Kinetics of Ozone Oxidation of Acid Red 131 Monoazo Dye in Aqueous Solution
Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 21, Issue 1
Abstract
The synthetic dye solution of Acid Red 131 monoazo dye was ozonated in a semibatch reactor. The effect of ozone dose, initial dye concentration in the solution, and solution pH on the rate of decolorization was studied and the results were analyzed in terms of color-removal efficiency (CRE), which was found to increase with an increase in the ozone dose. Alkaline pH of the synthetic solution was found suitable for ozonation and 100% CRE was obtained after 23 min of ozone treatment at pH 11. The CRE was found to decrease with an increase in initial dye concentration of the synthetic dye solution, but the quantity of the dye removal was greater at higher concentrations. The results of decolorization kinetic research showed that ozonation of the reactive dye were a pseudo-first-order reaction with respect to the dye concentration in the solution. Experiments were performed to remove dye from the textile industry effluent by oxidation with ozone and 100% CRE was obtained. The quantities of ozone and power consumption were determined.
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References
Alaton, I. A., Balcioglu, I. A., and Bahnemann, D. F. (2002). “Advanced oxidation of a reactive dye bath effluent: Comparison of , and processes.” Water Res., 36(5), 1143–1154.
Alkdasi, A., Idris, A., Saed, K., and Guan, C. T. (2004). “Treatment of textile wastewater by advanced oxidation process—A review.” Global Nest: Int. J., 6(3), 222–230.
Azbar, N., Yonar, T., and Kestioglu, K. (2004). “Comparison of various advanced oxidation processes and chemical treatment methods for COD and colour removal from a polyester and acetate fiber dyeing effluent.” Chemosphere, 55(1), 35–43.
Beninca, C., Peralta-Zamora, P., Tavarea, C. R. G., and Igarashi-Mafra, L. (2013). “Degradation of an azo dye (Ponceau 4R) and treatment of wastewater from a food industry by ozonation.” Ozone. Sci. Eng., 35(4), 295–301.
Choi, J. W., Song, H. K., Lee, W., Koo, K. K., Han, C., and Na, B. K. (2004). “Reduction of COD and colour of acid reactive dyestuff wastewater using ozone.” Korean J. Chem. Eng., 21(2), 398–403.
Correia, V. M., Stephnson, T., and Judd, S. J. (1994). “Characterization of textile wastewater—A review.” Environ. Tech., 15(10), 917–929.
Konsowas, A. H. (2003). “Decolorization of wastewater containing direct dye by ozonation in a batch bubble column reactor.” Desalination, 158(1–3), 233–240.
Kusvuran, E., Gulnaz, O., Samil, A., and Yildirim, O. (2011). “Decolorization of malachite green, decolorization kinetics, and stoichiometry of ozone-malachite green and removal of antibacterial activity with ozonation process.” J. Hazard. Mater., 186(1), 133–143.
Mehmet, F. S., and Hasan, Z. S. (2002). “Ozone treatment of textile effluents and dyes: Effect of applied ozone dose, pH and dye concentration.” J. Chem. Tech. Biotech., 77(7), 842–850.
Saroj, D. P., Kumar, A., Bose, P., Tare, V., and Dhopavkar, Y. (2005). “Mineralization of some natural refractory organic compounds by biodegradation and ozonation.” Water Res., 39(9), 1921–1933.
Schievano, E., Manegazzo, I., Marotta, E., and Mammi, S. (2011). “Structure elucidation of the dye Acid Red 131: Complete , and NMR data assignment.” Mag. Reason. Chem., 49(8), 523–528.
Singh, S., Fan, M., and Brown, R. C. (2008). “Ozone treatment of process water from a dry-mill ethanol plant.” Bioresour. Technol., 99(6), 1801–1805.
Srinivasan, S. V., et al. (2009). “Decolorization of leather dye ozonation.” Desalination, 235(1–3), 88–92.
Tizaoui, C., and Garima, N. (2011). “Kinetics of the ozone oxidation of Reactive Orange 16 azo-dye in aqueous solution.” Chem. Eng. J., 173(2), 463–473.
Turhan, K., Durukan, I., Ozturkcan, S. A., and Turgut, Z. (2012). “Decolorization of textile basic dye in aqueous solution by ozone.” Dyes Pigments, 92(3), 897–901.
Wu, J., Doan, H., and Upreti, S. (2008). “Decolorization of aqueous textile reactive dye by ozone.” Chem. Eng. J., 142(2), 156–160.
Wu, J., and Wang, T. (2001). “Ozonation of aqueous azo dye in a semi-batch reactor.” Water Res., 35(4), 1093–1099.
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© 2016 American Society of Civil Engineers.
History
Received: Jun 6, 2014
Accepted: Feb 12, 2016
Published online: May 10, 2016
Discussion open until: Oct 10, 2016
Published in print: Jan 1, 2017
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