Technical Notes
Jun 15, 2012

Air-Water Interfacial Area and Capillary Pressure: Porous-Medium Texture Effects and an Empirical Function

Publication: Journal of Hydrologic Engineering
Volume 17, Issue 7

Abstract

The relationship between air-water interfacial area and capillary pressure under higher water-content conditions is investigated for four natural porous media. The results show that the magnitude of the air-water interfacial area increases with increasing capillary pressure, consistent with the decrease in water saturation. The maximum observed air-water interfacial areas are dependent upon the magnitude of residual water saturation, which itself is condition-dependent. The more well-sorted porous-medium exhibited a greater rate of change of air-water interfacial area with capillary pressure than the more poorly sorted porous media. The observed relationship between air-water interfacial area and capillary pressure was quantified by coupling an empirical equation describing the air-water interfacial area versus water saturation relationship with the van Genuchten equation relating water saturation and capillary pressure. This equation produced reasonable simulations of the measured data.

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Acknowledgments

This research was funded by the USDA National Research Initiative Program, with additional support from the NIEHS Superfund Research Program (#ES-4940) and EPA Science to Achieve Results Program. We also thank Sheri Musil, Dr. Art Warrick, Dr. Mike Yao, and Dr. Janick Artiola for their kind assistance and the reviewers for their constructive comments.

References

Brusseau, M. L., Janousek, H., Murao, A., and Schnaar, G. (2008). “Synchrotron X-ray microtomography and interfacial partitioning tracer test measurements of NAPL-water interfacial areas.” Water Resour. Res.WRERAQ, 44, W01411.
Brusseau, M. L., Peng, S., Schnaar, G., and Costanza-Robinson, M. S. (2006). “Relationships among air-water interfacial area, capillary pressure, and water saturation for a sandy porous medium.” Water Resour. Res.WRERAQ, 42(3), W03501,.
Brusseau, M. L., Peng, S., Schnaar, G., and Murao, A. (2007). “Measuring air-water interfacial areas with x-ray microtomography and interfacial partitioning tracer tests.” Environ. Sci. Technol.ESTHAG, 41(6), 1956–1961.
Brusseau, M. L., Popovicova, J., and Silva, J. A. K. (1997). “Characterizing gas-water interfacial and bulk-water partitioning for gas-phase transport of organic contaminants in unsaturated porous media.” Environ. Sci. Technol.ESTHAG, 31(6), 1645–1649.
Chen, D. Q., Pyrak-Nolte, L. J., Griffin, J., and Giordano, N. J. (2007). “Measurement of interfacial area per volume for drainage and imbibition.” Water Resour. Res.WRERAQ, 43, (12), W12504.
Cheng, J.-T., Pyrak-Nolte, L. J., Nolte, D. D., and Giordano, N. J. (2004). “Linking pressure and saturation through interfacial areas in porous media.” Geophys. Res. Lett.GPRLAJ, 31(8), L08502.
Costanza-Robinson, M. S., and Brusseau, M. L. (2002). “Air-water interfacial areas in unsaturated soils: Evaluation of interfacial domains.” Water Resour. Res.WRERAQ, 38(10), 1195.
Culligan, K. A., Wildenschild, D., Christensen, B. S. B., Gray, W., Rivers, M. L., and Tompson, A. F. B. (2004). “Interfacial area measurements for unsaturated flow through a porous medium.” Water Resour. Res.WRERAQ, 40(12), W12413.
Dalla, E., Hilpert, M., and Miller, C. T. (2002). “Computation of the interfacial area for two-fluid porous medium systems.” J. Contam. Hydrol.JCOHE6, 56(1-2), 25–48.
Gvirtzman, H., and Roberts, P. V. (1991). “Pore scale spatial analysis of two immiscible fluids in porous media.” Water Resour. Res.WRERAQ, 27(6), 1165–1176.
Hassanizadeh, S. M., and Gray, W. G. (1993). “Thermodynamic basis of capillary pressure in porous media.” Water Resour. Res.WRERAQ, 29(10), 3389–3405.
Karkare, M. V., La, H. T., and Fort, T. (1996). “Determination of the air-water interfacial area in wet ‘unsaturated’ porous media.” LangmuirLANGD5, 12, 2041–4044.
Kim, H., Rao, P. S. C., and Annable, M. D. (1997). “Determination of effective air-water interfacial area in partially saturated porous media using surfactant adsorption.” Water Resour. Res.WRERAQ, 33(12), 2705–2711.
Kim, H., Rao., P. S. C., and Annable, M. D. (1999). “Gaseous tracer technique for estimating air-water interfacial areas and interface mobility.” Soil Sci. Soc. Am. J.SSSJD4, 63(6), 1554–1560.
Niemet, M. R., Rockhold, M. L., Weisbrod, N., and Selker, J. S. (2002). “Relationships between gas-liquid interfacial surface area, liquid saturation, and light transmission in variably saturated porous media.” Water Resour. Res.WRERAQ, 38(8), 1135.
Or, D., and Tuller, M. (1999). “Liquid retention and interfacial area in variably saturated porous media: Upscaling from single-pore to sample-scale model.” Water Resour. Res.WRERAQ, 35(12), 3591–3605.
Peng, S., and Brusseau, M. L. (2005). “Impact of soil texture on air-water interfacial areas in unsaturated sandy porous media.” Water Resour. Res.WRERAQ, 41(3), W03021.
Pyrak-Nolte, L. J., Nolte, D. D., Chen, D. Q., and Giordano, N. J. (2008). “Relating capillary pressure to interfacial areas.” Water Resour. Res.WRERAQ, 44, W06408.
Reeves, P. C., and Celia, M. A. (1996). “A functional relationship between capillary pressure, saturation, and interfacial area as revealed by a pore-scale network model.” Water Resour. Res.WRERAQ, 32(8), 2345–2358.
Schroth, M. H., Oostrom, M., Dobson, R., and Zeyer, J. (2008). “Thermodynamic model for fluid–fluid interfacial areas in porous media for arbitrary drainage–imbibition sequences.” Vadose Zone J.VZJAAB, 7(3), 966–971.
Warrick, A. W. (2003). Soil water dynamics, Oxford University Press, New York, 15–18.
van Genuchten, M. Th. (1980). “A closed-form equation for predicting the hydraulic conductivity of unsaturated soils.” Soil Sci. Soc. Am. J.SSSJD4, 44(5), 892–898.
van Genuchten, M. Th., Leij, F. J., and Yates, S. R. (1991). “The RETC code for quantifying the hydraulic functions of unsaturated soils.” U.S. Environmental Protection Agency Rep. 600/2-91/065. 〈http://www.ars.usda.gov/Services/docs.htm?docid=8952〉 (May 1, 2006).

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Information

Published In

Go to Journal of Hydrologic Engineering
Journal of Hydrologic Engineering
Volume 17Issue 7July 2012
Pages: 829 - 832

History

Received: Dec 22, 2010
Accepted: Sep 26, 2011
Published online: Jun 15, 2012
Published in print: Jul 1, 2012

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Authors

Affiliations

Sheng Peng
School of Environment, Beijing Normal Univ., Key Laboratory of Water and Sediment Sciences of Ministry of Education, Beijing 100875, China.
Mark L. Brusseau [email protected]
School of Earth and Environmental Sciences, 429 Shantz Building, #38, Univ. of Arizona, Tucson, AZ 85721 (corresponding author). E-mail: [email protected]

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