Di, A. E. Natalea, and D. Musmarraa. 2013. “A comparison between pump & treat technique and permeable reactive barriers for the remediation of groundwater contaminated by chlorinated organic compounds.” Chem. Eng. Trans. 32: 31–36.
Bürger, C. M., P. Bayer, and M. Finkel. 2007. “Algorithmic funnel-and-gate system design optimization.” Water Resour. Res. 43 (8): 1–9. https://doi.org/10.1029/2006WR005058.
Burger, C., and M. Finkel. 2005. “Performance of multiple gate funnel-and-gate systems in three-dimensional, anisotropic, heterogeneous aquifers.” IAHS Publ. 298: 125.
Chen, Y., J. Li, C. Lei, and H. Shim. 2011. “Interactions between BTEX, TPH, and TCE during their bio-removal from the artificially contaminated water.” In Proc., 2nd Int. Conf. on Bioenvironment, Biodiversity and Renewable Energies, 33–37. International Academy, Research, and Industry Association.
Darling, D. F., and P. H. Hayden. 1997. “Field trial of the biowall technology at a former manufactured gas plant site.” In Proc., 29th Mid-Atlantic Conf. Hazardous and Industrial Wastes, edited by D. K. Clark, D. F. Darling, T. L. Hineline, and P. H. Hayden, 397. Boca Raton, FL: CRC Press.
Erzova, V. A., V. G. Rumynin, A. M. Nikulenkov, K. V. Vladimirov, S. M. Sudarikov, and M. V. Vilkina. 2022. “Forecast of radionuclide migration in groundwater of the zone affected by construction drainage at the Leningrad NPP-2.” J. Min. Inst. 1–18. https://doi.org/10.31897/PMI.2022.27.
Freeze, R. A., and J. A. Cherry. 1979. Groundwater. No. 629.1 F7. Englewood Cliffs, NJ: Prentice-Hall.
Gavaskar, A. R., N. Gupta, B. Sass, R. Janosy, and D. O'Sullivan. 1998. Permeable barriers for groundwater remediation. Washington, DC: U.S. Department of Energy Office of Scientific and Technical Information.
Gavaskar, A., N. Gupta, B. Sass, R. Janosy, and J. Hicks. 2000. Design guidance for application of permeable reactive barriers for groundwater remediation. Columbus, OH: Battelle Operations.
Geranio, L. 2007. Review of zero valent iron and apatite as reactive materials for permeable reactive barrier. Term Paper, 7. Princeton, NJ: Citeseer.
Han, W., F. Fu, Z. Cheng, B. Tang, and S. Wu. 2016. “Studies on the optimum conditions using acid-washed zero-valent iron/aluminum mixtures in permeable reactive barriers for the removal of different heavy metal ions from wastewater.” J. Hazard. Mater. 302: 437–446. https://doi.org/10.1016/j.jhazmat.2015.09.041.
ITRC (Interstate Technology and Regulatory Council). 2005. Permeable reactive barriers: Lessons learned/new directions. technical/regulatory guidelines. Washington, DC: ITRC.
Järup, L. 2003. “Hazards of heavy metal contamination.” Br. Med. Bull. 68 (1): 167–182. https://doi.org/10.1093/bmb/ldg032.
Johnson, R. L., P. C. Johnson, D. B. McWhorter, R. E. Hinchee, and I. Goodman. 1993. “An overview of in situ air sparging.” Groundwater Monit. Rem. 13 (4): 127–135. https://doi.org/10.1111/j.1745-6592.1993.tb00456.x.
Keely, J. F. 1989. Performance evaluations of pump and treat remediations. Rep. EPA/540/8-89. Ada, OK: Environmental Protection Agency.
Konikow, L. F. 2011. “The secret to successful solute-transport modeling.” Ground Water 49 (2): 144–159. https://doi.org/10.1111/j.1745-6584.2010.00764.x.
Kumar, M., and A. Puri. 2012. “A review of permissible limits of drinking water.” Indian J. Occup. Environ. Med. 16 (1): 40. https://doi.org/10.4103/0019-5278.99696.
Kurniawan, T. A., G. Y. S. Chan, W.-H. Lo, and S. Babel. 2006. “Physico–chemical treatment techniques for wastewater laden with heavy metals.” Chem. Eng. J. 118 (1): 83–98. https://doi.org/10.1016/j.cej.2006.01.015.
Ludwig, R. D., R. G. McGregor, D. W. Blowes, S. G. Benner, and K. Mountjoy. 2002. “A permeable reactive barrier for treatment of heavy metals.” Ground Water 40 (1): 59–66. https://doi.org/10.1111/j.1745-6584.2002.tb02491.x.
Mackay, D. M., and J. A. Cherry. 1989. “Groundwater contamination: Pump-and-treat remediation.” Environ. Sci. Technol. 23 (6): 630–636. https://doi.org/10.1021/es00064a001.
Mayacela Rojas, C. M., M. F. Rivera Velasquez, A. Tavolaro, A. Molinari, and C. Fallico. 2017. “Use of vegetable fibers for PRB to remove heavy metals from contaminated aquifers—Comparisons among cabuya fibers, broom fibers and ZVI.” Int. J. Environ. Res. Public Health 14 (7): 684. https://doi.org/10.3390/ijerph14070684.
McMurtry, D. C., and R. O. Elton. 1985. “New approach to in-situ treatment of contaminated groundwaters.” Environ. Prog. 4 (3): 168–170. https://doi.org/10.1002/ep.670040311.
Mench, M., J. Vangronsveld, H. Clijsters, N. W. Lepp, and R. Edwards. 2020. “In situ metal immobilization and phytostabilization of contaminated soils.” In Phytoremediation of contaminated soil and water, edited by N. Terry and G. S. Banuelos, 323–358. Boca Raton, FL: CRC Press.
Morrison, S. J., and R. R. Spangler. 1993. “Chemical barriers for controlling groundwater contamination.” Environ. Prog. 12 (3): 175–181. https://doi.org/10.1002/ep.670120305.
Njaramba, L. K., J.-B. Park, C.-S. Lee, A. M. Nzioka, and Y.-J. Kim. 2021. “Permeable reactive barriers with zero-valent iron and pumice for remediation of groundwater contaminated with multiple heavy metals.” Environ. Eng. Sci. 38 (4): 245–255. https://doi.org/10.1089/ees.2020.0109.
Pandey, P. 2017. “Hybrid multi-objective optimization approach for optimal design of in-situ permeable reactive barrier.” Ph.D. thesis, Dept. of Civil Engineering, Indian Institute of Technology Delhi.
Pandey, P., and S. Mathur. 2013. “Impact of migration of arsenic on the aquifer and its remediation using an in situ innovative technology.” In Proc. Int. Conf. on Sustainable Innovative Techniques in Civil and Environmental Engineering, New Delhi, India. https://www.researchgate.net/publication/363487622.
Pandey, P., and S. Mathur. 2015. “Mathematical modelling and application of permeable reactive barrier into a hazardous waste contaminated site.” In Proc. Int. Conf. Advances in Engineering Science and Management, 318–324. Agra, Uttar Pradesh, India. https://www.researchgate.net/publication/363487436.
Pandey, P., and S. Mathur. 2018. “Optimization of continuous reactive barrier for optimal in-situ groundwater remediation.” Washington DC: Fall 2018 Virtual Poster Showcase, American Geophysical Union. https://abstractsearch.agu.org/vps/2018/15/107.html.
Peaceman, D. W., and and H. H. Rachford Jr. 1955. “The numerical solution of parabolic and elliptic differential equations.” J. Soc. Ind. Appl. Math. 3 (1): 28–41. https://doi.org/10.1137/0103003.
Phillips, D. H., B. Gu, D. B. Watson, Y. Roh, L. Liang, and S. Y. Lee. 2000. “Performance evaluation of a zerovalent iron reactive barrier: mineralogical characteristics.” Environ. Sci. Technol. 34 (19): 4169–4176. https://doi.org/10.1021/es001005z.
Philip, J. C., and R. M. Atlas. 2005. “Bioremediation of contaminated soils and aquifers.” In Bioremediation: Applied microbial solutions for real-world environmental cleanup, edited by R. M. Atlas, and J. Philip, 139–236. Chichester, UK: Wiley.
Prasad, R. K., and S. Mathur. 2008. “Potential well locations in in situ bioremediation design using neural network embedded Monte Carlo approach.” Pract. Period. Hazard. Toxic Radioact. Waste Manage. 12 (4): 260–269. https://doi.org/10.1061/(ASCE)1090-025X(2008)12:4(260).
Rathfelder, K., W. W.-G. Yeh, and D. Mackay. 1991. “Mathematical simulation of soil vapor extraction systems: Model development and numerical examples.” J. Contam. Hydrol. 8 (3): 263–297. https://doi.org/10.1016/0169-7722(91)90023-T.
Reeter, C., S. Chao, and A. Gavaskar. 1999. Permeable reactive wall remediation of chlorinated hydrocarbons in groundwater. Arlington, TX: Environmental Security Technology Certification Program Office.
Rifai, H. S., C. J. Newell, J. R. Gonzales, S. Dendrou, L. Kennedy, and J. T. Wilson. 1997. BIOPLUME III natural attenuation decision support system version 1.0 user’s manual. San Antonio: Air Force Center for Environmental Excellence, Brooks AFB.
Rodak, C., S. E. Silliman, and D. Bolster. 2014. “Time-Dependent health risk from contaminated groundwater including Use of reliability, resilience, and vulnerability as measures.” JAWRA J. Am. Water Resour. Assoc. 50 (1): 14–28. https://doi.org/10.1111/jawr.12103.
Schipper, L. A., W. D. Robertson, A. J. Gold, D. B. Jaynes, and S. C. Cameron. 2010. “Denitrifying bioreactors—an approach for reducing nitrate loads to receiving waters.” Ecol. Eng. 36 (11): 1532–1543. https://doi.org/10.1016/j.ecoleng.2010.04.008.
Shashi, M., and P. Pratiksha. 2017. “Optimal design of in-situ permeable reactive barrier.” WIT Trans. Ecol. Environ. 216: 251–259. https://doi.org/10.2495/WS170241.
Shieh, H.-J., and R. C. Peralta. 2005. “Optimal in situ bioremediation design by hybrid genetic algorithm-simulated annealing.” J. Water Resour. Plann. Manage. 131 (1): 67–78. https://doi.org/10.1061/(ASCE)0733-9496(2005)131:1(67).
Simon, F. G., and T. Meggyes. 2000. “Removal of organic and inorganic pollutants from groundwater using permeable reactive barriers.” Land Contam. Reclam. 8 (2): 103–116.
Skinner, S. J. W., and C. F. Schutte. 2007. “The feasibility of a permeable reactive barrier to treat acidic sulphate- and nitrate-contaminated groundwater.” Water SA 32 (2): 129–136.
Starr, R. C., and J. A. Cherry. 1994. “In situ remediation of contaminated ground water: The funnel-and-gate system.” Ground Water 32 (3): 465–476. https://doi.org/10.1111/j.1745-6584.1994.tb00664.x.
Suhag, R. 2016. Overview of ground water in India. No. id: 9504. Delhi, India: PRS Legislative Research Standing Committee on Water Resources.
USEPA (United States. Environmental Protection Agency. Technology Innovation Office, & Environmental Management Support (Firm)). 1999. Field applications of in situ remediation technologies: Permeable reactive barriers. Darby, PA: DIANE Publishing.
Van Genuchten, M. T., and W. J. Alves. 1982. Analytical solutions of the one-dimensional convective-dispersive solute transport equation. No. 157268. Washington, DC: USDA, Economic Research Service.
Wang, S., and J. Chen. 2006. “Multigrid ADI method for Two-dimensional electromagnetic simulations.” IEEE Trans. Antennas Propag. 54 (2): 715–720. https://doi.org/10.1109/TAP.2005.863093.
Wilson, J. L., and P. J. Miller. 1978. “Two-dimensional plume in uniform ground-water flow.” J. Hydraul. Div. 104 (4): 503–514. https://doi.org/10.1061/JYCEAJ.0004975.
Yadav, B. K., M. A. Siebel, and J. J. A. van Bruggen. 2011. “Rhizofiltration of a heavy metal (lead) containing wastewater using the wetland plant Carex pendula.” CLEAN - Soil Air Water 39 (5): 467–474. https://doi.org/10.1002/clen.201000385.
Zhu, F., X. Tan, W. Zhao, L. Feng, S. He, L. Wei, L. Yang, K. Wang, and Q. Zhao. 2022. “Efficiency assessment of ZVI-based media as fillers in permeable reactive barrier for multiple heavy metal-contaminated groundwater remediation.” J. Hazard. Mater. 424: 127605. https://doi.org/10.1016/j.jhazmat.2021.127605.

Information & Authors

Information

Published In

Go to Journal of Hazardous, Toxic, and Radioactive Waste
Journal of Hazardous, Toxic, and Radioactive Waste
Volume 27Issue 1January 2023

History

Received: Mar 9, 2022
Accepted: Jul 2, 2022
Published online: Oct 31, 2022
Published in print: Jan 1, 2023
Discussion open until: Mar 31, 2023

Permissions

Request permissions for this article.

Authors

Affiliations

Pratiksha Pandey [email protected]
Postdoctoral Research Associate, School of Natural and Built Environment, Queen’s Univ. Belfast, Northern Ireland BT9 5AG, UK (corresponding author). Email: [email protected]
Shashi Mathur
Emeritus Professor, Dept. of Civil Engineering, Indian Institute of Technology Delhi, New Delhi 110016, India.
V. Sivakumar
Reader, School of Natural and Built Environment, Queen’s Univ. Belfast, Northern Ireland BT9 5AG, UK.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share