Technical Papers
Jan 15, 2013

Chemical Compatibility of Model Soil-Bentonite Backfill Containing Multiswellable Bentonite

This article has a reply.
VIEW THE REPLY
This article has a reply.
VIEW THE REPLY
Publication: Journal of Geotechnical and Geoenvironmental Engineering
Volume 139, Issue 2

Abstract

The objective of this study was to evaluate the chemical compatibility of model soil-bentonite backfills containing multiswellable bentonite (MSB) relative to that of similar backfills containing untreated sodium (Na) bentonite or a commercially available, contaminant-resistant bentonite (SW101). Flexible-wall tests were conducted on consolidated backfill specimens (effective stress=34.5 kPa) containing clean sand and 4.5–5.7% bentonite (by dry weight) using tap water and calcium chloride (CaCl2) solutions (10–1,000 mM) as the permeant liquids. Final values of hydraulic conductivity (k) and intrinsic permeability (K) to the CaCl2 solutions were determined after achieving both short-term termination criteria as defined by ASTM D5084 and long-term termination criteria for chemical equilibrium between the influent and effluent. Specimens containing MSB exhibited the smallest increases in k and K upon permeation with a given CaCl2 solution relative to specimens containing untreated Na bentonite or SW101. However, none of the specimens exhibited more than a fivefold increase in k or K, regardless of CaCl2 concentration or bentonite type. Final k values for specimens permeated with a given CaCl2 solution after permeation with tap water were similar to those for specimens of the same backfill permeated with only the CaCl2 solution, indicating that the order of permeation had no significant effect on k. Also, final k values for all specimens were within a factor of two of the k measured after achieving the ASTM D5084 termination criteria. Thus, use of only the ASTM D5084 criteria would have been sufficient to obtain reasonable estimates of long-term hydraulic conductivity for the specimens in this study.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The writers thank Hojun Corporation (Japan), Central Builders Supply (Lewisburg, PA), and Wyo-Ben (Billings, MT) for donating the materials used in this study. The writers thank Professor Takeshi Katsumi, Professor Charles Shackelford, and Richard LaFredo for their assistance with various aspects of this work.

References

Alther, G., Evans, J. C., Fang, H. Y., and Witmer, K. (1985). “Influence of inorganic permeants upon the permeability of bentonite.” Hydraulic barriers in soil and rock, ASTM STP874, A. I. Johnson, R. K. Frobel, N. J. Cavalli, and C. B. Petterson, eds., ASTM, West Conshohocken, PA, 64–73.
Amorim, C. L. G., et al. (2007). “Effect of clay-water interactions on clay swelling by X-ray diffraction.” Nucl. Instrum. Methods Phys. Res. A, 580(1), 768–770.
Ashmawy, A. K., El-Hajji, D., Sotelo, N., and Muhammad, N. (2002). “Hydraulic performance of untreated and polymer-treated bentonite in inorganic landfill leachates.” Clays Clay Miner., 50(5), 546–552.
ASTM. (2006a). “Standard test method for permeability of granular soils (constant head).” D2434, West Conshohocken, PA.
ASTM. (2006b). “Standard test method for swell index of clay mineral component of geosynthetic clay liners.” D5890, West Conshohocken, PA.
ASTM. (2009). “Standard test method for slump of hydraulic-cement concrete.” C143, West Conshohocken, PA.
ASTM. (2010). “Standard test methods for measurement of hydraulic conductivity of saturated porous materials using a flexible wall permeameter.” D5084, West Conshohocken, PA.
ASTM. (2011). “Standard test method for hydraulic conductivity compatibility testing of soils with aqueous solutions.” D7100, West Conshohocken, PA.
Cheeseman, C. R., Batchelder, M., and Sechioti, P. (1999). “Effect of cations on permeant flow through bentonite clays using a rapid filter press test.” Environ. Technol., 20(5), 499–506.
D'Appolonia, D. J. (1980). “Soil-bentonite slurry trench cutoffs.” J. Geotech. Engrg. Div., 106(4), 399–417.
D'Appolonia, D. J. (1982). “Slurry trench cutoff walls for hazardous waste isolation.” Geotechnics of Waste Management, Proc., 13th Annual Geotechnical Lecture Series, Philadelphia Section, Z. I. Husami, ed., ASCE, Reston, VA, 1–25.
Day, S. R. (1994). “The compatibility of slurry cutoff wall materials with contaminated groundwater.” Hydraulic conductivity and waste contaminant transport in soil, ASTM STP1142, D. E. Daniel and S. J. Trautwein, eds., ASTM, West Conshohocken, PA, 284–299.
Evans, J. C. (1993). “Vertical cutoff walls.” Geotechnical practice for waste disposal, D. E. Daniel, ed., Chapman and Hall, London, 430–454.
Evans, J. C., Adams, T. L., and Dudiak, K. A. (1995). “Enhanced slurry walls as treatment zones for inorganic contaminants.” Hazardous and Industrial Wastes, Proc., 27th Mid-Atlantic Industrial Waste Conf., Lehigh University, Technomic, Lancaster, PA, 712–721.
Jo, H. Y., Benson, C. H., Shackelford, C. D., Lee, J.-M., and Edil, T. B. (2005). “Long-term hydraulic conductivity of a geosynthetic clay liner permeated with inorganic salt solutions.” J. Geotech. Geoenviron. Eng., 131(4), 405–417.
Jo, H. Y., Katsumi, T., Benson, C. H., and Edil, T. B. (2001). “Hydraulic conductivity and swelling of nonprehydrated GCLs permeated with single-species salt solutions.” J. Geotech. Geoenviron. Eng., 127(7), 557–567.
Kajita, L. S. (1997). “An improved contaminant resistant clay for environmental clay liner applications.” Clays Clay Miner., 45(5), 609–617.
Katsumi, T., Ishimori, H., Onikata, M., and Fukagawa, R. (2008). “Long-term barrier performance of modified bentonite materials against sodium and calcium permeant solutions.” Geotex. Geomem., 26(1), 14–30.
Kolstad, D. C., Benson, C. H., and Edil, T. B. (2004). “Hydraulic conductivity and swell of nonprehydrated geosynthetic clay liners permeated with multispecies inorganic solutions.” J. Geotech. Geoenviron. Eng., 130(12), 1236–1249.
Lee, J.-M., and Shackelford, C. D. (2005a). “Impact of bentonite quality on hydraulic conductivity of geosynthetic clay liners.” J. Geotech. Geoenviron. Eng., 131(1), 64–77.
Lee, J.-M., and Shackelford, C. D. (2005b). “Concentration dependency of the prehydration effect for a geosynthetic clay liner.” Soil Found., 45(4), 27–41.
Malusis, M. A., Barben, E. J., and Evans, J. C. (2009). “Hydraulic conductivity and compressibility of a model soil-bentonite backfill amended with activated carbon.” J. Geotech. Geoenviron. Eng., 135(5), 664–672.
Malusis, M. A., McKeehan, M. D., and LaFredo, R. A. (2010). “Multiswellable bentonite for soil-bentonite vertical barriers.” Proc., 6th Int. Conf. Environment Geotechnology, McGraw Hill, New York, 764–769.
Mazzieri, F., Van Impe, P. O., and Di Emidio, G. (2005). “Chemico-osmotic behavior of modified, multiswellable bentonite.” Proc., 16th Int. Conf. Soil Mechanics Geotechnical Engineering, Millpress Science Publishers, Rotterdam, Netherlands, 2297–2300.
McKeehan, M. D. (2010). “Chemical compatibility of soil-bentonite cutoff wall backfills containing modified bentonites.” M.S. thesis, Bucknell Univ., Lewisburg, PA.
McKnight, J. T., and Owaidat, L. M. (2001). “Quality control and performance of a cutoff wall for containment of a DNAPL plume.” Proc., 2001 Int. Containment and Remediation Technology Conf. (CD-ROM), Florida State Univ., Tallahassee, FL.
Meleshyn, A., and Bunnenberg, C. (2005). “The gap between crystalline and osmotic swelling of Na-montmorillonite: A Monte Carlo study.” J. Chem. Phys., 122(034705), 1–6.
Onikata, M., Kondo, M., Hayashi, N., and Yamanaka, S. (1999). “Complex formation of cation-exchanged montmorillonites with propylene carbonate: Osmotic swelling in aqueous electrolyte solutions.” Clays Clay Miner., 47(5), 672–677.
Onikata, M., Kondo, M., and Kamon, M. (1996). “Development and characterization of a multiswellable bentonite.” Proc., 2nd Int. Congress Environment Geotechnology, M. Kamon, ed., A.A. Balkema, Rotterdam, Netherlands, 587–590.
Patton, P., Day, S., and Byle, M. (2007). “Compatibility evaluation of groundwater cutoff wall using salt-resistant bentonite and BFS/cement for deep-mix barrier wall.” Proc., Geo-Denver 2007, ASCE GSP 172 (CD-ROM), ASCE, Reston, VA.
Ryan, C. R. (1987). “Vertical barriers in soil for pollution containment.” Geotechnical Special Publication Geotechnical Practice for Waste Disposal ’87, R. Woods, ed., Vol. 13, ASCE, Reston, VA, 182–204.
Ryan, C. R., and Day, S. R. (2003). “Soil-bentonite slurry wall specifications.” Proc., Soil and Rock America 2003, 12th Pan-American Conf. on Soil Mechanics Geotechnical Engineering, P. J. Culligan, A. J. Whittle, and H. H. Einstein, eds., Verlag Gluckauf, Essen, Germany, 8 p.
Shackelford, C. D. (1994). “Waste-soil interactions that alter hydraulic conductivity.” Hydraulic conductivity and waste contaminant transport in soil, ASTM STP1142, D. E. Daniel and S. J. Trautwein, eds., ASTM, West Conshohocken, PA, 111–168.
Shackelford, C. D., Benson, C. H., Katsumi, T., Edil, T. B., and Lin, L. (2000). “Evaluating the hydraulic conductivity of GCLs permeated with non-standard liquids.” Geotex. Geomem., 18(2–4), 133–161.
Shackelford, C. D., Malusis, M. A., Majeski, M. J., and Stern, R. T. (1999). “Electrical conductivity breakthrough curves.” J. Geotech. Geoenviron. Eng., 125(4), 260–270.
Shackelford, C. D., and Redmond, P. (1995). “Solute breakthrough curves for processed kaolin at low flow rates.” J. Geotech. Eng., 121(1), 17–32.
Shackelford, C. D., Sevick, G. W., and Eykholt, G. R. (2010). “Hydraulic conductivity of geosynthetic clay liners to tailings impoundment solutions.” Geotex. Geomem., 28(2), 149–162.
Stern, R. T., and Shackelford, C. D. (1998). “Permeability of sand-processed clay mixtures with calcium chloride solutions.” J. Geotech. Geoenviron. Eng., 124(3), 231–241.
Wahab, A., and Mahiuddin, S. (2001). “Isentropic compressibility and viscosity of aqueous and methanolic calcium chloride solutions.” J. Chem. Eng. Data, 46(6), 1457–1463.

Information & Authors

Information

Published In

Go to Journal of Geotechnical and Geoenvironmental Engineering
Journal of Geotechnical and Geoenvironmental Engineering
Volume 139Issue 2February 2013
Pages: 189 - 198

History

Received: Aug 17, 2011
Accepted: Mar 12, 2012
Published online: Jan 15, 2013
Published in print: Feb 1, 2013

Permissions

Request permissions for this article.

Authors

Affiliations

Michael A. Malusis, Ph.D., A.M.ASCE [email protected]
P.E.
Associate Professor, Dept. of Civil and Environmental Engineering, Bucknell Univ., Lewisburg, PA 17837 (corresponding author). E-mail: [email protected]
Matthew D. McKeehan
2nd Lt., U.S. Army Corps of Engineers, Fort Carson, CO 80913; formerly, Graduate Assistant, Dept. of Civil and Environmental Engineering, Bucknell Univ., Lewisburg, PA 17837.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share