Alkaline Hydrolysis of Resin-Based Combustible Cartridge Case and Application of its Hydrolysate as Crop Fertilizer
Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 16, Issue 4
Abstract
Disposal of hazardous and toxic waste arising out of combustible cartridge case (CCC)–based explosive munitions is an environmental issue of global concern. A large quantity of CCC waste is disposed of by open burning or detonation because there is no viable waste-disposal technology that is environmentally friendly and is found suitable for bulk treatment available at present. In the present study, the process of alkaline hydrolysis of CCC composition has been studied. It is found that CCCs waste can be suitably treated and neutralized by a simple chemical process (alkaline hydrolysis) that is eco-compliant. It is possible to recover a high proportion of nitrogen (87%) from this waste. The CCC hydrolysate can be suitably used as fertilizer for crop. Pot culture studies carried out using the hydrolysate as a fertilizer on wheat seed and plant give encouraging results of the main crop performance parameters like plant biomass, yield, plant growth, and chlorophyll content.
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Acknowledgments
The authors extend their sincere thanks to Dr. A. Subhananda Rao, Director, HEMRL, Defence Research and Developement Organization (DRDO), Pune, for his encouragement to carry out the present study and grant of his permission to publish this paper. We also extend our sincere thanks to Dr. P.B. Navle, Joint Director, HEMRL, DRDO, Pune, and his team for their timely help and support in the completion of this study.
References
Christodoulatos, C., Su, T., and Koutsospyros, L. A. (2001). “Kinetics of the alkaline hydrolysis of nitrocellulose.” Water Environ. Res., 73(2), 185–191.
David, R. W. (1994). “Advantages and disadvantages of selected alternative technologies.” Chemical Weapon Destruction, Appendix IV, National Security and International Affairs Division, Washington, DC.
Hayee, M. A., Shah, S. H., Malik, M. A., Rafiq, M., and Ali, M. A. (1989). “Effect of different levels of NPK on growth and grain yield of two wheat varieties.” Pak. J. Agric. Sci., 26(3), 236.
Kaplan, D. L., and Kaplan, A. M. (1982). “Thermophilic biotransformations of 2, 4, 6 trinitrotoluene under simulated composting conditions.” Appl. Environ. Microbiol., 44(3), 757–760.
Kim, B. J., Alleman, J., and Quivey, E. D. M. (1998). “Alkaline hydrolysis/biodegradation of nitrocellulose.”, Construction Engineering Research Laboratories, U.S. Army Corps of Engineers, Washington, DC.
Kiyoshi, F., Ukida, J., and Masakazu, M. (1963). “Hydrolysis of poly(vinyl acetate)s of various tacticities.” J. Polym. Sci. Part B, 1(2), 687–691 (Mar. 10, 2003).
Mead, R., and Curnow, R. N. (1983). Statistics methods in agricultural and experimental biology, Chapman and Hall, London.
Pandey, R. K. (2007). “Studies on conversion of high energy and hazardous materials into fertilizer.” Ph.D. thesis (THES-142), Univ. of Pune, Pune, Maharashtra.
Pandey, R. K., Asthana, S. N., Bhattacharya, B., Tiwari, I., and Ghole, V. S. (2007). “Waste explosives and other hazardous materials.” J. Environ. Sci. Eng., 49(3), 195–202.
Sharma Pritham, K., Sankhayan, N., Bhardwaj, S. K., and Dixit, S. P. (2002). “Studies on root characteristics and biomass productivity of wheat (Aradhana) in phosphorus, farm yard manure and mulch amended mountain acidic lands of western Himalayas.” 17th WCSS, Thailand (Aug. 14–21).
Rangasawamy, R. (2005). Agricultural statistics, 2nd Ed., New Age International, Delhi, India.
Rice, B. M., Politzer, P. A., and Murray, J. S. (2003). “Overview of research in energetic materials.” Energetic materials, part 1: Decomposition, crystal and molecular properties, theoretical and computational chemistry, Vol. 12, Elsevier, New York.
Robert, E. C., and Robin, A. (1998). Treatment of HMX and RDX, Amarillo National Resource Center for Plutonium, Amrillo, TX, 1–48.
Shedge, M. T., Patel, C. H., Tadkod, S. K., and Murthy, G. D. (2008). “Polyvinyl acetate resin as a binder effecting mechanical and combustion properties of combustible cartridge case formulations.” Def. Sci. J., 58(3), 390–397.
Spain, J. C., Hughes, J. B., and Knackmuss, H. J. (2000). Biodegradation of nitroaromatic compounds and explosives, Lewis Publishers, Washington, DC.
U.S. Army Corps of Engineers (USACE). (1999). “Nitrocellulose fines management strategy.”, Washington, DC.
Wolf, F. (1997). “Alkaline hydrolysis conversion of nitrocellulose ines.” Engineering Report of Badger Army Ammunition Plant, Baraboo, WI.
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© 2012 American Society of Civil Engineers.
History
Received: Mar 9, 2011
Accepted: Sep 30, 2011
Published online: Oct 3, 2011
Published in print: Oct 1, 2012
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