Case Studies
Sep 26, 2014

Heat, B10-Enriched Boric Acid, and Bromide as Recycled Groundwater Tracers for Managed Aquifer Recharge: Case Study

Publication: Journal of Hydrologic Engineering
Volume 20, Issue 3

Abstract

California guidelines for indirect potable recycled wastewater reuse projects currently require groundwater tracers to demonstrate subsurface residence time for pathogenic microorganism control. Residence times over 6 months from infiltration to drinking water extraction are required. Two prospective tracers were evaluated in this case study: boron-10 (as B10-enriched boric acid) and heat (with recharging water 10°C warmer than native groundwater). Bromide (Br) was also released as a control. B10 is attractive as a deliberate tracer because (1) reasonably accurate and affordable measurements can be made on an inductively coupled plasma mass spectrometer (ICP-MS) system, and (2) isotopic tracers require significantly less mass to tag an equivalent water volume than concentration-based salt tracers like Br. B10 and Br tracer breakthroughs were observed at seven of nine monitoring wells, although at one well the detection of B10 was barely observable and may have resulted from a slight change in source water composition. B10 arrived 25% later than Br on average, showing retardation through exchange with clay surfaces. Heat flow, requiring no artificial input, was interpreted from temperature changes recorded hourly at well loggers. Residence times to all wells were successfully determined from temperature changes with the longest flow path of 6 months. This implies that dilution of Br and B10 is a limitation the geochemical tracer experiment.

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Acknowledgments

This project was funded by the WateReuse Research Foundation (WRF-09-11) in cooperation with the Water Replenishment District of Southern California and the Orange County Water District. The authors thank Peter Piestrzeniewicz and Benny Chong from WRD for their assistance in field operations and for providing well logger data, as well as Nicole Gee and Andrew Benson for their field and laboratory work at UCSB.

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Go to Journal of Hydrologic Engineering
Journal of Hydrologic Engineering
Volume 20Issue 3March 2015

History

Received: Nov 6, 2013
Accepted: Jul 18, 2014
Published online: Sep 26, 2014
Discussion open until: Feb 26, 2015
Published in print: Mar 1, 2015

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Authors

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Timothy E. Becker
Graduate Student, Dept. of Earth Science, Univ. of California, Santa Barbara, CA 93106; and Staff Scientist, Kear Groundwater, P.O. Box 2601, Santa Barbara, CA 93120.
Jordan F. Clark [email protected]
Professor, Dept. of Earth Science, Univ. of California, Santa Barbara, CA 93106 (corresponding author). E-mail: [email protected]
Theodore A. Johnson
Chief Hydrogeologist, Water Replenishment District of Southern California, 4040 Paramount Blvd., Lakewood, CA 90712.

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