Technical Papers
Sep 21, 2021

Microexplosion Kinetics of Alcohol-Based Emulsified Biodiesel Droplets Evaporated in High Temperature

Publication: Journal of Energy Engineering
Volume 147, Issue 6

Abstract

An alcohol-based emulsified fuel is formed by mixing ethanol, biodiesel, and water in different proportions. This fuel can be used in internal combustion engines to reduce fossil fuel consumption. In high-temperature environments, the microexplosion phenomenon of alcohol-based emulsified fuel can be observed directly. In this study, a high-temperature fuel evaporation test device was set up. The microexplosion process of alcohol-based emulsified fuel with varying water content (0%, 1%, 2%, and 3%) in different temperatures (773 K, 873 K, and 973 K) was studied by high-speed photography, and the data were analyzed by morphological treatment. To evaluate the microexplosion characteristics of alcohol-based emulsified fuel, some kinetic parameters—such as microexplosion delay, mean interfacial tension, number of bubbles, and mean microexplosion intensity—were proposed. The results show that the kinetic parameters put forward in this paper are reasonable for evaluating the microexplosion process. If the water content in the alcohol-based emulsified fuel is kept the same, the microexplosion delay decreases, while the mean interfacial tension increases with increasing temperature. If the evaporation temperature is kept the same, the microexplosion delay and the number of bubbles increase with the content of water increasing. Within the range of tested content of water and temperature, the mean microexplosion intensity of emulsion fuel is 0.05366 N·(m·s)1 when the temperature is 973 K and the content of water is 3%, which is the largest.

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Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

We acknowledge funding from the National Natural Science Foundation of China (under Grant No. 51776089), Project of Natural Science Foundation of Jiangsu Province (BK20200910), Natural Science Foundation of Jiangsu Higher Education Institutions of China (20KJB470013, 20KJB470015), China Postdoctoral Science Foundation Project (2019M651732), and Open Project of State Key Laboratory of Internal Combustion Engine Combustion, Tianjin University (K2020-12). Authors Jialong Zhu and Ruina Li contributed equally to this work.

References

Ahmed Melo-Espinosa, E., J. Bellettre, D. Tarlet, A. Montillet, R. Piloto-Rodriguez, and S. Verhelst. 2018. “Experimental investigation of emulsified fuels produced with a micro-channel emulsifier: Puffing and micro-explosion analyses.” Fuel 219 (May): 320–330. https://doi.org/10.1016/j.fuel.2018.01.103.
Andersen, H. C. 1980. “Molecular dynamics simulations at constant pressure and/or temperature.” J. Chem. Phys. 72 (4): 2384–2393. https://doi.org/10.1063/1.439486.
Avedisian, C. T., and I. Glassman. 1981. “Superheating and boiling of water in hydrocarbons at high pressures.” Int. J. Heat Mass Transfer 24 (4): 695–706. https://doi.org/10.1016/0017-9310(81)90013-2.
Avulapati, M. M., T. Megaritis, J. Xia, and L. J. F. Ganippa. 2019. “Experimental understanding on the dynamics of micro-explosion and puffing in ternary emulsion droplets.” Fuel 239 (Mar): 1284–1292. https://doi.org/10.1016/j.fuel.2018.11.112.
Bartknecht, W. 2010. Explosionen—Ablauf und schutzmanahmen. New York: Springer.
Berendsen, H. J. C., J. P. M. Postma, W. F. V. Gunsteren, A. Dinola, and J. R. Haak. 1984. “Molecular dynamics with coupling to an external bath.” J. Chem. Phys. 81 (8): 3684–3690. https://doi.org/10.1063/1.448118.
Chao, C. Y., H. W. Tsai, K. L. Pan, C. W. J. Hsieh, and C. Flame. 2019. “On the microexplosion mechanisms of burning droplets blended with biodiesel and alcohol.” Combust. Flame 205 (Jul): 397–406. https://doi.org/10.1016/j.combustflame.2019.04.017.
Ewald, P. P. 1921. “Die Berechnung optischer und elektrostatischer Gitterpotentiale.” Ann. Phys. 369 (3): 253–287. https://doi.org/10.1002/andp.19213690304.
Geng, P., E. Cao, Q. Tan, and L. Wei. 2017. “Effects of alternative fuels on the combustion characteristics and emission products from diesel engines: A review.” Renewable Sustainable Energy Rev. 71 (May): 523–534. https://doi.org/10.1016/j.rser.2016.12.080.
Heywood, J. B. 1988. Internal combustion engine fundamentals. New York: McGraw-Hill.
Hou, S. S., F. M. Rizal, T. H. Lin, T. Y. Yang, and H. P. Wan. 2013. “Microexplosion and ignition of droplets of fuel oil/bio-oil (derived from lauan wood) blends.” Fuel 113 (Nov): 31–42. https://doi.org/10.1016/j.fuel.2013.05.066.
Hoxie, A., R. Schoo, and J. Braden. 2014. “Microexplosive combustion behavior of blended soybean oil and butanol droplets.” Fuel 120 (Mar): 22–29. https://doi.org/10.1016/j.fuel.2013.11.036.
Huang, X., J. Wang, Y. Wang, X. Qiao, D. Ju, C. Sun, and Q. Zhang. 2020. “Experimental study on evaporation and micro-explosion characteristics of biodiesel/n-propanol blended droplet.” Energy 205 (Aug): 118031. https://doi.org/10.1016/j.energy.2020.118031.
Jorgensen, W. L., R. C. Binning Jr., and B. Bigot. 1981. “ChemInform Abstract: Structures and properties of organic liquids: N-butane and 1,2-dichloroethane and their conformation equilibriums.” Chem. Inform. 12 (43): 178–181. https://doi.org/10.1002/chin.198143057.
Luo, M., O. A. Mazyar, Q. Zhu, M. W. Vaughn, W. L. Hase, and L. L. Dai. 2006. “Molecular dynamics simulation of nanoparticle self-assembly at a liquid-liquid interface.” Langmuir 22 (14): 6385–6390. https://doi.org/10.1021/la0607196.
Meng, K., L. Bao, Y. Shi, K. Han, Q. Lin, and C. Wang. 2020a. “Experimental investigation on ignition, combustion and micro-explosion of RP-3, biodiesel and ethanol blended droplets.” Appl. Therm. Eng. 178 (Sep): 115649. https://doi.org/10.1016/j.applthermaleng.2020.115649.
Meng, K., W. Fu, F. Li, Y. Lei, Q. Lin, and G. Wang. 2020b. “Comparison of ignition, injection and micro-explosion characteristics of RP-3/ethanol and biodiesel/ethanol mixed drops.” J. Energy Inst. 93 (1): 152–164. https://doi.org/10.1016/j.joei.2019.04.002.
Pandey, B., S. Kumar, and S. S. Ragit. 2017. “Production, characterization and performance of biodiesel blends of sesame oil and bitter almond oil as an alternative fuel in CI engine.” Ph.D. dissertation, Dept. of Mechanical Engineering, Thapar Institute of Engineering and Technology.
Sazhin, S. S., O. Rybdylova, C. Crua, M. Heikal, M. A. Ismael, Z. Nissar, and A. R. B. Aziz. 2018. “A simple model for puffing/micro-explosions in water-fuel emulsion droplets.” Int. J. Heat Mass Transfer 131 (Mar): 815–821. https://doi.org/10.1016/j.ijheatmasstransfer.
Shahir, S. A., H. H. Masjuki, M. A. Kalam, A. Imran, I. M. R. Fattah, and A. Sanjid. 2014. “Feasibility of diesel–biodiesel–ethanol/bioethanol blend as existing CI engine fuel: An assessment of properties, material compatibility, safety and combustion.” J. Renewable Sustainable Energy Rev. 32 (Apr): 379–395. https://doi.org/10.1016/j.rser.2014.01.029.
Shao, T., L. Bai, B. Yan, Y. Jin, and Y. Cheng. 2017. “Modeling the solidification of O/W-emulsion droplet in solvent evaporation technique.” Chem. Eng. Res. Des. Trans. Inst. Chem. Eng. Part A. 122 (Jun): 233–242. https://doi.org/10.1016/j.cherd.2017.04.022.
Shen, S., K. Sun, Z. Che, T. Wang, M. Jia, and J. Cai. 2019. “An experimental investigation of the heating behaviors of droplets of emulsified fuels at high temperature.” Appl. Therm. Eng. 161 (Oct): 114059. https://doi.org/10.1016/j.applthermaleng.2019.114059.
Sun, H. J. 1998. “COMPASS: An ab initio force-field optimized for condensed-phase applications—Overview with details on alkane and benzene compounds.” J. Phys. Chem. B 102 (38): 7338–7364. https://doi.org/10.1021/jp980939v.
Tarai, M., K. Kumar, and A. K. Mishra. 2016. “Study on the miscibility behavior of diesel–n-butanol–ethanol blends and fluorimetric estimation of diesel fraction.” Energy Fuels 30 (2): 1096–1102. https://doi.org/10.1021/acs.energyfuels.5b02619.
Tarlet, D., J. Bellettre, M. Tazerout, and C. Rahmouni. 2009. “Prediction of micro-explosion delay of emulsified fuel droplets.” Int. J. Therm. Sci. 48 (2): 449–460. https://doi.org/10.1016/j.ijthermalsci.2008.05.005.
Tóth, P., C. Brackmann, Y. Ögren, M. N. Mannazhi, J. Simonsson, A. Sepman, P.-E. Bengtsson, and H. Wiinikka. 2019. “Experimental and numerical study of biomass fast pyrolysis oil spray combustion: Advanced laser diagnostics and emission spectrometry.” Fuel 252 (Sep): 125–134. https://doi.org/10.1016/j.fuel.2019.04.043.
Verwey, C., and M. Birouk. 2020. “Experimental investigation of the evaporation of suspended mono-sized heptane droplets in turbulence intensities approaching unity.” Combust. Flame 219 (Sep): 425–436. https://doi.org/10.1016/j.combustflame.2020.06.007.
Vigneswaran, R., D. Balasubramanian, and B. D. S. Sastha. 2021. “Performance, emission and combustion characteristics of unmodified diesel engine with titanium dioxide (TiO2) nano particle along with water-in-diesel emulsion fuel.” Fuel 285 (Feb): 119115. https://doi.org/10.1016/j.fuel.2020.119115.
Wang, J., X. Qiao, D. Ju, L. Wang, and C. Sun. 2019. “Experimental study on the evaporation and micro-explosion characteristics of nanofuel droplet at dilute concentrations.” Energy 183 (Sep): 149–159. https://doi.org/10.1016/j.energy.2019.06.136.
Wang, Z., S. Shi, H. Sheng, J. Tang, and J. Y. Chen. 2018. “Effects of water content on evaporation and combustion characteristics of water emulsified diesel spray.” Appl. Energy 226 (Sep): 397–407. https://doi.org/10.1016/j.apenergy.2018.06.023.
Watanabe, H., Y. Suzuki, T. Harada, H. Aoki, and T. Miura. 2011. “Development of a mathematical model for predicting water vapor mass generated in micro-explosion.” Energy 36 (7): 4089–4096. https://doi.org/10.1016/j.energy.2011.04.038.
Won, J., S. W. Baek, and H. Kim. 2018. “Autoignition and combustion behavior of emulsion droplet under elevated temperature and pressure conditions.” Energy 163 (Nov): 800–810. https://doi.org/10.1016/j.energy.2018.08.185.
Yesilyurt, M. K. 2020. “A detailed investigation on the performance, combustion, and exhaust emission characteristics of a diesel engine running on the blend of diesel fuel, biodiesel and 1-heptanol (C7 alcohol) as a next-generation higher alcohol.” Fuel 275 (Sep): 117893 https://doi.org/10.1016/j.fuel.2020.117893.
Yi, P., T. Li, Y. Fu, and S. Xie. 2021. “Transcritical evaporation and micro-explosion of ethanol-diesel droplets under diesel engine-like conditions.” Fuel 284 (Jan): 118892. https://doi.org/10.1016/j.fuel.2020.118892.
Yilmaz, E., H. Solmaz, S. Polat, A. Uyumaz, F. Şahin, and M. S. Salman. 2014. “Preparation of diesel emulsion using auxiliary emulsifier mono ethylene glycol and utilization in a turbocharged diesel engine.” Energy Convers. Manage. 86 (Oct): 973–980. https://doi.org/10.1016/j.enconman.2014.06.033.
Zhang, X., T. Li, B. Wang, and Y. Wei. 2018a. “Superheat limit and micro-explosion in droplets of hydrous ethanol-diesel emulsions at atmospheric pressure and diesel-like conditions.” Energy 154 (Jul): 535–543. https://doi.org/10.1016/j.energy.2018.04.176.
Zhang, Y., Y. Huang, R. Huang, S. Huang, Y. Ma, S. Xu, and Z. Wang. 2018b. “A new puffing model for a droplet of butanol-hexadecane blends.” Appl. Therm. Eng. 133 (Mar): 633–644. https://doi.org/10.1016/j.applthermaleng.2018.01.096.

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Go to Journal of Energy Engineering
Journal of Energy Engineering
Volume 147Issue 6December 2021

History

Received: Apr 15, 2021
Accepted: Jul 1, 2021
Published online: Sep 21, 2021
Published in print: Dec 1, 2021
Discussion open until: Feb 21, 2022

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Jialong Zhu [email protected]
Master, School of Automotive and Traffic Engineering, Jiangsu Univ., Xuefu Rd. 301, Zhenjiang 212013, China. Email: [email protected]
Associate Professor, School of Automotive and Traffic Engineering, Jiangsu Univ., Xuefu Rd. 301, Zhenjiang 212013, China (corresponding author). Email: [email protected]
Professor, School of Automotive and Traffic Engineering, Jiangsu Univ., Xuefu Rd. 301, Zhenjiang 212013, China. Email: [email protected]
Lecturer, School of Automotive and Traffic Engineering, Jiangsu Univ., Xuefu Rd. 301, Zhenjiang 212013, China; Researcher, Tsinghua Univ. Suzhou Automobile Research Institute, Lianyang Rd. 129, Suzhou 215200, China. Email: [email protected]

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Cited by

  • Effect of ambient temperature and water content on emulsified heavy fuel oil droplets evaporation: Evaporation enhancement by droplet puffing and micro-explosion, Fuel, 10.1016/j.fuel.2022.126614, 334, (126614), (2023).
  • Experimental study on nucleation and micro-explosion characteristics of emulsified heavy fuel oil droplets at elevated temperatures during evaporation, Applied Thermal Engineering, 10.1016/j.applthermaleng.2023.120114, 224, (120114), (2023).
  • An Investigation of Emulsified Heavy Fuel Oil with High Water Content Applied to a High-Speed Diesel Engine, Journal of Energy Engineering, 10.1061/(ASCE)EY.1943-7897.0000843, 148, 4, (2022).
  • Behavior of child droplets during micro-explosion and puffing of suspension fuel droplets: The impact of the component mixing sequence, International Journal of Heat and Mass Transfer, 10.1016/j.ijheatmasstransfer.2022.123371, 197, (123371), (2022).

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