Technical Papers
Aug 4, 2022

Research on the Ammonia Removal from Synthetic Wastewater by Electrodialysis and Electrodeionization

Publication: Journal of Environmental Engineering
Volume 148, Issue 10

Abstract

In this work, the technical capabilities of lab-scale electrodialysis (ED) and the electrodeionization (EDI) processes on removing ammonia from synthetic wastewater were investigated. The overall performance of ED and EDI process in the removal of ammonia from high ammonia concentration synthetic wastewater was assessed by applied electric potential, feed concentration, and energy consumption. Under the conditions of working electric potential, ED showed that ammonia concentration could be reduced from 1,000 to 309  mg/L with a best removal efficiency of 69.1%, EDI showed that the ammonia concentration could be reduced from 1,000 to 120.9  mg/L with a best removal efficiency of 87.91%, the energy consumption of ED and EDI were in the range of 1.712.96  Wh/L and 6.2149.2  Wh/L, respectively. Under the conditions of feed concentration, ED and EDI obtained a best removal efficiency of 57.93% and 98.5%, respectively, the energy consumption was in the range of 9.3653.55  Wh/L and 62.7218.1  Wh/L, respectively, excessive applied electric potential and concentration will lower current efficiency and increase energy consumption. The ammonia removal efficiency of EDI was found to be higher than ED, but the current efficiency of EDI was lower than ED, and the stack current of EDI increased quickly under constant voltage when the feed concentration was over 1,000  mg/L. The results showed that EDI was suitable for low concentration solution treatment, whereas ED was suitable for high concentration solution treatment. As a novel technology of groundwater contamination treatment, the process was proved to be feasible and provided foundation for further research.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data included in this study are available upon request by contact with the corresponding author.

References

Adam, M. R., M. H. Othman, M. H. Puteh, A. F. Ismail, A. Mustafa, M. A. Rahman, and J. Jaafar. 2020. “Impact of sintering temperature and pH of feed solution on adsorptive removal of ammonia from wastewater using clinoptilolite based hollow fiber ceramic membrane.” J. Water Process Eng. 33 (Feb): 101063. https://doi.org/10.1016/j.jwpe.2019.101063.
Adam, M. R., M. H. Othman, R. A. Samah, M. H. Puteh, A. F. Ismail, A. Mustafa, M. A. Rahman, and J. Jaafar. 2019. “Current trends and future prospects of ammonia removal in wastewater: A comprehensive review on adsorptive membrane development.” Sep. Purif. Technol. 213 (Apr): 114–132. https://doi.org/10.1016/j.seppur.2018.12.030.
Ali, I., O. M. Alharbi, Z. A. Alothman, and A. Y. Badjah. 2018. “Kinetics, thermodynamics, and modeling of amido black dye photodegradation in water using Co/TiO2 nanoparticles.” Photochem. Photobiol. 94 (5): 935–941. https://doi.org/10.1111/php.12937.
Ali, I., and C. Jain. 1998. “Groundwater contamination and health hazards by some of the most commonly used pesticides.” Curr. Sci. 75 (10): 1011–1014.
Ali, M. B. S., A. Mnif, B. Hamrouni, and M. Dhahbi. 2010. “Denitrification of brackish water by electrodialysis: Effect of process parameters and water characteristics.” Surf. Eng. Appl. Electrochem. 46 (3): 253–262. https://doi.org/10.3103/S1068375510030117.
Almutairi, A., and L. R. Weatherley. 2015. “Intensification of ammonia removal from waste water in biologically active zeolitic ion exchange columns.” J. Environ. Manage. 160 (Sep): 128–138. https://doi.org/10.1016/j.jenvman.2015.05.033.
Alvarado, L., and A. Chen. 2014. “Electrodeionization: Principles, strategies and applications.” Electrochim. Acta 132 (Jun): 583–597. https://doi.org/10.1016/j.electacta.2014.03.165.
Arar, Ö., Ü. Yüksel, N. Kabay, and M. Yüksel. 2014. “Various applications of electrodeionization (EDI) method for water treatment—A short review.” Desalination 342 (Jun): 16–22. https://doi.org/10.1016/j.desal.2014.01.028.
Basheer, A. A. 2018a. “Chemical chiral pollution: Impact on the society and science and need of the regulations in the 21st century.” Chirality 30 (4): 402–406. https://doi.org/10.1002/chir.22808.
Basheer, A. A. 2018b. “New generation nano-adsorbents for the removal of emerging contaminants in water.” J. Mol. Liq. 261 (Jun): 583–593. https://doi.org/10.1016/j.molliq.2018.04.021.
Basheer, A. A., and I. Ali. 2018. “Stereoselective uptake and degradation of (±)-o, p-DDD pesticide stereomers in water-sediment system.” Chirality 30 (9): 1088–1095. https://doi.org/10.1002/chir.22989.
Belkada, F. D., O. Kitous, N. Drouiche, S. Aoudj, O. Bouchelaghem, N. Abdi, H. Grib, and N. Mameri. 2018. “Electrodialysis for fluoride and nitrate removal from synthesized photovoltaic industry wastewater.” Sep. Purif. Technol. 204 (Oct): 108–115. https://doi.org/10.1016/j.seppur.2018.04.068.
Bernier, J., V. Rocher, S. Guerin, and P. Lessard. 2014. “Modelling the nitrification in a full-scale tertiary biological aerated filter unit.” Bioprocess. Biosyst. Eng. 37 (2): 289–300. https://doi.org/10.1007/s00449-013-0996-1.
Blackburn, J. W. 1999. “Electrodialysis applications for pollution prevention in the chemical processing industry.” J. Air Waste Manage. Assoc. 49 (8): 934–942. https://doi.org/10.1080/10473289.1999.10463870.
Canter, L. 1997. Nitrates in groundwater. Boca Raton, FL: Lewis publishers.
Chen, G. 2004. “Electrochemical technologies in wastewater treatment.” Sep. Purif. Technol. 38 (1): 11–41. https://doi.org/10.1016/j.seppur.2003.10.006.
Drouiche, N., F. Djouadi-Belkada, T. Ouslimane, A. Kefaifi, J. Fathi, and E. Ahmetovic. 2013. “Photovoltaic solar cells industry wastewater treatment.” Desalin. Water Treat. 51 (31–33): 5965–5973. https://doi.org/10.1080/19443994.2012.763217.
Ertürk, E., E. Carus, and A. Görgülü. 2019. “Pure water production technology by electrodeionization method in dark factories scope.” Procedia Comput. Sci. 158 (Jan): 222–226. https://doi.org/10.1016/j.procs.2019.09.045.
Ervan, Y., and I. G. Wenten. 2002. “Study on the influence of applied voltage and feed concentration on the performance of electrodeionization.” Songklanakarin J. Sci. Technol. 24: 955–963.
Fu, L., X. Gao, Y. Yang, F. Aiyong, H. Hao, and C. Gao. 2014. “Preparation of succinic acid using bipolar membrane electrodialysis.” Sep. Purif. Technol. 127 (Apr): 212–218. https://doi.org/10.1016/j.seppur.2014.02.028.
Grabowski, A., G. Zhang, H. Strathmann, and G. Eigenberger. 2006. “The production of high purity water by continuous electrodeionization with bipolar membranes: Influence of the anion-exchange membrane permselectivity.” J. Membr. Sci. 281 (1–2): 297–306. https://doi.org/10.1016/j.memsci.2006.03.044.
Greiter, M., S. Novalin, M. Wendland, K. D. Kulbe, and J. Fischer. 2002. “Desalination of whey by electrodialysis and ion exchange resins: Analysis of both processes with regard to sustainability by calculating their cumulative energy demand.” J. Membr. Sci. 210 (1): 91–102. https://doi.org/10.1016/S0376-7388(02)00378-2.
Han, L., Y. Liu, and J. W. Chew. 2018. “Boron transfer during desalination by electrodialysis.” J. Membr. Sci. 547 (Feb): 64–72. https://doi.org/10.1016/j.memsci.2017.10.036.
Janssen, L., and L. Koene. 2002. “The role of electrochemistry and electrochemical technology in environmental protection.” Chem. Eng. J. 85 (2–3): 137–146. https://doi.org/10.1016/S1385-8947(01)00218-2.
Kameche, M., F. Xu, C. Innocent, and G. Pourcelly. 2003. “Electrodialysis in water-ethanol solutions: Application to the acidification of organic salts.” Desalination 154 (1): 9–15. https://doi.org/10.1016/S0011-9164(03)00203-0.
Krol, J., M. Wessling, and H. Strathmann. 1999. “Concentration polarization with monopolar ion exchange membranes: Current–voltage curves and water dissociation.” J. Membr. Sci. 162 (1–2): 145–154. https://doi.org/10.1016/S0376-7388(99)00133-7.
Laktionov, E., E. Dejean, J. Sandeaux, R. Sandeaux, C. Gavach, and G. Pourcelly. 1999. “Production of high resistivity water by electrodialysis. Influence of ion-exchange textiles as conducting spacers.” Sep. Sci. Technol. 34 (1): 69–84. https://doi.org/10.1081/SS-100100637.
Li, C., D. L. Ramasamy, M. Sillanpää, and E. Repo. 2021. “Separation and concentration of rare earth elements from wastewater using electrodialysis technology.” Sep. Purif. Technol. 254 (Jan): 117442. https://doi.org/10.1016/j.seppur.2020.117442.
Li, Y., S. Shi, H. Cao, X. Wu, Z. Zhao, and L. Wang. 2016. “Bipolar membrane electrodialysis for generation of hydrochloric acid and ammonia from simulated ammonium chloride wastewater.” Water Res. 89 (Feb): 201–209. https://doi.org/10.1016/j.watres.2015.11.038.
Lopez, A. M., and J. A. Hestekin. 2015. “Improved organic acid purification through wafer enhanced electrodeionization utilizing ionic liquids.” J. Membr. Sci. 493 (Nov): 200–205. https://doi.org/10.1016/j.memsci.2015.06.008.
Lu, J., Y. X. Wang, and J. Zhu. 2010. “Numerical simulation of the electrodeionization (EDI) process accounting for water dissociation.” Electrochim. Acta 55 (8): 2673–2686. https://doi.org/10.1016/j.electacta.2009.11.107.
Lüdtke, K., K. V. Peinemann, V. Kasche, and R. D. Behling. 1998. “Nitrate removal of drinking water by means of catalytically active membranes.” J. Membr. Sci. 151 (1): 3–11. https://doi.org/10.1016/S0376-7388(98)00227-0.
Meyer, N., W. J. Parker, P. J. Van Geel, and M. Adiga. 2005. “Development of an electrodeionization process for removal of nitrate from drinking water part 1: Single-species testing.” Desalination 175 (2): 153–165. https://doi.org/10.1016/j.desal.2004.07.051.
Moradihamedani, P. 2021. “Recent developments in membrane technology for the elimination of ammonia from wastewater: A review.” Polym. Bull. 78 (9): 5399–5425. https://doi.org/10.1007/s00289-020-03386-y.
Palakkal, V. M., L. Valentino, Q. Lei, S. Kole, Y. J. Lin, and C. G. Arges. 2020. “Advancing electrodeionization with conductive ionomer binders that immobilize ion-exchange resin particles into porous wafer substrates.” npj Clean Water 3 (1): 1–10. https://doi.org/10.1038/s41545-020-0052-z.
Rathi, B. S., and P. S. Kumar. 2020. “Electrodeionization theory, mechanism and environmental applications. A review.” Environ. Chem. Lett. 18 (4): 1209–1227. https://doi.org/10.1007/s10311-020-01006-9.
Rottiers, T., K. Ghyselbrecht, B. Meesschaert, B. Van der Bruggen, and L. Pinoy. 2014. “Influence of the type of anion membrane on solvent flux and back diffusion in electrodialysis of concentrated NaCl solutions.” Chem. Eng. Sci. 113 (Jul): 95–100. https://doi.org/10.1016/j.ces.2014.04.008.
Song, J.-H., K. H. Yeon, and S. H. Moon. 2007. “Effect of current density on ionic transport and water dissociation phenomena in a continuous electrodeionization (CEDI).” J. Membr. Sci. 291 (1–2): 165–171. https://doi.org/10.1016/j.memsci.2007.01.004.
Strathmann, H. 2010. “Electrodialysis, a mature technology with a multitude of new applications.” Desalination 264 (3): 268–288. https://doi.org/10.1016/j.desal.2010.04.069.
Temkin, A., S. Evans, T. Manidis, C. Campbell, and O. V. Naidenko. 2019. “Exposure-based assessment and economic valuation of adverse birth outcomes and cancer risk due to nitrate in United States drinking water.” Environ. Res. 176 (Sep): 108442. https://doi.org/10.1016/j.envres.2019.04.009.
Ulusoy Erol, H. B., C. N. Hestekin, and J. A. Hestekin. 2021. “Effects of resin chemistries on the selective removal of industrially relevant metal ions using wafer-enhanced electrodeionization.” Membranes 11 (1): 45. https://doi.org/10.3390/membranes11010045.
Wang, J., S. Wang, and M. Jin. 2000. “A study of the electrodeionization process—high-purity water production with a RO/EDI system.” Desalination 132 (1–3): 349–352. https://doi.org/10.1016/S0011-9164(00)00171-5.
Ward, M. H., R. R. Jones, J. D. Brender, T. M. De Kok, P. J. Weyer, B. T. Nolan, C. M. Villanueva, and S. G. Van Breda. 2018. “Drinking water nitrate and human health: An updated review.” Int. J. Environ. Res. Public Health 15 (7): 1557. https://doi.org/10.3390/ijerph15071557.
Wenten, I. G., and F. Arfianto. 2013. “Bench scale electrodeionization for high pressure boiler feed water.” Desalination 314 (Apr): 109–114. https://doi.org/10.1016/j.desal.2013.01.008.
Xu, F., C. Innocent, and G. Pourcelly. 2005. “Electrodialysis with ion exchange membranes in organic media.” Sep. Purif. Technol. 43 (1): 17–24. https://doi.org/10.1016/j.seppur.2004.09.009.
Xu, L., F. Dong, H. Zhuang, W. He, M. Ni, S. P. Feng, and P. H. Lee. 2017. “Energy upcycle in anaerobic treatment: Ammonium, methane, and carbon dioxide reformation through a hybrid electrodeionization–solid oxide fuel cell system.” Energy Convers. Manage. 140 (May): 157–166. https://doi.org/10.1016/j.enconman.2017.02.072.
Xu, T., and C. Huang. 2008. “Electrodialysis-based separation technologies: A critical review.” AlChE J. 54 (12): 3147–3159. https://doi.org/10.1002/aic.11643.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 148Issue 10October 2022

History

Received: Mar 30, 2022
Accepted: Jun 9, 2022
Published online: Aug 4, 2022
Published in print: Oct 1, 2022
Discussion open until: Jan 4, 2023

Permissions

Request permissions for this article.

ASCE Technical Topics:

Authors

Affiliations

Dexiang Liao
Professor, College of Ocean Science and Engineering, Shanghai Maritime Univ., Shanghai 200135, China.
Yechen Pang, Ph.D. [email protected]
College of Ocean Science and Engineering, Shanghai Maritime Univ., Shanghai 200135, China (corresponding author). Email: [email protected]
YanXia Bo, Ph.D.
College of Ocean Science and Engineering, Shanghai Maritime Univ., Shanghai 200135, China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

  • Electro-deionization (EDI) technology for enhanced water treatment and desalination: A review, Desalination, 10.1016/j.desal.2022.116254, 548, (116254), (2023).

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share